By the first-principles calculations, most studies indicated that the (1102)-CoO2 termination of LaCoO3 cannot be stabilized, which disagrees with the experimental observation. Besides the crystal structure, we foun...By the first-principles calculations, most studies indicated that the (1102)-CoO2 termination of LaCoO3 cannot be stabilized, which disagrees with the experimental observation. Besides the crystal structure, we found that the spin states of Co3+ ions could affect surface stability, which previously were not well considered. By examining the different states of Co3+ ions in hexagonal-phase LaCoO3, including low spin, intermediate spin, and high spin states, the surface grand potentials of these facets are calculated and compared. The results show that the spin states of Co3+ ions have an important influence on stability of the LaCoO3 facets. Different from the previous results, the stability diagrams demonstrate that the (1102)- CoO2 termination can stably exist under O-rich condition, which can get an agreement with the experimental ones. Furthermore, the surface oxygen vacancy formation energies (Eov) of stable facets are computed in different spin states. The Eov of these possible exposed terminations strongly depend on the spin state of Co3+ ions: in particular, the Eov of the HS states is lower than that of other spin states. This indicates that one can tune the properties of LaCoO3 by directly tuning the spin states of Co3+ ions.展开更多
In order to explore the propagation law of gas explosion in U type laneways,the propagation law of flame and shock wave in U type duct were experimentally and theoret- ically investigated.It is shown that the shock wa...In order to explore the propagation law of gas explosion in U type laneways,the propagation law of flame and shock wave in U type duct were experimentally and theoret- ically investigated.It is shown that the shock wave takes on the complicated stress state and the flame takes on complicated change rules in the U type duct.The propagation process of gas explosion in bend duct is the mutual action of explosion wave,flame and complicate flow,the destruction in bend surface is especially serious.In the mine exploita- tion and laneway design,the bend laneway should be avoided,especially continuous bend laneway.展开更多
The Lunggar iron deposit belongs to the Bangong-Nujiang metallogenic belt and is located in central Lhasa on the Tibetan Plateau.In the Lunggar deposit,iron mineralization formed in the skarnization contact zone betwe...The Lunggar iron deposit belongs to the Bangong-Nujiang metallogenic belt and is located in central Lhasa on the Tibetan Plateau.In the Lunggar deposit,iron mineralization formed in the skarnization contact zone between the Early Cretaceous granodiorite and the late Permian Xiala Formation limestone.In this study,we achieved detailed zircon U-Pb-Hf isotopes and mineral chemistry for the Early Cretaceous granodiorite.Zircon U-Pb dating results indicate that the Early Cretaceous granodiorite emplaced at ca.119 Ma.Based on the trace elements in zircons and the mineral chemical composition of amphibole and biotite,the Early Cretaceous granodiorite was believed to form under condition of high temperature(>700°C),low pressure(100400 MPa),and relatively high oxygen fugacity(lgfO2)(13.6 to 13.9)and H2O content(4%8%).Zircon trace elements,Hf isotope and biotite chemistry collectively reveal that significant juvenile mantle-derived magmas contributed to the source of the granodiorite.The relatively high logfO2 and shallow magma chamber are beneficial for skarn iron mineralization,implying remarkable potential for further prospecting in the Lunggar iron deposit.展开更多
The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located...The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust.展开更多
Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin, located on the western slope of the Da Hinggan Mountains. The deposit is considere...Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin, located on the western slope of the Da Hinggan Mountains. The deposit is considered as one of the hypabyssal low-temprature hydrothermal lead-zinc deposits associated with volca- nism. In order to lay the foundation on studying its diagenesis and mineralization ages, the detailed studies were carried out by dating the host rocks (i. e. rhyolitic lithic-crystal tufts) using zircon LA-ICP-MS U-Pb method. The dating results show three groups ot! ages. The first group is the captured zircons (the weighted mean ^206pb/238U age as 175.6± 2.3 Ma, MSWD = 0.70, n = 3). The second group can be regarded as the rock- forming age (the weighted mean ^206pb/238U age as 165.3± 1.9 Ma, MSWD = 2.40, n = 14). The third group should represent the late stage of the magmatic evolution (the weighted mean ^206pb/238U age as 161.0 ± 3.1 Ma, MSWD = 0.86, n = 4). According to the ages and the crystal form or CL image characteristics of zircons, it is determined that the diagenesis occurred in the late Middle Jurassic. Based on the regional geology and geo- chronological research, the acidic pyroclastic rocks are space accompaniment and time connection with the Tamu- langou Formation intermediate-mafic volcanic rocks. Both of them constitute the host rocks of the deposit together. The rock combination also provides favorable conditions for large-scale silver, lead and zinc mineralization in this area.展开更多
In this study, the Pb/U fractionation between zircon and uraninite during femtosecond Laser Ablation Inductively Coupled Plasma Mass Spectrometry (fs-LA-ICP-MS) analysis was studied in detail. The results show signi...In this study, the Pb/U fractionation between zircon and uraninite during femtosecond Laser Ablation Inductively Coupled Plasma Mass Spectrometry (fs-LA-ICP-MS) analysis was studied in detail. The results show significant Pb/U fractionation between zircon and uraninite during fs-LA-ICP-MS analysis that when calibrated against the zircon standard M257, the obtained U-Pb age of the Chinese national uraninite standard GBW04420 is 17% older than the recommended value. Thus, the accurate in-situ U-Pb dating of uraninite by LA-ICP-MS requires matrix-matched external standards for calibration. Uraninite in thin sections of two U-mineralized leucogranite from the Gaudeanmus in Namibia was analyzed by a fs-LA-ICP-MS equipped with a Signal Smooth Device (SSD), using laser spot and frequency of 10 μm and 1 Hz, respectively. When calibrated using GBW04420 as the external standard, two samples give weighted mean 2066pb/238U ages of 504±3 Ma (2σ, n=21) and 503±3 Ma (2σ, n=22), and only one of two samples yields a concordia U-Pb age of 507±1 Ma (2or, n=21). These results are consistent with ID-TIMS U-Pb ages of 509±1 and 508±12 Ma and are also indistinguishable from zircon U-Pb upper intercept ages of 506±33 Ma (2σ, n=29) and 501±51 Ma (2σ, n=29). The present study shows that in-situ U-Pb dating of uraninite can deliver more reliable formation ages of the deposit than dating coeval high-U zircon because the latter commonly suffer significant Pb loss after formation. Our results confirm that GBW04420 is an ideal matrix matching standard for in-situ U-Pb dating of uraninite.展开更多
Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investigation, mineral assemblage and mineral geochemistry, two t...Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investigation, mineral assemblage and mineral geochemistry, two types of pegmatites can be defined, i.e., hyalophane pegmatite and hyalophane-rich pegmatite. The hyalophane pegmatite is composed of pure hyalophane with 18.7 mol%-19.4 mol% celsian, whereas the hyalophane-rich pegmatite consists of clinopyroxene + titanite + epidote + hyalophane with 11.9 mol%-12.5 mol% celsian. Hyalophane-rich pegmatite has typical magmatic zircons with oscillatory zoning and high Th/U ratios, implying that this type of pegmatite crystallized from special melt similar to magma. SIMS (Cameca 1280) zircon U-Pb dating shows that the crystallization age of the hyalophane-rich pegmatite is 1812±5 Ma, younger than the regional metamorphic age (peak of ca. 1.85 Ga). Zircon δ18O (8.0 ‰-9.3 ‰) and ?Hf (-7.0 to-2.7) values measured by SIMS suggest that the high-pressure granulite terrain was the source of these veins. Therefore, the hyalophane-rich pegmatite veins were likely to be generated by melting of the high-pressure granulite terrain during post collisional uplift. A quick tectonic uplifting process with a velocity of 0.4 to 0.6 mm/a has been estimated for the high-pressure granulite terrane from the Central Zone of North China Craton.展开更多
