The effects of 4 wt% rhenium （Re） addition on isothermal oxidation behavior of Tribaloy T-800 alloy have been studied at 800 °C and 1 000 °C in air. At 800 °C,T-800 shows nonuniform oxidation between ...The effects of 4 wt% rhenium （Re） addition on isothermal oxidation behavior of Tribaloy T-800 alloy have been studied at 800 °C and 1 000 °C in air. At 800 °C,T-800 shows nonuniform oxidation between dendritic and eutectic areas. Re addition clearly promotes the nonuniform oxidation,leading to considerably higher mass gains than that of T-800 at this temperature. At 1 000 °C exposure,the thickness of scale on T-800 increases significantly,accompanied by severe scale spallation during cooling to room temperature. On the contrary,T-800Re shows a marked decrease of oxide growth rate compared to the linear one of T-800 at 1 000 °C. The scale adhesion is also improved with Re addition at this higher temperature. Therefore,the role of Re depends on the exposure temperature. Re addition gives high oxidation rate at 800 °C,however,the excellent oxidation resistance is obtained by the addition of Re at a higher temperature of 1 000 °C.展开更多
The investigated alloys are newly developed Tribaloy alloys with enhanced crack and oxidation resistance over the traditional Tribaloy alloys.The cyclic oxidation performance and effects of complex oxides on the hardn...The investigated alloys are newly developed Tribaloy alloys with enhanced crack and oxidation resistance over the traditional Tribaloy alloys.The cyclic oxidation performance and effects of complex oxides on the hardness of cobaltbased Tribaloy alloys T-401(hypoeutectic)and T-900(hypereutectic)were assessed.The results showed that T-900 alloy has a lower oxidation rate as compared to T-401 alloy at 800 and 1000℃,which attributed to the formation of dense continuous Cr2O3 layer with an upper thinner continuous layer of CoCr2O4 and NiCr2O4 oxides.At 1000℃,T-401 alloy exhibited poor oxidation resistance due to severe spallation after 3 cycles(45 h).After oxidation,T-900 alloy exhibits 98%and 18%lower mass gain than T-401 alloy at 1000 and 800℃,respectively.For T-900 alloy,relationship between mass gain and thickness of oxide layer revealed that mass will increase 0.162 mg/cm2 for every 1-μm increase in the oxides thickness.Internal SiO2 oxide was observed at 800 and 1000℃for both alloys.However,the extent of internal Si oxides increased with increasing oxidation temperature from 800 to 1000℃.Consequently,internal oxidation of Si led to the formation of Laves phase-depleted region near oxide/alloy interface in T-900 alloy at 1000℃.Thus,hardness of T-900 alloy decreased from 618 to 392 HV beneath the oxide/alloy interface at 1000℃,whereas hardness of T-900 and T-401 alloys after cyclic oxidation test at 800℃increased from 618 to 855 and 519 to 685 HV,respectively.展开更多
文摘The effects of 4 wt% rhenium （Re） addition on isothermal oxidation behavior of Tribaloy T-800 alloy have been studied at 800 °C and 1 000 °C in air. At 800 °C,T-800 shows nonuniform oxidation between dendritic and eutectic areas. Re addition clearly promotes the nonuniform oxidation,leading to considerably higher mass gains than that of T-800 at this temperature. At 1 000 °C exposure,the thickness of scale on T-800 increases significantly,accompanied by severe scale spallation during cooling to room temperature. On the contrary,T-800Re shows a marked decrease of oxide growth rate compared to the linear one of T-800 at 1 000 °C. The scale adhesion is also improved with Re addition at this higher temperature. Therefore,the role of Re depends on the exposure temperature. Re addition gives high oxidation rate at 800 °C,however,the excellent oxidation resistance is obtained by the addition of Re at a higher temperature of 1 000 °C.
文摘The investigated alloys are newly developed Tribaloy alloys with enhanced crack and oxidation resistance over the traditional Tribaloy alloys.The cyclic oxidation performance and effects of complex oxides on the hardness of cobaltbased Tribaloy alloys T-401(hypoeutectic)and T-900(hypereutectic)were assessed.The results showed that T-900 alloy has a lower oxidation rate as compared to T-401 alloy at 800 and 1000℃,which attributed to the formation of dense continuous Cr2O3 layer with an upper thinner continuous layer of CoCr2O4 and NiCr2O4 oxides.At 1000℃,T-401 alloy exhibited poor oxidation resistance due to severe spallation after 3 cycles(45 h).After oxidation,T-900 alloy exhibits 98%and 18%lower mass gain than T-401 alloy at 1000 and 800℃,respectively.For T-900 alloy,relationship between mass gain and thickness of oxide layer revealed that mass will increase 0.162 mg/cm2 for every 1-μm increase in the oxides thickness.Internal SiO2 oxide was observed at 800 and 1000℃for both alloys.However,the extent of internal Si oxides increased with increasing oxidation temperature from 800 to 1000℃.Consequently,internal oxidation of Si led to the formation of Laves phase-depleted region near oxide/alloy interface in T-900 alloy at 1000℃.Thus,hardness of T-900 alloy decreased from 618 to 392 HV beneath the oxide/alloy interface at 1000℃,whereas hardness of T-900 and T-401 alloys after cyclic oxidation test at 800℃increased from 618 to 855 and 519 to 685 HV,respectively.
