An experimental 2618(Al-Cu-Mg-Fe-Ni) alloy added with trace Sc and Zr was prepared by ingot metallurgy (IM) method. The aging behavior of the alloy was studied by Vickers hardness measurement at 200℃ and 300℃. and ...An experimental 2618(Al-Cu-Mg-Fe-Ni) alloy added with trace Sc and Zr was prepared by ingot metallurgy (IM) method. The aging behavior of the alloy was studied by Vickers hardness measurement at 200℃ and 300℃. and the tensile properties of alloy specimens were measured at 20℃, 200℃, 250℃ and 300℃. The microstructure was observed by using optical microscope, SEM and TEM. It was found that the addition of Sc and Zr to 2618 alloy resulted in a primary Al_3(Sc,Zr) phase which could refine the grain because it acts as nuclei of heterogeneous crystallization in the melt during solidification. The secondary Al_3(Sc,Zr) particles were full coherent with matrix and had obvious precipitation hardening effect. They also made the S' phase precipitate more homogeneous. So the strength of alloy increases at both ambient and elevated temperatures without a decrease of ductility. The ductile fracture of alloy occurs by microvoid nucleation, growth and coalescence, so the microvoid coalescence is the dominant fracture mechanism.展开更多
The effects of airborne particulate matter （PM） trace elements on health are widely concerned nowadays. Many achievements have been made while many unknowns exist. This article reports the recent research progresses...The effects of airborne particulate matter （PM） trace elements on health are widely concerned nowadays. Many achievements have been made while many unknowns exist. This article reports the recent research progresses, describes the effects of exposure to PM trace elements on health epidemiological evidence, toxicology findings, and raises some questions for future studies.展开更多
Information dissemination has become part of people’s daily communication and there is great interest for both academic and industrial communities. Most previous studies have focused on the strategy and mechanisms. T...Information dissemination has become part of people’s daily communication and there is great interest for both academic and industrial communities. Most previous studies have focused on the strategy and mechanisms. The methods controlling the process of information diffusion have rarely been studied. Thus, previous studies have failed to effectively mine the value of product information diffusion on social networks. In this study, based on the information diffusion product in consumer self-organized social networks, the control of the product information diffusion process was explored. The node identification principle of the QR code sender designed in this study and the linked list that associated information with specific nodes allowed the acquisition of effective traces in long-chain transmission from the information source to the value nodes, and solved user information disclosure during the transmission process. This method was applied to the tracing system of defective vehicles, achieving accurate recall of defective vehicles.展开更多
The distribution of trace metals in remote alpine region is an effective way to understand the impacts of regional human activity and vegetation on the alpine ecosystem. In this study, the concentrations of cadmium(Cd...The distribution of trace metals in remote alpine region is an effective way to understand the impacts of regional human activity and vegetation on the alpine ecosystem. In this study, the concentrations of cadmium(Cd), copper(Cu), lead(Pb), and zinc(Zn) in the soils of Gongga Mountain, Eastern Tibetan Plateau, were investigated to reveal their seasonal and spatial distribution and enrichment state, and to decipher the effects of atmospheric deposition and vegetation on their distributions among five vegetation zones. The results showed that the concentrations of Cd, Pb, and Zn were higher in the O horizon than in other horizons despite the seasonal changes, whereas Cu was enriched in the C horizon. The enrichment states of the metals studied in the soils decreased in the order of Cd > Pb > Zn > Cu. Cd and Pb were mainly sourced from atmospheric deposition; Zn was from both atmospheric deposition and parent materials, whereas Cu was mainly from parent materials.Seasonally, the trace metals were generally higher in May and December but lower in September, implying the impact of vegetation on the distribution of trace metals under the plant uptake and the litter decomposition. Spatially, the higher enrichment of Cu, Pb, and Zn in the soils existed in the mixed broadleafconiferous forests and coniferous forests(approximately 3000 m above sea level). The results suggested that atmospheric deposition and biological processes are main factors controlling the seasonal and spatial distribution of trace metals in the soils of the remote alpine ecosystem.展开更多
