Tris缓冲体系下,通过在NiTi表面包裹聚多巴胺薄膜来提高其耐腐蚀性能。研究分别在10mMTris pH=8.5和50mMTris p H=8.5条件下,改变多巴胺的初始浓度,考察了成膜后的NiTi耐蚀性能。结果表明,10mM的Tris体系下,聚多巴胺修饰NiTi的耐蚀性能...Tris缓冲体系下,通过在NiTi表面包裹聚多巴胺薄膜来提高其耐腐蚀性能。研究分别在10mMTris pH=8.5和50mMTris p H=8.5条件下,改变多巴胺的初始浓度,考察了成膜后的NiTi耐蚀性能。结果表明,10mM的Tris体系下,聚多巴胺修饰NiTi的耐蚀性能并不是随着多巴胺的浓度增加而增强;相比之下,50mM的Tris体系下,聚多巴胺修饰NiTi的耐腐蚀性能随着多巴胺浓度的增加而增强。展开更多
The ring-opening polymerization of e-caprolactone (CL) initiated by novel single lanthanide tris(4-tert-butylphenolate)s [Ln(OTBP)3] is reported. Single-component La(OTBP)3 can effectively prepare polycaprolactone (PC...The ring-opening polymerization of e-caprolactone (CL) initiated by novel single lanthanide tris(4-tert-butylphenolate)s [Ln(OTBP)3] is reported. Single-component La(OTBP)3 can effectively prepare polycaprolactone (PCL) with over 90% yield and viscosity average molecular weight about 60 x 10 under quite mild conditions: molar ratio of CL to initiator is 1000, 60 C, 2 h in toluene. Mechanism study indicates that the monomer inserts into the growing chain via the break of acyl-oxygen bond of CL.展开更多
The polymerization of n-hexyl isocyanate(HNCO) was carried out in the presence of a novel single initiator, rare earth tris(2,6-di-tert-butyl-4-methylphenolate)[Ln(OAr)_3]. The influences of reaction conditions such a...The polymerization of n-hexyl isocyanate(HNCO) was carried out in the presence of a novel single initiator, rare earth tris(2,6-di-tert-butyl-4-methylphenolate)[Ln(OAr)_3]. The influences of reaction conditions such as the monomer concentration, the polymerization temperature and time, and the types of solvents on the polymerization of HNCO were studied. Polymerizations of phenyl, i-propyl, p-tolyl, n-butyl and n-octyl isocyanates with La(OAr)_3 were also examined.展开更多
The extraction of Eu(Ⅲ) with β-diketone, HA, and monodentate or bidentate Lewis bases, B, into chloroform and the luminescence properties of the extracted species were studied. Pivaloyltrifluoroacetone, Hpta, and ...The extraction of Eu(Ⅲ) with β-diketone, HA, and monodentate or bidentate Lewis bases, B, into chloroform and the luminescence properties of the extracted species were studied. Pivaloyltrifluoroacetone, Hpta, and 2-thenoyltfifluoroacetone, Htta, were used as the β-diketones. The Lewis bases, B, were tetraethyl methylene diphosphonate, POPO, which was bidentate, and diethyl benzylphosphonate, PhPO which was monodentate. Based on the extraction data, the stability constants, log β, of the first complexes between tfis(β-diketonato)Eu(Ⅲ) and the phosphonate, EuA3B, were determined to be 6.0 for the POPO complex and 3.40 for the PhPO complex. The Eu(Ⅲ) luminescence intensity in the EuA3POPO was larger than EuA3 where A was either pta or tta at similar concentrations of Eu(Ⅲ), while that in Eu(pta)3PhPO was stronger than EuA3; however, in Eu(tta)3PhPO, it was weaker than Eu(tta)3. The POPO functions as a sensitizer, and the PhPO functions as a quencher for the tta chelate and as a sensitizer for the pta chelate. From the lifetime and quantum yield, φ, of the Eu(Ⅲ) luminescence in the complexes as well as the observation of the extractability of Eu(Ⅲ) with the Hpta and the phosphonates and of the luminescence spectra of the complexes, it was confirmed that the extraction of Eu(Ⅲ) was remarkably enhanced with a β-diketonate and a strong Lewis base, and also the ternary complex that was formed as the extracted species, showed luminescence enhancement. This phenomenon may be due the formation of a strong bond between the Eu(Ⅲ) and the strong Lewis base leading to more hydrophobicity in the extracted species and also to more effective energy transfer from the Lewis base to the Eu(Ⅲ). It was not significant whether the donor atoms were N or O.展开更多
