Temperature effect on atomic deformation of nanotwinned Ni (nt-Ni) under localized nanoindentation is investigated in comparison with nanocrystalline Ni (nc-Ni) through molecular simulation.The nt-Ni exhibits enhanced...Temperature effect on atomic deformation of nanotwinned Ni (nt-Ni) under localized nanoindentation is investigated in comparison with nanocrystalline Ni (nc-Ni) through molecular simulation.The nt-Ni exhibits enhanced critical load and hardness compared to nc-Ni,where perfect,stair-rod and Shockley dislocations are activated at (111),(111) and (111) slip planes in nt-Ni compared to only SSockley dislocation nucleation at (111) and (111) slip planes of nc-Ni.The nt-Ni exhibits a less significant indentation size effect in comparison with nc-Ni due to the dislocation slips hindrance of the twin boundary.The atomic deformation associated with the indentation size effect is investigated during dislocation transmission.Different from the decreasing partial slips parallel to the indenter surface in nc-Ni with increasing temperature,the temperaturedependent atomic deformation of nt-Ni is closely related to the twin boundary:from the partial slips parallel to the twin boundary (~10 K),to increased confined layer slips and decreased twin migration(300 K–600 K),to decreased confined layer slips and increased dislocation interaction of dislocation pinning and dissociation (900 K–1200 K).Dislocation density and atomic structure types through quantitative analysis are implemented to further reveal the above-mentioned dislocation motion and atomic structure alteration.Our study is helpful for understanding the temperature-dependent plasticity of twin boundary in nanotwinned materials.展开更多
Toluene methylation with methanol to produce para-xylene has been extensively and intensively studied.However,the methanol-to-hydrocarbons(MTH)side reaction in this reaction is difficult to be inhibited,which will cau...Toluene methylation with methanol to produce para-xylene has been extensively and intensively studied.However,the methanol-to-hydrocarbons(MTH)side reaction in this reaction is difficult to be inhibited,which will cause a mass of carbon deposition and cover the catalyst surface,resulting in catalyst deactivation.Here,a dual-functional Ru@HZSM-5 catalyst with high para-selectivity and low carbon deposition was prepared by encapsulating Ru metal with HZSM-5.According to catalytic performance studies,the Ru@HZSM-5 catalyst produced xylene selectivity of 98%and para-xylene selectivity of 96%.Meanwhile,we find that carbon precursors(e.g.ethylene)were very little when Ru catalyst was used,but the results of HZSM-5 catalyst were completely opposite.Ru@HZSM-5 catalyst achieves a lower carbon deposition rate of only 6%of HZSM-5.The main possible reason for this is that the initial C-C bond between methanol and the olefin is difficult to form.展开更多
This study investigates the variations in the microstructural characteristics of a pre-twinned Mg alloy with the temperature of the subsequent annealing treatment.To this end,a rolled AZ31 alloy is compressed to 3%pla...This study investigates the variations in the microstructural characteristics of a pre-twinned Mg alloy with the temperature of the subsequent annealing treatment.To this end,a rolled AZ31 alloy is compressed to 3%plastic strain along the rolling direction(RD)to activate{10-12}twinning and is subsequently annealed at 200,250,300,350,and 400℃.Numerous{10-12}twins are formed throughout the compressed material,leading to the formation of a RD-oriented texture.At an annealing temperature of 200℃,no microstructural variations occur during annealing.As the annealing temperature increases from 250 to 400℃,the residual strain energy and remaining twin boundaries of the annealed material decrease owing to the promoted static recovery and the increased area fraction of twin-free grown grains.Consequently,an increase in the annealing temperature results in a gradual microstructural transition from a fully twinned grain structure to a completely twin-free grain structure.The microstructural evolution during annealing is predominantly governed by the movement of high-angle grain boundaries via a strain-induced boundary migration mechanism,and a few twin boundaries migrate above 350℃ because of their lower boundary energy.The boundary migration behavior and resultant microstructural evolution are discussed in detail based on the variations in boundary mobility and driving force for boundary migration with annealing temperature.展开更多
To investigate the role of pre-twins in Mg alloy sheets during warm planar deformation, the stretch forming is conducted at 200 ℃. Results suggest the formability of the pre-twinned AZ31 Mg alloy sheet is enhanced to...To investigate the role of pre-twins in Mg alloy sheets during warm planar deformation, the stretch forming is conducted at 200 ℃. Results suggest the formability of the pre-twinned AZ31 Mg alloy sheet is enhanced to 11.30 mm. The mechanisms for the improved formability and the deformation behaviors during the planar stretch forming are systematically investigated based on the planar stress states. The Schmid factor for deformation mechanisms are calculated, the results reveal that planar stress states extremely affect the Schmid factor for {10-12}twinning. The detwinning is activated and the prismatic slip is enhanced in the pre-twinned sheet, especially under the planar extension stress state in the outer region. Consequently, the thickness-direction strain is accommodated better. The dynamic recrystallization(DRX) type is continuous DRX(CDRX) regardless of the planar stress state. However, the CDRX degree is greater under the planar extension stress state.Some twin lattices deviate from the perfect {10-12} twinning relation due to the planar compression stress state and the CDRX. The basal texture is weakened when the planar stress state tends to change the texture components.展开更多