A An analytical method using high resolution inductively coupled plasma mass spectrometry （HR-ICP-MS） for rapid simultaneous determination of 24 elements （Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, ...A An analytical method using high resolution inductively coupled plasma mass spectrometry （HR-ICP-MS） for rapid simultaneous determination of 24 elements （Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn Sb, Ba, Pt, Au, and Pb） in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCI. The matrix effects because of the presence of excess HCI and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits were 0.016-1.50 ].tg·g^-1, the recovery ratios were 92.2%-111.2%, and the RSD was less than 3.6%. The method was accurate, quick, and convenient. It was applied to the determination of trace impurities in high purity cobalt with satisfactory results.展开更多
An analytical method using high resolution inductively coupled plasma mass spectrometry （HR-ICP-MS） for rapid simultaneous determination of Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, ...An analytical method using high resolution inductively coupled plasma mass spectrometry （HR-ICP-MS） for rapid simultaneous determination of Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, Sb, Ba, Pt, Au and Pb in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCl. The matrix effects due to the presence of excess HCl and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination was tested and discussed. Correction for matrix effects, Sc, Rh and Bi were used as internal standards. The detection limits is 0.003-0.57 μg/g, the recovery ratio is 92.2%-111.2%, and the RSD is less than 3.6%. The method is accurate, quick and convenient. It has been applied to the determination of trace impurities in high purity cobalt with satisfactory results.展开更多
Instrumental Neutron Activation Analysis has been used to make a multi-elemental determi-nation in the Zingiber officinalis and Salvia offi-cinalis, plants used in traditional medicine therapy in Algeria and in most c...Instrumental Neutron Activation Analysis has been used to make a multi-elemental determi-nation in the Zingiber officinalis and Salvia offi-cinalis, plants used in traditional medicine therapy in Algeria and in most countries. The concentrations of five elements Co, Cr, Sc, Sb and Rb have been determined by long irradiation time with 2.7E13 n?cm–2?s–1 thermal flux using a NUR Algerian Reactor. All these elements are present at trace levels. Their implications in Human health are herein discussed. The quality control of the measurements have been evaluated by analysing a HAY (V-10) IAEA-Standard reference material.展开更多
文摘An experimental 2618(Al-Cu-Mg-Fe-Ni) alloy added with trace Sc and Zr was prepared by ingot metallurgy (IM) method. The aging behavior of the alloy was studied by Vickers hardness measurement at 200℃ and 300℃. and the tensile properties of alloy specimens were measured at 20℃, 200℃, 250℃ and 300℃. The microstructure was observed by using optical microscope, SEM and TEM. It was found that the addition of Sc and Zr to 2618 alloy resulted in a primary Al_3(Sc,Zr) phase which could refine the grain because it acts as nuclei of heterogeneous crystallization in the melt during solidification. The secondary Al_3(Sc,Zr) particles were full coherent with matrix and had obvious precipitation hardening effect. They also made the S' phase precipitate more homogeneous. So the strength of alloy increases at both ambient and elevated temperatures without a decrease of ductility. The ductile fracture of alloy occurs by microvoid nucleation, growth and coalescence, so the microvoid coalescence is the dominant fracture mechanism.
文摘The effects of airborne particulate matter （PM） trace elements on health are widely concerned nowadays. Many achievements have been made while many unknowns exist. This article reports the recent research progresses, describes the effects of exposure to PM trace elements on health epidemiological evidence, toxicology findings, and raises some questions for future studies.
文摘Information dissemination has become part of people’s daily communication and there is great interest for both academic and industrial communities. Most previous studies have focused on the strategy and mechanisms. The methods controlling the process of information diffusion have rarely been studied. Thus, previous studies have failed to effectively mine the value of product information diffusion on social networks. In this study, based on the information diffusion product in consumer self-organized social networks, the control of the product information diffusion process was explored. The node identification principle of the QR code sender designed in this study and the linked list that associated information with specific nodes allowed the acquisition of effective traces in long-chain transmission from the information source to the value nodes, and solved user information disclosure during the transmission process. This method was applied to the tracing system of defective vehicles, achieving accurate recall of defective vehicles.
