A Review on Technologies for the Use of CO2 as a Working Fluid in Refrigeration and Power Cycles

The use of carbon dioxide as a working fluid has been the subject of extensive studies in recent years, particularly in the field of refrigeration where it is at the heart of research to replace CFC and HCFC. Its thermodynamic properties make it a fluid of choice in the efficient use of energy at low and medium temperatures in engine cycles. However, the performance of transcritical CO2 cycles weakens under high temperature and pressure conditions, especially in refrigeration systems;On the other hand, this disadvantage becomes rather interesting in engine cycles where CO2 can be used as an alternative to the organic working fluid in small and medium-sized electrical systems for low quality or waste heat sources. In order to improve the performance of systems operating with CO2 in the field of refrigeration and electricity production, research has made it possible to develop several concepts, of which this article deals with a review of the state of the art, followed by analyzes in-depth and critical of the various developments to the most recent modifications in these fields. Detailed discussions on the performance and technical characteristics of the different evolutions are also highlighted as well as the factors affecting the overall performance of the systems studied. Finally, perspectives on the future development of the use of CO2 in these different cycles are presented.

Effect of an Internal Heat Exchanger on the Performances of a Double Evaporator Ejector Refrigeration Cycle

A theoretical investigation is presented about a double evaporator ejector refrigeration cycle(DEERC).Special attention is paid to take into account the influence of the sub-cooling and superheating effects induced by an internal heat exchanger(IHX).The ejector is introduced into the baseline cycle in order to mitigate the throttling process losses and increase the compressor suction pressure.Moreover,the IHX has the structure of a concentric counter-flow type heat exchanger and is intentionally used to ensure that the fluid at the compressor inlet is vapor.To assess accurately the influence of the IHX on the DEERC performance,a mathematical model is derived in the frame of the dominant one-dimensional theory for ejectors.The model also accounts for the friction effect in the ejector mixing section.The equations of this model are solved using an Engineering Equation Solver(EES)for different fluids.These are:R134a as baseline fluid and other environment friendly refrigerants used for comparison,namely,R1234yf,R1234ze,R600,R600a,R290,R717 and R1270.The simulation results show that the DEERC with an IHX can achieve COP(the coefficient of performance)improvements from 5.2 until 10%.

Performance analysis of ammonia-water absorption/compression combined refrigeration cycle

In view of different compressor adding ways in the ammonia-water absorption/compression combined refrigeration AWA /CCR cycle combining the Schulz state equation of the ammonia-water solution the theoretical analysis and calculations on two combination ways by adding the compressor in the high-pressure area and in the low-pressure area are conducted respectively.The effects of several factors including the evaporation temperature Te heat-source temperature Th as well as the cooling water temperature Tw on the equivalent heat consumption in compression qCW heat consumption in absorption qG and the system coefficient of performance COP are analyzed under the two combination configurations.The results show that the effect of the equivalent heat consumption in compression on the COP is less than that of the heat consumption in absorption.Besides the compressor set in the high-pressure area uses more energy than that in the low-pressure area. Moreover the compressor in the low-pressure area is superior to that in the high-pressure area with respect to the COP. Under the given intermediate pressure there is an optimum heat-source temperature corresponding to the maximum COP of the AWA/CCR cycle.

Energy Efficient Predictive Control for Vapor Compression Refrigeration Cycle Systems

Abstract--Vapor compression refrigeration cycle （VCC） system is a high dimensional coupling thermodynamic system for which the controller design is a great challenge. In this paper, a model predictive control based energy efficient control strategy which aims at maximizing the system efficiency is proposed. Firstly, according to the mass and energy conservation law, an analysis on the nonlinear relationship between superheat and cooling load is carried out, which can produce the maximal effect on the system performance. Then a model predictive control （MPC） based controller is developed for tracking the calculated setting curve of superheat degree and pressure difference based on model identified from data which can be obtained from an experimental rig. The proposed control strategy maximizes the coefficient of performance （COP） which depends on operating conditions, in the meantime, it meets the changing demands of cooling capacity. The effectiveness of the control performance is validated on the experimental rig. Index Terms--Cooling load, model predictive control （MPC）, superheat, vapor compression refrigeration cycle （VCC）.

