Phosphine-free synthesis of FeTe2 nanoparticles and self-assembly into tree-like nanoarchitectures

Manipulating the self-assembly of transition metal telluride nanocrystals(NCs) creates opportunities for exploring new properties and device applications. Iron ditelluride(FeTe2) has recently emerged as a new class of magnetic semiconductor with three-dimensional(3D) magnetic ordering and narrow band gap structure, yet the self-assembly of FeTe2 NCs has not been achieved. Herein, the tree-like FeTe2 nanoarchitectures with orthorhombic crystal structure have been successfully synthesized by hot-injection solvent thermal approach using phosphine-free Te precursor. The morphology, size, and crystal structure have been investigated using transmission electron microscopy(TEM), high-resolution TEM(HRTEM),and powder x-ray diffraction(XRD). We study the formation process of tree-like FeTe2 NCs according to trace the change of the sample morphology with the reaction time. It was found that the FeTe2 nanoparticles show oriented aggregation and self-assembly behavior with the increase of reaction time, which is attributed to size-dependent magnetism properties of the samples. The magnetic interaction is thought to be the driving force of nanoparticle self-organization.

Stability of weighted spectral distribution in a pseudo tree-like network model

The comparison of networks with different orders strongly depends on the stability analysis of graph features in evolving systems. In this paper, we rigorously investigate the stability of the weighted spectral distribution（i.e., a spectral graph feature） as the network order increases. First, we use deterministic scale-free networks generated by a pseudo treelike model to derive the precise formula of the spectral feature, and then analyze the stability of the spectral feature based on the precise formula. Except for the scale-free feature, the pseudo tree-like model exhibits the hierarchical and small-world structures of complex networks. The stability analysis is useful for the classification of networks with different orders and the similarity analysis of networks that may belong to the same evolving system.

Analysis of thermal conductivity in tree-like branched networks

Asymmetric tree-like branched networks are explored by geometric algorithms. Based on the network, an analysis of the thermal conductivity is presented. The relationship between effective thermal conductivity and geometric structures is obtained by using the thermal-electrical analogy technique. In all studied cases, a clear behaviour is observed, where angle （δ,θ） among parent branching extended lines, branches and parameter of the geometric structures have stronger effects on the effective thermal conductivity. When the angle δ is fixed, the optical diameter ratio β＋ is dependent on angle θ. Moreover, γand m are not related to β＊. The longer the branch is, the smaller the effective thermal conductivity will be. It is also found that when the angle θ〈δ2, the higher the iteration m is, the lower the thermal conductivity will be and it tends to zero, otherwise, it is bigger than zero. When the diameter ratio β1 〈 0.707 and angle δ is bigger, the optimal k of the perfect ratio increases with the increase of the angle δ; when β1 〉 0.707, the optimal k decreases. In addition, the effective thermal conductivity is always less than that of single channel material. The present results also show that the effective thermal conductivity of the asymmetric tree-like branched networks does not obey Murray＇s law.

A Combinatorial Analysis of Tree-Like Sentences

A sentence over a finite alphabet A, is a finite sequence of non-empty words over A. More generally, we define a graphical sentence over A by attaching a non-empty word over A to each arrow and each loop of a connected directed graph (digraph, for short). Each word is written according to the direction of its corresponding arrow or loop. Graphical sentences can be used to encode sets of sentences in a compact way: the readable sentences of a graphical sentence being the sentences corresponding to directed paths in the digraph. We apply combinatorial equations on enriched trees and rooted trees, in the context of combinatorial species and Pólya theories, to analyze parameters in classes of tree-like sentences. These are graphical sentences constructed on tree-like digraphs.

Improvement of tree-like network constructal method for heat conduction optimization

The analysis of the “tree-like network” construct method has been repeated. The high effective conduction channel distribution has been optimized again, without the premise that the new order assembly construct must be assembled by the optimized last order construct. It is proved that the “tree-like network” construct method is faultiness. A more optimal construct is obtained, and when the thermal conductivity and the proportion of the two heat conduction materials are constant, the limit of the minimum heat resistance is derived. All these conclusions can be used to guide the engineering application.

Convenient synthesis of twin-Christmas tree-like PbWO4 microcrystals and their photocatalytic properties

Novel twin-Christmas tree-like PbWO4 microcrystals have been prepared via a convenient aqueous solution route at room temperature under the assistance of 13- cyclodextrin （13-CD）. The product was characterized by XRD, EDX, SEM, TEM, UV-vis and PL and BET techniques. It was found that 13-CD plays an important role in the forming of twin-Christmas tree-like PbWO4 microcrystals. A five-step growth mechanism was proposed to explain the formation of such twin-Christmas tree-like structures. The photocatalytic performance of PbWO4 microcrystals was evaluated by measuring the decomposition rate of methylene blue （MB） and malachite green （MG） solution under the UV irradiation, and the photocatalytic results indicated that as-prepared PbWO4 microcrystals exhibit good and versatile photocatalytic activity as well as excellent recyclability.