The Yaojiazhuang ultramafic-syenitic complex is one of the representative Triassic alkaline plutons on the northern margin of the North China Craton (NCC). Based on detailed study of the zircon U-Pb age, petrologica...The Yaojiazhuang ultramafic-syenitic complex is one of the representative Triassic alkaline plutons on the northern margin of the North China Craton (NCC). Based on detailed study of the zircon U-Pb age, petrological, mineralogical, and geochemical data of the complex, the characteristics of the magmas system, the petrogenesis of different rock types, and the nature of the mantle source were discussed to provide new constraints on the origin and tectonic setting of the Triassic alkaline belt. Cumu- lus ultramafic rocks, clinopyroxene-syenites and syenites are the main rock types of the complex. The zircons from the sye- nites yielded a U-Pb age of 209 Ma. Diopside-augite, biotite, and sanidine-orthoclase are the major minerals, with subordinate apatite and magnetite. Rocks from the complex are enriched in large ion lithophile elements (LILE) and light rare earth ele- ments (LREE), depleted in high field strength elements (HFSE) and heavy rare earth elements (HREE), and the initial 878r]86Sr ranges from 0.7057 to 0.7061 and eNd(t) from -9.4 to -11.4. Mineralogy and geochemical data demonstrate that the parent magma of the complex is SiO2-undersaturated ultrapotassic alkaline-peralkaline, and is characterized by high CaO content and fluid compositions (P205, CO2, H20), and by high oxygen fugacity and high temperature. The complex was originated from a phlogopite-clinopyroxenite-rich lithospheric mantle source in the garnet-stable area (〉 80 km) that had previously been meta- somatized by melts/fluids from altered oceanic crust. The parent magma has been contaminated by little ancient TTG gneisses during magma emplacement. The development of the Yaojiazhuang complex indicates that the northern margin of the NCC has entered into an extensively extensional regime in the Late Triassic.展开更多
The south Gangdese region is the site of subduction of the Neo-Tethys and subsequent continental col- lision. Compared with widespread Cretaceous and Cenozoic magmatism, Early-Middle Jurassic magmatic rocks and relate...The south Gangdese region is the site of subduction of the Neo-Tethys and subsequent continental col- lision. Compared with widespread Cretaceous and Cenozoic magmatism, Early-Middle Jurassic magmatic rocks and related deposits are rarely reported, Our work identified a 〉200 km long felsic rock belt asso- ciated with Cu mineralization in the south Gangdese region. We report here zircon U-Pb ages, zircon Ce4+/Ce3+ values, and mineral assemblages of two Cu mineralized intrusions within the belt. A horn- blende granite and a diorite porphyry were emplaced at 177.3Ma and 166.3Ma, respectively. Geological occurrence and magmatic hematite-magnetite-chalcopyrite intergrowths suggest that Cu mineralization formed coeval with Jurassic intrusions. Mineralized intrusions have high zircon Ce4+/ Ce3+ and EuN/EuN ratios, and hematite-magnetite intergrowths, suggesting their parent magmas were highly oxidized, Hornblende is common and primary fluid inclusions are found in titanite and apatite, indicating their parent magmas were water-saturated and exsotved volatile phases at early stage of rnag- matic evolution. Those magma characters contribute to the formation of porphyry Cu deposits. Given that majority subduction-related porphyry Cu systems have been eroded following uplift and denudation, the well-preserved Early-Middle Jurassic cu mineralized igneous rocks in south Gangdese are favorable prospecting targets for subduction-related porphyry Cu deposits.展开更多