The three-dimensional(3D)graphene-based materials have raised significant interest due to excellent catalytic performance and unique electronic properties,while the preparation of uniform and stable 3D graphene struct...The three-dimensional(3D)graphene-based materials have raised significant interest due to excellent catalytic performance and unique electronic properties,while the preparation of uniform and stable 3D graphene structures remains a challenge.In this paper,using molecular dynamics simulations,we found that the nanotwinned copper(nt-Cu)matrix with small twin spacing can induce the wave-shaped wrinkling and sawtooth-shaped buckling graphene structures under uniaxial compression.The nt-Cu matrix possesses a symmetrical lattice structure for the lattice rotation with the dislocation annihilation,resulting in the transition of sandwiched graphene from 2D to 3D structures with good uniformity.The newly formed twin boundaries(TBs)in the nt-Cu matrix improve the resistance of graphene against the out-of-plane deformation so that graphene can maintain a stable wrinkling or buckling morphology in a wide strain range.These 3D texturing structures show great flexibility and their micro parameters can be controlled by applying different compressive strains.Furthermore,we propose a simple sliding method for decoupling graphene from the nt-Cu matrix without any damage.This work provides a novel strategy to induce and transfer the uniform wrinkling and buckling of graphene,which may expand the application of graphene in energy storage and catalysts.展开更多
The microstructural evolution and underlying grain growth mechanism of a{1012}-twin-containing Mg alloy during annealing are investigated through quasi in situ electron backscatter diffraction measurements of a rolled...The microstructural evolution and underlying grain growth mechanism of a{1012}-twin-containing Mg alloy during annealing are investigated through quasi in situ electron backscatter diffraction measurements of a rolled AZ31 alloy subjected to precompression along the rolling direction(RD).The precompressed material shows a partially twinned structure consisting of a twinned region and a residual matrix region,and this structure changes to an almost twin-free structure consisting of grown grains with serrated grain boundaries in twinand matrix-originated regions after annealing at 250℃ for 1 h.In addition,the average grain size almost doubles and the internal strain energy decreases significantly after annealing.These microstructural variations are induced mainly by grain growth through the strain-induced migration of high-angle grain boundaries without the movement of twin boundaries.The twinned region of the precompressed material has higher stored strain energy than the residual matrix region because the crystallographic orientation of the former region is favorable for basal slip and because of the occurrence of the dislocation transmutation reaction in the twins.For reducing the total strain energy accumulated in the precompressed material,the residual matrix region—having lower stored strain energy—preferentially grows while consuming the twinned regions formed in the surrounding grains during annealing.As a result,the area fraction of grains with a matrix texture increases whereas that of grains with a twin texture decreases after annealing.The twin texture intensity increases significantly and this texture becomes more concentrated along the RD because the highly RD oriented twins tend to grow during annealing on account of their fairly low stored strain energy.展开更多
The mechanical property and deformation mechanism of twinned gold nanowire with non-uniform distribution of twinned boundaries(TBs)are studied by the molecular dynamics(MD)method.It is found that the twin boundary spa...The mechanical property and deformation mechanism of twinned gold nanowire with non-uniform distribution of twinned boundaries(TBs)are studied by the molecular dynamics(MD)method.It is found that the twin boundary spacing(TBS)has a great effect on the strength and plasticity of the nanowires with uniform distribution of TBs.And the strength enhances with the decrease of TBS,while its plasticity declines.For the nanowires with non-uniform distribution of TBs,the differences in distribution among different TBSs have little effect on the Young's modulus or strength,and the compromise in strength appears.But the differences have a remarkable effect on the plasticity of twinned gold nanowire.The twinned gold nanowire with higher local symmetry ratio has better plasticity.The initial dislocations always form in the largest TBS and the fracture always appears at or near the twin boundaries adjacent to the smallest TBS.Some simulation results are consistent with the experimental results.展开更多
The first part of this report describes the data reduction of non-merohedrally twinned crystals measured on Bruker and Agilent area-detector diffractometers. The image frames of methyl-2-aminopyrazine-3-carboxylate we...The first part of this report describes the data reduction of non-merohedrally twinned crystals measured on Bruker and Agilent area-detector diffractometers. The image frames of methyl-2-aminopyrazine-3-carboxylate were processed with APEX2 to furnish a set of overlapping diffraction indices that were used for solution and refinement. CrysAlisPRO was used for processing the frames of bis(diethyldicarbamato)nickel, which exists in monoclinic and tetragonal polymorphs, and in untwinned and twinned forms. In the second part, the crystal structure of [(3-formyl-4- hydroxyphenyl)methyl]triphenylphosphanium chloride was refined through the ‘HKLF 5'(based on a combined set of diffraction indices) and PLATON(based on one set of diffraction indices) routes to give identical outcomes because the amount of overlap of the twin domains is small. For the third part, in a proof-of-concept investigation, the diffraction pattern of untwinned and twinned 4-{(E)-(4-aminophenyl)diazenyl]phenylamine was recorded simultaneously in one run; the three domains could be indexed and the crystal structure satisfactorily refined. The refinement was identical to those derived from independent measurements; the crystal structure features two independent centrosymmetric molecules, one of which is ordered and the other whole-molecule-disordered. This two-in-one run opens up the possibility that two or more crystals having different atomic compositions can be measured simultaneously if their reciprocal lattices do not overlap significantly.展开更多
