Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordov...Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordovician Majiagou Formation in Daniudi area of the Ordos Basin had experienced weathering for>130 Myr.Through thin section observation,major and trace element analysis,carbon,oxygen,and magnesium isotopes composition analysis,the dolomitization modes and weathering of ancient dolo-mite in Daniudi area were analyzed in detail.The results showed that the Sabkha and brine-reflux dolomitization modes had developed,and the Mg isotopes in different layers of the karst crust were fractionated by various factors.The vertical vadose zone was affected by weathering,the Mg isotope of dolomite(δ^(26)Mgdol)showed a downward decreasing trend;the horizontal underflow zone was controlled by diagenesis and formation fluid,δ^(26)Mgdol showed a vertical invariance and negative;the main reason for Mg isotope fractionation in the deep slow-flow zone was the brine-reflux dolomitization mode during early burial period,which showed a vertical downward increase.Finally,the Mg isotope characteristic data of the ancient weathering crust were provided and the process of Mg isotope frac-tionationinthekarstcrust was explained.展开更多
The deeply buried Lower Cambrian Longwangmiao Formation and Upper Ediacaran Dengying Formation from the Sichuan Basin,China,have a total natural gas reserve up to 3×10^(12)m^(3).The complex diagenetic evolution a...The deeply buried Lower Cambrian Longwangmiao Formation and Upper Ediacaran Dengying Formation from the Sichuan Basin,China,have a total natural gas reserve up to 3×10^(12)m^(3).The complex diagenetic evolution and their impacts on the present-day reservoir quality have not been systematically elucidated,hampering the current exploration.Crucially,the integration and comparation diagenetic study on these two formations,which may be able to shed new lights on reservoir formation mechanism,are yet to be systemically evaluated.By compiling geochemistry data,including carbonate U-Pb ages and petrophysics data,coupled with new petrology,trace elements,and strontium isotope data,of various types of diagenetic carbonates,this study aims to decipher the potential links between diagenesis and reservoir development of both formations.Intriguingly,similar diagenetic sequence,which contains five distinctive dolomite phases,is established in both formations.The matrix dolomite(D1)and early dolomite cement(D2)were likely formed by reflux dolomitization,as inferred by their nearly syn-depositional U-Pb ages and elevatedδ^(18)O caused by seawater evaporation.The subsequent moderate burial dolomite cement(D3)was most plausibly the product of burial compaction as indicated by its lighterδ^(18)O and slightly younger U-Pb ages compared with D1 and D2.Whereas deep burial dolomite cements(D4 and D5)yield markedly depletedδ^(18)O,elevated ^(87)Sr/^(86)Sr,along with much younger U-Pb ages and higher precipitation temperatures,suggesting that they were likely linked to hydrothermal fluids.Despite the wide occurrence of meteoric and organic acids leaching and thermochemical sulfate reduction,they may have only played a subsidiary role on these reservoirs development.Instead,superior reservoir quality is tightly linked to tectonics as inferred by higher reservoir quality closely related to the well-developed fractures and faults filled with abundant hydrothermal minerals.Notably,good reservoirs in both formations are mainly attributed to high permeability caused by tectonics.Hence,this new contribution emphasizes the crucial role of tectonics on spatially explicit reservoir prediction of deep to ultra-deep(up to>8000 m)carbonates in the Sichuan Basin,as well as other sedimentary basin analogues in China.展开更多
Exploration practice has proved that deep and ultra-deep reservoirs consist of mainly matrix-porous dolomite reservoirs and fractured-vuggy karst reservoirs and still will be very important targets for future explorat...Exploration practice has proved that deep and ultra-deep reservoirs consist of mainly matrix-porous dolomite reservoirs and fractured-vuggy karst reservoirs and still will be very important targets for future exploration, in which large oil and gas fields such as Anyue, Yuanba, Halahatang, Fuman and Shunbei have been discovered. This paper systematically summarizes three theoretical and technical achievements in studying deep and ultra-deep carbonate reservoirs in the past decade.(1) The micro-zone and multi-parameter experiment analysis technology featured by determining the “age, temperature, pressure and fluid properties” of carbonate reservoirs, together with experimental simulation of cross-tectonic-period pore formation and preservation featured by the “multi-stage, continuous, visualized and online detection technology”, providing useful tools for studying the pore formation and preservation mechanism of deep and ultra-deep carbonate rocks from the perspective of“forward” and “inversion”.(2) Deep and ultra-deep matrix-porous dolostone reservoirs are still controlled by sedimentary facies,among which reef(mound) and/or beach contribute most. The reservoir space is mainly composed of sedimentary primary pores and supergene dissolution pores and fractures, though some of reservoir spaces are formed by burial dissolution and they tend to develop and may locally concentrate following the pre-existing porous zone. In other words, burial dissolution vugs are inherited rather than newly formed. Early dolomite precipitation(or dolomitization) has a high potential to preserve early pores.(3) The development and preservation mechanism of fractured-vuggy karst limestone reservoirs in deep and ultra-deep realm was analyzed. Pene-contemporaneous dissolution and interlayer and buried-hill karstification control the development of early and late supergene fractured-vuggy reservoirs. Strike-slip faults superimposed with supergene karstification lead to the development of “fence-style” faulted karst reservoirs. Dissolution simulation experiments reveal that the development of karst fracturedvuggy reservoirs is facies-controlled in certain degree, mainly developed in packstone. Rock mechanics analysis reveals that the preservation of caves is under the control of lithology, cave size, and the distance to the unconformity, and caves can be well preserved at 10,000 m. The theoretical and technical achievements provide supports for carbonate oil and gas exploration into ten thousand meters deep.展开更多
基金supported by the National Natural Science Foundation of China(42072177)National Natural Science Foundation of China(U19B6003)Frontier Project of Chinese Academy of Sciences(XDA14010201).