基金supported by National Natural Science Foundation of China (Grant No. 41402313, Grant No. 41272200)National Key Research and Development Program of China (2016YFC0502401)the Fundamental Research Funds of Institute of Karst Geology, Chinese Academy of Geological Sciences (No. 2017008)
文摘The distribution of trace metals in remote alpine region is an effective way to understand the impacts of regional human activity and vegetation on the alpine ecosystem. In this study, the concentrations of cadmium(Cd), copper(Cu), lead(Pb), and zinc(Zn) in the soils of Gongga Mountain, Eastern Tibetan Plateau, were investigated to reveal their seasonal and spatial distribution and enrichment state, and to decipher the effects of atmospheric deposition and vegetation on their distributions among five vegetation zones. The results showed that the concentrations of Cd, Pb, and Zn were higher in the O horizon than in other horizons despite the seasonal changes, whereas Cu was enriched in the C horizon. The enrichment states of the metals studied in the soils decreased in the order of Cd > Pb > Zn > Cu. Cd and Pb were mainly sourced from atmospheric deposition; Zn was from both atmospheric deposition and parent materials, whereas Cu was mainly from parent materials.Seasonally, the trace metals were generally higher in May and December but lower in September, implying the impact of vegetation on the distribution of trace metals under the plant uptake and the litter decomposition. Spatially, the higher enrichment of Cu, Pb, and Zn in the soils existed in the mixed broadleafconiferous forests and coniferous forests(approximately 3000 m above sea level). The results suggested that atmospheric deposition and biological processes are main factors controlling the seasonal and spatial distribution of trace metals in the soils of the remote alpine ecosystem.
基金the Natural Science Foundation of Hunan Province, China (No. 05JJ40017).
文摘A An analytical method using high resolution inductively coupled plasma mass spectrometry （HR-ICP-MS） for rapid simultaneous determination of 24 elements （Be, Mg, A1, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn Sb, Ba, Pt, Au, and Pb） in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCI. The matrix effects because of the presence of excess HCI and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits were 0.016-1.50 ].tg·g^-1, the recovery ratios were 92.2%-111.2%, and the RSD was less than 3.6%. The method was accurate, quick, and convenient. It was applied to the determination of trace impurities in high purity cobalt with satisfactory results.
基金supported by the Natural Science Foundation of Hunan Province(No.05JJ40017)Education Department of Hunan Province(No.05B064).
文摘An analytical method using high resolution inductively coupled plasma mass spectrometry （HR-ICP-MS） for rapid simultaneous determination of Be, Mg, Al, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, Ge, As, Se, Mo, Ag, Cd, Sn, Sb, Ba, Pt, Au and Pb in high purity cobalt was described. Sample digestions were performed in closed microwave vessels using HNO3 and HCl. The matrix effects due to the presence of excess HCl and Co were evaluated. The usefulness of high mass resolution for overcoming some spectral interference was demonstrated. The optimum conditions for the determination was tested and discussed. Correction for matrix effects, Sc, Rh and Bi were used as internal standards. The detection limits is 0.003-0.57 μg/g, the recovery ratio is 92.2%-111.2%, and the RSD is less than 3.6%. The method is accurate, quick and convenient. It has been applied to the determination of trace impurities in high purity cobalt with satisfactory results.
文摘Instrumental Neutron Activation Analysis has been used to make a multi-elemental determi-nation in the Zingiber officinalis and Salvia offi-cinalis, plants used in traditional medicine therapy in Algeria and in most countries. The concentrations of five elements Co, Cr, Sc, Sb and Rb have been determined by long irradiation time with 2.7E13 n?cm–2?s–1 thermal flux using a NUR Algerian Reactor. All these elements are present at trace levels. Their implications in Human health are herein discussed. The quality control of the measurements have been evaluated by analysing a HAY (V-10) IAEA-Standard reference material.