The two component molecules of the co-crystal 0.69(C18H2ON206).0.31(C18H18N2O6) lie on a center-of-inversion that exists midway along the ethylene chain connecting the two aromatic rings. The two molecules are sup...The two component molecules of the co-crystal 0.69(C18H2ON206).0.31(C18H18N2O6) lie on a center-of-inversion that exists midway along the ethylene chain connecting the two aromatic rings. The two molecules are superimposed. The crystal is also a non-morohedral twin with a minor 37.7(2)% component. The refinement of this twinned and disordered crystal structure is detailed. Crystal data: C18H19.38N2O6, monoclinic, P21/c, a = 17.1687(8), b = 5.4389(2), c = 9.3261(4) A, b = 95.270(5)° and V= 867.18(6) A3 at -173 ℃.展开更多
The procedure for collecting diffraction data at –173 °C on a twinned specimen of methyl 2-aminopyrazine-3-carboxylate by using the APEX-II software followed by de-twinning the non-merohedrally-twinned reflectio...The procedure for collecting diffraction data at –173 °C on a twinned specimen of methyl 2-aminopyrazine-3-carboxylate by using the APEX-II software followed by de-twinning the non-merohedrally-twinned reflection data with PLATON is described. De-twinning significantly lowers the R index from 0.141 to 0.038 owing to 49% twinning. Crystal data: C6H7N3O2,monoclinic,P21/c (a = 6.3149(1),b = 16.5274(2),c = 6.4544(1) A,β = 95.759(1)°,V = 670.24(2) A^3).展开更多
The electronic properties of twinned ZnS nanowires (NWs) with different diameters were investigated based on first-principles calculations. The energy band structures, projected density of states and the spatial dis...The electronic properties of twinned ZnS nanowires (NWs) with different diameters were investigated based on first-principles calculations. The energy band structures, projected density of states and the spatial distributions of the bottom of conduction band and the top of the valence band were presented. The results show that the twinned nanowires exhibit a semiconducting character and the band gap decreases with increasing nanowire diameter due to quantum confinement effects. The valence band maximum and conduction band minimum originate mainly from the S-p and Zn-s orbitals at the core of the nanowires, respectively, which was confirmed by their spatial charge density distribution. We also found that no heterostructure is formed in the twinned ZnS NWs since the valence band maximum and conduction band minimum states are distributed along the NW axis uniformly. We suggest that the hexagonal (2H) stacking inside the cubic (3C) stacking has no effect on the electronic properties of thin ZnS NWs.展开更多
Effective bulk phase and surface charge separation is critical for charge utilization during the photo-catalytic energy conversion process.In this work,the ternary Ni_(2)P-NiS/twinned Mn_(0.5)Cd_(0.5)S(T-MCS)nanohybri...Effective bulk phase and surface charge separation is critical for charge utilization during the photo-catalytic energy conversion process.In this work,the ternary Ni_(2)P-NiS/twinned Mn_(0.5)Cd_(0.5)S(T-MCS)nanohybrids were successfully constructed via combining Ni_(2)P-NiS with T-MCS solid solution for visible light photocatalytic H_(2)evolution.T-MCS is composed of zinc blende Mn_(0.5)Cd_(0.5)S(ZB-MCS)and wurtzite Mn_(0.5)Cd_(0.5)S(WZ-MCS)and those two alternatively arranged crystal phases endow T-MCS with excellent bulk phase charge separation performance for the slight energy level difference between ZB-MCS and WZ-MCS.S-scheme carriers transfer route between NiS and T-MCS can accelerate the interfacial charge separation and retain the active electrons and holes,meanwhile,co-catalyst Ni_(2)P as electron receiver and proton reduction center can further optimize the H_(2)evolution reaction kinetics based on the surface Schottky barrier effect.The above-formed homo-heterojunctions can establish multiple charge transfer channels in the bulk phase of T-MCS and interface of T-MCS and Ni_(2)P-NiS.Under the synergistic effect of twinned homojunction,S-scheme heterojunction,and Schottky barrier,the ternary Ni_(2)P-NiS/T-MCS com-posite manifested an H_(2)production rate of 122.5 mmol h^(-1)g^(-1),which was 1.33,1.24,and 2.58 times higher than those of the NiS/T-MCS(92.4 mmol h^(-1)g^(-1)),Ni_(2)P/T-MCS(98.4 mmol h^(-1)g^(-1)),and T-MCS(47.5 mmol h^(-1)g^(-1)),respectively.This work demonstrates a promising strategy to develop efficient sul-fides photocatalyst toward targeted solar-driven H_(2)evolution through homo-heterojunction engineering.展开更多
The twinned substructure of lenticular martensite in a quenched Fe–33Ni alloy was studied.In contrary to the traditional viewpoint that the twinned laths come from{112}<111>deformation twins and show insignific...The twinned substructure of lenticular martensite in a quenched Fe–33Ni alloy was studied.In contrary to the traditional viewpoint that the twinned laths come from{112}<111>deformation twins and show insignificant hardening,we demonstrate that they are actually originated from the twinned Kurdjumov Sachs(KS)variants and can give rise to 3–4 times hardening up to~420 HV(~130 HV for the starting sample).The underlying mechanisms responsible for the propensity for twinned variants and the carbon-independent hardening for Fe–Ni system were discussed.展开更多
Twinned substructure in lath martensite was induced in the interstitial free(IF)steel via a high pressure thermal cycle(heating up to 1100℃and holding for 30 min,cooling at 10℃/s to room temperature under a pressure...Twinned substructure in lath martensite was induced in the interstitial free(IF)steel via a high pressure thermal cycle(heating up to 1100℃and holding for 30 min,cooling at 10℃/s to room temperature under a pressure of 4 GPa).Experimental observations and theoretical simulation confrm that the twinned substructure has the origin related to the twinned variants rather than the bcc{112}<111>twins,while extra difraction spots were caused by crystal overlapping rather than any extra phase.The diferences in crystallography and electron difraction behavior between twinned variants and{112}<111>twins were discussed in detail.展开更多
