A new review of single-ion conducting polymer electrolytes in the light of ion transport mechanisms

With the depletion of fossil fuels and the demand for high-performance energy storage devices,solidstate lithium metal batteries have received widespread attention due to their high energy density and safety advantages.Among them,the earliest developed organic solid-state polymer electrolyte has a promising future due to its advantages such as good mechanical flexibility,but its poor ion transport performance dramatically limits its performance improvement.Therefore,single-ion conducting polymer electrolytes(SICPEs)with high lithium-ion transport number,capable of improving the concentration polarization and inhibiting the growth of lithium dendrites,have been proposed,which provide a new direction for the further development of high-performance organic polymer electrolytes.In view of this,lithium ions transport mechanisms and design principles in SICPEs are summarized and discussed in this paper.The modification principles currently used can be categorized into the following three types:enhancement of lithium salt anion-polymer interactions,weakening of lithium salt anion-cation interactions,and modulation of lithium ion-polymer interactions.In addition,the advances in single-ion conductors of conventional and novel polymer electrolytes are summarized,and several typical highperformance single-ion conductors are enumerated and analyzed in what way they improve ionic conductivity,lithium ions mobility,and the ability to inhibit lithium dendrites.Finally,the advantages and design methodology of SICPEs are summarized again and the future directions are outlined.

Numerical simulation of gas transport mechanisms in tight shale gas reservoirs

Due to the nanometer scale pore size and extremely low permeability of a shale matrix,traditional Darcy＇s law can not exactly describe the combined gas transport mechanisms of viscous flow and Knudsen diffusion.Three transport models modified by the Darcy equation with apparent permeability are used to describe the combined gas transport mechanisms in ultra-tight porous media,the result shows that Knudsen diffusion has a great impact on the gas transport and Darcy＇s law cannot be used in a shale matrix with a pore diameter less than 1 μm.A single porosity model and a double porosity model with consideration of the combined gas transport mechanisms are developed to evaluate the influence of gas transport mechanisms and fracture parameters respectively on shale gas production.The numerical results show that the gas production predicted by Darcy＇s law is lower than that predicted with consideration of Knudsen diffusion and the tighter the shale matrix,the greater difference of the gas production estimates.In addition,the numerical simulation results indicate that shale fractures have a great impact on shale gas production.Shale gas cannot be produced economically without fractures.

A two-phase type-curve method with multiscale fluid transport mechanisms in hydraulically fractured shale reservoirs

The quantitative understanding of hydraulic fracture(HF)properties guides accurate production forecasts and reserve estimation.Type curve is a powerful technique to characterize HF and reservoir properties from flowback and long-term production data.However,two-phase flow of water and hydrocarbon after an HF stimulation together with the complex transport mechanisms in shale nanopores exacerbate the nonlinearity of the transport equation,causing errors in type-curve analysis.Accordingly,we propose a new two-phase type-curve method to estimate HF properties,such as HF volume and permeability of fracture,through the analysis of flowback data of multi-fractured shale wells.The proposed type curve is based on a semianalytical solution that couples the two-phase flow from the matrix with the flow in HF by incorporating matrix influx,slippage effect,stress dependence,and the spatial variation of fluid properties in inorganic and organic pores.For the first time,multiple fluid transport mechanisms are considered into two-phase type-curve analysis for shale reservoirs.We analyze the flowback data from a multi-fractured horizontal well in a shale gas reservoir to verify the field application of the proposed method.The results show that the fracture properties calculated by the type-curve method are in good agreement with the long-time production data.

Transport mechanism of reverse surface leakage current in AlGaN/GaN high-electron mobility transistor with SiN passivation

The transport mechanism of reverse surface leakage current in the AlGaN/GaN high-electron mobility transistor（HEMT） becomes one of the most important reliability issues with the downscaling of feature size.In this paper,the research results show that the reverse surface leakage current in AlGaN/GaN HEMT with SiN passivation increases with the enhancement of temperature in the range from 298 K to 423 K.Three possible transport mechanisms are proposed and examined to explain the generation of reverse surface leakage current.By comparing the experimental data with the numerical transport models,it is found that neither Fowler-Nordheim tunneling nor Frenkel-Poole emission can describe the transport of reverse surface leakage current.However,good agreement is found between the experimental data and the two-dimensional variable range hopping（2D-VRH） model.Therefore,it is concluded that the reverse surface leakage current is dominated by the electron hopping through the surface states at the barrier layer.Moreover,the activation energy of surface leakage current is extracted,which is around 0.083 eV.Finally,the SiN passivated HEMT with a high Al composition and a thin AlGaN barrier layer is also studied.It is observed that 2D-VRH still dominates the reverse surface leakage current and the activation energy is around 0.10 eV,which demonstrates that the alteration of the AlGaN barrier layer does not affect the transport mechanism of reverse surface leakage current in this paper.

