Characteristics of high-sulfate wastewater treatment by two-phase anaerobic digestion process with Jet-loop anaerobic fluidized bed

A new anaerobic reactor, Jet-loop anaerobic fluidized bed （JLAFB）, was designed for treating high-sulfate wastewater. The treatment characteristics, including the effect of influent COD/SO42 ratio and alkalinity and sulfide inhibition in reactors, were discussed for a JLAFB and a general anaerobic fiuidized bed （AFB） reactor used as sulfate-reducing phase and methane-producing phase, respectively, in two-phase anaerobic digestion process. The formation of granules in the two reactors was also examined. The results indicated that COD and sulfate removal had different demand of influent COD/SO4^2- ratios. When total COD removal was up to 85%, the ratio was only required up to 1.2, whereas, total sulfate removal up to 95% required it exceeding 3.0. The alkalinity in the two reactors increased linearly with the growth of influent alkalinity. Moreover, the change of influent alkalinity had no significant effect on pH and volatile fatty acids （VFA） in the two reactors. Influent alkalinity kept at 400-500 mg/L could meet the requirement of the treating process. The JLAFB reactor had great advantage in avoiding sulfide and free-H2S accumulation and toxicity inhibition on microorganisms. When sulfate loading rate was up to 8. 1 kg/（m^3.d）, the sulfide and free-H2S concentrations in JLAFB reactor were 58.6 and 49.7 mg/L, respectively. Furthermore, the granules, with offwhite color, ellipse shape and diameters of 1.0-3.0 mm, could be developed in JLAFB reactor. In granules, different groups of bacteria were distributed in different layers, and some inorganic metal compounds such as Fe, Ca, Mg etc. were found.

Treatment of methanol wastewater with two-stage and two-phase anaerobic process

The two-stage and two-phase anaerobic process (TSTP) composed of hydrolytic acidification reactor,first-order and second-order external circulation anaerobic reactors (EC) was taken to treat methanol wastewater. Test results show that TSTP process is quick start-up in 51 d, and the maximum VFA of hydrolytic acidification reactor effluent reaches 876 mg/L. Under the condition of volume loading of 6.56 kgCOD/m3·d, COD removal rate of the first-order EC reactor is about 85%, and under the condition of volume loading of 1.02 kgCOD/m3·d, COD removal rate of the second-order EC reactor is about 50%. When the inflow COD of TSTP process is between 7000-11000 mg/L, its effluent COD is lower than 600 mg/L. In the biological conversion process of methanol into methane,the production of acetic acids as an intermediate product can be ignored and the direct production of methane from methanol is predominant.

Effects of adding chicken manure to cattle manure on aerobic compost process parameters at low temperature

The research was aimed at studying the effect of adding certain proportion chicken manure to cattle manure on compost below 0℃ with aerobic compost method, which was suitable for northern cold climate. The results indicated that the mixed compost completed 3 days earlier than the single compost, the temperature of the mixed compost rose to 50.7℃ at the 1st day,and achieved its highest temperature 74.4℃ at the 3rd day. The temperature of the single compost rose to 40.0℃ at the 1st day,rose to 55.6℃ at the 3rd day,and achieved its highest temperature 70.1℃ at the 5th day. Adding chicken manure had no impact on the variety trend of the process parameters such as moisture content, pH and C/N ratio, hut increased the variety range of these parameters.

Kinetics model of aerobic phase in hybrid anoxic-oxic process

Kinetics models of COD degradation,biomass growth of the anoxic-oxic ( A/O) system as well as NH3-N degradation in aerobic phase were presented according to the mass balance theory,reaction-diffusion theory and Fick law. Then these models were testified by comparson with experimental results. It is demonstrated that the variation trends of theoretical and experimental values for COD degradation and biomass growth are similar. The deviation rate between theoretical and experimental values is always under 20% even it increases along with the fluctuation of influent organic loading. In terms of NH3-N degradation,nitrification can also be well simulated by the model as the substrates of influent are sufficient. It indicates that the model can accurately reflect the reaction in hybrid A/O process. Models presented herein provide a theoretical basis for the design, operation and control of hybrid A/O process.

