Aiming to analyze the damage mechanism of UTAO from the perspective of meso-mechanical mechanism using discrete element method(DEM),we conducted study of diseases problems of UTAO in several provinces in China,and fou...Aiming to analyze the damage mechanism of UTAO from the perspective of meso-mechanical mechanism using discrete element method(DEM),we conducted study of diseases problems of UTAO in several provinces in China,and found that aggregate spalling was one of the main disease types of UTAO.A discrete element model of UTAO pavement structure was constructed to explore the meso-mechanical mechanism of UTAO damage under the influence of layer thickness,gradation,and bonding modulus.The experimental results show that,as the thickness of UTAO decreasing,the maximum value and the mean value of the contact force between all aggregate particles gradually increase,which leads to aggregates more prone to spalling.Compared with OGFC-5 UTAO,AC-5 UTAO presents smaller maximum and average values of all contact forces,and the loading pressure in AC-5 UTAO is fully diffused in the lateral direction.In addition,the increment of pavement modulus strengthens the overall force of aggregate particles inside UTAO,resulting in aggregate particles peeling off more easily.The increase of bonding modulus changes the position where the maximum value of the tangential force appears,whereas has no effect on the normal force.展开更多
In many fields of high-tech industry the ultra-t hi n wall parts are employed. In this paper the experiments were carried out to dis cuss the surface microstructure of the camera’s guided drawtube by applying ult ras...In many fields of high-tech industry the ultra-t hi n wall parts are employed. In this paper the experiments were carried out to dis cuss the surface microstructure of the camera’s guided drawtube by applying ult rasonic vibration cutting device to the traditional lathe. The influence rule of the cutting condition on the surface roughness was put forward, which was drawn by comparing the ultrasonic cutting with the common cutting by use of the cemen ted carbide tool and the polycrystalline diamond (PCD) tool. The test results sh owed that the ultrasonic cutting performs better than the common cutting in the same condition. According to the test results analyzing, the surface characteriz ation is influenced clearly by the rigidity of the acoustic system and the machi ne tool, as well the setting height of the tool tip. Otherwise, the dense regula r low frequency vibration ripples will be scraped on the machined surface. When the tool tip is set higher than the rotating center of the work piece by three t imes of the amplitude of ultrasonic vibration, the vibration ripples behave alig ht; they turn light and shade alternatively when the tool tip is lower than the rotating center of the work piece by three times of the amplitude of ultrasonic vibration. According to the test result analyzing, the following conclusions are put forward: 1) The surface roughness in ultrasonic cutting is better than that in common cutting. Under a one third critical cutting velocity, the value of th e surface roughness in ultrasonic cutting rise slightly along with the cutting v elocity, while in common cutting it decreases contrast to the cutting velocity; the curves of the surface roughness in ultrasonic cutting and common cutting see m to be alike, both increase along with the feed rate and the cutting depth, but the value in ultrasonic cutting is smaller in the same condition.2) The influen ce of the coolant on the surface roughness cannot be ignored. The kerosene can b e employed to improve the surface roughness in ultrasonic machining.3) In ultras onic cutting process of aluminum alloy ultra-thin wall work piece, the PCD tool performs better than the cemented carbide tools.4) The vibration ripples result from the not enough rigidity of the acoustic system and the improper setting he ight of the tool tip. The departure of the tool tip from the rotating center of the work piece to some extent causes the vibration ripples on the machined surfa ce.展开更多
Due to the heat pipes' transient conduction,phase change and fluid dynamics during cooling/heating with high frequency charging/discharging of batteries,it is crucial to investigate in depth the experimental dynam...Due to the heat pipes' transient conduction,phase change and fluid dynamics during cooling/heating with high frequency charging/discharging of batteries,it is crucial to investigate in depth the experimental dynamic thermal characteristics in such complex heat transfer processes for more accurate thermal analysis and design of a BTMS. In this paper,the use of ultra?thin micro heat pipe(UMHP) for thermal management of a lithium?ion battery pack in EVs is explored by experiments to reveal the cooling/heating characteristics of the UMHP pack. The cooling performance is evaluated under di erent constant discharging and transient heat inputs conditions. And the heating e ciency is assessed under several sub?zero temperatures through heating films with/without UMHPs. Results show that the pro?posed UMHP BTMS with forced convection can keep the maximum temperature of the pack below 40 °C under 1 ~ 3 C discharging,and e ectively reduced the instant temperature increases and minimize the temperature fluctuation of the pack during transient federal urban driving schedule(FUDS) road conditions. Experimental data also indicate that heating films stuck on the fins of UMHPs brought about adequate high heating e ciency comparing with that stuck on the surface of cells under the same heating power,but has more convenient maintenance and less cost for the BTMS. The experimental dynamic temperature characteristics of UMHP which is found to be a high?e cient and low?energy consumption cooling/heating method for BTMSs,can be performed to guide thermal analysis and optimiza?tion of heat pipe BTMSs.展开更多