Tris(trimethylsilyl)borate(TMSB) has been intensively studied to improve the performances of lithiumion batteries. However, it is still an interesting issue needed to be resolved for the research on the Li^(+) solvati...Tris(trimethylsilyl)borate(TMSB) has been intensively studied to improve the performances of lithiumion batteries. However, it is still an interesting issue needed to be resolved for the research on the Li^(+) solvation structure affected by TMSB additive. Herein, the electrochemical tests, quantum chemistry calculations, potential-resolved in-situ electrochemical impedance spectroscopy measurements and surface analyses were used to explore the effects of Li^(+) solvation structure with TMSB additive on the formation of the cathode electrolyte interface(CEI) film in LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/Li half cells. The results reveal that the TMSB additive is easy to complex with Li^(+) ion, thus weaken the intermolecular force between Li^(+) ions and ethylene carbonate solvent, which is benefit for the cycle performance. Besides, the changed Li^(+) solvation structure results in a thin and dense CEI film containing compounds with Si–O and B–O bonds which is favorable to the transfer of Li^(+) ions. As a result, the performances of the LNCM811/Li half cells are effectively improved. This research provides a new idea to construct a high-performance CEI film by adjusting the Li^(+) solvation structures.展开更多
The ring-opening polymerization of 1,4-dioxan-2-one (PDO) was carried out by lanthanum tris(2,6-di-tert-butyl-4- methylphenolate) (La(OAr)3) as novel single component initiaLor. The influences of polymerizatio...The ring-opening polymerization of 1,4-dioxan-2-one (PDO) was carried out by lanthanum tris(2,6-di-tert-butyl-4- methylphenolate) (La(OAr)3) as novel single component initiaLor. The influences of polymerization reaction temperature and the molar ratio of monomer to initiator on the monomer conversion and molecular weight of poly(1,4-dioxan-2-one) (PPDO) were explored. PPDO with high viscosity average molecular weight of 1.95×10^5 can be prepared at 40℃ when [PDO]/ [La(OAr)3] molar ratio was 800. Mechanism investigation shows that the polymerization proceeds through a "coordination- insertion" mechanism with selective rupture of acyl-oxygen be,nd of PDO.展开更多
The optical properties of N,N’-bis (Inaphthyl)N,N’-diphenyl-1,1’-biphenyl-4,4’-diamine (NPB) and tris (8-hydroxyquinolinato) aluminum (Alq3) organic materials used as hole transport and electron transport layers i...The optical properties of N,N’-bis (Inaphthyl)N,N’-diphenyl-1,1’-biphenyl-4,4’-diamine (NPB) and tris (8-hydroxyquinolinato) aluminum (Alq3) organic materials used as hole transport and electron transport layers in organic light-emitting devices (OLED) have been investigated. The NPB and Alq3 layers were prepared using thermal evaporation method. The results show that the energy band gap of Alq3 is thickness independence while the energy band gap of NPB decreases with the increasing of sample thickness. For the case of photoluminescence the Alq3 with thickness of 84 nm shows the highest relative intensity peak at 510 nm.展开更多
The reaction of iron(Ⅲ)anions,FeCl 3 and Fe 2(SO 4)3 with tris(hydroxymethyl)aminomethane(Tris)in a 1∶2 molar ratio affords the new coordination compounds NH 4[Fe 2(Tris)2(H 2O)4(SO 4)](Ⅰ)and NH 4[Fe(Tris)2(H 2O)2]...The reaction of iron(Ⅲ)anions,FeCl 3 and Fe 2(SO 4)3 with tris(hydroxymethyl)aminomethane(Tris)in a 1∶2 molar ratio affords the new coordination compounds NH 4[Fe 2(Tris)2(H 2O)4(SO 4)](Ⅰ)and NH 4[Fe(Tris)2(H 2O)2](Ⅱ).These compounds were characterized by elemental analysis,and their molecular structures were determined by spectroscopic methods(infrared and electronic spectra),magnetic susceptibility,and molar conductivity measurements,and further corroborated by thermo gravimetric analysis and its differential(TGA/DrTGA).According to the experimental data,the complexes can be characterized in the solid state as mono-and binuclear,with a distorted octahedral stereochemistry.The distorted octahedral stereochemistry adopted by the complexes was confirmed by the magnetic susceptibility measurement of NH 4[Fe 2(Tris)2(H 2O)4(SO 4)],which consists of a six-coordinate iron atoms in a distorted octahedral environment constructed from four O atoms(two Tris molecules),two O atoms from the loosely associated SO 4 coordinated ligand,and O,N of second Tris molecule with occupying by four oxygen atoms of coordinated water molecules.Regarding,NH 4[Fe(Tris)2(H 2O)2]complex the mono iron atom is surrounded by six oxygen atoms as four by two Tris molecules and two coordinated water molecules in axial form.Antibacterial and anticancer activities of the complexes were studied and the complexes were screened against bacteria,colorectal adenocarcinoma(Caco-2)and breast cancer(Mcf-7)cell lines.展开更多
