Recently, a huge ultrahigh-pressure(UHP) metamorphic belt of oceanic-type has been recognized in southwestern(SW) Tianshan, China. Petrological studies show that the UHP metamorphic rocks of SW Tianshan orogenic belt ...Recently, a huge ultrahigh-pressure(UHP) metamorphic belt of oceanic-type has been recognized in southwestern(SW) Tianshan, China. Petrological studies show that the UHP metamorphic rocks of SW Tianshan orogenic belt include mafic eclogites and blueschists, pelitic garnet phengite schists, marbles and serpentinites. The well-preserved coesite inclusions were commonly found in eclogites, garnet phengite schists and marbles. Ti-clinohumite and Ti-chondrodite have been identified in UHP metamorphic serpentinites. Based on the PT pseudosection calculation and combined U-Pb zircon dating, the P-T-t path has been outlined as four stages: cold subduction to UHP conditions before^320 Ma whose peak ultrahigh pressure is about 30 kbar at 500 ℃, heating decompression from the Pmax to the Tmax stage before 305 Ma whose peak temperature is about 600 ℃ at 22 kbar, then the early cold exhumation from amphibolite eclogite facies to epidote-amphibolite facies metamorphism before 220 Ma and the last tectonic exhumation from epidote amphibolite facies to greenschist facies metamorphism. Combining with the syn-subduction arc-like 333-326 Ma granitic rocks and 280-260 Ma S-type granites in the coeval low-pressure and high-temperature(LP-HT) metamorphic belt, the tectonic evolution of Tianshan UHP metamorphic belt during late Cambrian to early Triassic has been proposed in this paper.展开更多
Lame modulus (λ) and shear modulus (μ) are among the most important, intrinsic, elastic constants of rocks. Using 7. and μ could be much more advantageous than using P- and S-wave velocities (Vp and Vs). Here...Lame modulus (λ) and shear modulus (μ) are among the most important, intrinsic, elastic constants of rocks. Using 7. and μ could be much more advantageous than using P- and S-wave velocities (Vp and Vs). Here we quantified these equivalent isotropic elastic moduli for 115 representative rocks from the ultrahigh pressure (UHP) metamorphic terrane of the Dabie-Sulu orogenic belt (China) and their variations with pressure (P), temperature (T), density (p), Vp, Vs and mineralogical composition. Both moduli increase nonlinearly and linearly with increasing pressure at low (〈200-300 MPa) and high (〉200-300 MPa) pressures, respectively. In the regime of high pressures, 7. and IX decrease quasi-linearly with increasing temperature with temperature derivatives dλ/dT and dμ/dT generally in the range of -10×10-3 to -1×10-3 GPa/℃. Dehydration of water-bearing minerals such as serpentine in peridotites and chlorite in retrograde eciogites results in an abrupt drop in 7. while μ remains almost unchanged. In Z-p, μ-p and 7.-IX plots, the main categories of UHP rocks can be characterized. Serpentinization leads to significant decreases in μ and 7. as serpentine has extremely low values of Z, μ and p. Eclogites, common mafic rocks (mafic gneiss, metagabbro and amphibolite), and felsic rocks (orthogneiss and paragneiss) have high, moderate and low μ and λ values, respectively. For pyroxenes and olivines, λ increases but μ decreases with increasing Fe/Mg ratios. For plagioclase feldspars, both Z and μ exhibit a significant positive correlation with anorthite content. SiO2-rich felsic rocks and quartzites are deviated remarkably from the general trend lines of the acid-intermediate-mafic rocks in Vs-p, μ-p, λ-Vp,λ-Vs and μ-λ diagrams because quartz has extremely low λ (-8.1 GPa) and p (2.65 g/cm3) but moderate μ (44.4 GPa) values. Increasing the contents of garnet, rutile, ilmenite and magnetite results in a significant increase in the λ and μ values of the UHP metamorphic rocks. However, either λ or μ is insensitive to the compositional variations for pyralspite (pyrope-almandine-spessartine) solution series. The results provide potentially improved constraints on characterization of crustal composition based on the elastic properties of rocks and in situ seismic data from deep continental roots.展开更多
Asthemaintectoniccomponentofthe Himalayan–Tibetan orogen,the Lhasa terrane has received much attention as it records the entire history of the orogeny.The occurrence of high pressure eclogite in the Sumdo complex in ...Asthemaintectoniccomponentofthe Himalayan–Tibetan orogen,the Lhasa terrane has received much attention as it records the entire history of the orogeny.The occurrence of high pressure eclogite in the Sumdo complex in central Lhasa terrane has a significant importance on the understanding of the Paleo-Tethys subduction and plate itineration processes in this area.The petrological,geochemical and geochronological data of eclogite and associated blueschist and garnet-bearing mica schist from Sumdo,Jilang and Bailang area have been briefly reviewed to explore the origin and metamorphic evolution of this suture.Eclogites from the Sumdo complex have experienced low temperature,high pressure to ultrahigh pressure metamorphism,revealing a fastsubduction and exhumation process in a typical oceanic subduction zone.The large P-T range between different eclogites in the literature may be affected by the big error of unappropriated using geothermobarometry and may also because of slices of subducted blocks derived from different depths juxtapose together during exhumation.By summarizing the U-Pb,Lu-Hf and Sm-Nd ages of eclogites,the eclogite facies metamorphism is likely to occur in early Triassic during 245-225 Ma,but not the previously accepted late Permian at ca.260 Ma by the reinterpretation of the former geochronological data from literature.The opening of Paleo-Tethys Ocean between the Lhasa terrane initiate prior to ca.280 Ma and ultimate closure to integrate the Lhasa terrane was no earlier than225 Ma and may triggered by the initial subduction of Bangong-Nujiang Tethys Ocean in the north.展开更多