In recent years,Cu_(2)ZnSnS_(4)(CZTS)semiconductor materials have received intensive attention in the field of thin-film solar cells owing to its non-toxic and low-cost elements.In this work,double-pressure sputtering...In recent years,Cu_(2)ZnSnS_(4)(CZTS)semiconductor materials have received intensive attention in the field of thin-film solar cells owing to its non-toxic and low-cost elements.In this work,double-pressure sputtering technology is applied to obtain highly efficient and ultra-thin(-450 nm)pure Cu_(2)ZnSnS_(4)(CZTS)solar cell.Using mixed materials with sulfides and copper powder as a quaternary target via spark plasma sintering(SPS)method and adopting double-layer sputtering(high+low pressure),a highly adhesive and large-grained CZTS thin film is achieved.As a result,the damage to the surface of Mo contact is decreased so that the reflectivity of incident light can be improved.Moreover,the composition of CZTS film was more uniform and the secondary phase separation at the Mo interface was reduced.Therefore,the interface defect state and deep level defect density in corresponding device with double-pressure is reduced and the ratio of depletion thickness to absorption layer thickness can reached to 0.58,which promoted the collection of photogenerated carriers.Finally,an efficiency of 9.3%for ultra-thin(~450 nm)CZTS film solar cell is obtained.展开更多
Oxygen vacancy plays vital roles in regulating the electronic and charge distribution of the oxygen deficient materials.Herein,abundant oxygen vacancies are created during assembling the two-dimensional(2D)ultra-thin ...Oxygen vacancy plays vital roles in regulating the electronic and charge distribution of the oxygen deficient materials.Herein,abundant oxygen vacancies are created during assembling the two-dimensional(2D)ultra-thin Bi_(2)MoO_(6) nanoflakes into three dimensional(3D)Bi_(2)MoO_(6) nanospheres,resulting in significantly improved performance for photocatalytical conversion of CO_(2) into liquid hydrocarbons.The increased performance is contributed by two primary sites,namely the abundant oxygen vacancy and the exposed molybdenum(Mo)atom induced by oxygen-migration,as revealed by the theoretical calculation.The oxygen vacancy(Ov)and uncovered Mo atom serving as dual binding sites for trapping CO_(2) molecules render the synchronous fixation-reduction process,resulting in the decline of activation energy for CO_(2) reduction from 2.15 eV on bulk Bi_(2)MoO_(6) to 1.42 eV on Ov-rich Bi_(2)MoO_(6).Such a striking decrease in the activation energy induces the efficient selective generation of liquid hydrocarbons,especially the methanol(C_(2)H_(5) OH)and ethanol(CH_(3) OH).The yields of CH_(3) OH and C_(2)H_(5) OH over the optimal Ov-Bi_(2)MoO_(6) is high up to 106.5 and 10.3μmol g^(-1) respectively,greatly outperforming that on the Bulk-Bi_(2)MoO_(6).展开更多
The Hi-B silicon steels were cold rolled by cross shear rolling (CSR) with different mismatch speed ratio(MSR)s and conventional rolling(CR) respectively, followed by primary recrystallization annealing. The effects o...The Hi-B silicon steels were cold rolled by cross shear rolling (CSR) with different mismatch speed ratio(MSR)s and conventional rolling(CR) respectively, followed by primary recrystallization annealing. The effects of MSR and annealing temperature on magnetic properties of ultra-thin grain oriented silicon steel were analyzed. Experimental results show that, with the increase of MSR, the magnetic properties can be remarkably improved. The higher the annealing temperature is, the higher the magnetic induction and the lower the iron loss in ultra-thin silicon steel is.展开更多
In the paper, the experimental researches were carr ie d out to discuss the roundness forming rule and the influence of cutting paramet ers on roundness by ultrasonic vibration cutting of the camera’s guiding drawtu ...In the paper, the experimental researches were carr ie d out to discuss the roundness forming rule and the influence of cutting paramet ers on roundness by ultrasonic vibration cutting of the camera’s guiding drawtu be with 47.75 mm diameter and 0.6~1.5 mm wall thickness. The research results s h ow that the roundness error of ultra-thin wall parts in ultrasonic vibration cu tting is only one third of that in common cutting. The relations between the rou ndness error and the cutting parameters behave as: (1) The roundness error in co mmon cutting decreases gradually with the rise of cutting speed, while in ultras onic cutting, the roundness changes not obviously till the cutting speed is up t o a value, which is nearly equal to one third of the critical velocity. Then the roundness of workpiece will begin to increase slowly. (2) The roundness error i ncreases along with the feed rate both in common cutting and ultrasonic cutting. (3) Within the range of cutting depth in experiment, the influence of cutting d epth on the roundness error is more obvious in common cutting than that in ultra sonic vibration cutting. The conclusions are useful in machining such precise ul tra-thin wall parts. According to the tests, the following conclusions can be o btained: 1) Compared with common cutting, ultrasonic cutting can decrease effect ively roundness error of the workpiece. Under the same condition, the roundness error of the ultra-thin wall part in ultrasonic turning is about one third of t hat in common cutting. 2) In common cutting, cutting depth and feed rate have mu ch influence on the roundness and the influence of cutting velocity is little. W hile in ultrasonic cutting, the roundness was influenced heavily only when feed rate is more than 0.1 mm/r and cutting speed is more than 1/3 of the critical ro tation speed, cutting depth has little influence on the roundness in the experim ent. 3) Kerosene-oil is an optimum cutting fluid in machining ultra-thin wall workpiece. 4) To machine the ultra-thin wall precision part, ultrasonic cutting is the perfect method which can decrease the roundness error effectively an d ensure high quality of the surface.展开更多
