The Panxi Rift Zone is a famous metallogenic province in Southwest China. Continental rifting developed in Hercynian period (P 2, 260～250Ma) accompany with a series of basic\|ultrabasic rocks. Various in lithologies,...The Panxi Rift Zone is a famous metallogenic province in Southwest China. Continental rifting developed in Hercynian period (P 2, 260～250Ma) accompany with a series of basic\|ultrabasic rocks. Various in lithologies, such as layered intrusions (V\|Ti\|Fe formation), small\|sized mafic\|ultramafic bodies (stocks) and large\|scale basalt (Emeishan Basalt) are constituted of a complete melanocratic rock system.Most of Cu\|Ni\|PGE sulfide deposits are related to small\|sized ultramafic rock bodies. It is a perfect possibility for them to be an affinity of basic eruptive lava and for the neck facies. But in ① Panzhihua\|Center Yunnan Province, the Gaojiacun, also Jinbaoshan, as large stratiform basic\|ultrabasic complex used to be thought that is older one intruded to basement rocks in Precambrian. However, new evidences suggest it is similar with the small\|sized ultramafic rock bodies containing Cu\|Ni\|PGE, and also the both are affinity of the Emeishan Basalt; ② Miyi district, Cu\|Pt mineralization was discovered in the Xinjie bedded basic complex, and in where ophitic olivine\|pyroxenite\|peridotite facies are exactly Pt\|bearing layers; ③ Longzhoushan district, we have recently researched basic\|ultrabasic clusters which intruded into fracture zones, and Cu\|Ni\|Pt, Pd mineralization developed at the salbands.Generally, the basalt is poor in PGE and rich in Cu. It is suggested as the result of PGE dispersion\|concentration processing in the melanocratic rock system when rifting happened.展开更多
Zircon is a common accessory mineral in various rocks,especially in the crustal ones.It is the best mineral for U-Pb dating.Meanwhile,trace elements and isotopes of the mineral can also provide much information concer...Zircon is a common accessory mineral in various rocks,especially in the crustal ones.It is the best mineral for U-Pb dating.Meanwhile,trace elements and isotopes of the mineral can also provide much information concerning the formation and evolution of rocks.There are a growing number of reports of zircon existing in mantle peridotite.However,it is generally considered that zircon is unlikely crystallized in ultrabasic rocks due to SiO_(2)-unsaturation.In this paper,the SiO_(2) activity and zircon/baddeleyite transition curve at different conditions were calculated through thermodynamic phase equilibrium modeling,to reveal the main factors affecting the SiO_(2) activity and the stability of zircon/baddeleyite in ultrabasic and basic rocks,especially in mantle peridotite.These results provide a thermodynamic basis for interpreting the genesis and significance of zircon in mantle rocks.That is,the SiO_(2) activity is mainly controlled by stable mineral assemblages and temperature-pressure conditions.The orthopyroxene+olivine assemblage in peridotite as an effective buffer restricts the SiO_(2) activity in a relatively high range with a small variation.The upper temperature limit of zircon can reach more than 1500℃ with this mineral assemblage.During the low-temperature serpentinization of peridotite,the replacement of olivine and pyroxene by serpentine can result in a significant decrease of SiO_(2) activity,and baddeleyite can be stabilized at<530℃ and<2.7 GPa.When peridotite is strongly metasomatized by the SiO_(2)-bearing fluid,the addition of SiO_(2) can increase its activity and make zircon stable at low temperatures.The SiO_(2) activity in ultrabasic-basic rocks is not only positively correlated with the SiO_(2) content but also negatively correlated with the Ca and Na contents of rocks.This is because Ca and Na preferentially combine with Si and Al to form Si-rich minerals,such as clinopyroxene and feldspar.This process will consume excessive SiO_(2),decreasing the SiO_(2) activity.This may be the reason why zircon can be found in ultrabasic rocks,while baddeleyite can exist in some basic and alkaline rocks.The thermodynamic modeling can also reasonably explain the mutual transformation between zircon and baddeleyite in ultrabasic-basic rocks.Our results indicate that zircon can exist stably in mantle peridotite in a wide range of temperature-pressure conditions and its formation is related to melt/fluid metasomatism.That is,the presence of zircon in mantle peridotite is an important information carrier of crust-mantle interaction for deep material cycling.展开更多