To improve the bearing pressure capacity of ultrahigh pressure apparatus,the internal autofrettaged cylinder with interlayer pressure(ACCIP)is introduced,and the analytical model for the ACCIP structure and its deriva...To improve the bearing pressure capacity of ultrahigh pressure apparatus,the internal autofrettaged cylinder with interlayer pressure(ACCIP)is introduced,and the analytical model for the ACCIP structure and its derivation are presented as well.Calculation showed that the ACCIP method enhance bearing pressure of the apparatus obviously;optimization results revealed that under the working pressure pw=1.07σs and different radius ratios,the ACCIP method can keep the apparatus in deformed-elastically state;And when the pw=1.07σs,the minimum radius ratio was approximate 3.29,in this case,no yielding happened.The above results demonstrate that the ACCIP method is a promising technique to improve the bearing pressure of ultrahigh pressure apparatus,and the analytical model for the ACCIP method is also reasonable.In addition,the minimum radius ratio ro/ri under randomly specified workload can be Fig.d out by the analytical model proposed in this work.展开更多
In this study,a robust macroscale liquid superlubricity with a coefficient of friction of 0.004 was achieved by introducing molybdenum carbide(Mo_(2)CT_(x))MXene nanoparticles as lubricating additives in a lithium hex...In this study,a robust macroscale liquid superlubricity with a coefficient of friction of 0.004 was achieved by introducing molybdenum carbide(Mo_(2)CT_(x))MXene nanoparticles as lubricating additives in a lithium hexafluorophosphate-based ionic liquid at Si_(3)N_(4)-sapphire interfaces.The maximal contact pressure in the superlubricity state could reach 1.42 GPa,which far exceeds the limit of the superlubricity regime in previous studies.The results indicate that a composite tribofilm(mainly containing molybdenum oxide and phosphorus oxide)that formed at the interface by a tribochemical reaction contributed to the excellent antiwear performance.Furthermore,the extremely low shear strength of the tribofilm and the interlayers of Mo_(2)CT_(x)MXene contributed to the superlubricity.This work demonstrates the promising potential of Mo_(2)CT_(x)MXene in improving superlubricity properties,which could accelerate the application of superlubricity in mechanical systems.展开更多
The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones ...The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones surrounding the core of the Luotian dome, and the separation of the UHP, HP and epidote blueschist units by the detachment zones, which form the vertically stacking sheet like slices of the HP and UHP metamorphic rocks. From the core outwards, exist the HP and UHP rock barren Dabie complex, UHP unit, HP unit and epidote blueschist unit. The extension tectonics of post HP and UHP metamorphic event constrain the distribution and present configuration of the HP and UHP metamorphic rocks, and the extensional tectonic framework bears some similarities to the Cordillera metamorphic core complex. It is suggested that partial melting happened in the Dabie gneiss complex (DGC) and UHP unit contemporaneously with the extrusion of UHP metamorphic rocks into the lower-middle crust. The formation and emplacement of the migmatite and granites are the response to the change in thermal state, facilitating the transfer from the compressive regime to extensional regime in the crust. The large scale crustal extension and uplift and the accompanying anatexis in Dabieshan are probably related to the delamination and magmatic underplating in the mantle and the lower crust.展开更多
A lot of previous experimental studies on ultramafic rocks(SiO2 unsaturated system)(Ringwood and Major, 1971;Irifune et al., 1986;Gasparik, 1989;Ono and Yasuda, 1996) have demonstrated that characteristics of Si-rich ...A lot of previous experimental studies on ultramafic rocks(SiO2 unsaturated system)(Ringwood and Major, 1971;Irifune et al., 1986;Gasparik, 1989;Ono and Yasuda, 1996) have demonstrated that characteristics of Si-rich and Al-deficient in garnet are resulted from coupled substitution of SiⅥ+MⅥ=AlⅥ+AlⅥ and SiⅥ+NaⅧ=AlⅥ+MⅧ(M=Mg, Fe, Ca) at ultrahigh pressures(UHP)(>5 GPa). The degree of substitution will be enhanced by increasing pressure which has a positive correlation with the content of SiⅥ, but a negative correlation with the content of AlⅥ in supersilic garnet. These experimental results established a theoretical foundation for further understanding the formation mechanism of the exsolution of pyroxene in garnet observed in deep mantle xenoliths and some ultrahigh pressure rocks, and also for estimating the pressure conditions of the formation of supersilic garnet before exsolution(Haggerty and Sautter, 1990;Sautter et al., 1991;van Roermund et al., 1998;Ye et al., 2000). Although some experimental studies on SiO2 saturated system have been reported(Irifune et al., 1994;Ono., 1998;Dobrazhinetskya and Green.,2007;Wu et al., 2009), the stability conditions of supersilic garnet are still lack of unified understanding. Therefore, HP-HT experiments were carried out on felsic rocks under conditions of 6–12 GPa and 1000℃–1400℃. Combined with previous experimental data, we try to figure out the minimum stable pressure and geological significants of supersilic garnet in SiO2 saturated system. Our experimental results from SiO2 saturated system show the minimum stable pressure of supersilic garnet should be ≥10 GP of stishovite stability field. These results are similar as that from experiments using starting composition similar to average upper continental crust reported by Irifune et al(1994) who yielded that garnet gradually became supersilic and Al-deficient as pressures increased above 10 GPa, especially in a pressure interval between 13 and 18 GPa. Moreover, experiments with different starting materials(Ono, 1998;Dobrazhinetskya and Green, 2007;Wu et al. 2009) also indicate the stable pressure condition of supersilic garnet is mainly ≥9 –10 GPa in SiO2 saturated system if data of small-size grains at low temperature are ignored due to measuring errors. Thus, it can be concluded that the minimum stable pressure of supersilic garnet in SiO2 saturated system is distinctly different from that in SiO2 unsaturated ultramafic rock system. The minimum pressure of the former is ≥9–10 GPa of stishovite stability field, while that of the latter is >5 GPa. Therefore, whether independent SiO2 phase exist or rock system is SiO2 saturated must be taken into considered when estimating the peak pressure of exsolutions in supersilic garnet in UHP rocks. Furthermore, pressure of >5 GPa directly estimated by supersilic garnet based on conclusion from SiO2 unsaturation system rather than SiO2 saturation in previous sdudies may have been underestimated and need to be re-estimated. Supersilic