Electrokinetic-mechanism of water and furfural oxidation on pulsed laser-interlaced Cu_(2)O and CoO on nickel foam

The electrocatalytic oxidation of biomass-derived furfural(FF)feedstocks into 2-furoic acid(FA)holds immense industrial potential in optics,cosmetics,polymers,and food.Herein,we fabricated Co O/Ni O/nickel foam(NF)and Cu_(2)O/Ni O/NF electrodes via in situ pulsed laser irradiation in liquids(PLIL)for the bifunctional electrocatalysis of oxygen evolution reaction(OER)and furfural oxidation reaction(FOR),respectively.Simultaneous oxidation of NF surface to NiO and deposition of CoO and/or Cu_(2)O on NF during PLIL offer distinct advantages for enhancing both the OER and FOR.CoO/NiO/NF electrocatalyst provides a consistently low overpotential of~359 m V(OER)at 10 m A/cm^(2),achieving the maximum FA yield(~16.37 m M)with 61.5%selectivity,79.5%carbon balance,and a remarkable Faradaic efficiency of~90.1%during 2 h of FOR at 1.43 V(vs.reversible hydrogen electrode).Mechanistic pathway via in situ electrochemical-Raman spectroscopy on CoO/NiO/NF reveals the involvement of phase transition intermediates(NiOOH and CoOOH)as surface-active centers during electrochemical oxidation.The carbonyl carbon in FF is attacked by hydroxyl groups to form unstable hydrates that subsequently undergo further oxidation to yield FA products.This method holds promise for large-scale applications,enabling simultaneous production of renewable building materials and fuel.

On the generation of high-quality Nyquist pulses in mode-locked fiber lasers

Nyquist pulses have wide applications in many areas,from electronics to optics.Mode-locked lasers are ideal platforms to generate such pulses.However,how to generate high-quality Nyquist pulses in mode-locked lasers remains elusive.We address this problem by managing different physical effects in mode-locked fiber lasers through extensive numerical simulations.We find that net dispersion,linear loss,gain and filter shaping can affect the quality of Nyquist pulses significantly.We also demonstrate that Nyquist pulses experience similariton shaping due to the nonlinear attractor effect in the gain medium.Our work may contribute to the design of Nyquist pulse sources and enrich the understanding of pulse shaping dynamics in mode-locked lasers.

Electromagnetic pulses produced by a picosecond laser interacting with solid targets

A high-power laser ablating solid targets induces giant electromagnetic pulses(EMPs),which are intimately pertinent to laser parameters,such as energy and pulse width.In this study,we reveal the features of EMPs generated from a picosecond(ps)laser irradiating solid targets at the SG-Ⅱpicosecond petawatt(PSPW)laser facility.The laser energy and pulse,as well as target material and thickness,show determinative effects on the EMPs’amplitude.More intense EMPs are detected behind targets compared to those at the other three positions,and the EMP amplitude decreases from 90.09 kV/m to 17.8 kV/m with the gold target thickness increasing from 10μm to 20μm,which is suppressed when the laser pulse width is enlarged.The results are expected to provide more insight into EMPs produced by ps lasers coupling with targets and lay the foundation for an effective EMP shielding design in high-power laser infrastructures.

Generation and regulation of electromagnetic pulses generated by femtosecond lasers interacting with multitargets

Ultrashort and powerful laser interactions with a target generate intense wideband electromagnetic pulses(EMPs).In this study,we report EMPs generated by the interactions between petawatt(30 fs,1.4×10^(20) W/cm^(2))femtosecond(fs)lasers with metal flat,plastic flat,and plastic nanowire-array(NWA)targets.Detailed analyses are conducted on the EMPs in terms of their spatial distribution,time and frequency domains,radiation energy,and protection.The results indicate that EMPs from metal targets exhibit larger amplitudes at varying angles than those generated by other types of targets and are enhanced significantly for NWA targets.Using a plastic target holder and increasing the laser focal spot can significantly decrease the radiation energy of the EMPs.Moreover,the composite shielding materials indicate an effective shielding effect against EMPs.The simulation results show that the NWA targets exert a collimating effect on thermal electrons,which directly affects the distribution of EMPs.This study provides guidance for regulating EMPs by controlling the laser focal spot,target parameters,and target rod material and is beneficial for electromagnetic-shielding design.

