Formation ages and source regions of the Palaeoproterozoic Gaofan, Hutuo and Dongjiao groups in the Wutai and Dongjiao areas of the North China Craton from SHRIMP U-Pb dating of detrital zircons: Resolution of debates over their stratigraphic relationships

这份报纸在北方中国 Craton 的 Wutai 和 Dongjiao 区域报导 Gaofan， Hutuo 和 Dongjiao 组的元沉积的岩石的由岩屑形成的锆石年龄分布。由岩屑形成的锆石一从 Gaofan 组的 quartzite 主要是在年龄的 2.5 Ga，与大约 2.7 Ga 并且更旧。A 石英岩从 Hutuo 组的基础集团企业的卵石在到 Gaofan 组的 quartzite 的由岩屑形成的锆石年龄分发是类似的。为从 Dongjiao 组的 meta-feldspar-quartz 沙岩，由岩屑形成的锆石的年龄主要在 2.5 Ga 被集中。比 2.6 Ga 旧的锆石都没被识别，但是在年龄与一些是 1.84 Ga 和 2.22.0 Ga。与更早的研究结合了，下列结论能被得出：(1 ) Gaofan 组是在年龄的早 Palaeoproterozoic 并且对迟了的 Neoarchaean Wutai 花岗石绿岩岩层年轻得多、无关，它 unconformably 躺它。因此， Gaofan 组是在诺思中国 Craton 的最旧的 Palaeoproterozoic 元沉积的单位之一。(2 ) Hutuo 组在一个大陆人地下室上在中间的 Palaeoproterozoic (2.14-2.09 Ga ) 被扔，在早 Palaeoproterozoic Gaofan 组后面。(3 ) Dongjiao 组在 1.84 Ga 以后被形成，并且可能属于 Changcheng 系统的更低的部分。(4 ) 从所有三个组的由岩屑形成的锆石显示出 2.5 Ga 的一座明显的年龄山峰，从在北方中国 Craton 在太古代的结束在强烈 tectono-magma-thermal 事件形成的火的岩石被采购。

Decoding Provenance and Tectonothermal Events by Detrital Zircon Fission-Track and U-Pb Double Dating: A Case of the Southern Ordos Basin

Multi-dating on the same detrital grains allows for determining multiple different geo-thermochronological ages simultaneously and thus could provide more details about regional tectonics.In this paper,we carried out detrital zircon fission-track and U-Pb double dating on the Permian-Middle Triassic sediments from the southern Ordos Basin to decipher the tectonic information archived in the sediments of intracratonic basins.The detrital zircon U-Pb ages and fission-track ages,together with lag time analyses,indicate that the Permian-Middle Triassic sediments in the southern Ordos Basin are characterized by multiple provenances.The crystalline basement of the North China Craton(NCC)and recycled materials from pre-Permian sediments that were ultimately sourced from the basement of the NCC are the primary provenance,while the Permian magmatites in the northern margin of NCC and Early Paleozoic crystalline rocks in Qinling Orogenic Collage act as minor provenance.In addition,the detrital zircon fission-track age peaks reveal four major tectonothermal events,including the Late Triassic-Early Jurassic post-depositional tectonothermal event and three other tectonothermal events associated with source terrains.The Late Triassic-Early Jurassic(225–179 Ma)tectonothermal event was closely related to the upwelling of deep material and energy beneath the southwestern Ordos Basin due to the coeval northward subduction of the Yangze Block and the following collision of the Yangze Block and the NCC.The Mid-Late Permian(275–263 Ma)tectonothermal event was associated with coeval denudation in the northern part of the NCC and North Qinling terrane,resulting from the subduction of the Paleo-Asian Ocean and Tethys Ocean toward the NCC.The Late Devonian-early Late Carboniferous(348±33 Ma)tectonothermal event corresponded the long-term denudation in the hinterland and periphery of the NCC because of the arc-continent collisions in the northern and southern margins of the NCC.The Late Neoproterozoic(813–565 Ma)tectonothermal event was associated with formation of the Great Unconformity within the NCC and may be causally related to the Rodinia supercontinent breakup driven by a large-scale mantle upwelling.