garnets have been recognized by interior exsolutions of clinopyroxene in garnet pyroxene from Yinggelisayi South Altyn(Liu et al., 2005), and exsolutions of rodlike quartz+rutile in felsic gneiss from Songshugou North Qinling(Liu et al., 2003). According to the experimental results from SiO2 unsaturated system, the peak metamorphic pressure of the both SiO2 saturated rocks have been estimated to be >7 Gpa and >5 Gpa, respectively. However, combined with the new experimental results above, we re-estimated that the peak metamorphic pressure of these SiO2 saturated rocks should be≥9–10 GPa at least, implying an ultra-deep subduction to mantle depth of stishovite stability field. This research, together with previous findings(Liu et al., 2007, 2018), shows that continental subduction to mantle depth(300 km) of stishovite stability field and then exhumation to the surface is obviously more common than previously thought, and the rock types are also diverse. At the same time, it provides a new indicator and thought for recognizing the subduction to the mantle depth of stishovite stability field in UHP metamorphic belt.展开更多
Extensive efforts have been made to pursue a low-friction state with promising applications in many fields,such as mechanical and biomedical engineering.Among which,the load capacity of the low-friction state has been...Extensive efforts have been made to pursue a low-friction state with promising applications in many fields,such as mechanical and biomedical engineering.Among which,the load capacity of the low-friction state has been considered to be crucial for industrial applications.Here,we report a low friction under ultrahigh contact pressure by building a novel self-assembled fluorinated azobenzene layer on an atomically smooth highly-oriented pyrolytic graphite(HOPG)surface.Sliding friction coefficients could be as low as 0.0005 or even lower under a contact pressure of up to 4 GPa.It demonstrates that the low friction under ultrahigh contact pressure is attributed to molecular fluorination.The fluorination leads to effective and robust lubrication between the tip and the self-assembled layer and enhances tighter rigidity which can reduce the stress concentration in the substrate,which was verified by density functional theory(DFT)and molecular dynamics(MD)simulation.This work provides a new approach to avoid the failure of ultralow friction coefficient under relatively high contact pressure,which has promising potential application value in the future.展开更多
The high-pressure behavior of solid hydrogen has been investigated by in situ Raman spectroscopy upon compression to 300 GPa at ambient temperature. The hydrogen vibron frequency begins to decrease after it initially ...The high-pressure behavior of solid hydrogen has been investigated by in situ Raman spectroscopy upon compression to 300 GPa at ambient temperature. The hydrogen vibron frequency begins to decrease after it initially increases with pressure up to 38 GPa. This softening behavior suggests the weakening of the intramolecular bond and the increased intermolecular interactions. Above 237 GPa, the vibron frequency softens very rapidly with pressure at a much higher rate than that of phase HI, corresponding to transformation from phase III into phase IV. The phase transition sequence has been confirmed from phase I to phase III and then to phase IV at 208 and 237 GPa, respectively. Previous theoretical calculations lead to the proposal of an energetically favorable monoclinic C2/c structure for phase HI and orthorhombic Pbcn structure for phase IV. Up to 304 GPa, solid hydrogen is not yet an alkali metal since the sample is still transparent.展开更多
In the Central Orogenic Belt, China, two UHP metamorphic belts are discriminated mainly based on a detailed structural analysis of the Kanfenggou UHP metamorphic fragment exposed in the eastern Qinling orogen, and tog...In the Central Orogenic Belt, China, two UHP metamorphic belts are discriminated mainly based on a detailed structural analysis of the Kanfenggou UHP metamorphic fragment exposed in the eastern Qinling orogen, and together with previous regional structural, petrological and geochronological data at the scale of the orogenic domain. The first one corresponds to the South Altun North Qaidam North Qinling UHP metamorphic belt. The other is the Dabie Sulu UHP and HP metamorphic belts. The two UHP metamorphic belts are separated by a series of tectonic slices composed by the Qinling rock group, Danfeng rock group and Liuling or Foziling rock group etc. respectively, and are different in age of the peak UHP metamorphism and geodynamic implications for continental deep subduction and collision. Regional field and petrological relationships suggest that the Kanfenggou UHP metamorphic fragment that contains a large volume of the coesite and microdiamond bearing eclogite lenses is compatible with the structures recognized in the South Altun and North Qaidam UHP metamorphic fragments exposed in the western part of China, thereby forming a large UHP metamorphic belt up to 1 000 km long along the orogen strike. This UHP metamorphic belt represents an intercontinental deep subduction and collision belt between the Yangtze and Sino Korean cratons, occurred during the Paleozoic. On the other hand, the well constrained Dabie Sulu UHP and HP metamorphic belts occurred mainly during Triassic time (250-220 Ma), and were produced by the intracontinental deep subduction and collision within the Yangtze craton. The Kanfenggou UHP metamorphic fragment does not appear to link with the Dabie Sulu UHP and HP metamorphic belts along the orogen. There is no reason to assume the two UHP metamorphic belts as a single giant deep subduction and collision zone in the Central Orogenic Belt situated between the Yangtze and Sino Korean cratons. Therefore, any dynamic model for the orogen must account for the development of UHP metamorphic rocks belonging to the separate two tectonic belts of different age and tectono metamorphic history.展开更多