Al-Sc alloys with high Sc contents are served as sputtering targets for making high-performance piezoelectric devices.The micro structure of these alloys would affect the sputtering process and the final quality of th...Al-Sc alloys with high Sc contents are served as sputtering targets for making high-performance piezoelectric devices.The micro structure of these alloys would affect the sputtering process and the final quality of the functional devices.In this study,the microstructure in as-c as ted Al-20%Sc(in atomic ratio)alloys is characterized and the feathery Al3Sc grains with twin relationships are reported for the first time.The crystallographic features of twined structures and growth directions are quantitatively analyzed by electron backscatter diffraction(EBSD)technique.展开更多
A Fe–1.0 wt%C alloy was quenched into water from 1100 ℃,leading to lath martensite and plate martensite of body-centered tetragonal structure.Both these two martensites have the twinned substructure that generates m...A Fe–1.0 wt%C alloy was quenched into water from 1100 ℃,leading to lath martensite and plate martensite of body-centered tetragonal structure.Both these two martensites have the twinned substructure that generates mirror symmetric diff raction patterns with extra diff raction spots around n/3(112).The twinned substructure has the origin from twinned martensitic variants,namely twin-related crystals separated by{110},rather than{112}<111>deformation twins.Tetragonality eff ect on the electron double diff raction of twinned variants was discussed.展开更多
Large size polysynthetically twinned crystals of Ti-46 Al-8 Nb alloy with a parallel lamellar microstructure were successfully prepared using a Ti-43 Al-3 Si seed by our new operation.A large amount of columnar B2 pha...Large size polysynthetically twinned crystals of Ti-46 Al-8 Nb alloy with a parallel lamellar microstructure were successfully prepared using a Ti-43 Al-3 Si seed by our new operation.A large amount of columnar B2 phase paralleling to the growth direction was found in the final lamellar microstructure.Higher growth rate(>30 mm/h)led to the failure of seeding process.Based on these results,a new mechanism is proposed to describe the seeding process of the hypo-peritectic Ti Al alloys.The peritecticαphase is suggested to directly nucleate from the melt,and then act as nucleus for transformedαphase in the subsequentβtoαtransformation.At the higher growth rate,the appearance ofβphase secondary dendrites and homogeneous nucleation lead to the failure of seeding process.High Nb addition leads to a large amount of residualβphase,and theseβdendrites finally evolve into B2 phase.The room temperature tensile elongation was measured to be 11.9-18.5%for Ti-46 Al-8 Nb PST crystals,which is the highest ever reported value for Ti Al based alloys.展开更多
Developing efficient and robust electrocatalysts toward ethanol oxidation reaction(EOR)with high C1 pathway selectivity is critical for commercialization of direct ethanol fuel cells(DEFCs).Unfortunately,current most ...Developing efficient and robust electrocatalysts toward ethanol oxidation reaction(EOR)with high C1 pathway selectivity is critical for commercialization of direct ethanol fuel cells(DEFCs).Unfortunately,current most EOR electrocatalysts suffer from rapid activity degradation and poor C1 pathway selectivity for complete oxidation of ethanol.Herein,we report a novel electrocatalyst of five-fold twinned(FFT)Ir-alloyed Pt nanorods(NRs)toward EOR.Such FFT Pt-Ir NRs bounded by five(100)facets on the sides and ten(111)facets at two ends possess high percentage of(100)facets with tensile strain.Owing to the inherent characteristics of the FFT NR and Ir alloying,the as-prepared FFT Pt-Ir NRs display excellent alkaline EOR performance with a mass activity(MA)of 4.18 A·mgPt^(-1),a specific activity(SA)of 10.22 mA·cm^(-2),and a Faraday efficiency of 61.21%for the C1 pathway,which are 6.85,5.62,and 7.70 times higher than those of a commercial Pt black,respectively.Besides,our catalyst also exhibits robust durability.The large percentage of open tensile-strained(100)facets and Ir alloying significantly promote the cleavage of C-C bonds and facilitate oxidation of the poisonous intermediates,leading to the transformation of the dominant reaction pathway for EOR from C2 to C1 pathway,and effectively suppress the deactivation of the catalyst.展开更多
基金supported by the National Natural Science Foundation of China (Grant No.11572090)。
文摘Temperature effect on atomic deformation of nanotwinned Ni (nt-Ni) under localized nanoindentation is investigated in comparison with nanocrystalline Ni (nc-Ni) through molecular simulation.The nt-Ni exhibits enhanced critical load and hardness compared to nc-Ni,where perfect,stair-rod and Shockley dislocations are activated at (111),(111) and (111) slip planes in nt-Ni compared to only SSockley dislocation nucleation at (111) and (111) slip planes of nc-Ni.The nt-Ni exhibits a less significant indentation size effect in comparison with nc-Ni due to the dislocation slips hindrance of the twin boundary.The atomic deformation associated with the indentation size effect is investigated during dislocation transmission.Different from the decreasing partial slips parallel to the indenter surface in nc-Ni with increasing temperature,the temperaturedependent atomic deformation of nt-Ni is closely related to the twin boundary:from the partial slips parallel to the twin boundary (~10 K),to increased confined layer slips and decreased twin migration(300 K–600 K),to decreased confined layer slips and increased dislocation interaction of dislocation pinning and dissociation (900 K–1200 K).Dislocation density and atomic structure types through quantitative analysis are implemented to further reveal the above-mentioned dislocation motion and atomic structure alteration.Our study is helpful for understanding the temperature-dependent plasticity of twin boundary in nanotwinned materials.