Performance of an irreversible quantum refrigeration cycle

A new model of a quantum refrigeration cycle composed of two adiabatic and two isomagnetic field processes is established. The working substance in the cycle consists of many non-interacting spin-1/2 systems. The performance of the cycle is investigated, based on the quantum master equation and semi-group approach. The general expressions of several important performance parameters, such as the coefficient of performance, cooling rate, and power input, are given. It is found that the coefficient of performance of this cycle is in the closest analogy to that of the classical Carnot cycle. Furthermore, at high temperatures the optimal relations of the cooling rate and the maximum cooling rate are analysed in detail. Some performance characteristic curves of the cycle are plotted, such as the cooling rate versus the maximum ratio between high and low ＂temperatures＂ of the working substances, the maximum cooling rate versus the ratio between high and low ＂magnetic fields＂ and the ＂temperature＂ ratio between high and low reservoirs. The obtained results are further generalized and discussed, so that they may be directly applied to describing the performance of the quantum refrigerator using spin-J systems as the working substance. Finally, the optimum characteristics of the quantum Carnot and Ericsson refrigeration cycles are derived by analogy.

Experiments on an Open-Loop Cycle Carbon Dioxide Refrigeration System

An open loop cycle carbon dioxide(CO2)refrigeration system is established,and the cooling performances of high-pressure CO2 under different storage conditions(25℃,30℃,and 35℃)are investigated.Moreover,the experimental mass flow rates of CO2 are compared with the theoretical values at different conditions and refrigeration capacities.The results indicate that the storage condition of CO2 has a significant impact on the refrigeration performance,and the mass flow rate of CO2 increases with the increasing storage temperature in a given refrigeration capacity.

Theoretical Study on CO_2 Transcritical Cycle Combined Ejector Cycle Refrigeration System

Chlorofluorocarbons(CFCs) or hydrochlorofluorocarbons(HCFCs) are as main refrigerants used in traditional refrigeration systems driven by electricity from burning fossil fuels, which is regarded as one of the major reasons for ozone depletion (man-made refrigerants emission) and global warming (CO 2 emission). So people pay more and more attention to natural refrigerants and energy saving technologies. An innovative system combining CO 2 transcritical cycle with ejector cycle is proposed in this paper. The CO 2 compression sub-cycle is powered by electricity with the characteristics of relatively high temperature in the gas cooler (defined as an intercooler by the proposed system). In order to recover the waste heat, an ejector sub-cycle operating with the natural refrigerants (NH 3, H 2O) is employed. The two sub-cycles are connected by an intercooler. This combined cycle joins the advantages of the two cycles together and eliminates the disadvantages. The influences of the evaporation temperature in CO 2 compression sub-cycle, the evaporation temperature in the ejector sub-cycle, the temperature in the intercooler and the condensation temperature in the proposed system performance are discussed theoretically in this study. In addition, some unique features of the system are presented.

Second Law of Thermodynamics Analysis of Transcritical Carbon Dioxide Refrigeration Cycle

In order to identify the locations of irreversible loss within the transcritical carbon dioxide refrigeration cycle with an expansion turbine, a method with respect to the second law of thermodynamics based on exergy analysis model is applied. The effects of heat rejection pressures, outlet temperatures of gas cooler and evaporating temperatures on the exergy loss, exergy efficiency and the coefficient of performance (COP) of the expansion turbine cycle are analyzed. It is found that the great percentages of exergy losses take place in the gas cooler and compressor. Moreover, heat rejection pressures, outlet temperatures of gas cooler and evaporating temperatures have strong influence on the exergy efficiency, COP and the exergy loss of each component. The analysis shows that there exists an optimal heat rejection pressure corresponding to the maximum exergy efficiency and COP, respectively. The results are of significance in providing theoretical basis for optimal design and the control of the transcritical carbon dioxide system with an expansion turbine.

Thermodynamic Analysis and Comparison on Low Temperature CO_2-NH_3 Cascade Refrigeration Cycle

This paper is focused on the cascade refrigeration cycle using natural refrigerant CO 2-NH 3. The properties of refrigerants CO 2 and NH 3 are introduced and analyzed.CO 2 has the advantage in low stage of cascade refrigeration cycle due to its good characteristics and properties. The thermodynamic analysis results of the CO 2-NH 3 cascade refrigeration cycle demonstrates that the cycle has an optimum condensation temperature of low stage and also has an optimum flow rate ratio.By comparing with the R13-R22 and NH 3-NH 3 cascade refrigeration cycles, the mass flow rate ratio of CO 2-NH 3 is larger than those of R13-R22 and NH 3-NH 3, the theoretical COP of CO 2-NH 3 cascade refrigeration cycle is larger than that of the R13-R22 cascade cycle and smaller than that of the NH 3-NH 3 cascade cycle. But the real COP of CO 2-NH 3 cascade cycle will be higher than those of R13-R22 and NH 3-NH 3 because the specific volume of CO 2 at low temperature does not change much and its dynamic viscosity is also small.