A NOVEL KIND OF PROTON EXCHANGE MEMBRANE:CHARACTERS AND PROTON TRANSPORT MECHANISM

A novel proton exchange membrane(PEM) was designed and prepared from a polymer containing calix[4]arene as the functional unit to transport proton.The proton-conductivity of this membrane is about the same order of magnitude as that of Nation~■ 112 membrane.It is of interest to note that very different from most of the currently known PEMs,this membrane can transport proton without the help of water or other solvents.It is deduced that the protons are transported via an ion tunneling model.This opens up a n...

Influence of gas transport mechanisms on the productivity of multi-stage fractured horizontal wells in shale gas reservoirs

In order to investigate the influence on shale gas well productivity caused by gas transport in nanometer- size pores, a mathematical model of multi-stage fractured horizontal wells in shale gas reservoirs is built, which considers the influence of viscous flow, Knudsen diffusion, surface diffusion, and adsorption layer thickness. A dis- crete-fracture model is used to simplify the fracture mod- cling, and a finite element method is applied to solve the model. The numerical simulation results indicate that with a decrease in the intrinsic matrix permeability, Knudsen diffusion and surface diffusion contributions to production become large and cannot be ignored. The existence of an adsorption layer on the nanopore surfaces reduces the effective pore radius and the effective porosity, resulting in low production from fractured horizontal wells. With a decrease in the pore radius, considering the adsorption layer, the production reduction rate increases. When the pore radius is less than 10 nm, because of the combined impacts of Knudsen diffusion, surface diffusion, and adsorption layers, the production of multi-stage fractured horizontal wells increases with a decrease in the pore pressure. When the pore pressure is lower than 30 MPa, the rate of production increase becomes larger with a decrease in pore pressure.

The Transport Mechanisms of Reverse Leakage Current in Ultraviolet Light-Emitting Diodes

The transport mechanisms of the reverse leakage current in the UV light-emitting diodes （380nm） are investi- gated by the temperature-dependent current-voltage measurement first. Three possible transport mechanisms, the space-limited-charge conduction, the variable-range hopping and the Poole-Frenkel emission, are proposed to explain the transport process of the reverse leakage current above 295 K, respectively. With the in-depth investigation, the former two transport mechanisms are excluded. It is found that the experimental data agree well with the Poole Frenkel emission model. Furthermore, the activation energies of the traps that cause the reverse leakage current are extracted, which are 0.05eV, 0.09eV, and 0.11 eV, respectively. This indicates that at least three types of trap states are located below the bottom of the conduction band in the depletion region of the UV LEDs.

Transport mechanism of eroded sediment particles under freeze-thaw and runoff conditions

Hydraulic erosion associated with seasonal freeze-thaw cycles is one of the most predominant factors,which drives soil stripping and transportation.In this study,indoor simulated meltwater erosion experiments were used to investigate the sorting characteristics and transport mechanism of sediment particles under different freeze-thaw conditions(unfrozen,shallow-thawed,and frozen slopes)and runoff rates(1,2,and 4 L/min).Results showed that the order of sediment particle contents was silt>sand>clay during erosion process on unfrozen,shallow-thawed,and frozen slopes.Compared with original soils,clay and silt were lost,and sand was deposited.On unfrozen and shallow-thawed slopes,the change of runoff rate had a significant impact on the enrichment of clay,silt,and sand particles.In this study,the sediment particles transported in the form of suspension/saltation were 83.58%–86.54%on unfrozen slopes,69.24%–84.89%on shallow-thawed slopes,and 83.75%–87.44%on frozen slopes.Moreover,sediment particles smaller than 0.027 mm were preferentially transported.On shallow-thawed slope,relative contribution percentage of suspension/saltation sediment particles gradually increased with the increase in runoff rate,and an opposite trend occurred on unfrozen and frozen slopes.At the same runoff rate,freeze-thaw process had a significant impact on the relative contribution percentage of sediment particle transport via suspension/saltation and rolling during erosion process.The research results provide an improved transport mechanism under freeze-thaw condition for steep loessal slopes.