Digital image processing of saturation for two-phase flow in planar porous media model

In this paper, the accuracy of estimating stained non-wetting phase saturation using digital image processing is examined, and a novel post-processing approach for calculating threshold is presented. In order to remove the effect of the background noise of images and to enhance the high-frequency component of the original image, image smoothing and image sharpening methods are introduced. Depending on the correct threshold, the image binarization processing is particularly useful for estimating stained non-wetting phase saturation. Calculated saturation data are compared with the measured saturation data during the two-phase flow experiment in an artificial steel planar porous media model. The results show that the calculated saturation data agree with the measured ones. With the help of an artificial steel planar porous media model, digital image processing is an accurate and simple method for obtaining the stained non-wetting phase saturation.

New numerical algorithm of gas-liquid two-phase flow considering characteristics of liquid metal during mold filling

A new program is developed for gas-liquid two-phase mold filling simulation in casting. The gas fluid, the superheated liquid metal and the liquid metal containing solid grains are assumed to be governed by Navier-Stokes equations and solved through Projection method. The Level set method is used to track the gas-liquid interface boundary. In order to demonstrate the correctness of this new program for simulation of gas-liquid two-phase mold filling in casting, a benchmark filling experiment is simulated （this benchmark test is designed by XU and the filling process is recorded by a 16-mm film camera）. The simulated results agree very well with the experimental results, showing that this new program can be used to properly predicate the gas-liquid two-phase mold filling simulation in casting.

Removal of nitrogen and phosphorus in a combined A^2/O-BAF system with a short aerobic SRT

A bench-scale anaerobic/anoxic/aerobic process-biological aerated filter （A^2/O-BAF） combined system was carded out to treat wastewater with lower C/N and C/P ratios. The A^2/O process was operated in a short aerobic sludge retention time （SRT） for organic pollutants and phosphorus removal, and denitrification. The subsequent BAF process was mainly used for nitrification. The BAF effluent was partially returned to anoxic zone of the A^2/O process to provide electron acceptors for denitrification and anoxic P uptake. This unique system formed an environment for reproducing the denitdfying phosphate-accumulating organisms （DPAOs）. The ratio of DPAOs to phosphorus accumulating organisms （PAOs） could be maintained at 28% by optimizing the organic loads in the anaerobic zone and the nitrate loads into the anoxic zone in the A^2/O process. The aerobic phosphorus over-uptake and discharge of excess activated sludge was the main mechanism of phosphorus removal in the combined system. The aerobic SRT of the A^2/O process should meet the demands for the development of aerobic PAOs and the restraint on the nitrifiers growth, and the contact time in the aerobic zone of the A^2/O process should be longer than 30 min, which ensured efficient phosphorus removal in the combined system. The adequate BAF effluent return rates should be controlled with 1--4 mg/L nitrate nitrogen in the anoxic zone effluent of A^2/O process to achieve the optimal nitrogen and phosphorus removal efficiencies.

Identification Method of Gas-Liquid Two-phase Flow Regime Based on Image Multi-feature Fusion and Support Vector Machine

The knowledge of flow regime is very important for quantifying the pressure drop, the stability and safety of two-phase flow systems. Based on image multi-feature fusion and support vector machine, a new method to identify flow regime in two-phase flow was presented. Firstly, gas-liquid two-phase flow images including bub- bly flow, plug flow, slug flow, stratified flow, wavy flow, annular flow and mist flow were captured by digital high speed video systems in the horizontal tube. The image moment invariants and gray level co-occurrence matrix texture features were extracted using image processing techniques. To improve the performance of a multiple classifier system, the rough sets theory was used for reducing the inessential factors. Furthermore, the support vector machine was trained by using these eigenvectors to reduce the dimension as flow regime samples, and the flow regime intelligent identification was realized. The test results showed that image features which were reduced with the rough sets theory could excellently reflect the difference between seven typical flow regimes, and successful training the support vector machine could quickly and accurately identify seven typical flow regimes of gas-liquid two-phase flow in the horizontal tube. Image multi-feature fusion method provided a new way to identify the gas-liquid two-phase flow, and achieved higher identification ability than that of single characteristic. The overall identification accuracy was 100%, and an estimate of the image processing time was 8 ms for online flow regime identification.

