A microcomputer-based UV/V in situ spectroelectrochemical measurement system has been developed.This paper presents a description of the experimental details regarding the methods and equipment.
Ultra-violet(UV)curing is an efficient method for composite molding.Firstly,thermophysical properties of UV cured glass-fiber reinforced plastics are conducted.Material properties are studied for various kinds of post...Ultra-violet(UV)curing is an efficient method for composite molding.Firstly,thermophysical properties of UV cured glass-fiber reinforced plastics are conducted.Material properties are studied for various kinds of postcuring modes.Then the UV curing method is suggested in manufacturing V-crimp folded core for sandwich panels.Two kinds of processing schemes for V-crimp folded core manufacturing using UV curing are presented.Finally,the effect of post-curing on the mechanical properties of folded core sandwiches is experimentally studied,and optimum modes of post-curing are determined.The experimental results show that the ultimate compressive strength of the folded sandwiches is increased by 60% after post-curing with the optimum post-curing mode.展开更多
This letter presents two improvements on 2.4 kb/s Mixed-Excitation Linear Prediction (MELP) vocoder. The one is a new parameter Redzc named energy to differential zerocrossing rate which is used in adaptation of V/UV ...This letter presents two improvements on 2.4 kb/s Mixed-Excitation Linear Prediction (MELP) vocoder. The one is a new parameter Redzc named energy to differential zerocrossing rate which is used in adaptation of V/UV decision of transitional segments and low energy level speech segments. The other is a multi-path searching method for Multi-Stage Vector Quantization (MSVQ) of line spectral frequency. Subjective tests show that the intelligiblity and naturallity of improved MELP vocoder are preferable to those of the original one.展开更多
A three-dimensional （3D） coordination polymer {[Co（bdc）（dpb）]·H2O}n （1） was prepared by solvothermal reaction of 1,3-dipyridyl benzene （dpb） with deprotonated 1,3-benzene- dicarboxylate （H2bdc）, and w...A three-dimensional （3D） coordination polymer {[Co（bdc）（dpb）]·H2O}n （1） was prepared by solvothermal reaction of 1,3-dipyridyl benzene （dpb） with deprotonated 1,3-benzene- dicarboxylate （H2bdc）, and was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It crystallizes in the monoclinic system, space group C2/c with α = 15.478（6）, b = 12.865（5）, c = 24.091（10） ？, β = 95.599（5）°, V = 4774（3） ？3, C24H18CoN2O5, Mr = 473.34, Dc = 1.267 g/cm3, F（000） = 1864.0, μ = 0.748 mm-1 and Z = 8. Each Co（II） ion links three bdc2- anions to form an infinitely 1D ladder-shaped chain containing binuclear [（COO）Co]2 cluster, and dpb links adjacent 1D chains to form a 3D pcu framework. In addition, the UV-vis of 1 was also studied.展开更多
Multiwalled carbon nanotubes (MWCNTs) mixed in poly(3-hexylthiophene) (P3HT) were used as a photoactive layer for organic solar cells (OSC). The flexible OSCs of a structure of PET/rGO-P3HT/P3CT/PCBM/LiF-Al were prepa...Multiwalled carbon nanotubes (MWCNTs) mixed in poly(3-hexylthiophene) (P3HT) were used as a photoactive layer for organic solar cells (OSC). The flexible OSCs of a structure of PET/rGO-P3HT/P3CT/PCBM/LiF-Al were prepared by spincoating. The UV-Vis absorption spectra of the photoactive films and current-voltage characteristics of the OSCs showed the advantage of the composite devices above the pristine-polymeric ones. Under illumination of light with a 100 mW/cm<sup>2</sup>-powerdensity, the photoelectrical conversion efficiency (PCE) of the OSCs with 3.0 wt% MWNCTs embedded in the photoactive layer possess a value as large as 2.35%. The obtained results suggest further useful applications of the flexible large-area solar cells.展开更多
Porphyrins occur in a number of important biomolecules and are also synthetically made for use as probe component of chemical and biological sensors. The performance of dye sensitized solar cells with two different po...Porphyrins occur in a number of important biomolecules and are also synthetically made for use as probe component of chemical and biological sensors. The performance of dye sensitized solar cells with two different porphyrin dyes was investigated in this work. The two porphyrin complexes comprised of a metal-free 5, 10, 15, 20-meso-tetrakis-(9H-2-fluorene-yl) porphyrin (H2TFP) and its Zinc complex (ZnTFP). UV-Vis, Fluorescence, and Fourier transformed infrared measurements of the two dyes were carried out to evaluate their absorption, emission and binding characteristics. Both dyes absorbed light in the UV-visible region all the way to the near-infrared. The surface morphology and elemental analysis of the porphyrin dye sensitized photoanodes were determined using Field Emission Scanning Electron Microscopy Imaging and Transmission Electron Microscopy Imaging. Cyclic voltammetry studies, current-voltage characteristics and the electrochemical impedance spectroscopic studies were also carried out. Solar-to-electric energy efficiency of H2TFP dye sensitized solar cell was higher (0.11%) than that of the zinc complex (0.08%). Thus the metal free porphyrin generated more power than the zinc complex under similar conditions. The impedance measurement also displayed less overall resistance for the free porphyrin (50 Ω) compared with the zinc complex (130 Ω). The LUMO levels of H2TFP and ZnTFP sensitizers were -0.87 eV and -0.77 eV respectively. Both of these LUMO values are higher than the lower bound level of the conduction band of TiO2 (-4.0 eV), ensuring the efficient injection of an electron from the excited porphyrin dye to the conduction band of the titanium dioxide.展开更多
基金This work wag supported by the National Natural Science Foundation of China.