A Framework for Supporting Tree-Like Indexes on the Chord Overlay

With the explosive growth of data, to support efficient data management including queries and updates, the database system is expected to provide tree-like indexes, such as R-tree, M-tree, B＋-tree, according to different types of data. In the distributed environment, the indexes have to be scattered across the compute nodes to improve reliability and scalability. Indexes can speed up queries, but they incur maintenance cost when updates occur. In the distributed environment, each compute node maintains a subset of an index tree, so keeping the communication cost small is more crucial, or else it occupies lots of network bandwidth and the scalability and availability of the database system are affected. Further, to achieve the reliability and scalability for queries, several replicas of the index are needed, but keeping the replicas consistent is not straightforward. In this paper, we propose a framework supporting tree-like indexes, based on Chord overlay, which is a popular P2P structure. The framework dynamically tunes the number of replicas of index to balance the query cost and the update cost. Several techniques are designed to improve the efficiency of updates without the cost of performance of the queries. We implement M-tree and R-tree in our framework, and extensive experiments on real- life and synthetic datasets verify the efficiency and scalability of our framework.

Exact Boundary Controllability on a Tree-Like Network of Nonlinear Planar Timoshenko Beams

This paper concerns a system of equations describing the vibrations of a planar network of nonlinear Timoshenko beams. The authors derive the equations and appropriate nodal conditions, determine equilibrium solutions and, using the methods of quasilinear hyperbolic systems, prove that for tree-like networks the natural initial-boundary value problem admits semi-global classical solutions in the sense of Li [Li, T. T., Controllability and Observability for Quasilinear Hyperbolic Systems, AIMS Ser. Appl. Math., vol 3,American Institute of Mathematical Sciences and Higher Education Press, 2010] existing in a neighborhood of the equilibrium solution. The authors then prove the local exact controllability of such networks near such equilibrium configurations in a certain specified time interval depending on the speed of propagation in the individual beams.

Exact Boundary Observability of Unsteady Supercritical Flows in a Tree-Like Network of Open Canals

The author establishes the exact boundary observability of unsteady supercritical flows in a tree-like network of open canals with general topology. An implicit duality between the exact boundary controllability and the exact boundary observability is also given for unsteady supercritical flows.

字典积图的任意可分性

给定n个顶点的图G,对于满足∑_(i=1)^(k)n_(i)=n的任意一个正整数序列(n_(1),n_(2),…,n_(k)),如果都存在顶点集V(G)的划分(V_(1),V_(2),…,V_(k)),满足Vi导出的子图G[V_(i)]是连通的,并且|V_(i)|=n_(i),其中1≤i≤k,则称图G是任意可分图(简称为AP).两个图G和H的字典积图记为G?H,其顶点集为V(G)×V(H),(g,h)(g,h)是G?H的一条边当且仅当gg∈E(G)或者g=g且hh∈E(H).讨论了可迹图和任意可分图的字典积图的任意可分性,证明了对于最大度至多为n+1的树T,如果T有一条路P满足全部度数为(T)的顶点属于顶点集V(P),则字典积图T○Pn是任意可分图;如果G是一个可迹图且H是任意可分图,则图G○H是任意可分图;如果G=S(2,a,b)是一个满足2≤a≤b的任意可分星型树,则图G○G是任意可分图;如果G是哈密顿图且H是一个图,则G○H是任意可分图.

漳浦县文体中心体育场对拉非对称双拱大跨度屋盖结构设计

对漳浦县文体中心体育场对拉非对称双拱大跨度屋盖结构设计的难点、关键点进行了介绍。大屋盖双巨拱跨度达132m,非对称布置,与水平面呈1488°夹角,前拱中段无支承,受力机制复杂。为解决该问题,前、后拱之间设置对拉钢桁架,将“树杈”状拱脚、前拱、后拱、看台V形混凝土斜柱等组成一个自平衡体系。为满足建筑自然采光,大屋盖上覆膜材选用高透光率的ETFE膜材,通过沿钢桁架方向的预应力拉索保证其受力及稳定性。采用SAP2000和MIDAS Gen软件对该创新体系进行了弹性计算与屈曲分析,并利用ABAQUS软件进行了罕遇地震下的弹塑性动力响应分析和整体稳定临界荷载分析。分析结果表明,该体系的各项指标基本满足规范要求,具体良好的整体稳定性和抗震性能。