Collision off-axis position dependence of relativistic nonlinear Thomson inverse scattering of an excited electron in a tightly focused circular polarized laser pulse

This paper presents a novel view of the impact of electron collision off-axis positions on the dynamic properties and relativistic nonlinear Thomson inverse scattering of excited electrons within tightly focused, circularly polarized laser pulses of varying intensities. We examine the effects of the transverse ponderomotive force, specifically how the deviation angle and speed of electron motion are affected by the initial off-axis position of the electron and the peak amplitude of the laser pulse. When the laser pulse intensity is low, an increase in the electron's initial off-axis distance results in reduced spatial radiation power, improved collimation, super-continuum phenomena generation, red-shifting of the spectrum's harmonic peak, and significant symmetry in the radiation radial direction. However, in contradiction to conventional understandings,when the laser pulse intensity is relatively high, the properties of the relativistic nonlinear Thomson inverse scattering of the electron deviate from the central axis, changing direction in opposition to the aforementioned effects. After reaching a peak, these properties then shift again, aligning with the previous direction. The complex interplay of these effects suggests a greater nuance and intricacy in the relationship between laser pulse intensity, electron position, and scattering properties than previously thought.

Pulsed laser interference patterning of transition-metal carbides for stable alkaline water electrolysis kinetics

We investigated the role of metal atomization and solvent decomposition into reductive species and carbon clusters in the phase formation of transition-metal carbides(TMCs;namely,Co_(3)C,Fe_(3)C,TiC,and MoC)by pulsed laser ablation of Co,Fe,Ti,and Mo metals in acetone.The interaction between carbon s-p-orbitals and metal d-orbitals causes a redistribution of valence structure through charge transfer,leading to the formation of surface defects as observed by X-ray photoelectron spectroscopy.These defects influence the evolved TMCs,making them effective for hydrogen and oxygen evolution reactions(HER and OER)in an alkaline medium.Co_(3)C with more oxygen affinity promoted CoO(OH)intermediates,and the electrochemical surface oxidation to Co_(3)O_(4)was captured via in situ/operando electrochemical Raman probes,increasing the number of active sites for OER activity.MoC with more d-vacancies exhibits strong hydrogen binding,promoting HER kinetics,whereas Fe_(3)C and TiC with more defect states to trap charge carriers may hinder both OER and HER activities.The results show that the assembled membrane-less electrolyzer with Co_(3)C∥Co_(3)C and MoC∥MoC electrodes requires~2.01 and 1.99 V,respectively,to deliver a 10 mA cm−2 with excellent electrochemical and structural stability.In addition,the ascertained pulsed laser synthesis mechanism and unit-cell packing relations will open up sustainable pathways for obtaining highly stable electrocatalysts for electrolyzers.

Generation mechanism of 100 MG magnetic fields in the interaction of ultra-intense laser pulse with nanostructured target

Experimental and simulation data[Moreau et al.,Plasma Phys.Control.Fusion 62,014013(2019);Kaymak et al.,Phys.Rev.Lett.117,035004(2016)]indicate that self-generated magnetic fields play an important role in enhancing the flux and energy of relativistic electrons accelerated by ultra-intense laser pulse irradiation with nanostructured arrays.A fully relativistic analytical model for the generation of the magnetic field based on electron magneto-hydrodynamic description is presented here.The analytical model shows that this self-generated magnetic field originates in the nonparallel density gradient and fast electron current at the interfaces of a nanolayered target.A general formula for the self-generated magnetic field is found,which closely agrees with the simulation scaling over the relevant intensity range.The result is beneficial to the experimental designs for the interaction of the laser pulse with the nanostructured arrays to improve laser-to-electron energy coupling and the quality of forward hot electrons.

Fundamental Architecture and Performance Analysis of Photofission Pulsed Space Propulsion System Using Ultra-Intense Laser

Photofission enables a unique capability for the domain of non-chemical space propulsion. An ultra-intense laser enables the capacity to induce nuclear fission through the development of bre- msstrahlung photons. A fundamental architecture and performance analysis of a photofission pulsed space propulsion system through the operation of an ultra-intense laser is presented. A historical perspective of previous conceptual nuclear fission propulsion systems is addressed. These applications use neutron derived nuclear fission;however, there is inherent complexity that has precluded further development. The background of photofission is detailed. The conceptual architecture of photofission pulsed space propulsion and fundamental performance parameters are established. The implications are the energy source and ultra-intense laser can be situated far remote from the propulsion system. Advances in supporting laser technologies are anticipated to increase the potential for photofission pulsed space propulsion. The fundamental performance analysis of the photofission pulsed space propulsion system indicates the architecture is feasible for further evaluation.