The energy bandgap is an intrinsic character of semiconductors, which largely determines their properties. The ability to continuously and reversibly tune the bandgap of a single device during real time operation is o...The energy bandgap is an intrinsic character of semiconductors, which largely determines their properties. The ability to continuously and reversibly tune the bandgap of a single device during real time operation is of great importance not only to device physics but also to technological applications. Here we demonstrate a widely tunable bandgap of few-layer black phosphorus(BP) by the application of vertical electric field in dual-gated BP field-effect transistors. A total bandgap reduction of 124 meV is observed when the electrical displacement field is increased from 0.10 V/nm to 0.83 V/nm. Our results suggest appealing potential for few-layer BP as a tunable bandgap material in infrared optoelectronics, thermoelectric power generation and thermal imaging.展开更多
A Monte Carlo Potts model was developed to simulate the recrystallization process of a cold-rolled ultra-thin grain-oriented silicon steel.The orientation and image quality data from electron backscatter diffraction m...A Monte Carlo Potts model was developed to simulate the recrystallization process of a cold-rolled ultra-thin grain-oriented silicon steel.The orientation and image quality data from electron backscatter diffraction measurements were used as input information for simulation.Three types of nucleation mechanisms,namely,random nucleation,high-stored-energy site nucleation(HSEN),and high-angle boundary nucleation(HABN),were considered for simulation.In particular,the nucleation and growth behaviors of Goss-oriented({011}<100>)grains were investigated.Results showed that Goss grains had a nucleation advantage in HSEN and HABN.The amount of Goss grains was the highest according to HABN,and it matched the experimental measurement.However,Goss grains lacked a size advantage across all mechanisms during the recrystallization process.展开更多
Carbonaceous materials have been regarded as highly promising anode candidates for potassium storage with their cost-effectiveness and environmental benignity.However,low specific capacity and difficulty in large-scal...Carbonaceous materials have been regarded as highly promising anode candidates for potassium storage with their cost-effectiveness and environmental benignity.However,low specific capacity and difficulty in large-scale synthesis largely hinder their further development.Herein,a thermal-induced potassium–carbon alloy phase(K_(x)C_(y))with the expanded interlayer spacing strategy is first put forward.Through in situ high-temperature X-ray diffraction,a K_(2)C_(2) phase is evoked by thermal energy during the in-situ carbonization process of carbon quantum dots intermediate derived from potassium-containing precursors,whereas no lithium or sodium–carbon alloy phase is observed from lithium/sodium-containing precursors.The asobtained ultra-thin carbon nanosheets achieve adjustable layer spacing,preparation in bulk,delivering reversible potassium storage of 403.4 mAh g^(−1) at 100 mA g^(−1) and 161.2 mAh g^(−1) even at 5.0 A g^(−1),which is one of the most impressive K-storage performances reported so far with great potential application.Furthermore,the assembled potassium-ion hybrid capacitor by combining the impressive CFMs-900 anode with the three-dimensional framework-activated carbon delivers a high energy-power density of 251.7 Wh kg^(−1) at 250Wkg^(−1) with long-term stability.This study opens a scalable avenue to realize the expanded interlayer spacing,which can be extended to other multicarboxyl potassium salts and can provide approach for the design of high-performance carbon anode materials for potassium storage.展开更多
Electrostatic discharge(ESD)event usually destroys the electrical properties of dielectric films,resulting in product failure.In this work,the breakdown characteristic of machine mode(MM)ESD on three different nano si...Electrostatic discharge(ESD)event usually destroys the electrical properties of dielectric films,resulting in product failure.In this work,the breakdown characteristic of machine mode(MM)ESD on three different nano size films of head gimble assemble are obtained experimentally.The breakdown voltage and thickness parameters show a positive proportional relationship,but they are generally very low and have large discrete characteristics(~30%).The maximum and minimum breakdown voltages of the tested samples are 1.08 V and 0.46 V,which are far lower than the requirement of the current standard(25 V).In addition,the judgment criterion of product damage is given,and the relationship between discharge voltage polarity,initial resistance and breakdown voltage is studied.Finally,the theoretical analysis of the breakdown characteristic law has been given.展开更多