Schottky forward current transport mechanisms in AlGaN/GaN HEMTs over a wide temperature range

The behavior of Schottky contacts in AlGaN/GaN high electron mobility transistors （HEMTs） is investigated by temperature-dependent current-voltage （T-I-V） measurements from 300 K to 473 K. The ideality factor and barrier height determined based on the thermionic emission （TE） theory are found to be strong functions of temperature, while present a great deviation from the theoretical value, which can be expounded by the barrier height inhomogeneities. In order to determine the forward current transport mechanisms, the experimental data are analyzed using numerical fitting method, considering the temperature-dependent series resistance. It is observed that the current flow at room temperature can be attributed to the tunneling mechanism, while thermionic emission current gains a growing proportion with an increase in temperature. Finally, the effective barrier height is derived based on the extracted thermionic emission component, and an evaluation of the density of dislocations is made from the I-V characteristics, giving a value of 1.49 × 10^7 cm^-2.

Optimization of recess-free AlGaN/GaN Schottky barrier diode by TiN anode and current transport mechanism analysis

:In this work,the optimization of reverse leakage current(IR)and turn-on voltage(VT)in recess-free AlGaN/GaN Schottky barrier diodes(SBDs)was achieved by substituting the Ni/Au anode with TiN anode.To explain this phenomenon,the current transport mechanism was investigated by temperature-dependent current–voltage(I–V)characteristics.For forward bias,the current is dominated by the thermionic emission(TE)mechanisms for both devices.Besides,the presence of inhomogeneity of the Schottky barrier height(qφb)is proved by the linear relationship between qφb and ideality factor.For reverse bias,the current is dominated by two different mechanisms at high temperature and low temperature,respectively.At high temperatures,the Poole–Frenkel emission(PFE)induced by nitrogen-vacancy(VN)is responsible for the high IR in Ni/Au anode.For TiN anode,the IR is dominated by the PFE from threading dislocation(TD),which can be attributed to the decrease of VN due to the suppression of N diffusion at the interface of Schottky contact.At low temperatures,the IR of both diodes is dominated by Fowler–Nordheim(FN)tunneling.However,the VN donor enhances the electric field in the barrier layer,thus causing a higher IR in Ni/Au anode than TiN anode,as confirmed by the modified FN model.

Plant pleiotropic drug resistance transporters:Transport mechanism, gene expression,and function

Pleiotropic drug resistance （PDR） transporters belonging to the ABCG subfamily of ATP-binding cassette （ABC） transporters are identified only in fungi and plants. Members of this family are expressed in plants in response to various biotic and abiotic stresses and transport a diverse array of moleculesacross membranes, Although their detailed transport mechanism is largely unknown, they play important roles in detoxification processes, preventing water loss, transport of phytohormones, and secondary metabolites. This review provides insights into transport mechanisms of plant PDR transporters, their expression profiles, and multitude functions in plants.

Mechanism model for shale gas transport considering diffusion, adsorption/desorption and Darcy flow

To improve the understanding of the transport mechanism in shale gas reservoirs and build a theoretical basic for further researches on productivity evaluation and efficient exploitation, various gas transport mechanisms within a shale gas reservoir exploited by a horizontal well were thoroughly investigated, which took diffusion, adsorption/desorption and Darcy flow into account. The characteristics of diffusion in nano-scale pores in matrix and desorption on the matrix surface were both considered in the improved differential equations for seepage flow. By integrating the Langmuir isotherm desorption items into the new total dimensionless compression coefficient in matrix, the transport function and seepage flow could be formalized, simplified and consistent with the conventional form of diffusion equation. Furthermore, by utilizing the Laplace change and Sethfest inversion changes, the calculated results were obtained and further discussions indicated that transfer mechanisms were influenced by diffusion, adsorption/desorption. The research shows that when the matrix permeability is closed to magnitude of 10^-9D, the matrix flow only occurs near the surfacial matrix; as to the actual production, the central matrix blocks are barely involved in the production; the closer to the surface of matrix, the lower the pressure is and the more obvious the diffusion effect is; the behavior of adsorption/desorption can increase the matrix flow rate significantly and slow down the pressure of horizontal well obviously.

Research Advance on the Mechanism of Cadmium Transport in Rice

Soils in part of rice production areas have been seriously contaminated by cadmium （Cd）. Rice with high Cd content over allowable limit produced in these areas is widely concerned. Low accumulation varieties can remarkably decrease the Cd content in rice as well as the risk of food safety. The translocation of Cd either from soil to root system or from roots to aboveground parts is identified by a lot of ion transport proteins. Transport efficiency of Cd in some rice varieties is regulated by special metal ionic transporters. However, most varieties transport Cd by cation transporters or universal ionic transporters. Both the expression levels and time of gens controlling ionic transporters directly influence the Cd transport rates inside rice plant and the accumulation amount in different organs. Screening and utilizing specific Cd transport genes are the genetic basis of breeding low accumulation varieties.