Synthesis and characterization of NMR T-1 relaxation properties of the title complexes and several transition metal-EDTA-bis[ tris(hydroxymethyl methylamide] complexes were performed for searching new contrast agents ...Synthesis and characterization of NMR T-1 relaxation properties of the title complexes and several transition metal-EDTA-bis[ tris(hydroxymethyl methylamide] complexes were performed for searching new contrast agents for magnetic resonance imaging(MRI). The ligands, abbr. to DTPA-BTris and EDTA-BTris, were obtained by modifying DTPA and EDTA with tris(hydroxymethyl) aminomethane. It was found that the relaxivities of solutions of the modified complexes in vitro are correspondingly greater than those of the parent complexes. For GdDTPA-BTris, MnEDTA-BTris, and FeEDTA-BTris, the relaxometry of lattice relaxation(R-1) is 5.4, 3.1, and 1.9 L.mmol(-1).s(-1) vs. 5.2, 2.8 and 1.7 L.mmol(-1).s(-1) for GdDTPA, MnEDTA, and FeEDTA, respectively. Additionally, the present complexes have the favorable properties such as high water solubility and chemical stability required of clinical useful contrast agent.展开更多
Detecting protein expression levels in organisms exposed to environmental pollutants can help us understand the action mechanism of toxicity. In the present study, adult female Sprague-Dawley (SD) rats received a cons...Detecting protein expression levels in organisms exposed to environmental pollutants can help us understand the action mechanism of toxicity. In the present study, adult female Sprague-Dawley (SD) rats received a consecutive intraperitoneal injection of tris(2,3-dibromopropyl) isocyanurate (TBC) for seven days, and the ^16O/^18O labeling comparative proteomic approach was used to study the change of liver proteome in these rats. Thirty six differential proteins were identified between the control group and the high-dose-exposed group (8 mg/kg), of which, twenty eight proteins were down-regulated and eight proteins were up-regulated. Bioinformatics analysis revealed that most of the differential proteins were related with the metabolic and cellular processes. In addition, the contents of malondialdehyde (MDA), catalase (CAT), and glutathione (GSH) in liver were measured to evaluate the oxidative stress status induced by TBC exposure. Together, these findings showed that TBC might be toxic to liver by disrupting metabolic process and apoptosis. The results might provide a better insight into the mechanism of toxicity induced by TBC.展开更多
Several kinds of racemic naproxen ester were successfully separated on CTMB chiral stationary phase with hexane-ethanol (98:2, vol./vol.) as the mobile phase. The influence of mobile phase composition and structure o...Several kinds of racemic naproxen ester were successfully separated on CTMB chiral stationary phase with hexane-ethanol (98:2, vol./vol.) as the mobile phase. The influence of mobile phase composition and structure of racemic naproxen ester on chiral separation was studied and the chiral recognition mechanism of CTMB was discussed.展开更多
A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-...A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-one (PDO) in bulk.The influence of reaction conditions,such as polymerization temperature,the molar ratio of the monomer to initiator (M/I) on the monomer conversion and molecular weight of the polymer has been investigated.Poly(1,4-dioxan-2-one) with a viscosity-average molecular weight (My) o...展开更多