There are two models of ultrahigh pressure metamorphism (UHPM) zone in Dabie: the model of under thrusting returning which even arrives at the mantle and the superimposed model of tectonics in the crust. There are tw...There are two models of ultrahigh pressure metamorphism (UHPM) zone in Dabie: the model of under thrusting returning which even arrives at the mantle and the superimposed model of tectonics in the crust. There are two points of view in the argument about formation depth of ultrahigh pressure metamorphism: (1) the depth can be calculated by hydrostatic equation; (2) the high pressure was composed of gravity, tectonic and other forces instead of merely gravity force. Some misunderstandings of mechanical conceptions presented in the paper showing the hydrostatic viewpoints should be open to question. The main conceptions are: (1) the confining pressure was only formed by gravity, and the differential stress was only formed by tectonic force; (2) the differential stress is not big enough to lead to form ultrahigh pressure metamorphism; (3) once tectonic overpressure goes beyond the limited strength of rocks the tectonic force would disappear and the rocks would be broken or rheomorphied at the same time. A short discussion in basic mechanics is made in this paper for a perfect process for discussing the argument.展开更多
Some current methods for the calculation of the geogenetic depth are based on the hydrostatic model, it is induced that the depth in certain underground place is equal to the pressure divided by the specific weight of...Some current methods for the calculation of the geogenetic depth are based on the hydrostatic model, it is induced that the depth in certain underground place is equal to the pressure divided by the specific weight of rock, on the assumption that the rock is hydrostatic and overlain by no other force but gravity. However, most of rock is in a deformation environment and non hydrostatic state, especially in an orogenic belt, so that the calculated depth may be exaggerated in comparison with the actual depth according to the hydrostatic formula. In the finite slight deformation and elastic model, the relative actual depth value from the 3 axis strain data was obtained with the measurement of strain including that of superimposed tectonic forces but excluding that of time factor for the strain. If some data on the strain speed are obtained, the depth would be more realistically calculated according to the rheological model because the geological body often experiences long term creep strains.展开更多
Eclogite, one of the important lithologies in the main hole of the Chinese Continental Scientific Drilling (CCSD) Project, exists above the depth of 3 245 m and has distinctive responses of gamma-ray, compensating d...Eclogite, one of the important lithologies in the main hole of the Chinese Continental Scientific Drilling (CCSD) Project, exists above the depth of 3 245 m and has distinctive responses of gamma-ray, compensating density and neutron well-logging, and so on. In this study, according to the diversities of minerals and chemical components and well-logging responses, edogites are classified from three aspects of origin, content of oxygen, and sub-mineral. We studied the logging identification method for eclogite sub-classes based on multi-element statistics and reconstructed 11 kinds of eclogite. As a result, eclogites can be divided into 6 types using well logs. In the light of this recognition, the eclogite in the main hole is divided into 20 sections, and the distribution characters of all sub-classes of eclogite are analyzed, which will provide important data for geological research of CCSD.展开更多
The transitional pressure of quartz coesite under the differential stress and highly strained conditions is far from the pressure of the stable field under the static pressure. Therefore, the effect of the different...The transitional pressure of quartz coesite under the differential stress and highly strained conditions is far from the pressure of the stable field under the static pressure. Therefore, the effect of the differential stress should be considered when the depth of petrogenesis is estimated about ultrahigh pressure metamorphic (UHPM) rocks. The rheological strength of typical ultrahigh pressure rocks in continental subduction zone was derived from the results of the laboratory experiments. The results indicate the following three points. (1) The rheological strength of gabbro, similar to that of eclogite, is smaller than that of clinopyroxenite on the same condition. (2) The calculated strength of rocks (gabbro, eclogite and clinopyroxenite) related to UHPM decreases by nearly one order of magnitude with the temperature rising by 100 ℃ in the range between 600 and 900 ℃. The calculated strength is far greater than the faulting strength of rocks at 600 ℃, and is in several hundred to more than one thousand mega pascals at 700-800 ℃, which suggests that those rocks are located in the brittle deformation region at 600 ℃, but are in the semi brittle to plastic deformation region at 700-800 ℃. Obviously, the 700 ℃ is a brittle plastic transition boundary. (3) The calculated rheological strength in the localized deformation zone on a higher strain rate condition (1.6×10 -12 s -l ) is 2-5 times more than that in the distributed deformation zone on a lower strain rate condition (1.6×10 -14 s -1 ). The average rheological stress (1 600 MPa) at the strain rate of 10 -12 s -1 stands for the ultimate differential stress of UHPM rocks in the semi brittle flow field, and the average rheological stress (550-950 MPa) at the strain rate of l0 -14 - 10 -13 s -l stands for the ultimate differential stress of UHPM rocks in the plastic flow field, suggesting that the depth for the formation of UHPM rocks is more than 20-60 km below the depth estimated under static pressure condition due to the effect of the differential stress.展开更多
The studies on ultra microstructure characteristics of quartz exsolution in eclogite and coesite in UHP eclogite of several localities are done with the appliance of laser Raman spectroscopy and U stage. Research re...The studies on ultra microstructure characteristics of quartz exsolution in eclogite and coesite in UHP eclogite of several localities are done with the appliance of laser Raman spectroscopy and U stage. Research results show that the phase transformation of coesite quartz in garnet and/or omphacite is a continuous process. Topological relationship is present between quartz exsolution in omphacite and its host mineral which shows orientations of two long axes of quartz exsolution parallel to (100) and (-101) of omphacite. At present, some scholars suggest that the quartz exsolution in omphacite of eclogite is the evidence of UHP metamorphism. However, temperature and pressure condition and the exsolution mechanism of oriented needlelike quartz in omphacite still remain unclear. Therefore, further study should be enhanced on experimental research on exsolution mechanism of super silicate clinopyroxene, which could provide experimental quantitative constraint on quartz exsolution as UHP indicator.展开更多