In this paper, some examples of GaAs/hlxGal-xAS ultra-thin heterostructures, including heterostructures, superlattices and multiquantum wells, are presented, which are studied in detail by using cross-sectional transm...In this paper, some examples of GaAs/hlxGal-xAS ultra-thin heterostructures, including heterostructures, superlattices and multiquantum wells, are presented, which are studied in detail by using cross-sectional transmission electron microscopy. Superlattices used as buffer layers can smooth out the interface roughness.展开更多
Ultra-thin hot-rolled strip is the developing result of the modern plate and strip rolling technology and can be used to replace cold-rolled products for energy saving and emission reduction.This work reviews recent p...Ultra-thin hot-rolled strip is the developing result of the modern plate and strip rolling technology and can be used to replace cold-rolled products for energy saving and emission reduction.This work reviews recent progress and breakthroughs in this field by focusing on three recent technologies,namely the conventional strip with hot coil box and endless rolling,thin slab continuous casting and rolling/semi endless rolling,and endless compact rolling.In summary,ensuring high-quality production is an important bottleneck for ultra-thin strip and ferritic hot rolling by endless compact rolling.This production technology has strong feasibility and broad prospects for future development.展开更多
Monte Carlo simulations reveal considerable straggling of energy loss by the same ions with the same energy in fully-depleted silicon-on-insulator (FDSOI) devices with ultra-thin sensitive silicon layers down to 2.5 n...Monte Carlo simulations reveal considerable straggling of energy loss by the same ions with the same energy in fully-depleted silicon-on-insulator (FDSOI) devices with ultra-thin sensitive silicon layers down to 2.5 nm. The absolute straggling of deposited energy decreases with decreasing thickness of the active silicon layer. While the relative straggling increases gradually with decreasing thickness of silicon films and exhibits a sharp rise as the thickness of the silicon film descends below a threshold value of 50 nm, with the dispersion of deposited energy ascending above ±10%. Ion species and energy dependence of the energy-loss straggling are also investigated. For a given beam, the dispersion of deposited energy results in large uncertainty on the actual linear energy transfer (LET) of incident ions, and thus single event effect (SEE) responses, which pose great challenges for traditional error rate prediction methods.展开更多
Circularly polarized(CP) lens antenna has been applied to numerous wireless communication systems based on its unique advantages such as high antenna gain, low manufacturing cost, especially stable data transmission b...Circularly polarized(CP) lens antenna has been applied to numerous wireless communication systems based on its unique advantages such as high antenna gain, low manufacturing cost, especially stable data transmission between the transmitter and the receiver. Unfortunately, current available CP lens antennas mostly suffer from high profile, low aperture efficiency as well as complex design. In this paper, we propose an ultra-thin CP lens antenna based on the designed singlelayered Pancharatnam–Berry(PB) transparent metasurface with focusing property. The PB metasurface exhibits a high transmissivity, which ensures a high efficiency of the focusing property. Launched the metasurface with a CP patch antenna at its focal point, a low-profile lens antenna is simulated and measured. The experimental results show that our lens antenna exhibits a series of advantages including high radiation gain of 20.7 dB, aperture efficiency better than 41.3%, and also narrow half power beam width(HPBW) of 13°at about 14 GHz. Our finding opens a door to realize ultra-thin transparent metasurface with other functionalities or at other working frequencies.展开更多
A new flexible substrate for flexible electronics has been developed. The developed substrate consists of an ultra thin glass and TAC (triacethyl cellulose) film. An ultra thin glass and TAC film were joined with TEOS...A new flexible substrate for flexible electronics has been developed. The developed substrate consists of an ultra thin glass and TAC (triacethyl cellulose) film. An ultra thin glass and TAC film were joined with TEOS-DAC (TEOS: tetraethyl orthosilicate, DAC: diacethy cellulose) adhesive resin synthesized by sol-gel method by means of thermo-compression bonding. This substrate has high transparency in visible-light region (90%), high flexibility (torsion strength and bending strength) and high gas barrier characteristics due to an ultra thin glass. The newly-developed substrate is superior to the substrates fabricated with commercially available adhesive resin in the same way in characteristics of heat resistance, transparency and flexibility.展开更多
A kind of photosensitive ultra-thin film was fabricated from diazoresin (DR) and various calixarenes by using the self-assembly technique. Under UV irradiation both the ionic- and hydrogen bonds between the layers of ...A kind of photosensitive ultra-thin film was fabricated from diazoresin (DR) and various calixarenes by using the self-assembly technique. Under UV irradiation both the ionic- and hydrogen bonds between the layers of the film will convert into covalent bonds. As a result, the stability of the film toward polar solvents increases dramatically.展开更多
