In this paper, the optimal policy is considered when the buyer faces two supply sources: one is the contract supplier from which the buyer orders over a specific contract period (say, a year) at a pre-agreed price,...In this paper, the optimal policy is considered when the buyer faces two supply sources: one is the contract supplier from which the buyer orders over a specific contract period (say, a year) at a pre-agreed price, and the other is the spot market. However, when ordering from the contract supplier, the buyer must fulfill a pre-determined total order quantity, or the so-called definite total order quantity commitment, over the whole contract period. In other words, the commitment secures the buyer a fixed price but obliges him/her a total order quantity over the contract period. Although the spot market gives the buyer more flexibility in terms of order quantities, its prices are volatile. Such a combination of contract and spot procurements is often observed in practice. Within the contract period, there are multiple sub-periods, during each of which the buyer reviews the inventory, issues an individual order, and uses the on-hand inventory to meet the random demand. Thus, in each (ordering) period, the buyer will weigh between the current known spot price (by procuring from the spot market) and a lower future price (by waiting while consuming the remaining commitment). An optimal dual ordering policy is characterized for each period, depending on the on-hand inventory level, the spot price, and the remaining commitment quantity. The optimal policy in each period is also shown to be independent of the contract price. Through a numerical study, the inventory cost is demonstrated to be (1) insensitive to the contract price when the total commitment quantity is lower than the total expected demand over the contract period and (2) non-increasing in the variability of spot prices.展开更多
Message total ordering is a critical part in active replication in order to maintain consistency among members in a fault tolerant group. The paper proposes a non-blocking message total ordering protocol (NBTOP) for...Message total ordering is a critical part in active replication in order to maintain consistency among members in a fault tolerant group. The paper proposes a non-blocking message total ordering protocol (NBTOP) for distributed systems. Non-blocking property refers to that the members in a fault tolerant group keep on running independently without waiting for installing the same group view when a fault tolerant group evolves even when decision messages collide. NBTOP takes advantage of token ring as its logical control way. Members adopt re-requesting mechanism (RR) to obtain their lost decisions. Forward acknowledgement mechanism (FA) is put forth to solve decision collisions. The paper further proves that NBTOP satisfies the properties of total order, agreement, and termination. NBTOP is implemented, and its performance test is done. Comparing with the performance of Totem, the results show that NBTOP has a better total ordering delay. It manifests that non-blocking property helps to improve protocol efficiency.展开更多
Certain perovskite-type oxynitrides have bandgaps suitable for renewable hydrogen production via photocatalytic and photoelectrochemical water splitting under visible light.Understanding the ordering of oxide and nitr...Certain perovskite-type oxynitrides have bandgaps suitable for renewable hydrogen production via photocatalytic and photoelectrochemical water splitting under visible light.Understanding the ordering of oxide and nitride anions in these materials is important because this ordering affects their semiconductor properties.However, the numerous possible orderings complicate systematic analyses based on density functional theory(DFT) calculations using defined elemental arrangements.This work shows that anion ordering in large-scale supercells within perovskite-type oxynitrides can be rapidly predicted based on machine learning, using BaNbO2N(capable of oxidizing water under irradiation up to 740 nm) as an example.Machine learning allows the calculation of the total energy of BaNbO2N directly from randomly selected initial atomic placements without costly structural optimization, thus reducing the computational cost by more than 99.99%.Combined with the Metropolis Monte Carlo method, machine learning permits exploration of the stable anion orderings of large supercells without costly DFT calculations.This work therefore demonstrates a means of predicting the properties of functional materials having complex compositions based on the most realistic elemental arrangements in conjunction with reasonable computational loads.展开更多