基金financial support from the Hongliu Outstanding Young Talents Funding Program of Lanzhou University of Technology(02/062214)。
文摘Toluene methylation with methanol to produce para-xylene has been extensively and intensively studied.However,the methanol-to-hydrocarbons(MTH)side reaction in this reaction is difficult to be inhibited,which will cause a mass of carbon deposition and cover the catalyst surface,resulting in catalyst deactivation.Here,a dual-functional Ru@HZSM-5 catalyst with high para-selectivity and low carbon deposition was prepared by encapsulating Ru metal with HZSM-5.According to catalytic performance studies,the Ru@HZSM-5 catalyst produced xylene selectivity of 98%and para-xylene selectivity of 96%.Meanwhile,we find that carbon precursors(e.g.ethylene)were very little when Ru catalyst was used,but the results of HZSM-5 catalyst were completely opposite.Ru@HZSM-5 catalyst achieves a lower carbon deposition rate of only 6%of HZSM-5.The main possible reason for this is that the initial C-C bond between methanol and the olefin is difficult to form.
基金supported by the National Research Foundation of Korea(NRF,Grant No.2019R1A2C1085272)funded by the Ministry of Science,ICTFuture Planning(MSIP,South Korea)。
文摘This study investigates the variations in the microstructural characteristics of a pre-twinned Mg alloy with the temperature of the subsequent annealing treatment.To this end,a rolled AZ31 alloy is compressed to 3%plastic strain along the rolling direction(RD)to activate{10-12}twinning and is subsequently annealed at 200,250,300,350,and 400℃.Numerous{10-12}twins are formed throughout the compressed material,leading to the formation of a RD-oriented texture.At an annealing temperature of 200℃,no microstructural variations occur during annealing.As the annealing temperature increases from 250 to 400℃,the residual strain energy and remaining twin boundaries of the annealed material decrease owing to the promoted static recovery and the increased area fraction of twin-free grown grains.Consequently,an increase in the annealing temperature results in a gradual microstructural transition from a fully twinned grain structure to a completely twin-free grain structure.The microstructural evolution during annealing is predominantly governed by the movement of high-angle grain boundaries via a strain-induced boundary migration mechanism,and a few twin boundaries migrate above 350℃ because of their lower boundary energy.The boundary migration behavior and resultant microstructural evolution are discussed in detail based on the variations in boundary mobility and driving force for boundary migration with annealing temperature.
基金the Central Government Guided Local Science and Technology Development Projects (YDZJSX2021A010)China Postdoctoral Science Foundation (No.2022M710541)+5 种基金the National Natural Science Foundation of China (51704209,52274397,U1810208)the Projects of International Cooperation in Shanxi (201803D421086)Shanxi Province Patent Promotion Implementation Fund (20200718)Research Project Supported by Shanxi Scholarship Council of China (2022-038)Science and Technology Major Project of Shanxi Province (20191102008,20191102007,20181101008)Taishan Scholars Project Special Fund (2021)。
文摘To investigate the role of pre-twins in Mg alloy sheets during warm planar deformation, the stretch forming is conducted at 200 ℃. Results suggest the formability of the pre-twinned AZ31 Mg alloy sheet is enhanced to 11.30 mm. The mechanisms for the improved formability and the deformation behaviors during the planar stretch forming are systematically investigated based on the planar stress states. The Schmid factor for deformation mechanisms are calculated, the results reveal that planar stress states extremely affect the Schmid factor for {10-12}twinning. The detwinning is activated and the prismatic slip is enhanced in the pre-twinned sheet, especially under the planar extension stress state in the outer region. Consequently, the thickness-direction strain is accommodated better. The dynamic recrystallization(DRX) type is continuous DRX(CDRX) regardless of the planar stress state. However, the CDRX degree is greater under the planar extension stress state.Some twin lattices deviate from the perfect {10-12} twinning relation due to the planar compression stress state and the CDRX. The basal texture is weakened when the planar stress state tends to change the texture components.