The influence of tris(trimethylsilyl) borate (TMSB) as an electrolyte additive on lithium ion cells have been studied using Li/LiCo1/3Ni1/3Mn1/3O2 cells at a higher voltage, 4.7 V versus Li/Li+. 1 wt% TMSB can dramati...The influence of tris(trimethylsilyl) borate (TMSB) as an electrolyte additive on lithium ion cells have been studied using Li/LiCo1/3Ni1/3Mn1/3O2 cells at a higher voltage, 4.7 V versus Li/Li+. 1 wt% TMSB can dramatically reduce the capacity fading that occurs during cycling at room temperature (RT) and elevated temperature (60 degrees C). After 150 cycles at 1 C rate (1 C= 278 mAh/g), the capacity retention of Li/LiCo1/3Ni1/3Mn1/3O2 is up to near 72% in the electrolyte with TMSB added, while it is only about 35% in the baseline electrolyte. The electrochemical behaviors, the surface chemistry and structure of Li/LiCo1/3Ni1/3Mn1/3O2 cathode are characterized with charge/discharge test, linear sweep voltammetry (LSV), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), thermal gravimetric analyses (TGA), scanning electron microscope (SEM) and transmission electron microscopy (TEM). These analysis results reveal that the addition of TMSB is able to protectively modify the electrode CEI film in a manner that suppresses electrolyte decomposition and degradation of electrode surface structure, even though at both a higher voltage of 4.7 V and an elevated temperature of 60 degrees C. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.展开更多
文摘Tris缓冲体系下,通过在NiTi表面包裹聚多巴胺薄膜来提高其耐腐蚀性能。研究分别在10mMTris pH=8.5和50mMTris p H=8.5条件下,改变多巴胺的初始浓度,考察了成膜后的NiTi耐蚀性能。结果表明,10mM的Tris体系下,聚多巴胺修饰NiTi的耐蚀性能并不是随着多巴胺的浓度增加而增强;相比之下,50mM的Tris体系下,聚多巴胺修饰NiTi的耐腐蚀性能随着多巴胺浓度的增加而增强。
基金supported by the National Natural Science Foundation of China.(Grant No.20174033 and 20254001)the Special Found for Major State Basic Research Project(Grant No.G1999064801)the Committee of Science and Technology of Zhejiang Province.
文摘The ring-opening polymerization of e-caprolactone (CL) initiated by novel single lanthanide tris(4-tert-butylphenolate)s [Ln(OTBP)3] is reported. Single-component La(OTBP)3 can effectively prepare polycaprolactone (PCL) with over 90% yield and viscosity average molecular weight about 60 x 10 under quite mild conditions: molar ratio of CL to initiator is 1000, 60 C, 2 h in toluene. Mechanism study indicates that the monomer inserts into the growing chain via the break of acyl-oxygen bond of CL.
文摘The polymerization of n-hexyl isocyanate(HNCO) was carried out in the presence of a novel single initiator, rare earth tris(2,6-di-tert-butyl-4-methylphenolate)[Ln(OAr)_3]. The influences of reaction conditions such as the monomer concentration, the polymerization temperature and time, and the types of solvents on the polymerization of HNCO were studied. Polymerizations of phenyl, i-propyl, p-tolyl, n-butyl and n-octyl isocyanates with La(OAr)_3 were also examined.
基金a Grant-in-Aid for Scientific Research(C), (No19550096) from the Ministry of Education, Science, Sports, and Culture, Japan
文摘The extraction of Eu(Ⅲ) with β-diketone, HA, and monodentate or bidentate Lewis bases, B, into chloroform and the luminescence properties of the extracted species were studied. Pivaloyltrifluoroacetone, Hpta, and 2-thenoyltfifluoroacetone, Htta, were used as the β-diketones. The Lewis bases, B, were tetraethyl methylene diphosphonate, POPO, which was bidentate, and diethyl benzylphosphonate, PhPO which was monodentate. Based on the extraction data, the stability constants, log β, of the first complexes between tfis(β-diketonato)Eu(Ⅲ) and the phosphonate, EuA3B, were determined to be 6.0 for the POPO complex and 3.40 for the PhPO complex. The Eu(Ⅲ) luminescence intensity in the EuA3POPO was larger than EuA3 where A was either pta or tta at similar concentrations of Eu(Ⅲ), while that in Eu(pta)3PhPO was stronger than EuA3; however, in Eu(tta)3PhPO, it was weaker than Eu(tta)3. The POPO functions as a sensitizer, and the PhPO functions as a quencher for the tta chelate and as a sensitizer for the pta chelate. From the lifetime and quantum yield, φ, of the Eu(Ⅲ) luminescence in the complexes as well as the observation of the extractability of Eu(Ⅲ) with the Hpta and the phosphonates and of the luminescence spectra of the complexes, it was confirmed that the extraction of Eu(Ⅲ) was remarkably enhanced with a β-diketonate and a strong Lewis base, and also the ternary complex that was formed as the extracted species, showed luminescence enhancement. This phenomenon may be due the formation of a strong bond between the Eu(Ⅲ) and the strong Lewis base leading to more hydrophobicity in the extracted species and also to more effective energy transfer from the Lewis base to the Eu(Ⅲ). It was not significant whether the donor atoms were N or O.