Some stochastic comparisons of generalized order statistics under the right spread order, the location independent riskier order and the total time transform order are investigated in this paper. The underlying distri...Some stochastic comparisons of generalized order statistics under the right spread order, the location independent riskier order and the total time transform order are investigated in this paper. The underlying distributions and parameters on which generalized order statistics are based are also surveyed to obtain the conditions for increasing the expectations of spacings between the first two generalized order statistics and between the last two generalized order statistics.展开更多
This work extends to fourth-order previously published work on developing the adjoint sensitivity and uncertainty analysis of the numerical model of a <u>p</u>oly<u>e</u>thylene-<u>r</...This work extends to fourth-order previously published work on developing the adjoint sensitivity and uncertainty analysis of the numerical model of a <u>p</u>oly<u>e</u>thylene-<u>r</u>eflected <u>p</u>lutonium (acronym: PERP) OECD/NEA reactor physics benchmark. Previous works showed that the third-order sensitivities of the PERP leakage response with respect to these total microscopic cross sections are far larger than the corresponding 1<sup>st</sup>-order and 2<sup>nd</sup>-order ones, thereby having the largest impact on the uncertainties induced in the PERP benchmark’s response. This finding has motivated the development of the original 4<sup>th</sup>-order formulas presented in this work, which are valid not only for the PERP benchmark but can also be used for computing the 4<sup>th</sup>-order sensitivities of response of any nuclear system involving fissionable material and internal or external neutron sources. Subsequent works will use the adjoint-based mathematical expressions obtained in this work to compute exactly and efficiently the numerical values of the largest fourth-order sensitivities of the PERP benchmark’s response to the total microscopic cross sections, and use them for a pioneering fourth-order uncertainty analysis of the PERP benchmark’s response.展开更多
The (180)<sup>3</sup> third-order mixed sensitivities of the leakage response of a polyethylene-reflected plutonium (PERP) experimental benchmark with respect to the benchmark’s 180 microscopic total cros...The (180)<sup>3</sup> third-order mixed sensitivities of the leakage response of a polyethylene-reflected plutonium (PERP) experimental benchmark with respect to the benchmark’s 180 microscopic total cross sections have been computed in accompanying works [1] [2]. This work quantifies the contributions of these (180)<sup>3</sup> third-order mixed sensitivities to the PERP benchmark’s leakage response distribution moments (expected value, variance and skewness) and compares these contributions to those stemming from the corresponding first- and second-order sensitivities of the PERP benchmark’s leakage response with respect to the total cross sections. The numerical results obtained in this work reveal that the importance of the 3<sup>rd</sup>-order sensitivities can surpass the importance of the 1<sup>st</sup>- and 2<sup>nd</sup>-order sensitivities when the parameters’ uncertainties increase. In particular, for a uniform standard deviation of 10% of the microscopic total cross sections, the 3<sup>rd</sup>-order sensitivities contribute 80% to the response variance, whereas the contribution stemming from the 1st- and 2nd-order sensitivities amount only to 2% and 18%, respectively. Consequently, neglecting the 3<sup>rd</sup>-order sensitivities could cause a very large non-conservative error by under-reporting the response variance by a factor of 506%. The results obtained in this work also indicate that the effects of the 3<sup>rd</sup>-order sensitivities are to reduce the response’s skewness in parameter space, rendering the distribution of the leakage response more symmetric about its expected value. The results obtained in this work are the first such results ever published in reactor physics. Since correlations among the group-averaged microscopic total cross sections are not available, only the effects of typical standard deviations for these cross sections could be considered. Due to this lack of correlations among the cross sections, the effects of the <em>mixed</em> 3<sup>rd</sup>-order sensitivities could not be quantified exactly at this time. These effects could be quantified only when correlations among the group-averaged microscopic total cross sections would be obtained experimentally by the nuclear physics community.展开更多