Electric transport mechanism and magnetoresistance of La_(0.80)Sr_(0.15)Ag_(0.05)MnO_3/x(CuO)

The samples of La0.80Sr0.15Ag0.05MnO3/x（CuO） （x = 0, 0.05, 0.10, 0.15, 0.20） were prepared by the solid-state reaction method, and the structure of the sampies was detected by X-ray diffraction （XRD）, scanning electron microscope （SEM） equipped with energy dispersive spectroscopy （EDS）, electric transport mechanism, and magnetoresistance enhancement, and the temperature stability of magnetoresistance of the samples was studied through resistivity-temperature （ρ-T） curves, ρ-T fitted curves, and magnetoresistance-temperature （MR-T） curves. The results indicate that ρ-T data can be fitted by the formula ρ = ρ0 ＋ AT^2 very well, and the electric transport mechanism of all the samples in metal-like area is the scattering of single magneton upon spin electron; the magnetoresistance of composite samples is far larger than that of the original material, and the MR peak value of the sample with x = 0.20 is nearly 4 times as large as that of the sample with x = 0; composite samples have comparatively good temperature stability of magnetoresistance in the temperature range of 200-260 K, and the magnetoresistance of the sample with x = 0.15 almost does not change with temperature and keeps at （5.03 ± 0.20） % in the temperature range of 210-260 K.

Low-field mobility and carrier transport mechanism transition in nanoscale MOSFETs

This paper extends the flux scattering method to study the carrier transport property in nanoscale MOSFETs with special emphasis on the low-field mobility and the transport mechanism transition. A unified analytical expression for the low-field mobility is proposed, which covers the entire regime from drift-diffusion transport to quasi-ballistic transport in 1-D, 2-D and 3-D MOSFETs. Two key parameters, namely the long-channel low-field mobility （λ0） and the low-field mean free path （λ0）, are obtained from the experimental data, and the transport mechanism transition in MOSFETs is further discussed both experimentally and theoretically. Our work shows that λ0 is available to characterize the inherent transition of the carrier transport mechanism rather than the low-field mobility. The mobility reduces in the MOSFET with the shrinking of the channel length; however, λ0 is nearly a constant, and λ0 can be used as the ＂entry criterion＂ to determine whether the device begins to operate under quasi-ballistic transport to some extent.

Microstructure and electrical transport mechanisms of the Ca-doped LaMnO_(3) films grown on MgO substrate

La_(0.7)Ca_(0.3)MnO_(3)(LCMO)thin films have been grown on MgO substrate using the metal organic deposition process.The lattice mismatch between LCMO and MgO is relatively large around 8.14% imposing large inplane-tensile strain and out-of-plane-compressive strain on the film.Hence the structural,microstructural and electrical properties have been found to be strongly correlated to the strain degree and relaxation.Cross-section transmission electron microscopy observations demonstrate the presence of microstructural defects due to the large lattice mismatch between the LCMO and MgO.In addition to structural and microstructural defects,X-ray diffraction and Raman spectroscopy measurements show the existence of a minor phase of MnO in the film.Magnetization versus temperature measurement show a relatively low Curie temperature around 75 K.The electrical behavior is found to be semiconducting over a large temperature interval.The electrical transport mechanisms have been investigated using the small polaron hopping and variable range hopping models and correlated to their microstructural properties.

Stability and transepithelial transport of oligopeptide(KRQKYD)with hepatocyte-protective activity from Jinhua ham in human intestinal Caco-2 monolayer cells

The study evaluated the stability of an oligopeptide(Lys-Arg-Gln-Lys-Tyr-Asp,KRQKYD)and its transport mechanism by simulating gastrointestinal digestion and a model of human intestinal Caco-2 monolayer cells in vitro.In this study,the effects of environmental factors(temperature,pH and NaCl concentration)and simulated gastrointestinal digestion on the stability of KRQKYD were evaluated by indicators of the levels of alanine transaminase(ALT),aspartate transaminase(AST)and malondialdehyde(MDA)in an alcoholinduced hepatocyte injury model.The results showed that KRQKYD still maintained satisfactory hepatocyteprotective activity after treatment with different temperatures(20-80℃),pH(3.0-9.0),NaCl concentration(1%-7%)and simulated gastrointestinal digestion,which indicated that KRQKYD showed good stability to environmental factors and simulated gastrointestinal digestion.Furthermore,the intact KRQKYD could be absorbed in a model of Caco-2 monolayer cells with a P_(app)value of(9.70±0.53)×10^(-7)cm/s.Pretreatment with an energy inhibitor(sodium azide),a competitive peptide transporter inhibitor(Gly-Pro)and a transcytosis inhibitor wortmannin did not decrease the level of transepithelial KRQKYD transport,indicating that the transport mechanism of KRQKYD was not associated with energy dependent,vector mediated and endocytosis.The tight junction disruptor cytochalasin D significantly increased the level of transepithelial KRQKYD transport(P<0.05),suggesting that intact KRQKYD was absorbed by paracellular transport.