文摘The Panxi Rift Zone is a famous metallogenic province in Southwest China. Continental rifting developed in Hercynian period (P 2, 260～250Ma) accompany with a series of basic\|ultrabasic rocks. Various in lithologies, such as layered intrusions (V\|Ti\|Fe formation), small\|sized mafic\|ultramafic bodies (stocks) and large\|scale basalt (Emeishan Basalt) are constituted of a complete melanocratic rock system.Most of Cu\|Ni\|PGE sulfide deposits are related to small\|sized ultramafic rock bodies. It is a perfect possibility for them to be an affinity of basic eruptive lava and for the neck facies. But in ① Panzhihua\|Center Yunnan Province, the Gaojiacun, also Jinbaoshan, as large stratiform basic\|ultrabasic complex used to be thought that is older one intruded to basement rocks in Precambrian. However, new evidences suggest it is similar with the small\|sized ultramafic rock bodies containing Cu\|Ni\|PGE, and also the both are affinity of the Emeishan Basalt; ② Miyi district, Cu\|Pt mineralization was discovered in the Xinjie bedded basic complex, and in where ophitic olivine\|pyroxenite\|peridotite facies are exactly Pt\|bearing layers; ③ Longzhoushan district, we have recently researched basic\|ultrabasic clusters which intruded into fracture zones, and Cu\|Ni\|Pt, Pd mineralization developed at the salbands.Generally, the basalt is poor in PGE and rich in Cu. It is suggested as the result of PGE dispersion\|concentration processing in the melanocratic rock system when rifting happened.
基金This work was supported by the National Natural Science Foundation of China(Grant Nos.41972067&41930215)the Fund from the Key Laboratory of Deep-Earth Dynamics of Ministry of Natural Resources(Grant No.J1901-11).
文摘Zircon is a common accessory mineral in various rocks,especially in the crustal ones.It is the best mineral for U-Pb dating.Meanwhile,trace elements and isotopes of the mineral can also provide much information concerning the formation and evolution of rocks.There are a growing number of reports of zircon existing in mantle peridotite.However,it is generally considered that zircon is unlikely crystallized in ultrabasic rocks due to SiO_(2)-unsaturation.In this paper,the SiO_(2) activity and zircon/baddeleyite transition curve at different conditions were calculated through thermodynamic phase equilibrium modeling,to reveal the main factors affecting the SiO_(2) activity and the stability of zircon/baddeleyite in ultrabasic and basic rocks,especially in mantle peridotite.These results provide a thermodynamic basis for interpreting the genesis and significance of zircon in mantle rocks.That is,the SiO_(2) activity is mainly controlled by stable mineral assemblages and temperature-pressure conditions.The orthopyroxene+olivine assemblage in peridotite as an effective buffer restricts the SiO_(2) activity in a relatively high range with a small variation.The upper temperature limit of zircon can reach more than 1500℃ with this mineral assemblage.During the low-temperature serpentinization of peridotite,the replacement of olivine and pyroxene by serpentine can result in a significant decrease of SiO_(2) activity,and baddeleyite can be stabilized at<530℃ and<2.7 GPa.When peridotite is strongly metasomatized by the SiO_(2)-bearing fluid,the addition of SiO_(2) can increase its activity and make zircon stable at low temperatures.The SiO_(2) activity in ultrabasic-basic rocks is not only positively correlated with the SiO_(2) content but also negatively correlated with the Ca and Na contents of rocks.This is because Ca and Na preferentially combine with Si and Al to form Si-rich minerals,such as clinopyroxene and feldspar.This process will consume excessive SiO_(2),decreasing the SiO_(2) activity.This may be the reason why zircon can be found in ultrabasic rocks,while baddeleyite can exist in some basic and alkaline rocks.The thermodynamic modeling can also reasonably explain the mutual transformation between zircon and baddeleyite in ultrabasic-basic rocks.Our results indicate that zircon can exist stably in mantle peridotite in a wide range of temperature-pressure conditions and its formation is related to melt/fluid metasomatism.That is,the presence of zircon in mantle peridotite is an important information carrier of crust-mantle interaction for deep material cycling.