文摘Aiming to analyze the damage mechanism of UTAO from the perspective of meso-mechanical mechanism using discrete element method(DEM),we conducted study of diseases problems of UTAO in several provinces in China,and found that aggregate spalling was one of the main disease types of UTAO.A discrete element model of UTAO pavement structure was constructed to explore the meso-mechanical mechanism of UTAO damage under the influence of layer thickness,gradation,and bonding modulus.The experimental results show that,as the thickness of UTAO decreasing,the maximum value and the mean value of the contact force between all aggregate particles gradually increase,which leads to aggregates more prone to spalling.Compared with OGFC-5 UTAO,AC-5 UTAO presents smaller maximum and average values of all contact forces,and the loading pressure in AC-5 UTAO is fully diffused in the lateral direction.In addition,the increment of pavement modulus strengthens the overall force of aggregate particles inside UTAO,resulting in aggregate particles peeling off more easily.The increase of bonding modulus changes the position where the maximum value of the tangential force appears,whereas has no effect on the normal force.
文摘In many fields of high-tech industry the ultra-t hi n wall parts are employed. In this paper the experiments were carried out to dis cuss the surface microstructure of the camera’s guided drawtube by applying ult rasonic vibration cutting device to the traditional lathe. The influence rule of the cutting condition on the surface roughness was put forward, which was drawn by comparing the ultrasonic cutting with the common cutting by use of the cemen ted carbide tool and the polycrystalline diamond (PCD) tool. The test results sh owed that the ultrasonic cutting performs better than the common cutting in the same condition. According to the test results analyzing, the surface characteriz ation is influenced clearly by the rigidity of the acoustic system and the machi ne tool, as well the setting height of the tool tip. Otherwise, the dense regula r low frequency vibration ripples will be scraped on the machined surface. When the tool tip is set higher than the rotating center of the work piece by three t imes of the amplitude of ultrasonic vibration, the vibration ripples behave alig ht; they turn light and shade alternatively when the tool tip is lower than the rotating center of the work piece by three times of the amplitude of ultrasonic vibration. According to the test result analyzing, the following conclusions are put forward: 1) The surface roughness in ultrasonic cutting is better than that in common cutting. Under a one third critical cutting velocity, the value of th e surface roughness in ultrasonic cutting rise slightly along with the cutting v elocity, while in common cutting it decreases contrast to the cutting velocity; the curves of the surface roughness in ultrasonic cutting and common cutting see m to be alike, both increase along with the feed rate and the cutting depth, but the value in ultrasonic cutting is smaller in the same condition.2) The influen ce of the coolant on the surface roughness cannot be ignored. The kerosene can b e employed to improve the surface roughness in ultrasonic machining.3) In ultras onic cutting process of aluminum alloy ultra-thin wall work piece, the PCD tool performs better than the cemented carbide tools.4) The vibration ripples result from the not enough rigidity of the acoustic system and the improper setting he ight of the tool tip. The departure of the tool tip from the rotating center of the work piece to some extent causes the vibration ripples on the machined surfa ce.
基金Supported by National Natural Science Foundation of China(Grant No.51775193)Guangdong Provincial Science and Technology Planning Project of China(Grant Nos.2014B010125001,2014B010106002,2016A050503021)Guangzhou Municipal Science and Technology Planning Project of China(Grant No.201707020045)
文摘Due to the heat pipes' transient conduction,phase change and fluid dynamics during cooling/heating with high frequency charging/discharging of batteries,it is crucial to investigate in depth the experimental dynamic thermal characteristics in such complex heat transfer processes for more accurate thermal analysis and design of a BTMS. In this paper,the use of ultra?thin micro heat pipe(UMHP) for thermal management of a lithium?ion battery pack in EVs is explored by experiments to reveal the cooling/heating characteristics of the UMHP pack. The cooling performance is evaluated under di erent constant discharging and transient heat inputs conditions. And the heating e ciency is assessed under several sub?zero temperatures through heating films with/without UMHPs. Results show that the pro?posed UMHP BTMS with forced convection can keep the maximum temperature of the pack below 40 °C under 1 ~ 3 C discharging,and e ectively reduced the instant temperature increases and minimize the temperature fluctuation of the pack during transient federal urban driving schedule(FUDS) road conditions. Experimental data also indicate that heating films stuck on the fins of UMHPs brought about adequate high heating e ciency comparing with that stuck on the surface of cells under the same heating power,but has more convenient maintenance and less cost for the BTMS. The experimental dynamic temperature characteristics of UMHP which is found to be a high?e cient and low?energy consumption cooling/heating method for BTMSs,can be performed to guide thermal analysis and optimiza?tion of heat pipe BTMSs.
