海南岛西部近岸海域海砂资源丰富、经济价值巨大,对其物质来源却缺乏系统研究。为解决这一科学问题,为该区域海砂资源的开发利用提供科学依据,对海南岛西部近岸海域和昌化江入海口1 471粒碎屑锆石开展了U-Pb同位素年代学和微区元素地球...海南岛西部近岸海域海砂资源丰富、经济价值巨大,对其物质来源却缺乏系统研究。为解决这一科学问题,为该区域海砂资源的开发利用提供科学依据,对海南岛西部近岸海域和昌化江入海口1 471粒碎屑锆石开展了U-Pb同位素年代学和微区元素地球化学研究。海南岛西部近岸海域年龄范围在3.45 Ga~82 Ma,具有99、241、252 Ma 3个主要年龄峰值,以及113、155、325、357 Ma 4个次要年龄峰值;昌化江入海口具有2.3 Ga~96 Ma的年龄范围,存在101、244、254 Ma 3个主要年龄峰值,以及122、266、281、307、342 Ma 4个次要年龄峰值。结果表明:海南岛西部近岸海域沉积物以具有~99 Ma的显著年龄峰,并缺乏晋宁期、加里东期和喜山期年龄峰为识别标志,海南岛应是其主要物源区,区内丰富的海砂资源来源于海南岛内岩浆岩和沉积岩的风化剥蚀和搬运沉积;海南岛西部近岸海域与昌化江沉积物年龄峰值的差异,指示海南岛西部近岸海域沉积物并非单纯来源于近源昌化江输入,也在北部湾逆时针环流的作用下接受琼西南部河流的物源贡献;更新昌化江入海口的碎屑锆石年龄组成,新识别出的380~310 Ma年龄群,可作为昌化江流域物源的识别标志;本次碎屑锆石年龄频谱特征与海南岛经历的多次重要地质事件相吻合,有助于了解海南岛复杂的地质演化历史。展开更多
The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform o...The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.展开更多
文摘海南岛西部近岸海域海砂资源丰富、经济价值巨大,对其物质来源却缺乏系统研究。为解决这一科学问题,为该区域海砂资源的开发利用提供科学依据,对海南岛西部近岸海域和昌化江入海口1 471粒碎屑锆石开展了U-Pb同位素年代学和微区元素地球化学研究。海南岛西部近岸海域年龄范围在3.45 Ga~82 Ma,具有99、241、252 Ma 3个主要年龄峰值,以及113、155、325、357 Ma 4个次要年龄峰值;昌化江入海口具有2.3 Ga~96 Ma的年龄范围,存在101、244、254 Ma 3个主要年龄峰值,以及122、266、281、307、342 Ma 4个次要年龄峰值。结果表明:海南岛西部近岸海域沉积物以具有~99 Ma的显著年龄峰,并缺乏晋宁期、加里东期和喜山期年龄峰为识别标志,海南岛应是其主要物源区,区内丰富的海砂资源来源于海南岛内岩浆岩和沉积岩的风化剥蚀和搬运沉积;海南岛西部近岸海域与昌化江沉积物年龄峰值的差异,指示海南岛西部近岸海域沉积物并非单纯来源于近源昌化江输入,也在北部湾逆时针环流的作用下接受琼西南部河流的物源贡献;更新昌化江入海口的碎屑锆石年龄组成,新识别出的380~310 Ma年龄群,可作为昌化江流域物源的识别标志;本次碎屑锆石年龄频谱特征与海南岛经历的多次重要地质事件相吻合,有助于了解海南岛复杂的地质演化历史。
基金supported by the National Natural Science Foundation of China (NSFC) (No. 41772062)
文摘The Dongfengnanshan Cu polymetallic deposit is one representative deposit of the Tianbaoshan ore district in the Yanbian area, northeast(NE) China. There occur two types of ore bodies in this deposit, the stratiform ore bodies and veintype ones, controlled by the Early Permian strata and the Late Hercynian diorite intrusion, respectively. Due to the ambiguous genetic type of the stratiform ore bodies, there has been controversy on the relationship between them and veintype ore bodies. To determine the genetic type of stratiform ore bodies, laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS) in situ trace elements and S–Pb isotope analysis have been carried on the sulfides in the stratiform ore bodies. Compared with that in skarn, Mississippi Valley-type(MVT), and epithermal deposits, sphalerite samples in the stratiform ore bodies of the Dongfengnanshan deposit are significantly enriched in Fe, Mn, and In, while depleted in Ga, Ge, and Cd, which is similar to the sphalerite in volcanic-associated massive sulfide(VMS) deposits. Co/Ni ratio of pyrrhotites in the stratiform ore bodies is similar to that in VMS-type deposits. The concentrations of Zn and Cd of chalcopyrites are similar to those of recrystallized VMS-type deposits. These characteristics also reflect the intermediate ore-forming temperature of the stratiform ore bodies in this deposit. Sulfur isotope compositions of sulfides are similar to those of VMS-type deposits, reflecting that sulfur originated from the Permian Miaoling Formation. Lead isotope compositions indicate mixed-source for lead. Moreover, the comparison of the Dongfengnanshan stratiform ore bodies with some VMStype deposits in China and abroad, on the trace elements and S–Pb isotope characteristics of the sulfides reveals that the stratiform ore bodies of the Dongfengnanshan deposit belong to the VMS-type, and have closely genetic relationship with the early Permian marine volcanic sedimentary rocks.