Conceptual Design of 25-Barrel Pellet Injector with Cycle Refrigerator for HL-2A Tokamak

The preliminary design of a multi-barrels pellet injector with cycle refrigerator as an advanced plasma-fuelling tool for HL-2A tokamak has been proposed. The design aims at precise temperature control, easy operation with high reliability and high flexibility. GM-cycle refrigerator and pipe-gun structure have been employed to produce 25 pellets in 25 gun barrels simultaneously and the design aims. have been accomplished. Prime design principle, engineering parameters, structure and layout of the cryostat components as well as calculation of heat load for the cryostat are presented.

Cooling High Power Dissipating Artificial Intelligence (AI) Chips Using Refrigerant

High power dissipating artificial intelligence (AI) chips require significant cooling to operate at maximum performance. Current trends regarding the integration of AI, as well as the power/cooling demands of high-performing server systems pose an immense thermal challenge for cooling. The use of refrigerants as a direct-to-chip cooling method is investigated as a potential cooling solution for cooling AI chips. Using a vapor compression refrigeration system (VCRS), the coolant temperature will be sub-ambient thereby increasing the total cooling capacity. Coupled with the implementation of a direct-to-chip boiler, using refrigerants to cool AI server systems can materialize as a potential solution for current AI server cooling demands. In this study, a comparison of 8 different refrigerants: R-134a, R-153a, R-717, R-508B, R-22, R-12, R-410a, and R-1234yf is analyzed for optimal performance. A control theoretical VCRS model is created to assess variable refrigerants under the same operational conditions. From this model, the coefficient of performance (COP), required mass flow rate of refrigerant, work required by the compressor, and overall heat transfer coefficient is determined for all 8 refrigerants. Lastly, a comprehensive analysis is provided to determine the most optimal refrigerants for cooling applications. R-717, commonly known as Ammonia, was found to have the highest COP value thus proving to be the optimal refrigerant for cooling AI chips and high-performing server applications.

Rare Earths and Magnetic Refrigeration

Magnetic refrigeration is a revolutionary, efficient, environmentally friendly cooling technology, which is on the threshold of commercialization. The magnetic rare earth materials are utilized as the magnetic refrigerants in most cooling devices, and for many cooling application the Nd2Fe14B permanent magnets are employed as the source of the magnetic field. The status of the near room temperature magnetic cooling was reviewed.

Thermodynamic design of a cascade refrigeration system of liquefied natural gas by applying mixed integer non-linear programming

Liquefied natural gas(LNG) is the most economical way of transporting natural gas(NG) over long distances. Liquefaction of NG using vapor compression refrigeration system requires high operating and capital cost. Due to lack of systematic design methods for multistage refrigeration cycles, conventional approaches to determine optimal cycle are largely trial-and-error. In this paper a novel mixed integer non-linear programming(MINLP)model is introduced to select optimal synthesis of refrigeration systems to reduce both operating and capital costs of an LNG plant. Better conceptual understanding of design improvement is illustrated on composite curve(CC) and exergetic grand composite curve(EGCC) of pinch analysis diagrams. In this method a superstructure representation of complex refrigeration system is developed to select and optimize key decision variables in refrigeration cycles(i.e. partition temperature, compression configuration, refrigeration features, refrigerant flow rate and economic trade-off). Based on this method a program(LNG-Pro) is developed which integrates VBA,Refprop and Excel MINLP Solver to automate the methodology. Design procedure is applied on a sample LNG plant to illustrate advantages of using this method which shows a 3.3% reduction in total shaft work consumption.

Performance comparison and analysis of a combined power and cooling system based on organic Rankine cycle

A novel power and cooling system combined system which coupled organic Rankine cycle(ORC) with vapor compression refrigeration cycle(VCRC) was proposed. R245 fa and butane were selected as the working fluid for the power and refrigeration cycle, respectively. A performance comparison and analysis for the combined system was presented. The results show that dual-pressure ORC-VCRC system can achieve an increase of 7.1% in thermal efficiency and 6.7% in exergy efficiency than that of basic ORC-VCRC. Intermediate pressure is a key parameter to both net power and exergy efficiency of dual-pressure ORC-VCRC system. Combined system can produce maximum net power and exergy efficiency at 0.85 MPa for intermediate pressure and 2.4 MPa for high pressure, respectively. However, superheated temperature at expander inlet has little impact on the two indicators. It can achieve higher overall COP, net power and exergy efficiency at smaller difference between condensation temperature and evaporation temperature of VCRC.