Mineral Chemistry,Trace Elements,Isotopic Analysis and Zircon U-Pb Dating in the Hesar Pluton,Northern UDMA,Iran:Implications for Pre-Collisional Magma Mixing

The Hesar pluton in the northern Urumieh-Dokhtar magmatic arc hosts numerous mafic-microgranular enclaves(MMEs).Whole rock geochemistry,mineral chemistry,zircon U-Pb and Sr-Nd isotopes were measured.It is suggested that the rocks are metaluminous(A/CNK=1.32-1.45),subduction-related I-type calc-alkaline gabbro to diorite with similar mineral assemblages and geochemical signatures.The host rocks yielded an U-Pb crystallization age of 37.3±0.4 Ma for gabbro-diorite.MMEs have relatively low SiO_(2) contents(52.9-56.6 wt%)and high Mg^(#)(49.8-58.7),probably reflecting a mantle-derived origin.Chondrite-and mantle-normalized trace element patterns are characterized by LREE and LILE enrichment,HREE and HFSE depletion with slight negative Eu anomalies(Eu/Eu^(*)=0.86-1.03).The host rocks yield(^(87)Sr/^(86)Sr)_(i) ratios of 0.70492-0.70510,positive ε_(Nd)(t)values of+1.55-+2.06 and T_(DM2)of 707-736 Ma,which is consistent with the associated mafic microgranular enclaves((^(87)Sr/^(86)Sr)_(i)=0.705014,ε_(Nd)(t)=+1.75,T_(DM2)=729 Ma).All data suggest magma-mixing for enclave and host rock formation,showing a complete equilibration between mixed-mafic and felsic magmas,followed by rapid diffusion.The T_(DM1)(Nd)and T_(DM2)(Nd)model ages and U-Pb dating indicate that the host pluton was produced by partial melting of the lower continental crust and subsequent mixing with injected lithospheric mantlederived magmas in a pre-collisional setting of Arabian-Eurasian plates.Clinopyroxene composition indicates a crystallization temperature of~1000℃ and a depth of~9 km.

U-Pb Age and Hf Isotope Study of Detrital Zircons from the Wanzi Supracrustals:Constraints on the Tectonic Setting and Evolution of the Fuping Complex,Trans-North China Orogen

Located in the middle segment of the Trans-North China Orogen, the Fuping Complex is considered as a critical area in understanding the evolution history of the North China Craton （NCC）. The complex is composed of various high-grade and multiply deformed rocks, including gray gneiss, basic granulite, amphibolite, fine-grained gneiss and marble, metamorphosed to upper amphibolite or granulite facies. It can be divided into four rock units： the Fuping TTG gneisses, Longquanguan augen gneisses, Wanzi supracrustals, and Nanying granitic gneisses. U-Pb age and Hf isotope compositions of about 200 detrital zircons from the Wanzi supracrustals of the Fuping Complex have been analyzed. The data on metamorphic zircon rims give ages of 1.82-1.84 Ga, corresponding to the final amalgamation event of the NCC, whereas the data for igneous zircon cores yield two age populations at -2.10 and -2.51 Ga, with some inherited ages scattering between 2.5 and 2.9 Ga. These results suggest that the Wanzi supracrustals were derived from the Fuping TTG gneisses （-2.5 Ga） and the Nanying granitic gneisses （2.0-2.1 Ga） and deposited between 2.10 and 1.84 Ga. All zircons with -2.51 Ga age have positive initial εHf values from ＋1.4 to ＋10.9, suggesting an important crustal growth event at -2.5 Ga through the addition of juvenile materials from the mantle. The Hf isotope data for the detrital zircons further imply that the 2.8 Ga rocks are important components in the lower crust, which is consistent with a suggestion from Nd isotope data for the Eastern Block. The zircons of 2.10 Ga population have initial εHf values of-4.9 to ＋6.1, interpreted as mixing of crustal re-melt with minor juvenile material contribution at 2.1 Ga. These results are distinct from that for the Western Block, supporting that the Fuping Complex was emplaced in a tectonic active environment at the western margin of the Eastern Block.