Phellodendron amurense has been used for many years as a medical plant in traditional Chinese medicine and has shown great prospect in recent clinical trials for future applications. Berberine is an essential active c...Phellodendron amurense has been used for many years as a medical plant in traditional Chinese medicine and has shown great prospect in recent clinical trials for future applications. Berberine is an essential active compound contained in P. amurense. Our objective in this study was to quantify the content of berberine in P.amurense from sites at different elevations on Changbai Mountain. We collected samples of P. amurense from five different elevations on Changbai Mountain. Berberine in samples was extracted by ultrahigh pressure extraction(UPE). And the quantity was measured by high performance liquid chromatography(HPLC). First, the optimal HPLC conditions for berberine were identified with satisfactory precision(relative standard deviation, R SD/5.6 %), good accuracy(relative error, R E/ 3.6 %) and good linear relation(R2= 0.9998) in the range of 6.576–328.8 mg L-1. Second, the combination of UPE and HPLC methods in quantitative analysis of berberine showed high repeatability(R SD= 3.28 %), reproducibility(R SD= 4.72 %),stability(R SD/ 1.27 %) and good recovery(99.54 %) for real plant materials. Samples from Heilongjiang Province at the lowest elevation contained the highest amount of berberine.Similarly, the lowest amount of berberine was recorded in samples from Changbai Forest Bureau of Jilin Province collected at the highest elevation in this paper. The proposed UPE–HPLC method is simple, reliable and low-cost for quantitative analysis of berberine. Content of berberine in P.amurense varied significantly by site on Changbai Mountain.展开更多
An attempt is made to confirm the existence of the two discrete UHP and HP metamorphic belts in the central orogenic belt in China. Detailed geological mapping and structural and petrological analyses of the Kanfengg...An attempt is made to confirm the existence of the two discrete UHP and HP metamorphic belts in the central orogenic belt in China. Detailed geological mapping and structural and petrological analyses of the Kanfenggou (看丰沟 ) and Xiangfanggou ( 香坊沟 ) slices exposed in the eastern Qinling (秦岭) orogen indicate that they experienced ultrahigh pressure and high pressure metamorphism, respectively. The former, situated in northern Qinling, contains a large volume of fine-grained coesite and quartz pseudomorphs after coesite- and microdiamond-bearing eclogite lenses, whereas the latter, located in southern Qinling, preserves the relicts of a high pressure metamorphic mineral assemblage. Based on extensive fieldwork together with compilations at the scale of the orogenic belt, and a comparison of Pb isotopic compositions between the UHP metamorphic rocks from Kanfenggou slice and the Dabie UHP metamorphic belt, we propose that there are at least two discrete ultrahigh pressure metamorphic belts with different ages and tectonic evolution within the central orogenic belt in China. The first is the South AItun-North Qaidam-North Qinling ultrahigh pressure metamorphic belt of Early Paleozoic age ( -500 -400 Ma). The Kanfenggou ultrahigh pressure slab is located at its eastern segment. The second is the well constrained Dabie ( 大别 )-Sulu (苏鲁 ) ultrahigh/high pressure metamorphic belt of Triassic age (-250-220 Ma). The Xiangfanggou high pressure metamorphic slab is a westward extension of the Dabie-Sulu ultrahigh/high pressure metamorphic belt. The Pb isotopic compositions of the UHP metamorphic rocks from Kanfenggou UHP fragment in East Qinling are different from those of the UHP rocks in Dabie UHP metamorphic belt, but are consistent with those of the rocks from the Qinling rock group and Erlangping (二郎坪) rock group. The East Qinling UHP metamorphic belt does not appear to link with the Dabie-Sulu UHP metamorphic belt. These two ultrahigh metamorphic belts are separated by the suture-like Shangnan ( 商南 )-Danfeng (丹凤 ) fault system or Guishan ( 龟山 )-Meishan ( 梅山) fault, and a series of fault-bounded tectonic slices with different ages and rock assemblages. The Early Paleozoic ultrahigh metamorphic belt towards the east cannot be linked to the Triassic Dabie-Sulu ultrahigh/high pressure metamorphic belt, and so does not form a huge ultrahigh pressure metamorphic belt extending more than 4 000 km in the central orogenic belt. In addition, the South Altun-North Qaidam- North Qinling ultrahigh metamorphic belt probably represents an intercontinental deep subduction/ collision belt between the Sino-Korean and Yangtze cratons, occurring during the Early Paleozoic. The Dabie-Sulu ultrahigh/high pressure belt may have been formed by an intracontinental deep subduction/ collision process occurring in the northern part of the Yangtze craton during the Triassic. It is suggested that the two phase crustal subduction/collision processes, with an interval of 4200--300 Ma, responsible for the formation of the two ultrahigh/high pressure metamorphic belts occurred along spatially different belts within the central orogenic belt, China.展开更多
A preliminary study of paleomagnetism and rock magnetism has been done on 55 eclogite samples collected from the Chinese Continental Scientific Drilling (CCSD) site at the Maobei (毛北) area, Donghai (东海) Coun...A preliminary study of paleomagnetism and rock magnetism has been done on 55 eclogite samples collected from the Chinese Continental Scientific Drilling (CCSD) site at the Maobei (毛北) area, Donghai (东海) County, Jiangsu (江苏) Province. Also the isothermal remanence, hysteresis loop, magnetic fabric, thermal susceptibility were measured, and analyses were made by electron-probe and scanning electric microscope on some samples synchronously. The result indicates that there are two groups of stable remanence, the normal and reversed magnetization. The remanence orientations are: D=94.3°, I=-29.1° and D=273.7°, I=15.4°, respectively. The magnetization intensity and the density of the samples which carry the normal magnetization are very different from those bearing reversed magnetization. The magnetic anisotropy is weak, and the minimum axis is hardly determined. The isothermal remanence and the hysteresis loop show that the magnetic carriers of the eclogite are likely SD (single domain) and PSD (pseudo.single domain) magnetite. According to the magnetic property, the cause of formation of magnetic carriers, the mechanism of the remanence, and the significance for the tectonics are discussed.展开更多