基金supported by the National Key R&D Program of China(No.2018YFE0203400)the Science and Technology plan project of Shenzhen(JCYJ20190808120001755)+1 种基金the National Natural Science Foundation of China(No.62074102)the Key Project of Department of Education of Guangdong Province(No.2018KZDXM059)China。
文摘In recent years,Cu_(2)ZnSnS_(4)(CZTS)semiconductor materials have received intensive attention in the field of thin-film solar cells owing to its non-toxic and low-cost elements.In this work,double-pressure sputtering technology is applied to obtain highly efficient and ultra-thin(-450 nm)pure Cu_(2)ZnSnS_(4)(CZTS)solar cell.Using mixed materials with sulfides and copper powder as a quaternary target via spark plasma sintering(SPS)method and adopting double-layer sputtering(high+low pressure),a highly adhesive and large-grained CZTS thin film is achieved.As a result,the damage to the surface of Mo contact is decreased so that the reflectivity of incident light can be improved.Moreover,the composition of CZTS film was more uniform and the secondary phase separation at the Mo interface was reduced.Therefore,the interface defect state and deep level defect density in corresponding device with double-pressure is reduced and the ratio of depletion thickness to absorption layer thickness can reached to 0.58,which promoted the collection of photogenerated carriers.Finally,an efficiency of 9.3%for ultra-thin(~450 nm)CZTS film solar cell is obtained.
基金financially supported by the National Natural Science Foundation of China(Grants 52072165,52070092,51662031)。
文摘Oxygen vacancy plays vital roles in regulating the electronic and charge distribution of the oxygen deficient materials.Herein,abundant oxygen vacancies are created during assembling the two-dimensional(2D)ultra-thin Bi_(2)MoO_(6) nanoflakes into three dimensional(3D)Bi_(2)MoO_(6) nanospheres,resulting in significantly improved performance for photocatalytical conversion of CO_(2) into liquid hydrocarbons.The increased performance is contributed by two primary sites,namely the abundant oxygen vacancy and the exposed molybdenum(Mo)atom induced by oxygen-migration,as revealed by the theoretical calculation.The oxygen vacancy(Ov)and uncovered Mo atom serving as dual binding sites for trapping CO_(2) molecules render the synchronous fixation-reduction process,resulting in the decline of activation energy for CO_(2) reduction from 2.15 eV on bulk Bi_(2)MoO_(6) to 1.42 eV on Ov-rich Bi_(2)MoO_(6).Such a striking decrease in the activation energy induces the efficient selective generation of liquid hydrocarbons,especially the methanol(C_(2)H_(5) OH)and ethanol(CH_(3) OH).The yields of CH_(3) OH and C_(2)H_(5) OH over the optimal Ov-Bi_(2)MoO_(6) is high up to 106.5 and 10.3μmol g^(-1) respectively,greatly outperforming that on the Bulk-Bi_(2)MoO_(6).
文摘The Hi-B silicon steels were cold rolled by cross shear rolling (CSR) with different mismatch speed ratio(MSR)s and conventional rolling(CR) respectively, followed by primary recrystallization annealing. The effects of MSR and annealing temperature on magnetic properties of ultra-thin grain oriented silicon steel were analyzed. Experimental results show that, with the increase of MSR, the magnetic properties can be remarkably improved. The higher the annealing temperature is, the higher the magnetic induction and the lower the iron loss in ultra-thin silicon steel is.