Constraints on sedimentary ages of the Chuanlinggou Formation in the Ming Tombs, Beijing, North China Craton: LA-ICP-MS and SHRIMP U–Pb dating of detrital zircons

Detrital zircons in five sedimentary samples, MC1 to MC5, from the bottom of the Chuanlinggou Formation in the Ming Tombs District, Beijing, were dated with the LA-ICP-MS and SHRIMP U-Pb methods. Age spectra of the five samples show a major peak at 2500 Ma and a secondary peak at 2000 Ma, suggesting their provenances were mainly from the crystalline basement of the North China Craton and the Trans-North China Orogen. The youngest zircon has an age of 1673 d： 44 Ma, indicating that the Chuanlinggou Formation was deposited after this age. From sample MC4 to MC5, lithology changed from a clastic rock （fine-grained sandstone） to a carbonate rock （fine-grained dolomite）, suggesting that the depositional basin became progressively deeper. The age spectrum of sample MC5 shows a major peak at 2500 Ma and a secondary peak at 2000 Ma. Sample MC4, which is stratigraphically lower than sample MC5, only had one peak at 2500 Ma. We conclude that there was a transgressive event when sediments represented by MC5 was deposited, and seawater carried ca. 2000 Ma clastic materials to the basin where the Chuanlinggou Formation was deposited, leading to the addition of ca. 2000 Ma detritus. Our research indicates that the source area for the sediments became more extensive with time. We conclude that the Chuanlinggou Formation in the Ming Tombs District was deposited in a low-energy mud fiat sedimentary environment in the inter-supra tidal zone because it is mainly composed of silty mudstone and fine-grained sandstone with relatively simple sedimentary structures.

Detrital Zircon U-Pb Ages and Geochemistry of the Silurian to Permian Sedimentary Rocks in Central Inner Mongolia, China: Implications for Closure of the Paleo-Asian Ocean

The Solonker suture zone has long been considered to mark the location of the final disappearance of the PaleoAsian Ocean in the eastern Central Asian Orogenic Belt(CAOB). However, the time of final suturing is still controversial with two main different proposals of late Permian to early Triassic, and late Devonian. This study reports integrated wholerock geochemistry and LA-ICP-MS zircon U-Pb ages of sedimentary rocks from the Silurian Xuniwusu Formation, the Devonian Xilingol Complex and the Permian Zhesi Formation in the Hegenshan-Xilinhot-Linxi area in central Inner Mongolia, China. The depositional environment, provenance and tectonic setting of the Silurian-Devonian and the Permian sediments are compared to constrain the tectonic evolution of the Solonker suture zone and its neighboring zones. The protoliths of the silty slates from the Xuniwusu Formation in the Baolidao zone belong to wacke and were derived from felsic igneous rocks with steady-state weathering, poor sorting and compositional immaturity. The protoliths of metasedimentary rocks from the Xilingol Complex were wackes and litharenites and were sourced from predominantly felsic igneous rocks with variable weathering conditions and moderate sorting. The Xuniwusu Formation and Xilingol Complex samples both have two groups of detrital zircon that peak at ca. 0.9-1.0 Ga and ca. 420-440 Ma, with maximum deposition ages of late Silurian and middle Devonian age, respectively. Considering the ca. 484-383 Ma volcanic arc in the Baolidao zone, the Xuxiniwu Formation represents an oceanic trench sediment and is covered by the sedimentary rocks in the Xilingol Complex that represents a continental slope sediment in front of the arc. The middle Permian Zhesi Formation metasandstones were derived from predominantly felsic igneous rocks and are texturally immature with very low degrees of rounding and sorting, indicating short transport and rapid burial. The Zhesi Formation in the Hegenshan zone has a main zircon age peak of 302 Ma and a subordinate peak of 423 Ma and was deposited in a back-arc basin with an early marine transgression during extension and a late marine regression during contraction. The formation also crops out locally in the Baolidao zone with a main zircon age peak of 467 Ma and a minor peak of 359 Ma, and suggests it formed as a marine transgression sedimentary sequence in a restricted extensional basin and followed by a marine regressive event. Two obvious zircon age peaks of 444 Ma and 280 Ma in the Solonker zone and 435 Ma and 274 Ma in Ondor Sum are retrieved from the Zhesi Formation. This suggests as a result of the gradual closure of the Paleo-Asian Ocean a narrow ocean sedimentary environment with marine regressive sedimentary sequences occupied the Solonker and Ondor Sum zones during the middle Permian. A restricted ocean is suggested by the Permian strata in the Bainaimiao zone. Early Paleozoic subduction until ca. 381 Ma and renewed subduction during ca. 310-254 Ma accompanied by the opening and closure of a back-arc basin during ca. 298-269 Ma occurred in the northern accretionary zone. In contrast, the southern accretionary zone documented early Paleozoic subduction until ca. 400 Ma and a renewed subduction during ca. 298-246 Ma. The final closure of the Paleo-Asian ocean therefore lasted at least until the early Triassic and ended with the formation of the Solonker suture zone.