基金Australia Research Council Discovery Project(DP170103092)National Natural Science Foundation of China(NSFC51701030).
文摘The three-dimensional(3D)graphene-based materials have raised significant interest due to excellent catalytic performance and unique electronic properties,while the preparation of uniform and stable 3D graphene structures remains a challenge.In this paper,using molecular dynamics simulations,we found that the nanotwinned copper(nt-Cu)matrix with small twin spacing can induce the wave-shaped wrinkling and sawtooth-shaped buckling graphene structures under uniaxial compression.The nt-Cu matrix possesses a symmetrical lattice structure for the lattice rotation with the dislocation annihilation,resulting in the transition of sandwiched graphene from 2D to 3D structures with good uniformity.The newly formed twin boundaries(TBs)in the nt-Cu matrix improve the resistance of graphene against the out-of-plane deformation so that graphene can maintain a stable wrinkling or buckling morphology in a wide strain range.These 3D texturing structures show great flexibility and their micro parameters can be controlled by applying different compressive strains.Furthermore,we propose a simple sliding method for decoupling graphene from the nt-Cu matrix without any damage.This work provides a novel strategy to induce and transfer the uniform wrinkling and buckling of graphene,which may expand the application of graphene in energy storage and catalysts.
基金This work was supported by a grant from the National Research Foundation of Korea(NRF)funded by the Korean government(MSIP,South Korea)(No.2019R1A2C1085272).
文摘The microstructural evolution and underlying grain growth mechanism of a{1012}-twin-containing Mg alloy during annealing are investigated through quasi in situ electron backscatter diffraction measurements of a rolled AZ31 alloy subjected to precompression along the rolling direction(RD).The precompressed material shows a partially twinned structure consisting of a twinned region and a residual matrix region,and this structure changes to an almost twin-free structure consisting of grown grains with serrated grain boundaries in twinand matrix-originated regions after annealing at 250℃ for 1 h.In addition,the average grain size almost doubles and the internal strain energy decreases significantly after annealing.These microstructural variations are induced mainly by grain growth through the strain-induced migration of high-angle grain boundaries without the movement of twin boundaries.The twinned region of the precompressed material has higher stored strain energy than the residual matrix region because the crystallographic orientation of the former region is favorable for basal slip and because of the occurrence of the dislocation transmutation reaction in the twins.For reducing the total strain energy accumulated in the precompressed material,the residual matrix region—having lower stored strain energy—preferentially grows while consuming the twinned regions formed in the surrounding grains during annealing.As a result,the area fraction of grains with a matrix texture increases whereas that of grains with a twin texture decreases after annealing.The twin texture intensity increases significantly and this texture becomes more concentrated along the RD because the highly RD oriented twins tend to grow during annealing on account of their fairly low stored strain energy.
基金the National Natural Science Foundation of China(Grant No.51771033).
文摘The mechanical property and deformation mechanism of twinned gold nanowire with non-uniform distribution of twinned boundaries(TBs)are studied by the molecular dynamics(MD)method.It is found that the twin boundary spacing(TBS)has a great effect on the strength and plasticity of the nanowires with uniform distribution of TBs.And the strength enhances with the decrease of TBS,while its plasticity declines.For the nanowires with non-uniform distribution of TBs,the differences in distribution among different TBSs have little effect on the Young's modulus or strength,and the compromise in strength appears.But the differences have a remarkable effect on the plasticity of twinned gold nanowire.The twinned gold nanowire with higher local symmetry ratio has better plasticity.The initial dislocations always form in the largest TBS and the fracture always appears at or near the twin boundaries adjacent to the smallest TBS.Some simulation results are consistent with the experimental results.
文摘The first part of this report describes the data reduction of non-merohedrally twinned crystals measured on Bruker and Agilent area-detector diffractometers. The image frames of methyl-2-aminopyrazine-3-carboxylate were processed with APEX2 to furnish a set of overlapping diffraction indices that were used for solution and refinement. CrysAlisPRO was used for processing the frames of bis(diethyldicarbamato)nickel, which exists in monoclinic and tetragonal polymorphs, and in untwinned and twinned forms. In the second part, the crystal structure of [(3-formyl-4- hydroxyphenyl)methyl]triphenylphosphanium chloride was refined through the ‘HKLF 5'(based on a combined set of diffraction indices) and PLATON(based on one set of diffraction indices) routes to give identical outcomes because the amount of overlap of the twin domains is small. For the third part, in a proof-of-concept investigation, the diffraction pattern of untwinned and twinned 4-{(E)-(4-aminophenyl)diazenyl]phenylamine was recorded simultaneously in one run; the three domains could be indexed and the crystal structure satisfactorily refined. The refinement was identical to those derived from independent measurements; the crystal structure features two independent centrosymmetric molecules, one of which is ordered and the other whole-molecule-disordered. This two-in-one run opens up the possibility that two or more crystals having different atomic compositions can be measured simultaneously if their reciprocal lattices do not overlap significantly.