新型喷射循环(Eject Cycle~)车用冷冻机的开发

喷射器循环是世界首创的高效新型制冷循环,通过回收膨胀过程中的动能,电装公司的新型车用冷冻机效率提高50%。

Calculating the Refrigeration Coefficient by Using the Second Law of Thermodynamics

Refrigeration coefficient, ε, is usually calculated by using the First Law of Thermodynamics. In this paper, a new derivation process is introduced through the combination of the Second Law of Thermodynamics with the First Law of Thermodynamics. As a result, two new calculation equations for refrigeration coefficient are proposed. One equation is equivalent to the common method, but its form is a little complicated for real calculation. Another equation is the further simplification, and can be used to calculate the refrigeration coefficient instead of common method with a oermit error.

Analysis of R134a Organic Regenerative Cycle

The analysis of organic regenerative cycles is necessary to verify the possibilities of increasing the work and efficiency of a thermodynamic cycle according to some control parameters. The results obtained from this work can be beneficial in several areas such as solar thermal energy. Simulations of an organic regenerative cycle with up to 4 extractions were carried out in order to analyze the behavior of maximum efficiency and the work generated in the turbine. R134a was used as an organic fluid, used in low temperature cycles. Evaporation temperature data between 60°C and 100°C and superheat temperatures equal to 120°C, 200°C and 300°C were tested for cycle analysis. Thus, it was possible to verify the work behavior and maximum efficiency depending on the number of extractions, superheating temperature and evaporation temperature. The models and simulations were made using the Engineering Equation Solver (EES) software and the results were analyzed in Excel. It was concluded that the maximum efficiency increases with the increase of the evaporation temperature and the number of extractions and decreases with the increase of the superheat temperature. The turbine work grows by increasing the evaporation and superheat temperatures, but decreases with the increase in extractions.

Refrigeration Performance Analysis and Its Applicability of a New Metal Hydride Couple in Auto Air-conditioning

With COP and dynamic characteristics in refrigeration cycle as criteria,a new metal hydride couple——LaNi 4.61 Mn 0.26 Al 0.13 /La 0.6 Y 0.4 Ni 4.8 Mn 0.2 was selected by establishing calculation procedure and metal hydride selection model.The experimental results show that the refigeration cycle of the selected couple is good in the performance.The recovered waste heat and refrigeration power from exhaust gas of several kinds of automobile are calculated by waste-heat formula,coefficient R Q and COP.Refrigeration cycle of the new couple can satisfy the air-conditioning requirement of truck and car and is not enough in passenger car,according to the respective cooling load.

Energetic and Exergetic Analysis of Organic Rankine Cycle Powered by Hot Geothermal Water

The paper presents an investigation of energy and exergy analysis of an existing ORC （organic rankine cycle） unit powered by hot geothermal water. The validated model of this unit was used to examine 25 refrigerants belonging to different chemical compositions. The study revealed that R141b and R123 produced the best net power, energy efficiency, and exergy efficiency, whereas R125 was the lowest. Hydrofluorocarbons （except R143a）, hydrocarbons, and inorganic reflected attractive energy and exergy efficiencies. All investigated mixtures gained low performance compared with other studied candidates. The R245ca was the best among the hydrofluorocarbons studied refrigerants, and R501 was the best among the mixture refrigerants. Furthermore, within the ORC system, the evaporator was found to have the highest exergy destruction and the refrigerant pump was the lowest.

新型低GWP制冷剂在-100~200℃的应用研究进展

制冷剂是蒸气压缩循环中必不可少的工作流体,氢氟烷烃类化合物是目前制冷、空调和热泵设备中的主要制冷剂,但该类制冷剂会引起全球变暖等问题,因此亟需开发应用性能相似、环境性能友好的新型制冷剂。介绍了不同制冷剂在-100~200℃蒸气压缩循环应用场景中的使用现状,并综述了具有前景的低GWP制冷剂替代方案研究进展;在此基础上,对HFO-1234yf、HFO-1234ze(E)、HFO-1234ze(Z)、HCFO-1233zd(E)、HFO-1336mzz(Z) 5种低GWP制冷剂在实际应用系统中的最新研究及关键问题进行总结。