A new copper strip production technology combined with continuous extrusion and rolling technology was proposed. The roll velocity must first be matched with the continuous extrusion velocity to achieve continuous ext...A new copper strip production technology combined with continuous extrusion and rolling technology was proposed. The roll velocity must first be matched with the continuous extrusion velocity to achieve continuous extrusion and roll forming. The bite condition of continuous extrusion was determined, and the compatibility equation between the roll velocity and parameters such as the extrusion wheel velocity, reduction, and strip size was established through mechanical by plastic theoretical calculations. The finite element model of continuous extrusion and rolling was then established by using the TLJ400 continuous extrusion machine with a roll diameter of 200 mm. The relationship between the continuous extrusion and rolling velocities was determined through numerical simulations by software DEFORM-3D, and the accuracy of compatibility equation of velocity was verified.展开更多
The kinetics of extraction and stripping of copper （Ⅱ） was investigated by the single drop technique with a new extractant N902 （a derivative of the salicylal-doxime） and the rate equations of extraction and stri...The kinetics of extraction and stripping of copper （Ⅱ） was investigated by the single drop technique with a new extractant N902 （a derivative of the salicylal-doxime） and the rate equations of extraction and stripping were derived, respectively. The apparent activation energies of extraction and stripping were estimated to be 20.14 kJ/mol and 30.0 k J/mol.展开更多
Adsorptive enhancements of several water-soluble polymers on copper(Ⅱ) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode. Increases in peak current of cu(Ⅱ) were observed in al...Adsorptive enhancements of several water-soluble polymers on copper(Ⅱ) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode. Increases in peak current of cu(Ⅱ) were observed in alkaline carbonate media. The enhancing power of poly(vinyl alcohol), starch and polyallylamine is 15, 4. 1, and 2.5 times, repectively展开更多
Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study on influence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has been carried out. The results indicated that...Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study on influence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has been carried out. The results indicated that copper segregation and enrichment at interfacial layer between oxidized surface and steel matrix is the key factor, which results in microcracks and edge flaws on the strips. The primary considerations to prevent detrimental effects from Cu include controlling copper content in proper level, higher soaking temperature and non-oxidizable atmosphere during soaking. Copper sulfide precipitates with nanometers in size were observed, they may be beneficial to the properties of CSP products, and influence of Cu on quality of CSP hot strips is discussed.展开更多
Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study oninfluence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has beencarried out. The results indicated that c...Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study oninfluence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has beencarried out. The results indicated that copper segregation and enrichment at interfacial layerbetween oxidized surface and steel matrix is the key factor, which results in microcracks and edgeflaws on the strips. The primary considerations to prevent detrimental effects from Cu includecontrolling copper content in proper level, higher soaking temperature and non-oxidizable atmosphereduring soaking. Copper sulfide precipitates with nanometers in size were observed, they may bebeneficial to the properties of CSP products, and influence of Cu on quality of CSP hot strips isdiscussed.展开更多
A stripping method for the determination of hypoxanthine in the presence of copper at the submicromolar concentration levels is described. The method is based on controlled adsorptive accumulation of hypoxanthine-copp...A stripping method for the determination of hypoxanthine in the presence of copper at the submicromolar concentration levels is described. The method is based on controlled adsorptive accumulation of hypoxanthine-copper at the thin-film mercury electrode followed by a fast linear scan voltammetric measurement of the surface species. Optimum experimental conditions were found to be the use of 1.0 × 10﹣3 mol·L﹣1 NaOH solution as electrolyte supporting, an accumulation potential of ﹣0.50 V and a linear scan rate of 200 mV·s﹣1. The response of hypoxanthine-copper is linear over the concentration ranges of 10 - 60 ppb. For an accumulation time of 30 minutes, the detection limit was found to be 250 ppt (1.8 × 10﹣9 mol·L﹣1). Adequate conditions for measuring the hypoxanthine in the presence of metal ions, xanthine, uric acid and other nitrogenated bases were also investigated. The utility of the method is demonstrated by the presence of hypoxanthine associated in ATP or ssDNA.展开更多
Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosp...Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosphate or media owing to adsorption Silicate can also enhance the peak current of Cu(II). The enhancing power phosphate,carbonate, and silicate is 33, 26, and 8.9 times, respectively.展开更多