This work presents the results of the exact computation of (180)<sup>3</sup> = 5,832,000 third-order mixed sensitivities of the leakage response of a polyethylene-reflected plutonium (PERP) experimental be...This work presents the results of the exact computation of (180)<sup>3</sup> = 5,832,000 third-order mixed sensitivities of the leakage response of a polyethylene-reflected plutonium (PERP) experimental benchmark with respect to the benchmark’s 180 microscopic total cross sections. This computation was made possible by applying the Third-Order Adjoint Sensitivity Analysis Methodology developed by Cacuci. The numerical results obtained in this work revealed that many of the 3<sup>rd</sup>-order sensitivities are significantly larger than their corresponding 1<sup>st</sup>- and 2<sup>nd</sup>-order ones, which is contrary to the widely held belief that higher-order sensitivities are all much smaller and hence less important than the first-order ones, for reactor physics systems. In particular, the largest 3<sup>rd</sup>-order relative sensitivity is the mixed sensitivity <img src="Edit_754b8437-dfdf-487d-af68-c78c637e6d4e.png" width="180" height="24" alt="" />of the PERP leakage response with respect to the lowest energy-group (30) total cross sections of <sup>1</sup>H (“isotope 6”) and <sup>239</sup>Pu (“isotope 1”). These two isotopes are shown in this work to be the two most important parameters affecting the PERP benchmark’s leakage response. By comparison, the largest 1<sup>st</sup>-order sensitivity is that of the PERP leakage response with respect to the lowest energy-group total cross section of isotope <sup>1</sup>H, having the value <img src="Edit_a5cfcc11-6a99-41ee-b844-a5ee84b454b3.png" width="100" height="24" alt="" />, while the largest 2<sup>nd</sup>-order sensitivity is <img src="Edit_05166a2b-97f7-43f1-98ff-b21368c00228.png" width="120" height="22" alt="" />. The 3<sup>rd</sup>-order sensitivity analysis presented in this work is the first ever such analysis in the field of reactor physics. The consequences of the results presented in this work on the uncertainty analysis of the PERP benchmark’s leakage response will be presented in a subsequent work.展开更多
This work extends to third-order previously published work on developing the adjoint sensitivity and uncertainty analysis of the numerical model of a <u>p</u>oly<u>e</u>thylene-<u>r</u...This work extends to third-order previously published work on developing the adjoint sensitivity and uncertainty analysis of the numerical model of a <u>p</u>oly<u>e</u>thylene-<u>r</u>eflected <u>p</u>lutonium (acronym: PERP) OECD/NEA reactor physics benchmark. The PERP benchmark comprises 21,976 imprecisely known (uncertain) model parameters. Previous works have used the adjoint sensitivity analysis methodology to compute exactly and efficiently all of the 21,976 first-order and (21,976)<sup>2</sup> second-order sensitivities of the PERP benchmark’s leakage response to all of the benchmark’s uncertain parameters, showing that the largest and most consequential 1<sup>st</sup>- and 2<sup>nd</sup>-order response sensitivities are with respect to the total microscopic cross sections. These results have motivated extending the previous adjoint-based derivations to third-order, leading to the derivation, in this work, of the exact mathematical expressions of the (180)<sup>3</sup> third-order sensitivities of the PERP leakage response with respect to these total microscopic cross sections. The formulas derived in this work are valid not only for the PERP benchmark but can also be used for computing the 3<sup>rd</sup>-order sensitivities of the leakage response of any nuclear system involving fissionable material and internal or external neutron sources. Subsequent works will use the adjoint-based mathematical expressions obtained in this work to compute exactly and efficiently the numerical values of these (180)<sup>3</sup> third-order sensitivities (which turned out to be very large and consequential) and use them for a third-order uncertainty analysis of the PERP benchmark’s leakage response.展开更多
目的为住院患者全肠外营养液(TPN)中氨基酸、维生素等营养素的合理应用提供参考。方法参照专家共识、相关指南及药品说明书制订TPN用药合理性评价标准,选取南京医科大学附属淮安第一医院2019年至2021年的246例住院患者的267份TPN用药医...目的为住院患者全肠外营养液(TPN)中氨基酸、维生素等营养素的合理应用提供参考。方法参照专家共识、相关指南及药品说明书制订TPN用药合理性评价标准,选取南京医科大学附属淮安第一医院2019年至2021年的246例住院患者的267份TPN用药医嘱,对其氨基酸、维生素、葡萄糖、脂肪乳等营养素的应用进行合理性评价。结果246例TPN患者中,≥60岁152例(61.79%);肝胆胰外科收治145例(58.94%);平均疗程(7.19±5.18)d,疗程5~10 d 119例(48.37%)。267份TPN医嘱中,肝功能正常使用复方氨基酸(20AA)107份(40.07%),肝功能异常使用复方氨基酸(18AA-Ⅱ)及复方氨基酸(18AA-Ⅱ-SF)11份(4.12%);使用维生素合理22份(8.24%),使用脂溶性维生素未使用水溶性维生素233份(87.27%);使用甘油磷酸钠21份(7.87%)。结论TPN中各种复方氨基酸注射液和维生素的应用存在较多问题,较突出的是磷制剂和药理营养素应用比例较低。临床药师应加强TPN医嘱前置审核,促进TPN中各种复方氨基酸注射液和维生素制剂的合理、规范使用。展开更多