Kinetics of aerobically activated sludge on terylene artificial silk printing and dyeing wastewater treatment

Aerobically activated sludge processing was carried out to treat terylene artificial silk printing and dyeing wastewater (TPD wastewater) in a lab-scale experiment, focusing on the kinetics of the COD removal. The kinetics pa-rameters determined from experiment were applied to evaluate the biological treatability of wastewater. Experiments showed that COD removal could be divided into two stages, in which the ratio BOD/COD (B/C) was the key factor for stage division. At the rapid-removal stage with B/C>0.1, COD removal could be described by a zero order reaction. At the mod-erate-removal stage with B/C<0.1, COD removal could be described by a first order reaction. Then Monod equation was introduced to indicate COD removal. The reaction rate constant (K) and half saturation constant (KS) were 0.0208-0.0642 L/(gMLSS)h and 0.44-0.59 (gCOD)/L respectively at 20 C-35 C. Activation energy (Ea) was 6.05104 J/mol. By comparison of kinetic parameters, the biological treatability of TPD wastewater was superior to that of traditional textile wastewater. But COD removal from TPD-wastewater was much more difficult than that from domestic and industrial wastewater, such as papermaking, beer, phenol wastewater, etc. The expected effluent quality strongly related to un-biodegradable COD and kinetics rather than total COD. The results provide useful basis for further scaling up and efficient operation of TPD wastewater treatment.

DIFFERENCE SCHEME FOR TWO-PHASE FLOW

A numerical method for two-phase flow with hydrodynamics behavior was considered. The nonconservative hyperbolic governing equations proposed by Saurel and Gallout were adopted. Dissipative effects were neglected but they could be included in the model without major difficulties. Based on the opinion proposed by Abgrall that “a two phase system, uniform in velocity and pressure at t=0 will be uniform on the same variable during its temporal evolution", a simple accurate and fully Eulerian numerical method was presented for the simulation of multiphase compressible flows in hydrodynamic regime. The numerical method relies on Godunov-type scheme, with HLLC and Lax-Friedrichs type approximate Riemann solvers for the resolution of conservation equations, and nonconservative equation. Speed relaxation and pressure relaxation processes were introduced to account for the interaction between the phases. Test problem was presented in one space dimension which illustrated that our scheme is accurate, stable and oscillation free.

Petro-chemical wastewater treatment by biological process

In order to study the feasibility of treating petro chemical wastewater by the combination of anaerobic and aerobic biological process, a research of treating wastewater in UASB reactor and aeration basin has been conducted. The test results shows that under moderate temperature, with 5\^2 kgCOD/(m\+3·d) volumetric load of COD Cr in the UASB reactor and 24h of HRT, 85% removal rate of BOD 5 and 83% of COD \{Cr\} and 1\^34 m\+3/(m\+3·d) volumetric gas production rate can be obtained respectively. The aerobic bio degradability can be increased by 20%—30% after the petro chemical wastewater has been treated by anaerobic process. As Ns=0\^45 kgCOD/(kgMLSS·d), HRT=4h in the aeration tank, 94% removal rate of BOD 5, 93% of COD \{Cr\}, 98\^8% total removal rate of COD \{Cr\} and 99% removal rate of BOD 5 can be reached.