基金supported by the National Natural Science Foundation of China(51962019)the Natural Science Foundation of Gansu Province(20JR5RA469)+1 种基金the Education Department of Gansu Province:"Star of Innovation"Project for Outstanding Graduate Students(2021CXZX-455)the Lanzhou University of Technology Hongliu First-class Discipline Construction Program。
文摘Tris(trimethylsilyl)borate(TMSB) has been intensively studied to improve the performances of lithiumion batteries. However, it is still an interesting issue needed to be resolved for the research on the Li^(+) solvation structure affected by TMSB additive. Herein, the electrochemical tests, quantum chemistry calculations, potential-resolved in-situ electrochemical impedance spectroscopy measurements and surface analyses were used to explore the effects of Li^(+) solvation structure with TMSB additive on the formation of the cathode electrolyte interface(CEI) film in LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)/Li half cells. The results reveal that the TMSB additive is easy to complex with Li^(+) ion, thus weaken the intermolecular force between Li^(+) ions and ethylene carbonate solvent, which is benefit for the cycle performance. Besides, the changed Li^(+) solvation structure results in a thin and dense CEI film containing compounds with Si–O and B–O bonds which is favorable to the transfer of Li^(+) ions. As a result, the performances of the LNCM811/Li half cells are effectively improved. This research provides a new idea to construct a high-performance CEI film by adjusting the Li^(+) solvation structures.
基金This work was financially supported by the financial support of National Natural Science Foundation of China (No. 20434020)
文摘The ring-opening polymerization of 1,4-dioxan-2-one (PDO) was carried out by lanthanum tris(2,6-di-tert-butyl-4- methylphenolate) (La(OAr)3) as novel single component initiaLor. The influences of polymerization reaction temperature and the molar ratio of monomer to initiator on the monomer conversion and molecular weight of poly(1,4-dioxan-2-one) (PPDO) were explored. PPDO with high viscosity average molecular weight of 1.95×10^5 can be prepared at 40℃ when [PDO]/ [La(OAr)3] molar ratio was 800. Mechanism investigation shows that the polymerization proceeds through a "coordination- insertion" mechanism with selective rupture of acyl-oxygen be,nd of PDO.
文摘The optical properties of N,N’-bis (Inaphthyl)N,N’-diphenyl-1,1’-biphenyl-4,4’-diamine (NPB) and tris (8-hydroxyquinolinato) aluminum (Alq3) organic materials used as hole transport and electron transport layers in organic light-emitting devices (OLED) have been investigated. The NPB and Alq3 layers were prepared using thermal evaporation method. The results show that the energy band gap of Alq3 is thickness independence while the energy band gap of NPB decreases with the increasing of sample thickness. For the case of photoluminescence the Alq3 with thickness of 84 nm shows the highest relative intensity peak at 510 nm.
基金The Deanship of Scientific Research at Princess Nourah bint Abdulrahman University,through the Research Groups Program(RGP-1440-0001)(2)。
文摘The reaction of iron(Ⅲ)anions,FeCl 3 and Fe 2(SO 4)3 with tris(hydroxymethyl)aminomethane(Tris)in a 1∶2 molar ratio affords the new coordination compounds NH 4[Fe 2(Tris)2(H 2O)4(SO 4)](Ⅰ)and NH 4[Fe(Tris)2(H 2O)2](Ⅱ).These compounds were characterized by elemental analysis,and their molecular structures were determined by spectroscopic methods(infrared and electronic spectra),magnetic susceptibility,and molar conductivity measurements,and further corroborated by thermo gravimetric analysis and its differential(TGA/DrTGA).According to the experimental data,the complexes can be characterized in the solid state as mono-and binuclear,with a distorted octahedral stereochemistry.The distorted octahedral stereochemistry adopted by the complexes was confirmed by the magnetic susceptibility measurement of NH 4[Fe 2(Tris)2(H 2O)4(SO 4)],which consists of a six-coordinate iron atoms in a distorted octahedral environment constructed from four O atoms(two Tris molecules),two O atoms from the loosely associated SO 4 coordinated ligand,and O,N of second Tris molecule with occupying by four oxygen atoms of coordinated water molecules.Regarding,NH 4[Fe(Tris)2(H 2O)2]complex the mono iron atom is surrounded by six oxygen atoms as four by two Tris molecules and two coordinated water molecules in axial form.Antibacterial and anticancer activities of the complexes were studied and the complexes were screened against bacteria,colorectal adenocarcinoma(Caco-2)and breast cancer(Mcf-7)cell lines.