基金support from Hong Kong RGC Grant No: 2150518/410907support from NSFC projects under Grant Nos. 70725001,70821001 and 71090401/71090400
文摘In this paper, the optimal policy is considered when the buyer faces two supply sources: one is the contract supplier from which the buyer orders over a specific contract period (say, a year) at a pre-agreed price, and the other is the spot market. However, when ordering from the contract supplier, the buyer must fulfill a pre-determined total order quantity, or the so-called definite total order quantity commitment, over the whole contract period. In other words, the commitment secures the buyer a fixed price but obliges him/her a total order quantity over the contract period. Although the spot market gives the buyer more flexibility in terms of order quantities, its prices are volatile. Such a combination of contract and spot procurements is often observed in practice. Within the contract period, there are multiple sub-periods, during each of which the buyer reviews the inventory, issues an individual order, and uses the on-hand inventory to meet the random demand. Thus, in each (ordering) period, the buyer will weigh between the current known spot price (by procuring from the spot market) and a lower future price (by waiting while consuming the remaining commitment). An optimal dual ordering policy is characterized for each period, depending on the on-hand inventory level, the spot price, and the remaining commitment quantity. The optimal policy in each period is also shown to be independent of the contract price. Through a numerical study, the inventory cost is demonstrated to be (1) insensitive to the contract price when the total commitment quantity is lower than the total expected demand over the contract period and (2) non-increasing in the variability of spot prices.
基金the National Natural Science Foundation of China (Grant Nos. 60273038 and 90412014)the Program for New Centary Excellent Talents in University of MOE (Grant No. NCET-04-0478)Jiangsu "Six Top Talents" program
文摘Message total ordering is a critical part in active replication in order to maintain consistency among members in a fault tolerant group. The paper proposes a non-blocking message total ordering protocol (NBTOP) for distributed systems. Non-blocking property refers to that the members in a fault tolerant group keep on running independently without waiting for installing the same group view when a fault tolerant group evolves even when decision messages collide. NBTOP takes advantage of token ring as its logical control way. Members adopt re-requesting mechanism (RR) to obtain their lost decisions. Forward acknowledgement mechanism (FA) is put forth to solve decision collisions. The paper further proves that NBTOP satisfies the properties of total order, agreement, and termination. NBTOP is implemented, and its performance test is done. Comparing with the performance of Totem, the results show that NBTOP has a better total ordering delay. It manifests that non-blocking property helps to improve protocol efficiency.
基金financially supported by Grants-in-Aid for Scientific Research (A) (no.16H02417)Young Scientists (A) (no.15H05494) from the Japan Society for the Promotion of Science (JSPS)partly supported by MEXT as “Priority Issue on Post-K computer” (Development of new fundamental technologies for highefficiency energy creation, conversion/storage and use)
文摘Certain perovskite-type oxynitrides have bandgaps suitable for renewable hydrogen production via photocatalytic and photoelectrochemical water splitting under visible light.Understanding the ordering of oxide and nitride anions in these materials is important because this ordering affects their semiconductor properties.However, the numerous possible orderings complicate systematic analyses based on density functional theory(DFT) calculations using defined elemental arrangements.This work shows that anion ordering in large-scale supercells within perovskite-type oxynitrides can be rapidly predicted based on machine learning, using BaNbO2N(capable of oxidizing water under irradiation up to 740 nm) as an example.Machine learning allows the calculation of the total energy of BaNbO2N directly from randomly selected initial atomic placements without costly structural optimization, thus reducing the computational cost by more than 99.99%.Combined with the Metropolis Monte Carlo method, machine learning permits exploration of the stable anion orderings of large supercells without costly DFT calculations.This work therefore demonstrates a means of predicting the properties of functional materials having complex compositions based on the most realistic elemental arrangements in conjunction with reasonable computational loads.