Numerical simulation of mould filling process for pressure plate and valve handle in LFC

In lost foam casting (LFC), the distribution of polymer beads during the bead filling process is not uniform, and the collision between polymer beads determines the distribution of two-phase flow of gas and solid. The interaction between the gas and solid phases reveals as coupling effect of the force that gas exerts on particles or vice versa, or that among particles. The gas-solid flow in filling process is nonlinearity, which makes the coupling effect an essential point to carry out a simulation properly. Therefore, information of each particle's motion is important for acquiring the law of filling process. In bead filling process, compressed air is pressed into mold cavity, and discharged from gas vent, creating a pressure difference between outer and inner space near the gas vent. This pressure difference directly changes the spatial distribution and motion trace of gas and solid phases. In this paper, Discrete Element Method (DEM) and Computational Fluid Dynamics (CFD) are employed to simulate the fluid dynamic character based on Newton's Third Law of Motion. The simulation results of some casting products such as pressure plate and valve handle are compared with the result obtained from practical experiment in order to test the feasibility of DEM. The comparison shows that this DEM method can be a very promising tool in the mould filling simulation of beads' movement.

Process intensification in vapor–liquid mass transfer: The state-of-the-art

The concept of process intensification(PI) has absorbed diverse definitions and stays true to the mission—'do more with less', which is an approach purposed by chemical engineers to solve the global energy & environment problems. To date, the focus of PI has been on processes mainly involving vapor/liquid systems. Based on the fundamental principles of vapor–liquid mass transfer process like distillation and absorption, there are three strategies to intensify interphase mass transfer: enhancing the overall driving force, improving the mass transfer coefficient and enlarging the vapor–liquid interfacial area. More specifically, this article herein provides an overview of various technologies to strengthen the vapor–liquid mass transfer, including application of external fields, addition of third substances, micro-chemical technology and usage of solid foam, with the objective to contribute to the future developments and potential applications of PI in scientific research and industrial sectors.

Numerical simulation and analysis of mould filling process in lost foam casting

In lost foam casting(LFC)the foam pattern is the key criterion,and the filling process is crucialto ensure the high quality of the foam pattern.Filling which lacks uniformity and denseness will cause variousdefects and affect the surface quality of the casting.The influential factors of the filling process are realized in thisresearch.Optimization of the filling process,enhancement of efficiency,decrease of waste,etc.,are obtained bythe numerical simulation of the filling process using a computer.The equations governing the dense gas-solid two-phase flow are established,and the physical significanceof each equation is discussed.The Euler/Lagrange numerical model is used to simulate the fluid dynamiccharacteristics of the dense two-phase flow during the mould filling process in lost foam casting.The experimentsand numerical results showed that this method can be a very promising tool in the mould filling simulation of beads’movement.

Study on an improved rotating microchannel separator in the intensification for demulsification and separation process

An improved rotating microchannel(IRM) separator was further explored in the intensification for demulsification and separation process. Oil-in-water(O/W) emulsion system of 2-ethylhexyl phosphoric acid-2-ethylhexyl ester(P507)–water without emulsifier was employed to evaluate the performance of the new equipment. In this experiment, the influence on demulsification separation process was explored by changing the geometrical structure and channel height of the microchannel and combining the liquid–liquid two-phase flow pattern, and the correlation general graph between demulsification efficiency and dimensionless parameters was established. The total demulsification effect of the IRM and the separation capacity of the clear organic phase recovered from demulsification are significantly improved. In addition, the liquid–liquid two-phase flow pattern of the clear organic phase after demulsification and the remaining emulsion in the IRM are observed and recorded by high-speed photography. The separation ability of organic phase from the upper outlet can be significantly improved when the total demulsification rate of IRM is up to 90%. There are 3 types and 6 kinds of flow patterns observed. The results demonstrated that the suitable demulsification performance is obtained when the liquid–liquid two-phase inside the IRM is in a parallel pattern. Finally, the relation map between total demulsification efficiency and the universal flow is drawn, which provides a basis for the accurate control of the IRM device.

