原位构筑Type-Ⅱ型异质结MgSnOH6/SnO2及其光催化降解罗丹明B的研究

本文采用一锅法水热制备Type-Ⅱ型光催化复合材料MgSn(OH)6/SnO2,并将其用于降解罗丹明B溶液的研究。通过粉末X射线多晶衍射和傅里叶红外反射光谱进行结构表征。研究结果表明,原料MgCl2·6H2O/SnCl4·5H2O=4/6 mmol时,具有最优的光催化降解效果,其降解率在60 min达到99%,光催化降解行为满足赝一级动力学模型,速率常数为0.076 min^-1。光催化活性自由基捕获实验发现,羟基自由基(·OH),超氧自由基(·O2^-)和空穴(h^+)均为主要的氧化活性物种。此外,我们还采用光电化学测量研究了其光催化机理。光催化活性的增强是由于在MgSn(OH)6和SnO2之间形成了Type-II型异质结,加速了光生电子和空穴的有效分离。循环实验表明MSOH-SO-50样品具有良好的光催化降解和结构稳定性。本文的研究为探索新型、高效的半导体光催化剂提供了重要的研究指导。

二氧化钛基Z型异质结光催化剂

二氧化钛(TiO2)因廉价、无毒、化学性质稳定以及具有较强的光催化氧化还原能力,在光催化领域占据着重要的地位。然而,可见光利用率低以及光生电子-空穴对的快速复合是限制其应用的2个主要因素。二氧化钛基Z型异质结作为一种新型光催化剂,既改善了二氧化钛的2个缺陷,又表现出比TiO2更强的氧化或还原能力。本文概括了TiO2光催化剂、异质结光催化剂和TiO2基Z型光催化剂的能带排列和电子传递原则,探讨了Z型异质结和type-Ⅱ异质结的异同点以及区分方法,并归纳总结了TiO2基Z型异质结在光催化领域中的应用。

Experimental method to explore the adaptation degree of type-Ⅱand all-solid-state Z-scheme heterojunction structures in the same degradation system

TiO2 nanoparticles were prepared using the hydrothermal method and modified with CgN to syn-thesize a Type-Ⅱheterojunction semiconductor photocatalyst,TiO2-C;Na.In addition,a carbon layerwas coated onto the TiO2 nanoparticles and the obtained material was uniformly covered on thesurface of CaNa to form an all-solid-state Z-scheme semiconductor photocatalyst,TiO2-C-C3N4,Through characterization by XRD,XPS,SEM,TEM,BET,photoelectrochemical experiments,UV-visible diffuse reflection,and PL spectroscopy,the charge transfer mechanism and band gappositions for the composite photocatalysts were analyzed.The Type-Ⅱand all-solid-state Z-schemeheterojunction structures were compared.By combining microscopic internal mechanisms withmacroscopic experimental phenomena,the relationship between performance and structure wasverified.Experimental methods were used to explore the adaptation degree of different photocata-lytic mechanisms using the same degradation system.This study highlights effective photocatalystdesign to meet the requirements for specific degradation conditions.