Baotoudong syenite pluton is located to the east of Baotou City, Inner Mongolia, the westernmost part of the Trias- sic alkaline magmatic belt along the northern margin of the North China Craton (NCC). Zircon U-Pb a...Baotoudong syenite pluton is located to the east of Baotou City, Inner Mongolia, the westernmost part of the Trias- sic alkaline magmatic belt along the northern margin of the North China Craton (NCC). Zircon U-Pb age, petrological, miner- alogical and geochemical data of the pluton were obtained in this paper, to constrain its origin and mantle source characteris- tics. The pluton is composed of nepheline-clinopyroxene syenite and alkali-feldspar syenite, with zircon U-Pb age of 214.7±1.1 Ma. Diopside (cores)-aegirine-augite (rims), biotite, orthoclase and nepheline are the major minerals. The Bao- toudong syenites have high contents of rare earth elements (REE), and are characterized by enrichment in light rare earth ele- ments (LREE) and large ion lithophile elements (LILE; e.g., Rb, Ba, Sr), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE). They show enriched Sr-Nd isotopic compositions with initial 87Sr/86Sr ranging from 0.7061 to 0.7067 and eNd(t) values from -9.0 to -11.2. Mineralogy, petrology and geochemical studies show that the parental magma of the syenites is SiO2-undersaturated potassic-ultrapotassic, and is characterized by high contents of CaO, Fe2O3, K2O, Na2O and fluid compositions (H2O), and by high temperature and high oxygen fugacity. The syenites were originated from a phlogopite-rich, enriched lithospheric mantle source in garnet-stable area (〉80 km). The occurrence of the Baotoudong sye- nites, together with many other ultrapotassic, alkaline complexes of similar ages on the northern margin of the NCC in Late Triassic implies that the lithospheric mantle beneath the northern margin of the NCC was previously metasomatized by melts/fluids from the subducted, altered paleo-Mongolian oceanic crust, and the northern margin of the craton has entered into an extensively extensional regime as a destructive continental margin in Late Triassic.展开更多
基金This work was supported by the National Natural Science Foundation of China (No.U1232118, No.21203099), the National Basic Research Program (No.2014CB932403), the Program of Introducing Talents of Disciplines to China Universities (No.B06006), Research Program for Advanced and Applied Technology of Tianjin (No.13JCYBJC36800), Doctoral Fund of Ministry of Education of China (No.20120031120033), Fok Ying Tung Education Foundation (No.151008), and Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund (the second phase). We appreciate the supports from the National Super-Computing Center at Tianjin and Guangzhou.
文摘By the first-principles calculations, most studies indicated that the (1102)-CoO2 termination of LaCoO3 cannot be stabilized, which disagrees with the experimental observation. Besides the crystal structure, we found that the spin states of Co3+ ions could affect surface stability, which previously were not well considered. By examining the different states of Co3+ ions in hexagonal-phase LaCoO3, including low spin, intermediate spin, and high spin states, the surface grand potentials of these facets are calculated and compared. The results show that the spin states of Co3+ ions have an important influence on stability of the LaCoO3 facets. Different from the previous results, the stability diagrams demonstrate that the (1102)- CoO2 termination can stably exist under O-rich condition, which can get an agreement with the experimental ones. Furthermore, the surface oxygen vacancy formation energies (Eov) of stable facets are computed in different spin states. The Eov of these possible exposed terminations strongly depend on the spin state of Co3+ ions: in particular, the Eov of the HS states is lower than that of other spin states. This indicates that one can tune the properties of LaCoO3 by directly tuning the spin states of Co3+ ions.
基金the National Natural Science Foundation of China(50674047,50534090,50574093)State Key Base Development Plan(2005CB221506)
文摘In order to explore the propagation law of gas explosion in U type laneways,the propagation law of flame and shock wave in U type duct were experimentally and theoret- ically investigated.It is shown that the shock wave takes on the complicated stress state and the flame takes on complicated change rules in the U type duct.The propagation process of gas explosion in bend duct is the mutual action of explosion wave,flame and complicate flow,the destruction in bend surface is especially serious.In the mine exploita- tion and laneway design,the bend laneway should be avoided,especially continuous bend laneway.