The lithologies of the Chinese Continental Scientific Drilling main hole (CCSD-MH) are mainly comprised of orthogneiss,paragneiss,eclogite,amphibolite,and ultramafic rocks.The statistical results of logs of CCSD-MH ...The lithologies of the Chinese Continental Scientific Drilling main hole (CCSD-MH) are mainly comprised of orthogneiss,paragneiss,eclogite,amphibolite,and ultramafic rocks.The statistical results of logs of CCSD-MH indicate that ultramafic rocks are characterized by very high CNL (neutron log) and very low GR (gamma ray log) and RD (resistivity log);eclogites are characterized by high DEN (density),VP (P-wave velocity) and PE (photoelectric absorption capture cross section);orthogneiss and paragneiss are characterized by high GR,U (uranium content),Th (thorium content),K (potassium content) and RD,and low DEN,PE,and CNL;logging values of amphibolite are between the logging values of eclogites and paragneiss.In addition,the logs could reflect the degree of retrograde metamorphism of eclogites.The upper section (100-2 000 m) shows higher DEN,PE,VP,and lower GR,U,Th,K,RD than the lower section (2 000-5 000 m).Most logs of the upper section are more fluctuant than those of the lower section.This indicates that the upper section has more heterogeneities than the lower section.The cross plots of logs indicate that DEN,GR,K,and CNL are more powerful in identifying ultrahigh pressure metamorphic (UHPM) rocks at the CCSD-MH.GR value of the rocks from CCSD-MH shows obviously an increasing trend from ultramafic rock (the most mafic rocks at CCSD-MH) to orthogneiss (the most acid rocks at CCSD-MH).On the contrary,DEN value decreases from the ultramafic rock to the orthogneiss.CNL log is a good indicator of the content of structure water in crystalline rocks.展开更多
文摘Recently, a huge ultrahigh-pressure(UHP) metamorphic belt of oceanic-type has been recognized in southwestern(SW) Tianshan, China. Petrological studies show that the UHP metamorphic rocks of SW Tianshan orogenic belt include mafic eclogites and blueschists, pelitic garnet phengite schists, marbles and serpentinites. The well-preserved coesite inclusions were commonly found in eclogites, garnet phengite schists and marbles. Ti-clinohumite and Ti-chondrodite have been identified in UHP metamorphic serpentinites. Based on the PT pseudosection calculation and combined U-Pb zircon dating, the P-T-t path has been outlined as four stages: cold subduction to UHP conditions before^320 Ma whose peak ultrahigh pressure is about 30 kbar at 500 ℃, heating decompression from the Pmax to the Tmax stage before 305 Ma whose peak temperature is about 600 ℃ at 22 kbar, then the early cold exhumation from amphibolite eclogite facies to epidote-amphibolite facies metamorphism before 220 Ma and the last tectonic exhumation from epidote amphibolite facies to greenschist facies metamorphism. Combining with the syn-subduction arc-like 333-326 Ma granitic rocks and 280-260 Ma S-type granites in the coeval low-pressure and high-temperature(LP-HT) metamorphic belt, the tectonic evolution of Tianshan UHP metamorphic belt during late Cambrian to early Triassic has been proposed in this paper.
基金supported by the Sino Probe-deep exploration in Ministry of land and Resources of China(Sino Probe-07)the knowledge Innovation Program from Guangzhou Institute of Geochemistry,the Chinese Academy of Sciences(GIGCX-09-02)+1 种基金This is contribution No.IS-1386 from GIGCASthe Natural Sciences and Engineering Council of Canada and the Chinese Academy of Geological Sciences for the discovery and research grants(No.1212011121274)
文摘Lame modulus (λ) and shear modulus (μ) are among the most important, intrinsic, elastic constants of rocks. Using 7. and μ could be much more advantageous than using P- and S-wave velocities (Vp and Vs). Here we quantified these equivalent isotropic elastic moduli for 115 representative rocks from the ultrahigh pressure (UHP) metamorphic terrane of the Dabie-Sulu orogenic belt (China) and their variations with pressure (P), temperature (T), density (p), Vp, Vs and mineralogical composition. Both moduli increase nonlinearly and linearly with increasing pressure at low (〈200-300 MPa) and high (〉200-300 MPa) pressures, respectively. In the regime of high pressures, 7. and IX decrease quasi-linearly with increasing temperature with temperature derivatives dλ/dT and dμ/dT generally in the range of -10×10-3 to -1×10-3 GPa/℃. Dehydration of water-bearing minerals such as serpentine in peridotites and chlorite in retrograde eciogites results in an abrupt drop in 7. while μ remains almost unchanged. In Z-p, μ-p and 7.-IX plots, the main categories of UHP rocks can be characterized. Serpentinization leads to significant decreases in μ and 7. as serpentine has extremely low values of Z, μ and p. Eclogites, common mafic rocks (mafic gneiss, metagabbro and amphibolite), and felsic rocks (orthogneiss and paragneiss) have high, moderate and low μ and λ values, respectively. For pyroxenes and olivines, λ increases but μ decreases with increasing Fe/Mg ratios. For plagioclase feldspars, both Z and μ exhibit a significant positive correlation with anorthite content. SiO2-rich felsic rocks and quartzites are deviated remarkably from the general trend lines of the acid-intermediate-mafic rocks in Vs-p, μ-p, λ-Vp,λ-Vs and μ-λ diagrams because quartz has extremely low λ (-8.1 GPa) and p (2.65 g/cm3) but moderate μ (44.4 GPa) values. Increasing the contents of garnet, rutile, ilmenite and magnetite results in a significant increase in the λ and μ values of the UHP metamorphic rocks. However, either λ or μ is insensitive to the compositional variations for pyralspite (pyrope-almandine-spessartine) solution series. The results provide potentially improved constraints on characterization of crustal composition based on the elastic properties of rocks and in situ seismic data from deep continental roots.