A novel solvent extraction process for extraction and separation of copper from other base metal ions using a bifunctional ionic liquid (IL) (trioctylmethylammonium/2,4,4-trimethylpentyl phosphinate, [A336/Cy272]) in ...A novel solvent extraction process for extraction and separation of copper from other base metal ions using a bifunctional ionic liquid (IL) (trioctylmethylammonium/2,4,4-trimethylpentyl phosphinate, [A336/Cy272]) in kerosene was reported. This IL was found to extract copper more efficiently than the individual extractants Aliquat 336 or Cyanex 272. Formation of an octahedral copper-IL complex was characterized by UV-Visible spectra and metal ligand interaction was confirmed by FTIR spectra. The loading capacity of 0.1 mol/L [A336/Cy272] was found to be 1.71 g/L. Stripping studies reported that 0.298 g/L copper ions were efficiently stripped using 0.1 mol/L sulfuric acid from 0.05 mol/L loaded IL. The selectivity of copper against nickel, cadmium and iron was investigated from their equimolar binary mixtures using 0.05 mol/L [A336/Cy272] in kerosene. The highest separation factorβCu/Cd=8.41 was obtained at pH 3.56. Copper can be effectively separated from nickel over the pH range studied. The IL extracts preferentially iron over copper and the highest separation factorβFe/Cuwas 3246 at pH 2.4. The extraction rate of metal ions from a synthetic solution containing copper with other metal impurities was in the order of Fe>Zn>Cu>Cd>Co>Ni.展开更多
The chemical compositions and microstructures of the armor strips excavated from the Emperor Qin Shi Huang's mausoleum were examined systematically by using optical microscopy and electron microscopy.It was found ...The chemical compositions and microstructures of the armor strips excavated from the Emperor Qin Shi Huang's mausoleum were examined systematically by using optical microscopy and electron microscopy.It was found that the armor strips were made of pure copper.Based on the morphology of α-Cu recrystal grain and copper sulphide(Cu2S) inclusions in the armor strips,the manufacturing techniques were proposed as follows:smelting pure copper,casting a lamellar plate,forming the cast ingots into sheets through repeated cold forging combined with annealing heat treatment,and finally cutting the sheets into filaments.Furthermore,through the deformation of copper sulphide(Cu2S) inclusions in the strips,the work rate during forging was evaluated and calculated to be close to 75%.展开更多
Nanomolar levels of the hypoxanthine in NaOH electrolyte cantaining copper(Ⅱ) can be determined by anodic stripping voltammetry at a glassy carbon electrode. In the present article hypoxanthine Cu + is shown to be ...Nanomolar levels of the hypoxanthine in NaOH electrolyte cantaining copper(Ⅱ) can be determined by anodic stripping voltammetry at a glassy carbon electrode. In the present article hypoxanthine Cu + is shown to be adsorbed on the electrode surface in the presence of an excess of copper(Ⅱ). After accumulation period, hypoxanthine Cu + was stripped from the electrode surface and the anodic current coming near to the oxidation of Cu(Ⅰ) to Cu(Ⅱ) was measured. A linear calibration curve in the range of 5 nmol/L 1.5 mmol/L hypoxanthine, with a detection limit of 0.5 nmol/L hypoxanthine were obtained.展开更多
基金Project(51175055) supported by the National Natural Science Foundation of ChinaProject(201102020) supported by the Natural Science Foundation of Liaoning Province,ChinaProject(2011BAE23B01) supported by the National Key Technology R&D Program of China
文摘A new copper strip production technology combined with continuous extrusion and rolling technology was proposed. The roll velocity must first be matched with the continuous extrusion velocity to achieve continuous extrusion and roll forming. The bite condition of continuous extrusion was determined, and the compatibility equation between the roll velocity and parameters such as the extrusion wheel velocity, reduction, and strip size was established through mechanical by plastic theoretical calculations. The finite element model of continuous extrusion and rolling was then established by using the TLJ400 continuous extrusion machine with a roll diameter of 200 mm. The relationship between the continuous extrusion and rolling velocities was determined through numerical simulations by software DEFORM-3D, and the accuracy of compatibility equation of velocity was verified.
基金Project supported by the Shanghai Leading Academic Discipline Project(Grant No.S30109)the Opening Project of Key Laboratory of Solid Waste Treatment and Resource Recycle(SWUST)+1 种基金the Ministry of Education(Grant No.09zxgk02)the Science and Technology Commission of Shanghai Municipality(Grant No.09DZ1204403)
文摘The kinetics of extraction and stripping of copper （Ⅱ） was investigated by the single drop technique with a new extractant N902 （a derivative of the salicylal-doxime） and the rate equations of extraction and stripping were derived, respectively. The apparent activation energies of extraction and stripping were estimated to be 20.14 kJ/mol and 30.0 k J/mol.
文摘Adsorptive enhancements of several water-soluble polymers on copper(Ⅱ) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode. Increases in peak current of cu(Ⅱ) were observed in alkaline carbonate media. The enhancing power of poly(vinyl alcohol), starch and polyallylamine is 15, 4. 1, and 2.5 times, repectively
文摘Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study on influence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has been carried out. The results indicated that copper segregation and enrichment at interfacial layer between oxidized surface and steel matrix is the key factor, which results in microcracks and edge flaws on the strips. The primary considerations to prevent detrimental effects from Cu include controlling copper content in proper level, higher soaking temperature and non-oxidizable atmosphere during soaking. Copper sulfide precipitates with nanometers in size were observed, they may be beneficial to the properties of CSP products, and influence of Cu on quality of CSP hot strips is discussed.