基金Project(2018YSJS14)supported by the Open Research Fund Program of Key Laboratory of Metallogenic Prediction of Nonferrous Metals and Geological Environment Monitoring(Central South University),Ministry of Education,China
文摘The Lunggar iron deposit belongs to the Bangong-Nujiang metallogenic belt and is located in central Lhasa on the Tibetan Plateau.In the Lunggar deposit,iron mineralization formed in the skarnization contact zone between the Early Cretaceous granodiorite and the late Permian Xiala Formation limestone.In this study,we achieved detailed zircon U-Pb-Hf isotopes and mineral chemistry for the Early Cretaceous granodiorite.Zircon U-Pb dating results indicate that the Early Cretaceous granodiorite emplaced at ca.119 Ma.Based on the trace elements in zircons and the mineral chemical composition of amphibole and biotite,the Early Cretaceous granodiorite was believed to form under condition of high temperature(>700°C),low pressure(100400 MPa),and relatively high oxygen fugacity(lgfO2)(13.6 to 13.9)and H2O content(4%8%).Zircon trace elements,Hf isotope and biotite chemistry collectively reveal that significant juvenile mantle-derived magmas contributed to the source of the granodiorite.The relatively high logfO2 and shallow magma chamber are beneficial for skarn iron mineralization,implying remarkable potential for further prospecting in the Lunggar iron deposit.
基金supported by grants by the National Natural Science Foundation of China (No.41272097)the China Geological Survey Project (No.12120114016601)+1 种基金the Special Fund for Basic Scientific Research of Central Colleges, China University of Geosciences (Wuhan) (No.CUG120702)the Teaching Laboratory Foundation of China University of Geosciences (Wuhan) (No.SKJ2013085,SKJ2014010)
文摘The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust.
基金Supported by National Natural Science Foundation of China(No.41390444)
文摘Erdaohezi lead-zinc deposit belongs to the Derbugan metallogenic belt lying on the northwestern Hailaer-Genhe Mesozoic volcanic basin, located on the western slope of the Da Hinggan Mountains. The deposit is considered as one of the hypabyssal low-temprature hydrothermal lead-zinc deposits associated with volca- nism. In order to lay the foundation on studying its diagenesis and mineralization ages, the detailed studies were carried out by dating the host rocks (i. e. rhyolitic lithic-crystal tufts) using zircon LA-ICP-MS U-Pb method. The dating results show three groups ot! ages. The first group is the captured zircons (the weighted mean ^206pb/238U age as 175.6± 2.3 Ma, MSWD = 0.70, n = 3). The second group can be regarded as the rock- forming age (the weighted mean ^206pb/238U age as 165.3± 1.9 Ma, MSWD = 2.40, n = 14). The third group should represent the late stage of the magmatic evolution (the weighted mean ^206pb/238U age as 161.0 ± 3.1 Ma, MSWD = 0.86, n = 4). According to the ages and the crystal form or CL image characteristics of zircons, it is determined that the diagenesis occurred in the late Middle Jurassic. Based on the regional geology and geo- chronological research, the acidic pyroclastic rocks are space accompaniment and time connection with the Tamu- langou Formation intermediate-mafic volcanic rocks. Both of them constitute the host rocks of the deposit together. The rock combination also provides favorable conditions for large-scale silver, lead and zinc mineralization in this area.