文摘In the paper, the experimental researches were carr ie d out to discuss the roundness forming rule and the influence of cutting paramet ers on roundness by ultrasonic vibration cutting of the camera’s guiding drawtu be with 47.75 mm diameter and 0.6~1.5 mm wall thickness. The research results s h ow that the roundness error of ultra-thin wall parts in ultrasonic vibration cu tting is only one third of that in common cutting. The relations between the rou ndness error and the cutting parameters behave as: (1) The roundness error in co mmon cutting decreases gradually with the rise of cutting speed, while in ultras onic cutting, the roundness changes not obviously till the cutting speed is up t o a value, which is nearly equal to one third of the critical velocity. Then the roundness of workpiece will begin to increase slowly. (2) The roundness error i ncreases along with the feed rate both in common cutting and ultrasonic cutting. (3) Within the range of cutting depth in experiment, the influence of cutting d epth on the roundness error is more obvious in common cutting than that in ultra sonic vibration cutting. The conclusions are useful in machining such precise ul tra-thin wall parts. According to the tests, the following conclusions can be o btained: 1) Compared with common cutting, ultrasonic cutting can decrease effect ively roundness error of the workpiece. Under the same condition, the roundness error of the ultra-thin wall part in ultrasonic turning is about one third of t hat in common cutting. 2) In common cutting, cutting depth and feed rate have mu ch influence on the roundness and the influence of cutting velocity is little. W hile in ultrasonic cutting, the roundness was influenced heavily only when feed rate is more than 0.1 mm/r and cutting speed is more than 1/3 of the critical ro tation speed, cutting depth has little influence on the roundness in the experim ent. 3) Kerosene-oil is an optimum cutting fluid in machining ultra-thin wall workpiece. 4) To machine the ultra-thin wall precision part, ultrasonic cutting is the perfect method which can decrease the roundness error effectively an d ensure high quality of the surface.
基金Supported by the National Basic Research Program of China under Grant Nos 2013CB921900 and 2014CB920900the National Natural Science Foundation of China under Grant No 11374021)(S.Yan,Z.Xie,J.-H,Chen)+1 种基金support from the Elemental Strategy Initiative conducted by the MEXT,Japana Grant-in-Aid for Scientific Research on Innovative Areas"Science of Atomic Layers"from JSPS
文摘The energy bandgap is an intrinsic character of semiconductors, which largely determines their properties. The ability to continuously and reversibly tune the bandgap of a single device during real time operation is of great importance not only to device physics but also to technological applications. Here we demonstrate a widely tunable bandgap of few-layer black phosphorus(BP) by the application of vertical electric field in dual-gated BP field-effect transistors. A total bandgap reduction of 124 meV is observed when the electrical displacement field is increased from 0.10 V/nm to 0.83 V/nm. Our results suggest appealing potential for few-layer BP as a tunable bandgap material in infrared optoelectronics, thermoelectric power generation and thermal imaging.
基金The authors acknowledge the financial support from the National Key Research and Development Program of China(No.2017YFB0903901).
文摘A Monte Carlo Potts model was developed to simulate the recrystallization process of a cold-rolled ultra-thin grain-oriented silicon steel.The orientation and image quality data from electron backscatter diffraction measurements were used as input information for simulation.Three types of nucleation mechanisms,namely,random nucleation,high-stored-energy site nucleation(HSEN),and high-angle boundary nucleation(HABN),were considered for simulation.In particular,the nucleation and growth behaviors of Goss-oriented({011}<100>)grains were investigated.Results showed that Goss grains had a nucleation advantage in HSEN and HABN.The amount of Goss grains was the highest according to HABN,and it matched the experimental measurement.However,Goss grains lacked a size advantage across all mechanisms during the recrystallization process.
基金National Natural Science Foundation of China,Grant/Award Numbers:52004338,51904342,52074359Guangdong Provincial Department of Natural Resources,Grant/Award Number:2020-011Hunan Provincial Natural Science Foundation,Grant/Award Number:2020JJ5696。
文摘Carbonaceous materials have been regarded as highly promising anode candidates for potassium storage with their cost-effectiveness and environmental benignity.However,low specific capacity and difficulty in large-scale synthesis largely hinder their further development.Herein,a thermal-induced potassium–carbon alloy phase(K_(x)C_(y))with the expanded interlayer spacing strategy is first put forward.Through in situ high-temperature X-ray diffraction,a K_(2)C_(2) phase is evoked by thermal energy during the in-situ carbonization process of carbon quantum dots intermediate derived from potassium-containing precursors,whereas no lithium or sodium–carbon alloy phase is observed from lithium/sodium-containing precursors.The asobtained ultra-thin carbon nanosheets achieve adjustable layer spacing,preparation in bulk,delivering reversible potassium storage of 403.4 mAh g^(−1) at 100 mA g^(−1) and 161.2 mAh g^(−1) even at 5.0 A g^(−1),which is one of the most impressive K-storage performances reported so far with great potential application.Furthermore,the assembled potassium-ion hybrid capacitor by combining the impressive CFMs-900 anode with the three-dimensional framework-activated carbon delivers a high energy-power density of 251.7 Wh kg^(−1) at 250Wkg^(−1) with long-term stability.This study opens a scalable avenue to realize the expanded interlayer spacing,which can be extended to other multicarboxyl potassium salts and can provide approach for the design of high-performance carbon anode materials for potassium storage.