Purification Processes and Market Potential of Bromelain in Brazil

Bromelain is the denomination given to the group of endoproteases obtained from members of Bromeliacea family. These enzymes have a wide range of proven applications and have been an object of study for worldwide researchers for decades. Over the years, several different downstream processes were studied in order to determine which technique would be worthwhile to be implemented in Brazil and provide the national market with such product. The objective of the present study is to relate the main studies in Brazil that has proven that bromelain purification can be cost-effective, in addition to the well-known benefits owned by such enzymes, and highlight the applications that create their market potential in the Brazilian market.

鸡粪堆肥过程中氮素损失研究综述

好氧堆肥是实现鸡粪资源化处理最主要的技术手段之一。然而在鸡粪堆肥过程中氮素损失较为严重,在降低肥效的同时,还引起严重的面源污染。本文总结影响鸡粪堆肥过程氮素损失的主要原因,并综述初始C/N、初始含水率、翻堆频率、添加剂种类对鸡粪堆肥过程氮素损失的影响,得出减少鸡粪堆肥氮素损失的最适初始C/N为20~25、初始含水率为60%~65%、翻堆频率为7天1次。复合添加剂较单一添加剂更能降低堆肥过程中的氮素损失。最后提出鸡粪堆肥未来方向的研究展望,为今后进行鸡粪堆肥过程中氮素损失的研究提供理论依据。

高效包埋好氧颗粒污泥在农药废水处理中的应用研究

为了高效处理有毒有害的农药废水,研究了包埋好氧颗粒污泥对实际农药废水的处理效果,并对比了包埋好氧颗粒污泥、市政好氧污泥及两者混合体系在实际农药废水活性污泥法处理中的表现。结果表明:在实际农药废水处理中,市政好氧污泥的硝化速率和COD降解速率分别为0.67 mg[N]/(g[SS]·h)和3.54 mg[COD]/(g[SS]·h),两者混合体系的平均硝化速率和COD降解速率分别为5.0 mg[N]/(g[包埋颗粒]·h)和49.05 mg[COD]/(g[包埋颗粒]·h),而包埋好氧颗粒污泥的平均COD降解速率为91.14 mg[COD]/(g[包埋颗粒]·h),并且具有更好的硝化性能,平均硝化速率为18.8 mg[N]/(g[SS]·h)。包埋好氧颗粒污泥对农药废水表现出较强的耐冲击负荷能力,说明了包埋好氧颗粒污泥的投加对提高农药废水氨氮降解效果显著。

The wind-water two-phase erosion and sediment-producing processes in the middle Yellow River basin, China

Based on data from the middle Yellow River basin, a wind-water two-phase mechanism for erosion and sediment-producing processes has been found. By using this mechanism, the extremely strong erosion and sediment yield in the study area can be better explained. The operation of wind and water forces is different in different seasons within a year. During winter and spring, strong wind blows large quantities of eolian sand to gullies and river channels, which are temporally stored there. During the next summer, rainstorms cause runoff that contains much fine loessic material and acts as a powerful force to carry the previously prepared coarse material. As a result, hyperconcentrated flows occur, resulting in high-intensity erosion and sediment yield.

一体化厌氧-变级数缺氧/好氧循环流污水处理装置中试研究

针对现有村镇污水处理技术与装备的不足,开发出适用于村镇污水处理的新型一体化厌氧-变级数缺氧/好氧循环流(A-(AO)_n)同步脱氮除磷、沉淀分离技术与装备,以长沙某污水提升泵站沉砂池的出水作为处理对象开展中试实验。对好氧区不同溶解氧、填料填充比和分区进水条件下装置污水处理效能的变化进行研究,结果表明:当好氧区溶解氧控制在1.5~2.0 mg/L,好氧区填料填充比为30%时,装置的脱氮除磷效果最佳。在不外加碳源且不投加化学除磷药剂的条件下,出水水质优于《城镇污水处理厂污染物排放标准》(GB 18918—2002)的一级A标准。高通量测序结果显示,好氧区投加悬浮球填料后,系统中微生物总量和多样性明显提高,为系统中发生同步硝化反硝化(SND)现象创造了条件。