Statistical Tensile Strength for High Strain Rate of Aramid and UHMWPE Fibers

Dynamic tensile impact properties of aramid (Technora) and UHMWPE (DC851) fiber bundles were studied at two high strain rates by means of reflecting type Split Hopkinson Bar, and stress-strain curves of fiber yarns at different strain rates were obtained. Experimental results show that the initial elastic modulus, failure strength and unstable strain of aramid fiber yarns are strain rate insensitive, whereas the initial elastic modulus and unstable strain of UHMWPE fiber yarns are strain rate sensitive. A fiber-bundle statistical constitutive equation was used to describe the tensile behavior of aramid and UHMWPE fiber bundles at high strain rates. The good consistency between the simulated results and experimental data indicates that the modified double Weibull function can represent the tensile strength distribution of aramid and UHMWPE fibers and the method of extracting Weibull parameters from fiber bundles stress-strain data is valid.

Adjusting the interfacial adhesion via surface modification to prepare high-performance fibers

Ultra-high molecular weight polyethylene(UHMWPE)fiber is a new kind of high-performance fiber.Due to its excellent physical and chemical characteristics,it is widely used in various fields.However,the surface UHMWPE fiber is smooth and demonstrates no-polar groups.The weak interfacial adhesion between fiber and resin seri-ously restricts the applications of UHMWPE fiber.Therefore,the surface modification treatments of UHMWPE fiber are used to improve the interfacial adhesion strength.The modified method by adding nanomaterials elu-cidates the easy fabrication,advanced equipment and proper technology.Thus,the progress of UHMWPE nanocomposite fibers prepared via adding various nanofillers are reviewed.Meanwhile,the effects of other various methods on surface modification are also reviewed.This work advances the various design strategies about nano technologies on improving interfacial adhesion performance via treatment methodologies.

Residual Characteristic of High-Velocity Steel Fragments Penetrating UHMWPE FRP Laminates

The mechanical performance of ultra-high molecular weight polyethylene fiber (UHMWPE) and its composites were proposed. Penetrated properties of different thicknesses UHMWPE FRP laminates (URP) impacted by 3.3g cubic high velocity fragments were studied. According to the ballistic experimental results and theoretical analysis, the linear relation between ballistic limit vBL and area density AD was confirmed. The relative parameters of showing experientially residual velocity vr were expressed by the function of AD. In the end, versatile experiential expression between vr and AD was found. Prediction of vr and vBL using obtained expressions under the above stated condition of impacting URP was consistent with the experimentaled results. Consequently, the two experiential relations can be used to predict the residual velocity and ballistic limit of cubic high velocity fragments impacting URP. The residual characteristic of high-velocity steel fragments penetrating UHMWPE FRP laminates can be more exactly forecasted by the two derived experiential formulas.

Synthesis of Granular Hydroxy‑Functionalized Ultra‑high‑molecular‑weight Polyethylene and Its Fiber Properties

Granular hydroxyl-functionalized UHMWPE was successfully prepared through copolymerization of ethylene and 10-undecen-1-ol protected by tri-iso-butylaluminum using a titanium complex.[tBuNSiMe_(2)(2,7-tBu2Flu)]TiMe_(2) was activated in hexane by silica-supported modified-methylaluminoxane.Without any additional pretreatments,the obtained polymer powders were transformed into fibers through a gel-spinning and heat drawing process.When compared to fibers generated from the equivalent unfunctionalized UHMWPE or the commercial HUMWPE,both creep resistance and hydrophilic properties were improved in the hydroxy-functionalized UHMWPE fibers without losing tensile strength.