基金Supported by Program for Young Talents in Artillery College.
文摘Some stochastic comparisons of generalized order statistics under the right spread order, the location independent riskier order and the total time transform order are investigated in this paper. The underlying distributions and parameters on which generalized order statistics are based are also surveyed to obtain the conditions for increasing the expectations of spacings between the first two generalized order statistics and between the last two generalized order statistics.
文摘This work extends to fourth-order previously published work on developing the adjoint sensitivity and uncertainty analysis of the numerical model of a <u>p</u>oly<u>e</u>thylene-<u>r</u>eflected <u>p</u>lutonium (acronym: PERP) OECD/NEA reactor physics benchmark. Previous works showed that the third-order sensitivities of the PERP leakage response with respect to these total microscopic cross sections are far larger than the corresponding 1<sup>st</sup>-order and 2<sup>nd</sup>-order ones, thereby having the largest impact on the uncertainties induced in the PERP benchmark’s response. This finding has motivated the development of the original 4<sup>th</sup>-order formulas presented in this work, which are valid not only for the PERP benchmark but can also be used for computing the 4<sup>th</sup>-order sensitivities of response of any nuclear system involving fissionable material and internal or external neutron sources. Subsequent works will use the adjoint-based mathematical expressions obtained in this work to compute exactly and efficiently the numerical values of the largest fourth-order sensitivities of the PERP benchmark’s response to the total microscopic cross sections, and use them for a pioneering fourth-order uncertainty analysis of the PERP benchmark’s response.
文摘The (180)<sup>3</sup> third-order mixed sensitivities of the leakage response of a polyethylene-reflected plutonium (PERP) experimental benchmark with respect to the benchmark’s 180 microscopic total cross sections have been computed in accompanying works [1] [2]. This work quantifies the contributions of these (180)<sup>3</sup> third-order mixed sensitivities to the PERP benchmark’s leakage response distribution moments (expected value, variance and skewness) and compares these contributions to those stemming from the corresponding first- and second-order sensitivities of the PERP benchmark’s leakage response with respect to the total cross sections. The numerical results obtained in this work reveal that the importance of the 3<sup>rd</sup>-order sensitivities can surpass the importance of the 1<sup>st</sup>- and 2<sup>nd</sup>-order sensitivities when the parameters’ uncertainties increase. In particular, for a uniform standard deviation of 10% of the microscopic total cross sections, the 3<sup>rd</sup>-order sensitivities contribute 80% to the response variance, whereas the contribution stemming from the 1st- and 2nd-order sensitivities amount only to 2% and 18%, respectively. Consequently, neglecting the 3<sup>rd</sup>-order sensitivities could cause a very large non-conservative error by under-reporting the response variance by a factor of 506%. The results obtained in this work also indicate that the effects of the 3<sup>rd</sup>-order sensitivities are to reduce the response’s skewness in parameter space, rendering the distribution of the leakage response more symmetric about its expected value. The results obtained in this work are the first such results ever published in reactor physics. Since correlations among the group-averaged microscopic total cross sections are not available, only the effects of typical standard deviations for these cross sections could be considered. Due to this lack of correlations among the cross sections, the effects of the <em>mixed</em> 3<sup>rd</sup>-order sensitivities could not be quantified exactly at this time. These effects could be quantified only when correlations among the group-averaged microscopic total cross sections would be obtained experimentally by the nuclear physics community.