New detrital zircon U-Pb ages from BIF-related metasediments in the Ntem Complex (Congo craton) of southern Cameroon, West Africa

Banded Iron Formations (BIFs) were formed by contemporaneous events of active sediments supply and the venting of a hydrothermal fluid source at the Mid-Ocean-Ridge. BIFs within the Ntem Complex at the northern edge of the Congo Craton are intercalated with metasandstones and siltstones. SHRIMP U-Pb analysis on detrital zircons obtained from these metasediments gave variable ages from over 3000 Ma to 1000 Ma with the maximum age of deposition clustered around 1200 Ma and the peak of deposition at 1800 Ma. This age range suggested that the sub-basin was opened sometime in the Archean and remained active up till the Neoproterozoic. Zircons with Archean ages have a provenance linked to the charnockitic suite and the high-K granites within the Ntem Complex. The Paleoproterozoic ages are attributed to clastic inputs from the neigbouring Nyong Series west of the Ntem Complex. Also the peak of deposition in the Proterozoic could probably be explained by the globally recognized intense crust-forming processes in the Early Proterozoic time. The provenance of the younger Neoproterozoic ages is tied to various lithologies within the northern mobile belts of the Adamawa-Yade massifs and correlates with Neoproterozoic sedimentation ages in the Yaoundé, Lom and Poli series. The Neoproterozoic ages obtained are comparable to those obtained from metasediments of the Amazonian Craton and provide evidence of Pre-Gondwana assemblage of the Congo and the S?o Francisco Cratons.

Detrital Zircon U-Pb Geochronology： New Insight into the Provenance of Sanya Formation in the Yinggehai Basin

Objective The NNW-SSE trending Yinggehai Basin, located on the continental shelf at water depths of 50-200 m in the northwestern South China Sea, is a Cenozoic conversion extensional basin. Over the past decades, a number of hydrocarbon reservoirs have been discovered in the deepwater area of the basin, including the Lingtou Formation （Eocene）, Yacheng and Lingshui formations （Oligocene）, Sanya, Meishan and Huangliu formations （Miocene） and Yinggehai Formation （Pliocene）, which are covered by Quaternary sediments and underlain by pre- Paleogene strata.

Detrital zircon U-Pb age perspective on the sediment provenance and its geological significance of sandstones in the Lamandau region, SW Borneo, Indonesia

The Southwest Borneo(SW Borneo)block belongs to Sundaland and is the oldest continental fragment of Borneo that is believed to derive from the Gondwana land.The U-Pb isotopic dating ages of 113 detrital zircons from sandstones of the Ketapang Complex in SW Borneo range from 3298 Ma to 78 Ma,and show six major age populations:2476-2344 Ma,2016-1831 Ma,1296-759 Ma,455-406 Ma,262-210 Ma,and 187-78 Ma.The youngest age of these detrital zircons is 78 Ma,indicating that the maximum depositional age of the sandstones is Campanian.Permian-Late Cretaceous detrital zircons are interpreted as having been derived from the nearby Schwaner Mountains and the Permian-Triassic tin belt granitoids in Southeast Asia(SE Asia).Archean-Carboniferous detrital zircons have a continental Gondwana provenance,with their age spectra similar to those of northwestern Australia,indicating that these zircons could be derived from the orogenic belts and cratons in northwestern and central Australia.The provenance of these detrital zircons in this study indicates the SW Borneo block was located on the northwestern margin of Australia during the Paleozoic,in the region of the Banda Embayment.SW Borneo rifted from Australia and moved northward in the Early Jurassic,and this block was added to Sundaland in the Early Cretaceous.The Luconia-Dangerous Grounds continental fragment derived from East Asia collided with SW Borneo after subduction in the Cretaceous,which induced the widespread magmatism in the Schwaner Mountains in SW Borneo.