文摘Asthemaintectoniccomponentofthe Himalayan–Tibetan orogen,the Lhasa terrane has received much attention as it records the entire history of the orogeny.The occurrence of high pressure eclogite in the Sumdo complex in central Lhasa terrane has a significant importance on the understanding of the Paleo-Tethys subduction and plate itineration processes in this area.The petrological,geochemical and geochronological data of eclogite and associated blueschist and garnet-bearing mica schist from Sumdo,Jilang and Bailang area have been briefly reviewed to explore the origin and metamorphic evolution of this suture.Eclogites from the Sumdo complex have experienced low temperature,high pressure to ultrahigh pressure metamorphism,revealing a fastsubduction and exhumation process in a typical oceanic subduction zone.The large P-T range between different eclogites in the literature may be affected by the big error of unappropriated using geothermobarometry and may also because of slices of subducted blocks derived from different depths juxtapose together during exhumation.By summarizing the U-Pb,Lu-Hf and Sm-Nd ages of eclogites,the eclogite facies metamorphism is likely to occur in early Triassic during 245-225 Ma,but not the previously accepted late Permian at ca.260 Ma by the reinterpretation of the former geochronological data from literature.The opening of Paleo-Tethys Ocean between the Lhasa terrane initiate prior to ca.280 Ma and ultimate closure to integrate the Lhasa terrane was no earlier than225 Ma and may triggered by the initial subduction of Bangong-Nujiang Tethys Ocean in the north.
基金the Natural Science Foundation of Jiangsu Province of China(Grant No.BK20200999),meanwhile I am also grateful to Prof.Renshu Yuan for his help.
文摘To improve the bearing pressure capacity of ultrahigh pressure apparatus,the internal autofrettaged cylinder with interlayer pressure(ACCIP)is introduced,and the analytical model for the ACCIP structure and its derivation are presented as well.Calculation showed that the ACCIP method enhance bearing pressure of the apparatus obviously;optimization results revealed that under the working pressure pw=1.07σs and different radius ratios,the ACCIP method can keep the apparatus in deformed-elastically state;And when the pw=1.07σs,the minimum radius ratio was approximate 3.29,in this case,no yielding happened.The above results demonstrate that the ACCIP method is a promising technique to improve the bearing pressure of ultrahigh pressure apparatus,and the analytical model for the ACCIP method is also reasonable.In addition,the minimum radius ratio ro/ri under randomly specified workload can be Fig.d out by the analytical model proposed in this work.
基金This work was financially supported by the National Key R&D Program of China(No.2020YFA0711003)the National Natural Science Foundation of China(Nos.52005290,51775295,and 52175174)the Open Research Fund of Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments(No.KF202004).
文摘In this study,a robust macroscale liquid superlubricity with a coefficient of friction of 0.004 was achieved by introducing molybdenum carbide(Mo_(2)CT_(x))MXene nanoparticles as lubricating additives in a lithium hexafluorophosphate-based ionic liquid at Si_(3)N_(4)-sapphire interfaces.The maximal contact pressure in the superlubricity state could reach 1.42 GPa,which far exceeds the limit of the superlubricity regime in previous studies.The results indicate that a composite tribofilm(mainly containing molybdenum oxide and phosphorus oxide)that formed at the interface by a tribochemical reaction contributed to the excellent antiwear performance.Furthermore,the extremely low shear strength of the tribofilm and the interlayers of Mo_(2)CT_(x)MXene contributed to the superlubricity.This work demonstrates the promising potential of Mo_(2)CT_(x)MXene in improving superlubricity properties,which could accelerate the application of superlubricity in mechanical systems.
文摘The most prominent feature of the extensional tectonic framework of post high pressure (HP) and ultrahigh pressure (UHP) metamorphism in Dabieshan is the development of the multi layered extension detachment zones surrounding the core of the Luotian dome, and the separation of the UHP, HP and epidote blueschist units by the detachment zones, which form the vertically stacking sheet like slices of the HP and UHP metamorphic rocks. From the core outwards, exist the HP and UHP rock barren Dabie complex, UHP unit, HP unit and epidote blueschist unit. The extension tectonics of post HP and UHP metamorphic event constrain the distribution and present configuration of the HP and UHP metamorphic rocks, and the extensional tectonic framework bears some similarities to the Cordillera metamorphic core complex. It is suggested that partial melting happened in the Dabie gneiss complex (DGC) and UHP unit contemporaneously with the extrusion of UHP metamorphic rocks into the lower-middle crust. The formation and emplacement of the migmatite and granites are the response to the change in thermal state, facilitating the transfer from the compressive regime to extensional regime in the crust. The large scale crustal extension and uplift and the accompanying anatexis in Dabieshan are probably related to the delamination and magmatic underplating in the mantle and the lower crust.