文摘This work presents the results of the exact computation of (180)<sup>3</sup> = 5,832,000 third-order mixed sensitivities of the leakage response of a polyethylene-reflected plutonium (PERP) experimental benchmark with respect to the benchmark’s 180 microscopic total cross sections. This computation was made possible by applying the Third-Order Adjoint Sensitivity Analysis Methodology developed by Cacuci. The numerical results obtained in this work revealed that many of the 3<sup>rd</sup>-order sensitivities are significantly larger than their corresponding 1<sup>st</sup>- and 2<sup>nd</sup>-order ones, which is contrary to the widely held belief that higher-order sensitivities are all much smaller and hence less important than the first-order ones, for reactor physics systems. In particular, the largest 3<sup>rd</sup>-order relative sensitivity is the mixed sensitivity <img src="Edit_754b8437-dfdf-487d-af68-c78c637e6d4e.png" width="180" height="24" alt="" />of the PERP leakage response with respect to the lowest energy-group (30) total cross sections of <sup>1</sup>H (“isotope 6”) and <sup>239</sup>Pu (“isotope 1”). These two isotopes are shown in this work to be the two most important parameters affecting the PERP benchmark’s leakage response. By comparison, the largest 1<sup>st</sup>-order sensitivity is that of the PERP leakage response with respect to the lowest energy-group total cross section of isotope <sup>1</sup>H, having the value <img src="Edit_a5cfcc11-6a99-41ee-b844-a5ee84b454b3.png" width="100" height="24" alt="" />, while the largest 2<sup>nd</sup>-order sensitivity is <img src="Edit_05166a2b-97f7-43f1-98ff-b21368c00228.png" width="120" height="22" alt="" />. The 3<sup>rd</sup>-order sensitivity analysis presented in this work is the first ever such analysis in the field of reactor physics. The consequences of the results presented in this work on the uncertainty analysis of the PERP benchmark’s leakage response will be presented in a subsequent work.
文摘This work extends to third-order previously published work on developing the adjoint sensitivity and uncertainty analysis of the numerical model of a <u>p</u>oly<u>e</u>thylene-<u>r</u>eflected <u>p</u>lutonium (acronym: PERP) OECD/NEA reactor physics benchmark. The PERP benchmark comprises 21,976 imprecisely known (uncertain) model parameters. Previous works have used the adjoint sensitivity analysis methodology to compute exactly and efficiently all of the 21,976 first-order and (21,976)<sup>2</sup> second-order sensitivities of the PERP benchmark’s leakage response to all of the benchmark’s uncertain parameters, showing that the largest and most consequential 1<sup>st</sup>- and 2<sup>nd</sup>-order response sensitivities are with respect to the total microscopic cross sections. These results have motivated extending the previous adjoint-based derivations to third-order, leading to the derivation, in this work, of the exact mathematical expressions of the (180)<sup>3</sup> third-order sensitivities of the PERP leakage response with respect to these total microscopic cross sections. The formulas derived in this work are valid not only for the PERP benchmark but can also be used for computing the 3<sup>rd</sup>-order sensitivities of the leakage response of any nuclear system involving fissionable material and internal or external neutron sources. Subsequent works will use the adjoint-based mathematical expressions obtained in this work to compute exactly and efficiently the numerical values of these (180)<sup>3</sup> third-order sensitivities (which turned out to be very large and consequential) and use them for a third-order uncertainty analysis of the PERP benchmark’s leakage response.
文摘目的为住院患者全肠外营养液(TPN)中氨基酸、维生素等营养素的合理应用提供参考。方法参照专家共识、相关指南及药品说明书制订TPN用药合理性评价标准,选取南京医科大学附属淮安第一医院2019年至2021年的246例住院患者的267份TPN用药医嘱,对其氨基酸、维生素、葡萄糖、脂肪乳等营养素的应用进行合理性评价。结果246例TPN患者中,≥60岁152例(61.79%);肝胆胰外科收治145例(58.94%);平均疗程(7.19±5.18)d,疗程5~10 d 119例(48.37%)。267份TPN医嘱中,肝功能正常使用复方氨基酸(20AA)107份(40.07%),肝功能异常使用复方氨基酸(18AA-Ⅱ)及复方氨基酸(18AA-Ⅱ-SF)11份(4.12%);使用维生素合理22份(8.24%),使用脂溶性维生素未使用水溶性维生素233份(87.27%);使用甘油磷酸钠21份(7.87%)。结论TPN中各种复方氨基酸注射液和维生素的应用存在较多问题,较突出的是磷制剂和药理营养素应用比例较低。临床药师应加强TPN医嘱前置审核,促进TPN中各种复方氨基酸注射液和维生素制剂的合理、规范使用。