LA-ICP-MS U-Pb Geochronology of Detrital Zircons in Eastern Liaoning Province： An Early Paleozoic Formation Associated with the Gondwana Supercontinent Event

Objective The Liao-Ji orogenic belt is a famous Paleoproterozoic orogenic belt in the East Block of the North China Craton(NCC),which extend in NE-SW direction.The geological mass in the Paleoproterozoic Liao-Ji belt is mainly composed of the Liaoji granites and metamorphic volcanic-sedimentary rocks of the Liaohe group(and its

Detrital Zircon U-Pb Ages of the Zhaojiazhuang Formation, Middle–South Section, Taihang Mountains, China and their Geological Significance

The sedimentary Zhaojiazhuang Formation overlies the ancient Paleo-proterozoic crystalline basement in the middle-south sections of the Taihang Mountains,China.It is a complete stratigraphic sequence with clear boundaries.The formation has an angular unconformity with the underlying Paleo-proterozoic Tongyu Formation and a parallel unconformity with the overlying Changzhougou Formation from the Changcheng System,which is widely distributed throughout the W utai-Zhongtiao-T aihang Mountains.Qiu Zhen et al.(2007)and Wang Qingchun et al.

The Tectonic Implications of the Hongliuhe-Xichangjing Ophiolitic Mélanges Belt in the Central Region of the Beishan Orogen, NW China——Constrained by the U-Pb Ages of Detrital Zircons of the Metasandstones

The tectonic attributes of different blocks within orogenic belts are of great significance for the study of accretionary processes and the evolution of Earth. The Hongliuhe-Niujianzi-Baiyunshan-Xichangjing ophiolitic mélange belt(HXOMB) is distributed in the heart of the Beishan Orogen, the Shuangyingshan and Minshui-Hanshan blocks being distributed in the south and north of the HXOMB respectively, and a large number of Early Paleozoic geological units are exposed on the blocks. According to the zircon age populations of the metasandstones in the Baiyunshan area recovered in this paper, when compared with the zircon age populations of the Paleozoic metasandstones reported in the Niujuanzi and Hanshan areas, we found that the metasandstones of the Shuangyingshan Block have age peaks at c. 598 Ma, 742 Ma, 828 Ma, 941 Ma, 990 Ma, 1168 Ma, 1636 Ma, 2497 Ma with non-significant age populations of 1500–1300 Ma, showing a possible affinity with the Tarim Craton;the metasandstones of the Minshui-Hanshan Block have age peaks at c. 606 Ma, 758 Ma, 914 Ma, 1102 Ma, 1194 Ma, 1304 Ma, 1672 Ma with significant age populations of 1500-1300 Ma, showing a possible affinity with the Chinese Central Tianshan Block. Therefore, the HXOMB of the Beishan Orogen is of great significance in plate segmentation, which separates the Tarim Craton in the south and the Chinese Central Tianshan Block in the north. Based on the evolutionary process of the Hongliuhe-Xichangjing ocean in the Beishan Orogen, we believe that break-up and convergence can be recognized as having occurred twice between the Chinese Central Tianshan Block and the Tarim Craton since the Mesoproterozoic in the Beishan area. This was related firstly to the break-up of the Columbia Supercontinent and the convergence of the Rodinia Supercontinent, mainly during the Middle Mesoproterozoic to Early Neoproterozoic, and secondly to the opening and closing of the Hongliuhe-Xichangjing ocean, mainly during the Early Paleozoic.