文摘Weathering has always been a concerned around the world,as the first and most important step in the global cycle of elements,which leads to the fractionation of isotopes on the scale of geological age.The Middle Ordovician Majiagou Formation in Daniudi area of the Ordos Basin had experienced weathering for>130 Myr.Through thin section observation,major and trace element analysis,carbon,oxygen,and magnesium isotopes composition analysis,the dolomitization modes and weathering of ancient dolo-mite in Daniudi area were analyzed in detail.The results showed that the Sabkha and brine-reflux dolomitization modes had developed,and the Mg isotopes in different layers of the karst crust were fractionated by various factors.The vertical vadose zone was affected by weathering,the Mg isotope of dolomite(δ^(26)Mgdol)showed a downward decreasing trend;the horizontal underflow zone was controlled by diagenesis and formation fluid,δ^(26)Mgdol showed a vertical invariance and negative;the main reason for Mg isotope fractionation in the deep slow-flow zone was the brine-reflux dolomitization mode during early burial period,which showed a vertical downward increase.Finally,the Mg isotope characteristic data of the ancient weathering crust were provided and the process of Mg isotope frac-tionationinthekarstcrust was explained.
基金supported by grants from the National Natural Science Foundation of China(41972149,41890843).
文摘The deeply buried Lower Cambrian Longwangmiao Formation and Upper Ediacaran Dengying Formation from the Sichuan Basin,China,have a total natural gas reserve up to 3×10^(12)m^(3).The complex diagenetic evolution and their impacts on the present-day reservoir quality have not been systematically elucidated,hampering the current exploration.Crucially,the integration and comparation diagenetic study on these two formations,which may be able to shed new lights on reservoir formation mechanism,are yet to be systemically evaluated.By compiling geochemistry data,including carbonate U-Pb ages and petrophysics data,coupled with new petrology,trace elements,and strontium isotope data,of various types of diagenetic carbonates,this study aims to decipher the potential links between diagenesis and reservoir development of both formations.Intriguingly,similar diagenetic sequence,which contains five distinctive dolomite phases,is established in both formations.The matrix dolomite(D1)and early dolomite cement(D2)were likely formed by reflux dolomitization,as inferred by their nearly syn-depositional U-Pb ages and elevatedδ^(18)O caused by seawater evaporation.The subsequent moderate burial dolomite cement(D3)was most plausibly the product of burial compaction as indicated by its lighterδ^(18)O and slightly younger U-Pb ages compared with D1 and D2.Whereas deep burial dolomite cements(D4 and D5)yield markedly depletedδ^(18)O,elevated ^(87)Sr/^(86)Sr,along with much younger U-Pb ages and higher precipitation temperatures,suggesting that they were likely linked to hydrothermal fluids.Despite the wide occurrence of meteoric and organic acids leaching and thermochemical sulfate reduction,they may have only played a subsidiary role on these reservoirs development.Instead,superior reservoir quality is tightly linked to tectonics as inferred by higher reservoir quality closely related to the well-developed fractures and faults filled with abundant hydrothermal minerals.Notably,good reservoirs in both formations are mainly attributed to high permeability caused by tectonics.Hence,this new contribution emphasizes the crucial role of tectonics on spatially explicit reservoir prediction of deep to ultra-deep(up to>8000 m)carbonates in the Sichuan Basin,as well as other sedimentary basin analogues in China.
基金supported by the National Natural Science Foundation of China (Grant No. U23B20154)。
文摘Exploration practice has proved that deep and ultra-deep reservoirs consist of mainly matrix-porous dolomite reservoirs and fractured-vuggy karst reservoirs and still will be very important targets for future exploration, in which large oil and gas fields such as Anyue, Yuanba, Halahatang, Fuman and Shunbei have been discovered. This paper systematically summarizes three theoretical and technical achievements in studying deep and ultra-deep carbonate reservoirs in the past decade.(1) The micro-zone and multi-parameter experiment analysis technology featured by determining the “age, temperature, pressure and fluid properties” of carbonate reservoirs, together with experimental simulation of cross-tectonic-period pore formation and preservation featured by the “multi-stage, continuous, visualized and online detection technology”, providing useful tools for studying the pore formation and preservation mechanism of deep and ultra-deep carbonate rocks from the perspective of“forward” and “inversion”.(2) Deep and ultra-deep matrix-porous dolostone reservoirs are still controlled by sedimentary facies,among which reef(mound) and/or beach contribute most. The reservoir space is mainly composed of sedimentary primary pores and supergene dissolution pores and fractures, though some of reservoir spaces are formed by burial dissolution and they tend to develop and may locally concentrate following the pre-existing porous zone. In other words, burial dissolution vugs are inherited rather than newly formed. Early dolomite precipitation(or dolomitization) has a high potential to preserve early pores.(3) The development and preservation mechanism of fractured-vuggy karst limestone reservoirs in deep and ultra-deep realm was analyzed. Pene-contemporaneous dissolution and interlayer and buried-hill karstification control the development of early and late supergene fractured-vuggy reservoirs. Strike-slip faults superimposed with supergene karstification lead to the development of “fence-style” faulted karst reservoirs. Dissolution simulation experiments reveal that the development of karst fracturedvuggy reservoirs is facies-controlled in certain degree, mainly developed in packstone. Rock mechanics analysis reveals that the preservation of caves is under the control of lithology, cave size, and the distance to the unconformity, and caves can be well preserved at 10,000 m. The theoretical and technical achievements provide supports for carbonate oil and gas exploration into ten thousand meters deep.
