The unique characteristics of nanofibers in rational electrode design enable effec-tive utilization and maximizing material properties for achieving highly efficient and sustainable CO_(2) reduction reactions( CO_(2)R...The unique characteristics of nanofibers in rational electrode design enable effec-tive utilization and maximizing material properties for achieving highly efficient and sustainable CO_(2) reduction reactions( CO_(2)RRs)in solid oxide elec-trolysis cells(SOECs).However,practical appli-cation of nanofiber-based electrodes faces chal-lenges in establishing sufficient interfacial contact and adhesion with the dense electrolyte.To tackle this challenge,a novel hybrid nanofiber electrode,La_(0.6)Sr_(0.4)Co_(0.15)Fe_(0.8)Pd_(0.05)O_(3-δ)(H-LSCFP),is developed by strategically incorporating low aspect ratio crushed LSCFP nanofibers into the excess porous interspace of a high aspect ratio LSCFP nanofiber framework synthesized via electrospinning technique.After consecutive treatment in 100% H_(2) and CO_(2) at 700°C,LSCFP nanofibers form a perovskite phase with in situ exsolved Co metal nanocatalysts and a high concentration of oxygen species on the surface,enhancing CO_(2) adsorption.The SOEC with the H-LSCFP electrode yielded an outstanding current density of 2.2 A cm^(-2) in CO_(2) at 800°C and 1.5 V,setting a new benchmark among reported nanofiber-based electrodes.Digital twinning of the H-LSCFP reveals improved contact adhesion and increased reaction sites for CO_(2)RR.The present work demonstrates a highly catalytically active and robust nanofiber-based fuel electrode with a hybrid structure,paving the way for further advancements and nanofiber applications in CO_(2)-SOECs.展开更多
A novel synergetic arc control method was used to control twin-electrode alternating current （ AC） to direct current （DC） pulsed arc welding and the mechanism of poor sidewall fusion in narrow gap welding was inve...A novel synergetic arc control method was used to control twin-electrode alternating current （ AC） to direct current （DC） pulsed arc welding and the mechanism of poor sidewall fusion in narrow gap welding was investigated. The synergetic arc control method easured that the arc voltage of DC welding source could switch in phase with the AC welding source. To test the reliability and operability of this method, a twin-electrode AC to DC pulsed arc welding system was set up and data was acquired through high-speed photography and electrical signal measurement system. The results show that the interactions between the two arcs can be controlled effectively and the control method is a sensitive and efficient control method.展开更多
基金This work was supported by the National Research Foundation of Korea(NRF)grant funded by the Korean Government(MSIT)(2019M3E6A1103944,2020R1A2C2010690).
文摘The unique characteristics of nanofibers in rational electrode design enable effec-tive utilization and maximizing material properties for achieving highly efficient and sustainable CO_(2) reduction reactions( CO_(2)RRs)in solid oxide elec-trolysis cells(SOECs).However,practical appli-cation of nanofiber-based electrodes faces chal-lenges in establishing sufficient interfacial contact and adhesion with the dense electrolyte.To tackle this challenge,a novel hybrid nanofiber electrode,La_(0.6)Sr_(0.4)Co_(0.15)Fe_(0.8)Pd_(0.05)O_(3-δ)(H-LSCFP),is developed by strategically incorporating low aspect ratio crushed LSCFP nanofibers into the excess porous interspace of a high aspect ratio LSCFP nanofiber framework synthesized via electrospinning technique.After consecutive treatment in 100% H_(2) and CO_(2) at 700°C,LSCFP nanofibers form a perovskite phase with in situ exsolved Co metal nanocatalysts and a high concentration of oxygen species on the surface,enhancing CO_(2) adsorption.The SOEC with the H-LSCFP electrode yielded an outstanding current density of 2.2 A cm^(-2) in CO_(2) at 800°C and 1.5 V,setting a new benchmark among reported nanofiber-based electrodes.Digital twinning of the H-LSCFP reveals improved contact adhesion and increased reaction sites for CO_(2)RR.The present work demonstrates a highly catalytically active and robust nanofiber-based fuel electrode with a hybrid structure,paving the way for further advancements and nanofiber applications in CO_(2)-SOECs.
基金Supported by National Natural Science Foundation of China （Grant No. 51175374）, the Application of Basic ＆ Frontier Technology Program of Tianjin （Grant No. 09JCYBJC05000） and the Science ＆ Technology Pillar Program of Tianjin（ Grant No. 10ZCKFSF00200）.
文摘A novel synergetic arc control method was used to control twin-electrode alternating current （ AC） to direct current （DC） pulsed arc welding and the mechanism of poor sidewall fusion in narrow gap welding was investigated. The synergetic arc control method easured that the arc voltage of DC welding source could switch in phase with the AC welding source. To test the reliability and operability of this method, a twin-electrode AC to DC pulsed arc welding system was set up and data was acquired through high-speed photography and electrical signal measurement system. The results show that the interactions between the two arcs can be controlled effectively and the control method is a sensitive and efficient control method.