文摘Electron microscopy and X-ray Energy Dispersive Spectroscopy (XEDS) study oninfluence of Cu on low carbon hot strips produced by CSP (Compact Strip Production) process has beencarried out. The results indicated that copper segregation and enrichment at interfacial layerbetween oxidized surface and steel matrix is the key factor, which results in microcracks and edgeflaws on the strips. The primary considerations to prevent detrimental effects from Cu includecontrolling copper content in proper level, higher soaking temperature and non-oxidizable atmosphereduring soaking. Copper sulfide precipitates with nanometers in size were observed, they may bebeneficial to the properties of CSP products, and influence of Cu on quality of CSP hot strips isdiscussed.
文摘A stripping method for the determination of hypoxanthine in the presence of copper at the submicromolar concentration levels is described. The method is based on controlled adsorptive accumulation of hypoxanthine-copper at the thin-film mercury electrode followed by a fast linear scan voltammetric measurement of the surface species. Optimum experimental conditions were found to be the use of 1.0 × 10﹣3 mol·L﹣1 NaOH solution as electrolyte supporting, an accumulation potential of ﹣0.50 V and a linear scan rate of 200 mV·s﹣1. The response of hypoxanthine-copper is linear over the concentration ranges of 10 - 60 ppb. For an accumulation time of 30 minutes, the detection limit was found to be 250 ppt (1.8 × 10﹣9 mol·L﹣1). Adequate conditions for measuring the hypoxanthine in the presence of metal ions, xanthine, uric acid and other nitrogenated bases were also investigated. The utility of the method is demonstrated by the presence of hypoxanthine associated in ATP or ssDNA.
文摘Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosphate or media owing to adsorption Silicate can also enhance the peak current of Cu(II). The enhancing power phosphate,carbonate, and silicate is 33, 26, and 8.9 times, respectively.
基金support of the authorities of Siksha ‘O’Anusandhan University
文摘A novel solvent extraction process for extraction and separation of copper from other base metal ions using a bifunctional ionic liquid (IL) (trioctylmethylammonium/2,4,4-trimethylpentyl phosphinate, [A336/Cy272]) in kerosene was reported. This IL was found to extract copper more efficiently than the individual extractants Aliquat 336 or Cyanex 272. Formation of an octahedral copper-IL complex was characterized by UV-Visible spectra and metal ligand interaction was confirmed by FTIR spectra. The loading capacity of 0.1 mol/L [A336/Cy272] was found to be 1.71 g/L. Stripping studies reported that 0.298 g/L copper ions were efficiently stripped using 0.1 mol/L sulfuric acid from 0.05 mol/L loaded IL. The selectivity of copper against nickel, cadmium and iron was investigated from their equimolar binary mixtures using 0.05 mol/L [A336/Cy272] in kerosene. The highest separation factorβCu/Cd=8.41 was obtained at pH 3.56. Copper can be effectively separated from nickel over the pH range studied. The IL extracts preferentially iron over copper and the highest separation factorβFe/Cuwas 3246 at pH 2.4. The extraction rate of metal ions from a synthetic solution containing copper with other metal impurities was in the order of Fe>Zn>Cu>Cd>Co>Ni.
文摘The chemical compositions and microstructures of the armor strips excavated from the Emperor Qin Shi Huang's mausoleum were examined systematically by using optical microscopy and electron microscopy.It was found that the armor strips were made of pure copper.Based on the morphology of α-Cu recrystal grain and copper sulphide(Cu2S) inclusions in the armor strips,the manufacturing techniques were proposed as follows:smelting pure copper,casting a lamellar plate,forming the cast ingots into sheets through repeated cold forging combined with annealing heat treatment,and finally cutting the sheets into filaments.Furthermore,through the deformation of copper sulphide(Cu2S) inclusions in the strips,the work rate during forging was evaluated and calculated to be close to 75%.
文摘Nanomolar levels of the hypoxanthine in NaOH electrolyte cantaining copper(Ⅱ) can be determined by anodic stripping voltammetry at a glassy carbon electrode. In the present article hypoxanthine Cu + is shown to be adsorbed on the electrode surface in the presence of an excess of copper(Ⅱ). After accumulation period, hypoxanthine Cu + was stripped from the electrode surface and the anodic current coming near to the oxidation of Cu(Ⅰ) to Cu(Ⅱ) was measured. A linear calibration curve in the range of 5 nmol/L 1.5 mmol/L hypoxanthine, with a detection limit of 0.5 nmol/L hypoxanthine were obtained.