Fundamental Architecture and Analysis of an Antimatter Ultra-Intense Laser Derived Pulsed Space Propulsion System

Antimatter has been generated in large quantities by the Lawrence Livermore National Laboratory Titan laser. The Titan laser is an ultra-intense laser system on the order of approximately 1020W/cm2 with pulse durations of roughly 1ps. With the Titan laser incident on a high atomic number target, such as gold, antimatter on the scale of 2 × 1010 positrons are generated. Roughly 90% of the generated positrons are ejected anisotropic and aft to the respective target. The mechanisms for the laser-derived positron antimatter generation involve electron interaction with the nuclei based on bremsstrahlung photons that yield electron-positron pairs as a consequence of the Bethe-Heitler process, which predominates the Trident process. Given the constraints of the current and near future technology space, a pulsed space propulsion configuration is advocated for antimatter derived space propulsion, similar in concept to pulsed radioisotope propulsion. Antimatter is generated through an ultra-intense laser on the scale of a Titan laser incident on a gold target and annihilated in a closed chamber, representative of a combustion chamber. Upon reaching a temperature threshold, the closed chamber opens, producing a pulse of thrust. The implication of the pulsed space propulsion antimatter architecture is that the energy source for the antimatter propulsion system can be decoupled from the actual spacecraft. In contrast to conventional chemical propulsion systems, which require storage of its respective propulsive chemical potential energy, the proposed antimatter propulsion architecture may have the energy source at a disparate location from the spacecraft. The ultra-intense laser could convey its laser energy over a distance to the actual spacecraft equipped with the positron antimatter pulsed space propulsion system. Hydrogen is considered as the propulsive fluid, in light of its low molecular weight. Fundamental analysis is applied to preliminarily define the performance of the positron antimatter derived pulsed space propulsion system. The fundamental performance analysis of the antimatter pulsed space propulsion system successfully reveals the architecture is viable for further evaluation.

Project New Orion: Pulsed Nuclear Space Propulsion Using Photofission Activated by Ultra-Intense Laser

Project New Orion entails a pulsed nuclear space propulsion system that utilizes photofission through the implementation of an ultra-intense laser. The historical origins derive from the endeavors of Project Orion, which utilized thermonuclear devices to impart a considerable velocity increment on the respective spacecraft. The shear magnitude of Project Orion significantly detracts from the likelihood of progressive research development testing and evaluation. Project New Orion incorporates a more feasible pathway for the progressive research development testing and evaluation of the pulsed nuclear space propulsion system. Photofission through the application of an ultra-intense laser enables a much more controllable and scalable nuclear yield. The energy source for the ultra-intense laser is derived from a first stage liquid hydrogen and liquid oxygen chemical propulsion system. A portion of the thermal/kinetic energy of the rocket propulsive fluid is converted to electrical energy through a magneto-hydrodynamic generator with cryogenic propellant densification for facilitating the integral superconducting magnets. Fundamental analysis of Project New Orion demonstrates the capacity to impart a meaningful velocity increment through ultra-intense laser derived photofission on a small spacecraft.

Positron Induced Fusion Pulsed Space Propulsion through an Ultra-Intense Laser

A pulsed space propulsion system using position antimatter to induce Deuterium-Tritium fusion through an ultra-intense laser incident on a gold target is conceptually presented through fundamental performance analysis. As opposed to traditional strategies positron antimatter is considered rather than antiproton antimatter. Positron antimatter can be produced by an ultra- intense laser incident on a high atomic number target, such as gold. The ultra-intense laser production of positron antimatter mechanism greatly alleviates constraints, such as requirements for antimatter storage imperative for antiproton antimatter. Also the ultra-intense laser and associated energy source can be stationary or positioned remote while the pulsed space propulsion system using position antimatter to induce Deuterium-Tritium fusion is in flight. Various mechanisms for antimatter catalyzed fusion are considered, for which the preferred mechanism is the antiproton hotspot ignition strategy. Fundamental performance analysis is subsequently applied to derive positron antimatter generation requirements and associated propulsion performance. The characteristics of the pulsed space propulsion system using position antimatter to induce Deuterium-Tritium fusion through an ultra-intense laser incident on a gold target imply a promising non-chemical propulsion alternative for the transport of bulk cargo to support space missions.