文摘Electrostatic discharge(ESD)event usually destroys the electrical properties of dielectric films,resulting in product failure.In this work,the breakdown characteristic of machine mode(MM)ESD on three different nano size films of head gimble assemble are obtained experimentally.The breakdown voltage and thickness parameters show a positive proportional relationship,but they are generally very low and have large discrete characteristics(~30%).The maximum and minimum breakdown voltages of the tested samples are 1.08 V and 0.46 V,which are far lower than the requirement of the current standard(25 V).In addition,the judgment criterion of product damage is given,and the relationship between discharge voltage polarity,initial resistance and breakdown voltage is studied.Finally,the theoretical analysis of the breakdown characteristic law has been given.
文摘In this paper, some examples of GaAs/hlxGal-xAS ultra-thin heterostructures, including heterostructures, superlattices and multiquantum wells, are presented, which are studied in detail by using cross-sectional transmission electron microscopy. Superlattices used as buffer layers can smooth out the interface roughness.
文摘Ultra-thin hot-rolled strip is the developing result of the modern plate and strip rolling technology and can be used to replace cold-rolled products for energy saving and emission reduction.This work reviews recent progress and breakthroughs in this field by focusing on three recent technologies,namely the conventional strip with hot coil box and endless rolling,thin slab continuous casting and rolling/semi endless rolling,and endless compact rolling.In summary,ensuring high-quality production is an important bottleneck for ultra-thin strip and ferritic hot rolling by endless compact rolling.This production technology has strong feasibility and broad prospects for future development.
基金supported by the National Natural Science Foundation of China (Grant Nos. 11179003 and 10975164)
文摘Monte Carlo simulations reveal considerable straggling of energy loss by the same ions with the same energy in fully-depleted silicon-on-insulator (FDSOI) devices with ultra-thin sensitive silicon layers down to 2.5 nm. The absolute straggling of deposited energy decreases with decreasing thickness of the active silicon layer. While the relative straggling increases gradually with decreasing thickness of silicon films and exhibits a sharp rise as the thickness of the silicon film descends below a threshold value of 50 nm, with the dispersion of deposited energy ascending above ±10%. Ion species and energy dependence of the energy-loss straggling are also investigated. For a given beam, the dispersion of deposited energy results in large uncertainty on the actual linear energy transfer (LET) of incident ions, and thus single event effect (SEE) responses, which pose great challenges for traditional error rate prediction methods.
基金Project supported by the National Natural Science Foundation of China(Grant No.61372034)
文摘Circularly polarized(CP) lens antenna has been applied to numerous wireless communication systems based on its unique advantages such as high antenna gain, low manufacturing cost, especially stable data transmission between the transmitter and the receiver. Unfortunately, current available CP lens antennas mostly suffer from high profile, low aperture efficiency as well as complex design. In this paper, we propose an ultra-thin CP lens antenna based on the designed singlelayered Pancharatnam–Berry(PB) transparent metasurface with focusing property. The PB metasurface exhibits a high transmissivity, which ensures a high efficiency of the focusing property. Launched the metasurface with a CP patch antenna at its focal point, a low-profile lens antenna is simulated and measured. The experimental results show that our lens antenna exhibits a series of advantages including high radiation gain of 20.7 dB, aperture efficiency better than 41.3%, and also narrow half power beam width(HPBW) of 13°at about 14 GHz. Our finding opens a door to realize ultra-thin transparent metasurface with other functionalities or at other working frequencies.
文摘A new flexible substrate for flexible electronics has been developed. The developed substrate consists of an ultra thin glass and TAC (triacethyl cellulose) film. An ultra thin glass and TAC film were joined with TEOS-DAC (TEOS: tetraethyl orthosilicate, DAC: diacethy cellulose) adhesive resin synthesized by sol-gel method by means of thermo-compression bonding. This substrate has high transparency in visible-light region (90%), high flexibility (torsion strength and bending strength) and high gas barrier characteristics due to an ultra thin glass. The newly-developed substrate is superior to the substrates fabricated with commercially available adhesive resin in the same way in characteristics of heat resistance, transparency and flexibility.
基金Project supported by the National Natural Science Foundation of China (Grant No 60625403), the State Key Development Program for Basic Research of China (Grant No 2006CB302701).
基金This work was supported by the National Natural Science Foundation of China (No. 50173002 and 20274002).
文摘A kind of photosensitive ultra-thin film was fabricated from diazoresin (DR) and various calixarenes by using the self-assembly technique. Under UV irradiation both the ionic- and hydrogen bonds between the layers of the film will convert into covalent bonds. As a result, the stability of the film toward polar solvents increases dramatically.