基金the University of Malaya (grant No. UM.C/HIR/MOHE/SC/12) for supporting this study
文摘The two component molecules of the co-crystal 0.69(C18H2ON206).0.31(C18H18N2O6) lie on a center-of-inversion that exists midway along the ethylene chain connecting the two aromatic rings. The two molecules are superimposed. The crystal is also a non-morohedral twin with a minor 37.7(2)% component. The refinement of this twinned and disordered crystal structure is detailed. Crystal data: C18H19.38N2O6, monoclinic, P21/c, a = 17.1687(8), b = 5.4389(2), c = 9.3261(4) A, b = 95.270(5)° and V= 867.18(6) A3 at -173 ℃.
文摘The procedure for collecting diffraction data at –173 °C on a twinned specimen of methyl 2-aminopyrazine-3-carboxylate by using the APEX-II software followed by de-twinning the non-merohedrally-twinned reflection data with PLATON is described. De-twinning significantly lowers the R index from 0.141 to 0.038 owing to 49% twinning. Crystal data: C6H7N3O2,monoclinic,P21/c (a = 6.3149(1),b = 16.5274(2),c = 6.4544(1) A,β = 95.759(1)°,V = 670.24(2) A^3).
基金Project supported by the Special Funds of the National Natural Science Foundation of China (Grant No. 10947102)the Foundation of the Education Committee of Chongqing (Grant No. KJ090503)
文摘The electronic properties of twinned ZnS nanowires (NWs) with different diameters were investigated based on first-principles calculations. The energy band structures, projected density of states and the spatial distributions of the bottom of conduction band and the top of the valence band were presented. The results show that the twinned nanowires exhibit a semiconducting character and the band gap decreases with increasing nanowire diameter due to quantum confinement effects. The valence band maximum and conduction band minimum originate mainly from the S-p and Zn-s orbitals at the core of the nanowires, respectively, which was confirmed by their spatial charge density distribution. We also found that no heterostructure is formed in the twinned ZnS NWs since the valence band maximum and conduction band minimum states are distributed along the NW axis uniformly. We suggest that the hexagonal (2H) stacking inside the cubic (3C) stacking has no effect on the electronic properties of thin ZnS NWs.
基金supported by the National Natu-ral Science Foundation of China(Nos.22078261,21676213,and 11974276)Natural Science Basic Research Program of Shaanxi(No.2023-JC-YB-115)+1 种基金Shaanxi Key Science and Technology Innovation Team Project(No.2022TD-33)National College Student Inno-vation and Entrepreneurship Training Program(No.202210697069)for the financial support of this work.
文摘Effective bulk phase and surface charge separation is critical for charge utilization during the photo-catalytic energy conversion process.In this work,the ternary Ni_(2)P-NiS/twinned Mn_(0.5)Cd_(0.5)S(T-MCS)nanohybrids were successfully constructed via combining Ni_(2)P-NiS with T-MCS solid solution for visible light photocatalytic H_(2)evolution.T-MCS is composed of zinc blende Mn_(0.5)Cd_(0.5)S(ZB-MCS)and wurtzite Mn_(0.5)Cd_(0.5)S(WZ-MCS)and those two alternatively arranged crystal phases endow T-MCS with excellent bulk phase charge separation performance for the slight energy level difference between ZB-MCS and WZ-MCS.S-scheme carriers transfer route between NiS and T-MCS can accelerate the interfacial charge separation and retain the active electrons and holes,meanwhile,co-catalyst Ni_(2)P as electron receiver and proton reduction center can further optimize the H_(2)evolution reaction kinetics based on the surface Schottky barrier effect.The above-formed homo-heterojunctions can establish multiple charge transfer channels in the bulk phase of T-MCS and interface of T-MCS and Ni_(2)P-NiS.Under the synergistic effect of twinned homojunction,S-scheme heterojunction,and Schottky barrier,the ternary Ni_(2)P-NiS/T-MCS com-posite manifested an H_(2)production rate of 122.5 mmol h^(-1)g^(-1),which was 1.33,1.24,and 2.58 times higher than those of the NiS/T-MCS(92.4 mmol h^(-1)g^(-1)),Ni_(2)P/T-MCS(98.4 mmol h^(-1)g^(-1)),and T-MCS(47.5 mmol h^(-1)g^(-1)),respectively.This work demonstrates a promising strategy to develop efficient sul-fides photocatalyst toward targeted solar-driven H_(2)evolution through homo-heterojunction engineering.
基金We gratefully acknowledge the financial support of the Natural Science Foundation-Steel and Iron Foundation of Hebei Province(E2021203051)the Hundred Outstanding Creative Talents Projects in universities of Hebei Province,China,the Project Program of Heavy Machinery Collaborative Innovation Center,China,the Natural Science Foundation of Hubei Province(2020BED011).
文摘The twinned substructure of lenticular martensite in a quenched Fe–33Ni alloy was studied.In contrary to the traditional viewpoint that the twinned laths come from{112}<111>deformation twins and show insignificant hardening,we demonstrate that they are actually originated from the twinned Kurdjumov Sachs(KS)variants and can give rise to 3–4 times hardening up to~420 HV(~130 HV for the starting sample).The underlying mechanisms responsible for the propensity for twinned variants and the carbon-independent hardening for Fe–Ni system were discussed.