树形柱支撑铝合金屋盖结构综合施工技术

某医院总建筑面积约19.8万m^(2),门诊大厅采用钢制树形柱+单层铝合金屋盖结构体系,采用Z字形单层铝合金屋盖结构,东西向长度为104.963 m,南北向最宽处为47.427 m。为了营造轻松的视觉氛围,在南北主楼中间的位置采用铝合金门诊大厅“飘带”,形成一个以流畅曲面覆盖的公共大厅,作为患者踏入医院的起始点和主要交通空间。用流畅的曲面“飘带”作为院区的视觉中心,体现轻盈、现代、时尚的理念,空间通透明亮,极具现代感。虽然大跨度铝合金结构应用越来越多,但目前我国暂无Z字形大跨度钢铝组合屋盖结构安装案例可参考,因此研究轻材质大跨度铝合金屋盖结构综合施工技术具有重要的意义。

一种树状仿生结构的动力电池液冷板

为了使新能源汽车的动力电池在工作时保持在最佳工作温度范围内,本文提出了一种新型的树状结构通道的冷板。通过对比入口通道的数量来分析不同树状结构通道的冷板对电池的散热能力,并选出热性能较好的树状结构与传统直通型冷板进行对比。结果显示在树状结构上,随着入口通道数的增加电池的高温区域减少,冷板的散热均匀性也得到提升,对比传统直通型冷板的热性能有巨大提升。该散热结构可为其他液冷结构提供一定参考。

基于维生素K2、IGFBP-3、Omentin-1构建特发性矮小症儿童疗效预测模型的研究

目的探讨维生素K_(2)、胰岛素样生长因子结合蛋白3(IGFBP-3)、网膜素(Omentin-1)与特发性矮小症(ISS)儿童疗效的关系,并以此构建预测模型。方法选取2019-2021年济南市第二妇幼保健院收治的242例ISS儿童,均接受重组人生长激素(rhGH)治疗,根据治疗12个月后的疗效分为有效组和无效组。统计两组一般资料及维生素K2、IGFBP-3、Omentin-1水平,采用Logistic回归模型、决策树模型分析ISS儿童治疗疗效的影响因素,采用受试者工作特征(ROC)曲线分析两种模型预测效能。结果两组25-羟维生素D[25(OH)D]、甲状旁腺激素(PTH)、促甲状腺激素(TSH)、维生素K2、IGFBP-3、Omentin-1、rhGH剂量、每周户外运动时间比较,差异有统计学意义(P<0.05);PTH(OR=7.011,95%CI:2.456~20.014)、维生素K2(OR=0.605,95%CI:0.465~0.788)、IGFBP-3(OR=0.458,95%CI:0.321~0.654)、Omentin-1(OR=0.514,95%CI:0.389~0.679)、rhGH剂量(OR=0.563,95%CI:0.445~0.712)是ISS儿童治疗无效的影响因素(P<0.05);决策树模型显示,维生素K2、IGFBP-3、Omentin-1是ISS治疗疗效的影响因素,其中IGFBP-3的影响最为显著;ROC曲线结果显示,决策树模型、Logistic回归模型对预测ISS治疗无效的曲线下面积分别为0.922、0.908,模型分类效果均良好。结论ISS儿童的治疗疗效受维生素K2、IGFBP-3、Omentin-1等因素影响,且IGFBP-3影响最为显著,Logistic回归模型、决策树模型可互为补充,从不同方面为改善ISS儿童治疗疗效提供参考。

静电纺树枝状聚偏氟乙烯纳米纤维膜的制备

通过向聚偏氟乙烯(PVDF)纺丝液中添加有机支化盐四丁基六氟磷酸铵(TBAHP),采用一步静电纺丝法制备了PVDF树枝状纳米纤维膜。探讨了TBAHP添加量、静电纺丝工艺参数及溶剂体积比对纤维树枝状形貌的影响,同时研究了TBAHP添加量对纤维膜力学性能、孔径和孔隙率的影响。结果表明,TBAHP摩尔浓度为0.05 mol/L、N,N-二甲基甲酰胺(DMF)与丙酮(ACE)体积比为7:3、电压为27 kV、接收距离为12 cm时,制备的纳米纤维膜分支纤维较多,呈现形貌良好的树枝状结构,其断裂强度达4.93 MPa,远大于纯PVDF纳米纤维膜的1.82 MPa,孔径仅0.2μm,孔隙率达90%,在过滤、油水分离、电化学及膜蒸馏等领域具有很好的应用前景。