LA-ICP-MS U-Pb Geochronology of Detrital Zircon in the Guanzhong Basin, China and Its Tectonic Response

Objective The Guanzhong Basin in the transitional zone of the Qinling orogenic belt and the southern margin of the Ordos Basin has been extensively studied in recent years.Although some results have been obtained,some problems such as whether the materials from the North China craton and the Qinling orogenic belt are detrital sedimentary rocks of the Guanzhong Basin still remain unresolved.

Detrital Zircon U-Pb Dating for Clastic Rocks from Boreholes in the Eastern Junggar Basin:Constraints on Permian Tectonics in the Southern Central Asian Orogenic Belt

Permian sedimentary successions,widely distributed in the eastern Junggar Basin,may record key details on the closure of the Paleo-Asian Ocean in this region.Results of boreholes show that Permian strata is mainly composed of mudstone,sandy mudstone,siltstone,sandstone,sandy conglomerate,dolomite,and limestone.Detrital zircon U-Pb dating results of three sandstone samples yielded the calculated maximum ages of 296 Ma,278 Ma and 293 Ma,indicating they possibly deposited during the Early Permian.Permian strata in the eastern Junggar Basin show similar rock associations and detrital zircon age data distribution patterns.Our new and compiled age data for sandstone samples in the eastern Junggar Basin and Bogda region yield predominant Paleozoic ages,close to their sedimentary ages.Such detrital zircon age data distribution patterns support the hypothesis that these Early Permian meta-clastic rocks in the eastern Junggar Basin and Bogda region were deposited in a subduction-related basin,and indicate an Early Permian Ocean prevented Precambrian detritus from the Central Tianshan block from depositing in the eastern Junggar Basin and Bogda region.

Chronology and Sources of Mesozoic Intrusive Complexes in the Xuzhou-Huainan Region, Central China: Constraints from SHRIMP Zircon U-Pb Dating

SHRIMP zircon U-Pb dating in the Liguo and Jiagou intrusives indicates that they were formed at -130 Ma in the Early Cretaceous. Most inherited zircons in the Liguo intrusive were formed at 2509±43 Ma. Most inherited and detrital zircons in the Jiagou intrusive were formed at -2500 Ma, -2000 Ma and -1800 Ma. The SHRIMP zircon U-Pb dating in two gneiss xenoliths from the Jiagou intrusive yields the ages of 2461±22 Ma and 2508±15 Ma, respectively. The dating results from inherited and detrital zircons in the intrusives and the gneiss xenoliths imply that the magmas could be derived from the partial melting of the basement of the North China Block (NCB). The magmatism is strong and extensive in the periods from 115 to 132 Ma, which is of typical bimodal characteristics. It is suggested that the lithospheric thinning in the eastern North China Block reached its peak in 115-132 Ma.

An Important Spreading Event of the Neo-Tethys Ocean during the Late Jurassic and Early Cretaceous: Evidence from Zircon U-Pb SHRIMP Dating on Diabase in Nagarze, Southern Tibet

Widely distributed in Gyangzê-Chigu area, southern Tibet, NW- and nearly E-W-trending diabase（gabbro）-gabbro diorite dykes are regarded as the product of the large-scale spreading of the late Neo-Tethys Ocean. In order to constrain the emplacement age of these dykes, zircons of two samples from diabases in Nagarzê were dated by using the U-Pb SHRIMP method. Two nearly the same weighted mean ^206pb/^23SU ages were obtained in this paper, which are 134.9±1.8 Ma （MSWD=0.65） and 135.5 ± 2.1 Ma （MSWD=1.40）, respectively. They not only represent the crystallization age of the diabase, but also documented an important spreading event of the Neo-Tethys Ocean during the late Jurassic and early Cretaceous. This dating result is of great significance to reconstruct the temporal framework of the late Neo-Tethys Ocean in the Qinghai-Tibet Plateau.