基金supported by the National Natural Science Foundation of China(Grant Nos.41203027 and 41473031)the State Administration of Foreign Expert Affairs of China(Grant No.B07039)the Special Fund for Basic Scientific Research of Central Colleges,China University of Geosciences(Wuhan)(Grant No.CUGL140403)
文摘In this study, the Pb/U fractionation between zircon and uraninite during femtosecond Laser Ablation Inductively Coupled Plasma Mass Spectrometry (fs-LA-ICP-MS) analysis was studied in detail. The results show significant Pb/U fractionation between zircon and uraninite during fs-LA-ICP-MS analysis that when calibrated against the zircon standard M257, the obtained U-Pb age of the Chinese national uraninite standard GBW04420 is 17% older than the recommended value. Thus, the accurate in-situ U-Pb dating of uraninite by LA-ICP-MS requires matrix-matched external standards for calibration. Uraninite in thin sections of two U-mineralized leucogranite from the Gaudeanmus in Namibia was analyzed by a fs-LA-ICP-MS equipped with a Signal Smooth Device (SSD), using laser spot and frequency of 10 μm and 1 Hz, respectively. When calibrated using GBW04420 as the external standard, two samples give weighted mean 2066pb/238U ages of 504±3 Ma (2σ, n=21) and 503±3 Ma (2σ, n=22), and only one of two samples yields a concordia U-Pb age of 507±1 Ma (2or, n=21). These results are consistent with ID-TIMS U-Pb ages of 509±1 and 508±12 Ma and are also indistinguishable from zircon U-Pb upper intercept ages of 506±33 Ma (2σ, n=29) and 501±51 Ma (2σ, n=29). The present study shows that in-situ U-Pb dating of uraninite can deliver more reliable formation ages of the deposit than dating coeval high-U zircon because the latter commonly suffer significant Pb loss after formation. Our results confirm that GBW04420 is an ideal matrix matching standard for in-situ U-Pb dating of uraninite.
基金supported by National Natural Science Foundation of China (Grant Nos. 40730315 and 41023009)State Key Laboratory of Lithospheric Evolution
文摘Hyalophane-rich pegmatites are identified from the Manjinggou high-pressure granulite terrain in the Central Zone of North China Craton. Based on field investigation, mineral assemblage and mineral geochemistry, two types of pegmatites can be defined, i.e., hyalophane pegmatite and hyalophane-rich pegmatite. The hyalophane pegmatite is composed of pure hyalophane with 18.7 mol%-19.4 mol% celsian, whereas the hyalophane-rich pegmatite consists of clinopyroxene + titanite + epidote + hyalophane with 11.9 mol%-12.5 mol% celsian. Hyalophane-rich pegmatite has typical magmatic zircons with oscillatory zoning and high Th/U ratios, implying that this type of pegmatite crystallized from special melt similar to magma. SIMS (Cameca 1280) zircon U-Pb dating shows that the crystallization age of the hyalophane-rich pegmatite is 1812±5 Ma, younger than the regional metamorphic age (peak of ca. 1.85 Ga). Zircon δ18O (8.0 ‰-9.3 ‰) and ?Hf (-7.0 to-2.7) values measured by SIMS suggest that the high-pressure granulite terrain was the source of these veins. Therefore, the hyalophane-rich pegmatite veins were likely to be generated by melting of the high-pressure granulite terrain during post collisional uplift. A quick tectonic uplifting process with a velocity of 0.4 to 0.6 mm/a has been estimated for the high-pressure granulite terrane from the Central Zone of North China Craton.
基金supported by a "Tianshan Scholar" grant from Xinjiang University to Chen Bin
文摘The Yaojiazhuang ultramafic-syenitic complex is one of the representative Triassic alkaline plutons on the northern margin of the North China Craton (NCC). Based on detailed study of the zircon U-Pb age, petrological, mineralogical, and geochemical data of the complex, the characteristics of the magmas system, the petrogenesis of different rock types, and the nature of the mantle source were discussed to provide new constraints on the origin and tectonic setting of the Triassic alkaline belt. Cumu- lus ultramafic rocks, clinopyroxene-syenites and syenites are the main rock types of the complex. The zircons from the sye- nites yielded a U-Pb age of 209 Ma. Diopside-augite, biotite, and sanidine-orthoclase are the major minerals, with subordinate apatite and magnetite. Rocks from the complex are enriched in large ion lithophile elements (LILE) and light rare earth ele- ments (LREE), depleted in high field strength elements (HFSE) and heavy rare earth elements (HREE), and the initial 878r]86Sr ranges from 0.7057 to 0.7061 and eNd(t) from -9.4 to -11.4. Mineralogy and geochemical data demonstrate that the parent magma of the complex is SiO2-undersaturated ultrapotassic alkaline-peralkaline, and is characterized by high CaO content and fluid compositions (P205, CO2, H20), and by high oxygen fugacity and high temperature. The complex was originated from a phlogopite-clinopyroxenite-rich lithospheric mantle source in the garnet-stable area (〉 80 km) that had previously been meta- somatized by melts/fluids from altered oceanic crust. The parent magma has been contaminated by little ancient TTG gneisses during magma emplacement. The development of the Yaojiazhuang complex indicates that the northern margin of the NCC has entered into an extensively extensional regime in the Late Triassic.