文摘Synthesis and characterization of NMR T-1 relaxation properties of the title complexes and several transition metal-EDTA-bis[ tris(hydroxymethyl methylamide] complexes were performed for searching new contrast agents for magnetic resonance imaging(MRI). The ligands, abbr. to DTPA-BTris and EDTA-BTris, were obtained by modifying DTPA and EDTA with tris(hydroxymethyl) aminomethane. It was found that the relaxivities of solutions of the modified complexes in vitro are correspondingly greater than those of the parent complexes. For GdDTPA-BTris, MnEDTA-BTris, and FeEDTA-BTris, the relaxometry of lattice relaxation(R-1) is 5.4, 3.1, and 1.9 L.mmol(-1).s(-1) vs. 5.2, 2.8 and 1.7 L.mmol(-1).s(-1) for GdDTPA, MnEDTA, and FeEDTA, respectively. Additionally, the present complexes have the favorable properties such as high water solubility and chemical stability required of clinical useful contrast agent.
基金Supported by the Basic Research Foundation of Beijing Institute of Technology(20141642002)
文摘Detecting protein expression levels in organisms exposed to environmental pollutants can help us understand the action mechanism of toxicity. In the present study, adult female Sprague-Dawley (SD) rats received a consecutive intraperitoneal injection of tris(2,3-dibromopropyl) isocyanurate (TBC) for seven days, and the ^16O/^18O labeling comparative proteomic approach was used to study the change of liver proteome in these rats. Thirty six differential proteins were identified between the control group and the high-dose-exposed group (8 mg/kg), of which, twenty eight proteins were down-regulated and eight proteins were up-regulated. Bioinformatics analysis revealed that most of the differential proteins were related with the metabolic and cellular processes. In addition, the contents of malondialdehyde (MDA), catalase (CAT), and glutathione (GSH) in liver were measured to evaluate the oxidative stress status induced by TBC exposure. Together, these findings showed that TBC might be toxic to liver by disrupting metabolic process and apoptosis. The results might provide a better insight into the mechanism of toxicity induced by TBC.
文摘Several kinds of racemic naproxen ester were successfully separated on CTMB chiral stationary phase with hexane-ethanol (98:2, vol./vol.) as the mobile phase. The influence of mobile phase composition and structure of racemic naproxen ester on chiral separation was studied and the chiral recognition mechanism of CTMB was discussed.
基金supported by the National Natural Science Foundation of China (Key program,Nos.G20434020 and G20774078).
文摘A rare earth Schiff base complex:lanthanum tris(N-phenylethyl-3,5-di-t-butylsalicylaldiminato)s [La(OPEBS)_3] was successfully applied as single component initiator for the ring-opening polymerization of 1,4-dioxan-2-one (PDO) in bulk.The influence of reaction conditions,such as polymerization temperature,the molar ratio of the monomer to initiator (M/I) on the monomer conversion and molecular weight of the polymer has been investigated.Poly(1,4-dioxan-2-one) with a viscosity-average molecular weight (My) o...
文摘The influence of tris(trimethylsilyl) borate (TMSB) as an electrolyte additive on lithium ion cells have been studied using Li/LiCo1/3Ni1/3Mn1/3O2 cells at a higher voltage, 4.7 V versus Li/Li+. 1 wt% TMSB can dramatically reduce the capacity fading that occurs during cycling at room temperature (RT) and elevated temperature (60 degrees C). After 150 cycles at 1 C rate (1 C= 278 mAh/g), the capacity retention of Li/LiCo1/3Ni1/3Mn1/3O2 is up to near 72% in the electrolyte with TMSB added, while it is only about 35% in the baseline electrolyte. The electrochemical behaviors, the surface chemistry and structure of Li/LiCo1/3Ni1/3Mn1/3O2 cathode are characterized with charge/discharge test, linear sweep voltammetry (LSV), X-ray photoelectron spectroscopy (XPS), electrochemical impedance spectroscopy (EIS), thermal gravimetric analyses (TGA), scanning electron microscope (SEM) and transmission electron microscopy (TEM). These analysis results reveal that the addition of TMSB is able to protectively modify the electrode CEI film in a manner that suppresses electrolyte decomposition and degradation of electrode surface structure, even though at both a higher voltage of 4.7 V and an elevated temperature of 60 degrees C. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.