Geological Characteristics and Zircon U-Pb Dating of Volcanic Rocks from the Beizhan Iron Deposit in Western Tianshan Mountains, Xinjiang, NW China

The Beizhan large iron deposit located in the east part of the Awulale metallogenic belt in the western Tianshan Mountains is hosted in the Unit 2 of the Dahalajunshan Formation as lens, veinlets and stratoid, and both of the hanging wall and footwall are quartz-monzonite; the dip is to the north with thick and high-grade ore bodies downwards. Ore minerals are mainly magnetite with minor sulfides, such as pyrite, pyrrhotite, chalcopyrite and sphalerite. Skarnization is widespread around the ore bodies, and garnet, diopside, wollastonite, actinolite, epidote, uralite, tourmaline sericite and calcite are ubiquitous as gangues. Radiating outwards from the center of the ore body the deposit can be classified into skarn, calcite, serpentinite and marble zones. LA-ICP-MS zircon U-Pb dating of the rhyolite and dacite from the Dahalajunshan Formation indicates that they were formed at 301.3±0.8 Ma and 303.7±0.9 Ma, respectively, which might have been related to the continental arc magmatism during the late stage of subduction in the western Tianshan Mountains. Iron formation is genetically related with volcanic eruption during this interval. The Dahalajunshan Formation and the quartz-monzonite intrusion jointly control the distribution of ore bodies. Both ore textures and wall rock alteration indicate that the Beizhan iron deposit is probably skarn type.

Geochemical Characteristics and LA-ICP-MS Zircon U-Pb Dating of Amphibolites in the Songshugou Ophiolite in the Eastern Qinling

Geochemical studies on the arnphibolites in the Songshugou ophiolite from Shangnan County, Shaanxi Province demonstrate that the protolith of the amphibolites is tholeiitic. The arnphibolites can be classified into two groups according to their REE patterns and trace element features. Rocks of the first group are depleted in LREE while rocks of the second group are slightly depleted in LREE or flat from LREE to HREE without significant Eu anomaly. The first group of rocks have (La/Yb)N=0.33-0.55, (La/Sm)N= 0.45-0.65, and their La/Nb, Ce/Zr, Zr/Nb, Zr/Y and Ti/Y ratios are averaged at 1.20, 0.12, 31.02, 2.92 and 198, respectively, close to those of typical N-MORB. The second group of rocks have (La/Yb)N=0.63-0.95, (La/ Sm)N = 0.69--0.90, and their average La/Nb, Ce/Zr, Zr/Nb, Zr/Y and Ti/Y ratios are 0.82, 0.83, 1.15, 0.16, 19.00, 2.58 and 225, respectively, which lie between those of typical N-MORB and E-MORB but closer to the former. The two groups of rocks both exhibit flat patterns from Th to Yb in the highly incompatible elements spider diagram, but the first group of rocks have lower element abundances than the modern N-MORB, indicating a derivation of their mantle source from more depleted mantle source than the present N-MORB. The abundances of Th, Ta, Nb, La and Ce in the second group of rocks are slightly higher than those of the present N-MORB, and other elements, such as Hf, Zr, Sm, Ti, Y and Yb, are close to those of the N-MORB, indicating that the original magma was derived from depleted mantle but mixed with the enriched mantle. These characteristics, combined with the regional geology and previous studies, provide further evidence that the mafic-ultramafic rocks have the features of a typical ophiolite.Zircon grains from the amphibolite are generally rounded, and in most of them a distinguishable core-mantle texture is preserved as shown in the cathodoluminescence (CL) images. The core or core-mantle parts of the zircon grains are also rounded, same as those in basalts from other regions of the world. The LA-ICP-MS trace element and U-Pb isotopic analyses show that the zircon grains from the amphibolites are similar to the typical magmatic zircon in terms of their very low U and Th contents (62.36-0.10 μg/g and 78.47-0.003 μg/g, respectively). Seven pits from the core and core-mantle parts of the zircon grains yielded an average weighted 206Pb/ 238U age of 973±35 (2σ) Ma with the Th/U ratios range from 0.01 to 8.38 and mostly greater than 0.23. This age is consistent within the error range with the whole-rock Sm-Nd isochron age of 1030±46 Ma for the same kind of rocks reported by Dong et al. (1997a). In a combined analysis with the zircon positions on the CL images and the corresponding Th/U ratios, the age of 973±35 Ma is probably the formation age of tholeiite, the protolith of the Songshugou amphibolite. The geochronological determination gives further evidence that the Songshugou ophiolite was formed during the Neoproterozoic. In addition, there is one pit from the rim of a zircon grain giving a 206Pb/ 238U age of 5721199 (1σ) Ma with a Th/U ratio of 0.08. It may represent the age of the accretionary zircon in the amphibolite-facies metamorphism.