树形偏序自动机的同步问题

对于给定的自动机,能将所有状态都转换到同一状态的输入字被称为该自动机的同步字.有同步字的自动机称为同步自动机.同步自动机已广泛应用于系统测试、编码、工业自动化、机器人技术及生物计算等领域.同步自动机研究的基本问题是自动机的同步问题(含同步性判定问题和同步字查找问题),最具挑战性的课题是证实或证伪关于同步自动机最短同步字长度的Cerny猜想.偏序自动机是具有一个相容偏序结构的自动机.同步自动机的研究从理论上可以归结到同步偏序自动机的研究上,因此,Cerny猜想成立当且仅当其对所有的偏序自动机都成立.现有的研究工作表明,Cerny猜想只对于一些结构较为特殊的偏序自动机类,包括单演自动机、广义单演自动机以及有界偏序自动机是成立的.作为偏序自动机的另一类特殊情形,本文研究关于树形偏序自动机的同步性检测问题,同步字查找问题以及Cerny猜想,主要贡献包括:讨论了树形偏序自动机与现有的几类偏序自动机之间的关系,说明了树形偏序自动机包含所有单演自动机和有界偏序自动机,并且不同于广义单演自动机类;给出了树形偏序自动机的同步性判定和同步字计算方法,特别地,证明了Cerny猜想对树形偏序自动机成立;设计了树形偏序自动机的专用同步算法,该算法的时间复杂度低于通用的自动机同步算法,且对任意n-状态同步树形偏序自动机都可以找到长度不超过(n-1)^(2)的同步字.

锂离子电池仿生树状通道液冷板数值优化

目的 将锂离子电池在5C放电倍率、环境温度298.15K的工作条件下的最大温度和温差控制在适宜范围内。方法 在锂电池两侧插入带通道的仿生树状液冷板,建立电池模块液冷散热模型。首先验证液冷数值模型的准确性,然后通过正交试验设计研究分支流道角度、入口流速、分支流道宽度和液冷板厚度对冷板散热性能的影响,并通过极差分析对4种影响因素进行重要程度排序,确定最佳的参数组合。结果 经优化后,锂电池的最高温度为302.4 K、温差为3.4 K,满足设计要求,但冷却剂在流动循环过程中存在泄漏风险。结论 提出的树状液冷板满足锂电池热管理性能的要求,优化后电池模块的表面温度在安全范围内,同时电池的温度均匀性显著提高。应选择导热系数高的冷板材料,并注重冷板结构设计,防止冷却剂泄漏。

基于BiLSTM-CRF的中文分词和词性标注联合方法

针对中文分词、词性标注等序列标注任务,提出结合双向长短时记忆模型、条件随机场模型和马尔可夫族模型或树形概率构建的中文分词和词性标注联合方法。隐马尔可夫词性标注方法忽略了词本身到词性的发射概率。在基于马尔可夫族模型或树形概率的词性标注中,当前词的词性不但与前面词的词性有关,而且与当前词本身有关。使用联合方法有助于使用词性标注信息实现分词,有机地将两者结合起来有利于消除歧义和提高分词、词性标注任务的准确率。实验结果表明:本文使用的中文分词和词性标注联合方法相比于通常的双向长短时记忆模型−条件随机场分词模型能够大幅度提高分词的准确率,并且相比于传统的隐马尔可夫词性标注方法能够大幅度提高词性标注的准确率。

基于BERT-BiLSTM-CRF的中文分词和词性标注联合方法

针对中文分词、词性标注等序列标注任务,本文提出了结合BERT语言模型、BiLSTM(双向长短时记忆模型)、CRF(条件随机场模型)和马尔可夫族模型(MFM)或树形概率(TLP)构建的中文分词和词性标注联合方法.隐马尔可夫(HMM)词性标注方法忽略了词本身到词性的发射概率,而在利用树形概率或马尔可夫族统计模型的词性标记中,一个词的词性不仅和该词前一个词的词性关联,且与该词自身关联.使用联合方法有助于使用词性信息帮助分词,将两者紧密结合能够帮助消除歧义和改进分词、词性标记的性能.实验结果表明本文使用的中文分词和词性标注联合方法与普通的BiLSTM-CRF分词算法相比,可以明显提升分词性能,而且相比于通常的隐马尔可夫词性标注方法能够大幅度提高词性标注的准确率.

类型教育视域下高职公共英语课程思政改革

职业教育和普通教育作为不同的教育类型,其区别主要表现在培养目标、培养对象、培养模式上。应然,高职教育的课程思政改革也要区别于普通教育,主要表现在产教融合、知行合一、德技并修等方面。高职公共英语作为通识必修课程,在类型教育视域下进行的课程思政改革,可深耕其职业教育特点,从教学内容与设计、教学方法与实施、教学评价与考核着手,构建其特色课程思政改革的树状教学模式。