Laser shaping and optical power limiting of pulsed Laguerre–Gaussian laser beams of high-order radial modes in fullerene C60

We study the strong nonlinear optical dynamics of nanosecond pulsed Laguerre–Gaussian laser beams of high-order radial modes with zero orbital angular momentum propagating in the fullerene C60molecular medium. It is found that the spatiotemporal profile of the incident pulsed Laguerre–Gaussian laser beam is strongly reshaped during its propagation in the C60molecular medium. The centrosymmetric temporal profile of the incident pulse gradually evolves into a noncentrosymmetric meniscus shape, and the on-axis pulse duration is clearly depressed. Furthermore, the field intensity is distinctly attenuated due to the field-intensity-dependent reverse saturable absorption, and clear optical power limiting behavior is observed for different orders of the input pulsed Laguerre–Gaussian laser beams before the takeover of the saturation effect;the lower the order of the Laguerre–Gaussian beam, the lower the energy transmittance.

Diagnosis of ultrafast ultraintense laser pulse characteristics by machine-learning-assisted electron spin

The rapid development of ultrafast ultraintense laser technology continues to create opportunities for studying strong-field physics under extreme conditions.However,accurate determination of the spatial and temporal characteristics of a laser pulse is still a great challenge,especially when laser powers higher than hundreds of terawatts are involved.In this paper,by utilizing the radiative spin-flip effect,we find that the spin depolarization of an electron beam can be employed to diagnose characteristics of ultrafast ultraintense lasers with peak intensities around 10^(20)–10^(22) W/cm^(2).With three shots,our machine-learning-assisted model can predict,simultaneously,the pulse duration,peak intensity,and focal radius of a focused Gaussian ultrafast ultraintense laser(in principle,the profile can be arbitrary)with relative errors of 0.1%–10%.The underlying physics and an alternative diagnosis method(without the assistance of machine learning)are revealed by the asymptotic approximation of the final spin degree of polarization.Our proposed scheme exhibits robustness and detection accuracy with respect to fluctuations in the electron beam parameters.Accurate measurements of ultrafast ultraintense laser parameters will lead to much higher precision in,for example,laser nuclear physics investigations and laboratory astrophysics studies.Robust machine learning techniques may also find applications in more general strong-field physics scenarios.

High harmonic generation in crystal SiO_(2) by sub-10-fs laser pulses

The high harmonic generation(HHG)by few-cycle laser pulses is essential for research in strong-field solid-state physics.Through comparison of high harmonic spectra of solids generated by laser pulses with varying durations,we discovered that lasers with good dispersion compensation are capable of producing a broad spectrum of high harmonics.As the pulse duration is further compressed,several interference peaks appear in the broad spectrum.Moreover,we conducted simulations using the semiconductor Bloch equation,considering the effect of Berry curvature,to better understand this process.Our work provides a valuable approach for studying HHG by few-cycle laser pulses in solid materials,expanding the application of HHG in attosecond physics.

Exploration of growth conditions of TaAs Weyl semimetal thin film using pulsed laser deposition

Ta As,the first experimentally discovered Weyl semimetal material,has attracted a lot of attention due to its high carrier mobility,high anisotropy,nonmagnetic properties and strong interaction with light.These make it an ideal candidate for the study of Weyl fermions and applications in quantum computation,thermoelectric devices,and photodetection.For further basic physics studies and potential applications,large-size and high-quality Ta As films are urgently needed.However,it is difficult to grow As-stoichiometry Ta As films due to the volatilization of As during the growth.To solve this problem,we attempted to grow Ta As films on different substrates using targets with different As stoichiometric ratios via pulsed laser deposition(PLD).In this work,we found that partial As ions of the Ga As substrate are likely to diffuse into the Ta As films during growth,which was preliminarily confirmed by structural characterization,surface topography and composition analysis.As a result,the As content in the Ta As film was improved and the Ta As phase was achieved.Our work presents an effective method for the fabrication of Ta As films using PLD,enabling possible use of the Weyl semimetal film for functional devices.

Optimization of large-area YBa_(2)Cu_(3)O_(7-δ)thin films by pulsed laser deposition for planar microwave devices

This paper presents high quality YBa_(2)Cu_(3)O_(7-δ)(YBCO)thin films on LaAlO_(3)substrate for microwave devices prepared by pulsed laser deposition(PLD).The double-sided YBCO films cover a large area and have been optimized for key parameters relevant to microwave device applications,such as surface morphology and surface resistance(R_(s)).This was achieved by improving the target quality and increasing the oxygen pressure during deposition,respectively.To evaluate the suitability of the YBCO films for microwave devices,a pair of microwave filters based on microstrip fabricated on films from this work and a commercial company were compared.The results show that the YBCO films in this work could completely meet the requirements for microwave devices.