基金supported by Strategic Priority Research Program of Chinese Academy of Sciences(XDB03010302)the DREAM project of MOST,China(2016YFC0600407)a contribution No.IS-2396 from GIGCAS
文摘The south Gangdese region is the site of subduction of the Neo-Tethys and subsequent continental col- lision. Compared with widespread Cretaceous and Cenozoic magmatism, Early-Middle Jurassic magmatic rocks and related deposits are rarely reported, Our work identified a 〉200 km long felsic rock belt asso- ciated with Cu mineralization in the south Gangdese region. We report here zircon U-Pb ages, zircon Ce4+/Ce3+ values, and mineral assemblages of two Cu mineralized intrusions within the belt. A horn- blende granite and a diorite porphyry were emplaced at 177.3Ma and 166.3Ma, respectively. Geological occurrence and magmatic hematite-magnetite-chalcopyrite intergrowths suggest that Cu mineralization formed coeval with Jurassic intrusions. Mineralized intrusions have high zircon Ce4+/ Ce3+ and EuN/EuN ratios, and hematite-magnetite intergrowths, suggesting their parent magmas were highly oxidized, Hornblende is common and primary fluid inclusions are found in titanite and apatite, indicating their parent magmas were water-saturated and exsotved volatile phases at early stage of rnag- matic evolution. Those magma characters contribute to the formation of porphyry Cu deposits. Given that majority subduction-related porphyry Cu systems have been eroded following uplift and denudation, the well-preserved Early-Middle Jurassic cu mineralized igneous rocks in south Gangdese are favorable prospecting targets for subduction-related porphyry Cu deposits.
基金the National Natural Science Foundation of China (Grant No. 41302038) Institute of Geology, Chinese Academy of Geological Sciences (Grant No. J1205)
文摘Baotoudong syenite pluton is located to the east of Baotou City, Inner Mongolia, the westernmost part of the Trias- sic alkaline magmatic belt along the northern margin of the North China Craton (NCC). Zircon U-Pb age, petrological, miner- alogical and geochemical data of the pluton were obtained in this paper, to constrain its origin and mantle source characteris- tics. The pluton is composed of nepheline-clinopyroxene syenite and alkali-feldspar syenite, with zircon U-Pb age of 214.7±1.1 Ma. Diopside (cores)-aegirine-augite (rims), biotite, orthoclase and nepheline are the major minerals. The Bao- toudong syenites have high contents of rare earth elements (REE), and are characterized by enrichment in light rare earth ele- ments (LREE) and large ion lithophile elements (LILE; e.g., Rb, Ba, Sr), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE). They show enriched Sr-Nd isotopic compositions with initial 87Sr/86Sr ranging from 0.7061 to 0.7067 and eNd(t) values from -9.0 to -11.2. Mineralogy, petrology and geochemical studies show that the parental magma of the syenites is SiO2-undersaturated potassic-ultrapotassic, and is characterized by high contents of CaO, Fe2O3, K2O, Na2O and fluid compositions (H2O), and by high temperature and high oxygen fugacity. The syenites were originated from a phlogopite-rich, enriched lithospheric mantle source in garnet-stable area (〉80 km). The occurrence of the Baotoudong sye- nites, together with many other ultrapotassic, alkaline complexes of similar ages on the northern margin of the NCC in Late Triassic implies that the lithospheric mantle beneath the northern margin of the NCC was previously metasomatized by melts/fluids from the subducted, altered paleo-Mongolian oceanic crust, and the northern margin of the craton has entered into an extensively extensional regime as a destructive continental margin in Late Triassic.