文摘A microcomputer-based UV/V in situ spectroelectrochemical measurement system has been developed.This paper presents a description of the experimental details regarding the methods and equipment.
基金supported by the Ministry of Education and Science of Russian Federation (No.RFMEFI57414X0078)
文摘Ultra-violet(UV)curing is an efficient method for composite molding.Firstly,thermophysical properties of UV cured glass-fiber reinforced plastics are conducted.Material properties are studied for various kinds of postcuring modes.Then the UV curing method is suggested in manufacturing V-crimp folded core for sandwich panels.Two kinds of processing schemes for V-crimp folded core manufacturing using UV curing are presented.Finally,the effect of post-curing on the mechanical properties of folded core sandwiches is experimentally studied,and optimum modes of post-curing are determined.The experimental results show that the ultimate compressive strength of the folded sandwiches is increased by 60% after post-curing with the optimum post-curing mode.
文摘This letter presents two improvements on 2.4 kb/s Mixed-Excitation Linear Prediction (MELP) vocoder. The one is a new parameter Redzc named energy to differential zerocrossing rate which is used in adaptation of V/UV decision of transitional segments and low energy level speech segments. The other is a multi-path searching method for Multi-Stage Vector Quantization (MSVQ) of line spectral frequency. Subjective tests show that the intelligiblity and naturallity of improved MELP vocoder are preferable to those of the original one.
基金supported by the National Natural Science Foundation of China(21301005,21271008,51173002)Natural Science Foundation of Anhui Province(1308085QB34)the young teacher’s research foundation of Anhui University of Science and Technology(11227,2012QNZ08)
文摘A three-dimensional （3D） coordination polymer {[Co（bdc）（dpb）]·H2O}n （1） was prepared by solvothermal reaction of 1,3-dipyridyl benzene （dpb） with deprotonated 1,3-benzene- dicarboxylate （H2bdc）, and was characterized by elemental analysis, IR spectroscopy, and X-ray single-crystal diffraction. It crystallizes in the monoclinic system, space group C2/c with α = 15.478（6）, b = 12.865（5）, c = 24.091（10） ？, β = 95.599（5）°, V = 4774（3） ？3, C24H18CoN2O5, Mr = 473.34, Dc = 1.267 g/cm3, F（000） = 1864.0, μ = 0.748 mm-1 and Z = 8. Each Co（II） ion links three bdc2- anions to form an infinitely 1D ladder-shaped chain containing binuclear [（COO）Co]2 cluster, and dpb links adjacent 1D chains to form a 3D pcu framework. In addition, the UV-vis of 1 was also studied.
文摘Multiwalled carbon nanotubes (MWCNTs) mixed in poly(3-hexylthiophene) (P3HT) were used as a photoactive layer for organic solar cells (OSC). The flexible OSCs of a structure of PET/rGO-P3HT/P3CT/PCBM/LiF-Al were prepared by spincoating. The UV-Vis absorption spectra of the photoactive films and current-voltage characteristics of the OSCs showed the advantage of the composite devices above the pristine-polymeric ones. Under illumination of light with a 100 mW/cm<sup>2</sup>-powerdensity, the photoelectrical conversion efficiency (PCE) of the OSCs with 3.0 wt% MWNCTs embedded in the photoactive layer possess a value as large as 2.35%. The obtained results suggest further useful applications of the flexible large-area solar cells.
文摘Porphyrins occur in a number of important biomolecules and are also synthetically made for use as probe component of chemical and biological sensors. The performance of dye sensitized solar cells with two different porphyrin dyes was investigated in this work. The two porphyrin complexes comprised of a metal-free 5, 10, 15, 20-meso-tetrakis-(9H-2-fluorene-yl) porphyrin (H2TFP) and its Zinc complex (ZnTFP). UV-Vis, Fluorescence, and Fourier transformed infrared measurements of the two dyes were carried out to evaluate their absorption, emission and binding characteristics. Both dyes absorbed light in the UV-visible region all the way to the near-infrared. The surface morphology and elemental analysis of the porphyrin dye sensitized photoanodes were determined using Field Emission Scanning Electron Microscopy Imaging and Transmission Electron Microscopy Imaging. Cyclic voltammetry studies, current-voltage characteristics and the electrochemical impedance spectroscopic studies were also carried out. Solar-to-electric energy efficiency of H2TFP dye sensitized solar cell was higher (0.11%) than that of the zinc complex (0.08%). Thus the metal free porphyrin generated more power than the zinc complex under similar conditions. The impedance measurement also displayed less overall resistance for the free porphyrin (50 Ω) compared with the zinc complex (130 Ω). The LUMO levels of H2TFP and ZnTFP sensitizers were -0.87 eV and -0.77 eV respectively. Both of these LUMO values are higher than the lower bound level of the conduction band of TiO2 (-4.0 eV), ensuring the efficient injection of an electron from the excited porphyrin dye to the conduction band of the titanium dioxide.