Sensitivity study of the SiGe heterojunction bipolar transistor single event effect based on pulsed laser and technology computer-aided design simulation

The single event effect of a silicon–germanium heterojunction bipolar transistor(SiGe HBT) was thoroughly investigated. By considering the worst bias condition, the sensitive area of the proposed device was scanned with a pulsed laser.With variation of the collector bias and pulsed laser incident energy, the single event transient of the SiGe HBT was studied.Moreover, the single event transient produced by laser irradiation at a wavelength of 532 nm was more pronounced than at a wavelength of 1064 nm. Finally, the impact of the equivalent linear energy transfer of the 1064 nm pulsed laser on the single event transient was qualitatively examined by performing technology computer-aided design simulations, and a good consistency between the experimental data and the simulated outcomes was attained.

Structural Analysis of TiC and TiC-C Core-Shell Nanostructures Produced by Pulsed-Laser Ablation

This paper reports on the ablation process of a pure Ti solid target immersed in a C-enriched acetone solution, leading to the production of titanium carbide (TiC) and Ti-C core-shell nanostructures. The used route of synthesis is generally called pulsed laser ablation in liquid (PLAL). The presence of carbon structures in the solution contributed to the carbon content in the produced Ti-based nanomaterials. The atomic composition of the produced nanostructures was analyzed using SEM-EDS, while TEM micrographs revealed the formation of spherical TiC and core-shell nanostructures ranging from 40 to 100 nm. The identification of atomic planes by HRTEM confirmed a 10 nm diameter C-shell with a graphite structure surrounding the Ti-core. Raman spectroscopy allowed for the identification of D and G peaks for graphite and a Raman signal at 380 and 600 cm−1, assigned to TiC. The results contribute to the state-of-the-art production of TiC and Ti-C core-shell nanostructures using the PLAL route.

Pulsed Laser Annealed Ga Hyperdoped Poly-Si/SiO_(x)Passivating Contacts for High-Efficiency Monocrystalline Si Solar Cells

Polycrystalline Si(poly-Si)-based passivating contacts are promising candidates for high-efficiency crystalline Si solar cells.We show that nanosecond-scale pulsed laser melting(PLM)is an industrially viable technique to fabricate such contacts with precisely controlled dopant concentration profiles that exceed the solid solubility limit.We demonstrate that conventionally doped,hole-selective poly-Si/SiO_(x)contacts that provide poor surface passivation of c-Si can be replaced with Ga-or B-doped contacts based on non-equilibrium doping.We overcome the solid solubility limit for both dopants in poly-Si by rapid cooling and recrystallization over a timescale of∼25 ns.We show an active Ga dopant concentration of∼3×10^(20)cm^(−3)in poly-Si which is six times higher than its solubility limit in c-Si,and a B dopant concentration as high as∼10^(21) cm^(−3).We measure an implied open-circuit voltage of 735 mV for Ga-doped poly-Si/SiO_(x)contacts on Czochralski Si with a low contact resistivity of 35.5±2.4 mΩcm^(2).Scanning spreading resistance microscopy and Kelvin probe force microscopy show large diffusion and drift current in the p-n junction that contributes to the low contact resistivity.Our results suggest that PLM can be extended for hyperdoping of other semiconductors with low solubility atoms to enable high-efficiency devices.

Advanced Concept Ramjet Propulsion System Utilizing In-Situ Positron Antimatter Derived from Ultra-Intense Laser with Fundamental Performance Analysis

The fundamental performance analysis of an advanced concept ramjet propulsion system using antimatter is presented. Antimatter is generated by ultra-intense laser pulses incident on a gold target. The scientific foundation for the generation of antimatter by an ultra-intense laser was established in the early 1970’s and later demonstrated at Lawrence Livermore National Laboratory from 2008 to 2009. Antimatter on the scale of 2 × 1010 positrons were generated through a ~1 ps pulse from the Lawrence Livermore National Laboratory Titan laser that has an intensity of ~1020 W/cm2. The predominant mechanism is the Bethe-Heitler process, which involves high-energy bremsstrahlung photons as a result of electron-nuclei interaction. Propulsion involving lasers through chemical rather than non-chemical interaction has been previously advocated by Phipps. The major utilities of the ultra-intense laser derived antimatter ramjet are the capability to generate antimatter without a complex storage system and the ability to decouple the antimatter ramjet propulsion system from the energy source. For instance the ultra-intense laser and energy source could be terrestrial, while the ramjet could be mounted to a UAV as a propulsion system. With the extrapolation of current technologies, a sufficient number of pulses by ultra-intense lasers are eventually anticipated for the generation of antimatter to heat the propulsive flow of a ramjet. Fundamental performance analysis is provided based on an ideal ramjet derivation that is modified to address the proposed antimatter ramjet architecture.