Zircon U-Pb Dating on Granitoids from the Northern South China Sea and its Geotectonic Relevance

Zircon U-Pb ages of 163.8-100.4 Ma and 146.6-134.5 Ma are obtained for the granitoids from the Pearl River mouth basin, and from southern Guangdong Province, respectively. These new dating data accord well with the crystallization ages of Yanshanian granitoids broadly in the Nanling. The active continental margin of South China, as revealed by a combination of zircon U-Pb data, underwent a key granitoid-dominated magmatism in 165-100 Ma. Its evolution varied temporally, and spatially, registering under control of the paleo-Pacific slab subduction. The granitoids that occurred in 165-150 Ma broadly from the South China Sea to the Nanling are preferably related to two settings from volcanic-arc to back-arc extension, respectively. The activities of Cretaceous granitoids migrated from the southeastern Guangdong （148-130 Ma） to the Pearl River Mouth basin （127-112 Ma）, corresponding to the model of a retreating subduction. The subduction-related granitoid magmatism in South China continued until 108-97 Ma. A tectonic transformation from slab-subduction to extension should occur at -100 Ma.

LA-ICP-MS Zircon U-Pb Dating of Intermediate-Acidic Intrusive Rocks and Molybdenite Re-Os Dating from the Bangpu Mo (Cu) Deposit, Tibet and its Geological Implication

The multi-stage intrusions of intermediate-acid magma occur in the Bangpu mining district, the petrogenic ages of which have been identified. The times and sequences of their emplacement have been collated and stipulated in detail in this paper by using the laser ablation-inductively coupled plasma-mass spectrometry （LA-ICP-MS） zircon U-Pb dating method. The ages of biotite monzogranite that were formed before mineralization in the southwest of this mining district are 70±1 Ma （mean square of weighted deviates （MSWD） =9.5, n=8） and 60.60±0.31 Ma （MSWD=3.8, n=16）, which belong to the late Cretaceous-early Paleocene in age. That means, they are products of an early tectonicmagmatic event of the collision between the Indian and Asian continentals. The ages of ore-bearing monzogranite porphyry and ore-bearing diorite porphyrite are 16.23±0.19 Ma （MSWD=2.0, n=26） and 15.16±0.09 Ma （MSWD=3.9, n=5） separately, which belong to the middle Miocene in age; namely, they are products of the Gangdese post-collision extensional stage when crust-mantle materials melted and mixed as well as magmatic intrusion simultaneously occurred. Some zircons with ages of 203.6±2.2 Ma （MSWD=1.18, n=7） were captured in the ore-bearing diorite porphyrite, which shows that there had been tectono-magmatic events in the late Triassic-early Jurassic. Molybdenum （copper） ore-bodies produced in the monzogranite porphyry and copper （molybdenum） ore-bodies produced in the diorite porphyrite are the main ore types in this ore deposit. The model ages of Re-Os isotopic dating for the 11 molybdenite are 13.97-15.84 Ma, while isochron ages are 14.09±0.49 Ma （MSWD=26）. The isochron ages of seven molybdenite from molybdenum （copper） ore with monzogranite porphyry type are 14.11±0.31 Ma （MSWD=5.2）. There is great error in the isochron ages of four molybdenite from copper （molybdenum） ore with diorite porphyrite type, and their weighted average model ages of 14.6±1.2 Ma （MSWD=41）, which generally represent the mineralization age. The results about the Re-Os isotopic dating of molybdenite in the ore of different types have limited exactly that, the minerlazation age of this ore deposits is about 14.09 Ma, which belongs to the middle Miocene mineralization. The Bangpu deposit has a uniform metallogenic dynamics background with the porphyry type and skarn-type deposits such as Jiama, Qulong and others.