Lithium-ion transport in inorganic solid state electrolyte

An overview of ion transport in lithium-ion inorganic solid state electrolytes is presented, aimed at exploring and de signing better electrolyte materials. Ionic conductivity is one of the most important indices of the performance of inorganic solid state electrolytes. The general definition of solid state electrolytes is presented in terms of their role in a working cell （to convey ions while isolate electrons）, and the history of solid electrolyte development is briefly summarized. Ways of using the available theoretical models and experimental methods to characterize lithium-ion transport in solid state elec- trolytes are systematically introduced. Then the various factors that affect ionic conductivity are itemized, including mainly structural disorder, composite materials and interface effects between a solid electrolyte and an electrode. Finally, strategies for future material systems, for synthesis and characterization methods, and for theory and calculation are proposed, aiming to help accelerate the design and development of new solid electrolytes.

Sr-doping effects on conductivity,charge transport,and ferroelectricity of Ba_(0.7)La_(0.3)TiO_(3) epitaxial thin films

Sr-doped Ba_(0.7)La_(0.3)TiO_(3)(BSLTO)thin films are deposited by pulsed laser deposition,and their microstructure,conductivity,carrier transport mechanism,and ferroelectricity are systematically investigated.The x-ray diffraction measurements demonstrate that Sr-doping reduces the lattice constant of BSLTO thin films,resulting in the enhanced phonon energy in the films as evidenced by the Raman measurements.Resistivity-temperature and Hall effect measurements demonstrate that Sr can gradually reduce electrical resistivity while the electron concentration remains almost unchanged at high temperatures.For the films with semiconducting behavior,the charge transport model transforms from variable range hopping to small polaron hopping as the measurement temperature increases.The metalic conductive behaviors in the films with Sr=0.30,0.40 conform to thermal phonon scattering mode.The difference in charge transport behavior dependent on the A-site cation doping,is clarified.It is revealed that the increasing of phonon energy by Sr doping is responsible for lower activation energy of small polaron hopping,higher carrier mobility,and lower electrical resistivity.Interestingly,the piezoelectric force microscopy(PFM)results demonstrate that all the BSLTO films can exhibit ferroelectricity,especially for the room temperature metallic conduction film with Sr=0.40.These results imply that Sr-doping could be a potential way to explore ferroelectric metal materials for other perovskite oxides.

A multiscale 3D finite element analysis of fluid/solute transport in mechanically loaded bone

The transport of fluid, nutrients, and signaling molecules in the bone lacunar-canalicular system （LCS） is critical for osteocyte survival and function. We have applied the fluorescence recovery after photobleaching （FRAP） approach to quantify load-induced fluid and solute transport in the LCS in situ, but the measurements were limited to cortical regions 30-50 μm underneath the periosteum due to the constrains of laser penetration. With this work, we aimed to expand our understanding of load-induced fluid and solute transport in both trabecular and cortical bone using a multiscaled image-based finite element analysis （FEA） approach. An intact murine tibia was first re-constructed from microCT images into a three-dimensional （3D） linear elastic FEA model, and the matrix deformations at various locations were calculated under axial loading. A segment of the above 3D model was then imported to the biphasic poroelasticity analysis platform （FEBio） to predict load-induced fluid pressure fields, and interstitial solute/fluid flows through LCS in both cortical and trabecular regions. Further, secondary flow effects such as the shear stress and/or drag force acting on osteocytes, the presumed mechano-sensors in bone, were derived using the previously developed ultrastructural model of Brinkman flow in the canaliculi. The material properties assumed in the FEA models were validated against previously obtained strain and FRAP transport data measured on the cortical cortex. Our results demonstrated the feasibility of this computational approach in estimating the fluid flux in the LCS and the cellular stimulation forces （shear and drag forces） for osteocytes in any cortical and trabecular bone locations, allowing further studies of how the activation of osteocytes correlates with in vivo functional bone formation. The study provides a promising platform to reveal potential cellular mechanisms underlying the anabolic power of exercises and physical activities in treating patients with skeletal deficiencies.