基金supported by the Natural Science Foundation-Steel and Iron Foundation of Hebei Province(No.E2021203051)the Hundred Outstanding Creative Talents Projects in Universities of Hebei Province,China,and the Project Program of Heavy Machinery Collaborative Innovation Center,China.
文摘Twinned substructure in lath martensite was induced in the interstitial free(IF)steel via a high pressure thermal cycle(heating up to 1100℃and holding for 30 min,cooling at 10℃/s to room temperature under a pressure of 4 GPa).Experimental observations and theoretical simulation confrm that the twinned substructure has the origin related to the twinned variants rather than the bcc{112}<111>twins,while extra difraction spots were caused by crystal overlapping rather than any extra phase.The diferences in crystallography and electron difraction behavior between twinned variants and{112}<111>twins were discussed in detail.
基金financially supported by the National Key R&D Program of China(No.2017YFB0405901)。
文摘Al-Sc alloys with high Sc contents are served as sputtering targets for making high-performance piezoelectric devices.The micro structure of these alloys would affect the sputtering process and the final quality of the functional devices.In this study,the microstructure in as-c as ted Al-20%Sc(in atomic ratio)alloys is characterized and the feathery Al3Sc grains with twin relationships are reported for the first time.The crystallographic features of twined structures and growth directions are quantitatively analyzed by electron backscatter diffraction(EBSD)technique.
基金financially supported by the Hundred Outstanding Creative Talents Projects in Hebei University(SLRC2017058)the Natural Science Foundation—Steel and Iron Foundation of Hebei Province(E2021203051)+1 种基金the Project Program of Heavy Machinery Collaborative Innovation Centerthe National Natural Science Foundation(51171182)。
文摘A Fe–1.0 wt%C alloy was quenched into water from 1100 ℃,leading to lath martensite and plate martensite of body-centered tetragonal structure.Both these two martensites have the twinned substructure that generates mirror symmetric diff raction patterns with extra diff raction spots around n/3(112).The twinned substructure has the origin from twinned martensitic variants,namely twin-related crystals separated by{110},rather than{112}<111>deformation twins.Tetragonality eff ect on the electron double diff raction of twinned variants was discussed.
基金National Natural Science Foundation of China(No.51701209)National Key Research and Development Program of China(Nos.2016YFB0701304)。
文摘Large size polysynthetically twinned crystals of Ti-46 Al-8 Nb alloy with a parallel lamellar microstructure were successfully prepared using a Ti-43 Al-3 Si seed by our new operation.A large amount of columnar B2 phase paralleling to the growth direction was found in the final lamellar microstructure.Higher growth rate(>30 mm/h)led to the failure of seeding process.Based on these results,a new mechanism is proposed to describe the seeding process of the hypo-peritectic Ti Al alloys.The peritecticαphase is suggested to directly nucleate from the melt,and then act as nucleus for transformedαphase in the subsequentβtoαtransformation.At the higher growth rate,the appearance ofβphase secondary dendrites and homogeneous nucleation lead to the failure of seeding process.High Nb addition leads to a large amount of residualβphase,and theseβdendrites finally evolve into B2 phase.The room temperature tensile elongation was measured to be 11.9-18.5%for Ti-46 Al-8 Nb PST crystals,which is the highest ever reported value for Ti Al based alloys.
基金This work was supported by the National Natural Science Foundation of China(No.21908036)the China Postdoctoral Science Foundation(No.2019M662143)+1 种基金the Natural Science Foundation of Anhui Province(No.2008085QB74)the Fundamental Research Funds for the Central Universities(No.JZ2021HGTB0116).
文摘Developing efficient and robust electrocatalysts toward ethanol oxidation reaction(EOR)with high C1 pathway selectivity is critical for commercialization of direct ethanol fuel cells(DEFCs).Unfortunately,current most EOR electrocatalysts suffer from rapid activity degradation and poor C1 pathway selectivity for complete oxidation of ethanol.Herein,we report a novel electrocatalyst of five-fold twinned(FFT)Ir-alloyed Pt nanorods(NRs)toward EOR.Such FFT Pt-Ir NRs bounded by five(100)facets on the sides and ten(111)facets at two ends possess high percentage of(100)facets with tensile strain.Owing to the inherent characteristics of the FFT NR and Ir alloying,the as-prepared FFT Pt-Ir NRs display excellent alkaline EOR performance with a mass activity(MA)of 4.18 A·mgPt^(-1),a specific activity(SA)of 10.22 mA·cm^(-2),and a Faraday efficiency of 61.21%for the C1 pathway,which are 6.85,5.62,and 7.70 times higher than those of a commercial Pt black,respectively.Besides,our catalyst also exhibits robust durability.The large percentage of open tensile-strained(100)facets and Ir alloying significantly promote the cleavage of C-C bonds and facilitate oxidation of the poisonous intermediates,leading to the transformation of the dominant reaction pathway for EOR from C2 to C1 pathway,and effectively suppress the deactivation of the catalyst.