基金granted by the National Natural Science Foundation of China(Grant Nos.41430209)the Chinese Ministry of Science and Technology(Grant No.2015CB856100)the MOST Special Fund from the State Key Laboratory of Continental Dynamics(Grant No.201210133)
文摘A lot of previous experimental studies on ultramafic rocks(SiO2 unsaturated system)(Ringwood and Major, 1971;Irifune et al., 1986;Gasparik, 1989;Ono and Yasuda, 1996) have demonstrated that characteristics of Si-rich and Al-deficient in garnet are resulted from coupled substitution of SiⅥ+MⅥ=AlⅥ+AlⅥ and SiⅥ+NaⅧ=AlⅥ+MⅧ(M=Mg, Fe, Ca) at ultrahigh pressures(UHP)(>5 GPa). The degree of substitution will be enhanced by increasing pressure which has a positive correlation with the content of SiⅥ, but a negative correlation with the content of AlⅥ in supersilic garnet. These experimental results established a theoretical foundation for further understanding the formation mechanism of the exsolution of pyroxene in garnet observed in deep mantle xenoliths and some ultrahigh pressure rocks, and also for estimating the pressure conditions of the formation of supersilic garnet before exsolution(Haggerty and Sautter, 1990;Sautter et al., 1991;van Roermund et al., 1998;Ye et al., 2000). Although some experimental studies on SiO2 saturated system have been reported(Irifune et al., 1994;Ono., 1998;Dobrazhinetskya and Green.,2007;Wu et al., 2009), the stability conditions of supersilic garnet are still lack of unified understanding. Therefore, HP-HT experiments were carried out on felsic rocks under conditions of 6–12 GPa and 1000℃–1400℃. Combined with previous experimental data, we try to figure out the minimum stable pressure and geological significants of supersilic garnet in SiO2 saturated system. Our experimental results from SiO2 saturated system show the minimum stable pressure of supersilic garnet should be ≥10 GP of stishovite stability field. These results are similar as that from experiments using starting composition similar to average upper continental crust reported by Irifune et al(1994) who yielded that garnet gradually became supersilic and Al-deficient as pressures increased above 10 GPa, especially in a pressure interval between 13 and 18 GPa. Moreover, experiments with different starting materials(Ono, 1998;Dobrazhinetskya and Green, 2007;Wu et al. 2009) also indicate the stable pressure condition of supersilic garnet is mainly ≥9 –10 GPa in SiO2 saturated system if data of small-size grains at low temperature are ignored due to measuring errors. Thus, it can be concluded that the minimum stable pressure of supersilic garnet in SiO2 saturated system is distinctly different from that in SiO2 unsaturated ultramafic rock system. The minimum pressure of the former is ≥9–10 GPa of stishovite stability field, while that of the latter is >5 GPa. Therefore, whether independent SiO2 phase exist or rock system is SiO2 saturated must be taken into considered when estimating the peak pressure of exsolutions in supersilic garnet in UHP rocks. Furthermore, pressure of >5 GPa directly estimated by supersilic garnet based on conclusion from SiO2 unsaturation system rather than SiO2 saturation in previous sdudies may have been underestimated and need to be re-estimated. Supersilic garnets have been recognized by interior exsolutions of clinopyroxene in garnet pyroxene from Yinggelisayi South Altyn(Liu et al., 2005), and exsolutions of rodlike quartz+rutile in felsic gneiss from Songshugou North Qinling(Liu et al., 2003). According to the experimental results from SiO2 unsaturated system, the peak metamorphic pressure of the both SiO2 saturated rocks have been estimated to be >7 Gpa and >5 Gpa, respectively. However, combined with the new experimental results above, we re-estimated that the peak metamorphic pressure of these SiO2 saturated rocks should be≥9–10 GPa at least, implying an ultra-deep subduction to mantle depth of stishovite stability field. This research, together with previous findings(Liu et al., 2007, 2018), shows that continental subduction to mantle depth(300 km) of stishovite stability field and then exhumation to the surface is obviously more common than previously thought, and the rock types are also diverse. At the same time, it provides a new indicator and thought for recognizing the subduction to the mantle depth of stishovite stability field in UHP metamorphic belt.
基金the support of the National Natural Science Foundation of China(51922058).
文摘Extensive efforts have been made to pursue a low-friction state with promising applications in many fields,such as mechanical and biomedical engineering.Among which,the load capacity of the low-friction state has been considered to be crucial for industrial applications.Here,we report a low friction under ultrahigh contact pressure by building a novel self-assembled fluorinated azobenzene layer on an atomically smooth highly-oriented pyrolytic graphite(HOPG)surface.Sliding friction coefficients could be as low as 0.0005 or even lower under a contact pressure of up to 4 GPa.It demonstrates that the low friction under ultrahigh contact pressure is attributed to molecular fluorination.The fluorination leads to effective and robust lubrication between the tip and the self-assembled layer and enhances tighter rigidity which can reduce the stress concentration in the substrate,which was verified by density functional theory(DFT)and molecular dynamics(MD)simulation.This work provides a new approach to avoid the failure of ultralow friction coefficient under relatively high contact pressure,which has promising potential application value in the future.
基金Project supported by the National Basic Research Program of China(Grant No.2011CB808200)the Program for Changjiang Scholars and Innovative Research Team in University,China(Grant No.IRT1132)+2 种基金the National Natural Science Foundation of China(Grant Nos.51032001,11074090,10979001,51025206,11274137,11474127, and 11504127)the National Found for Fostering Talents of Basic Science,China(Grant No.J1103202)the China Postdoctoral Science Foundation(Grant No.2015M570265)
文摘The high-pressure behavior of solid hydrogen has been investigated by in situ Raman spectroscopy upon compression to 300 GPa at ambient temperature. The hydrogen vibron frequency begins to decrease after it initially increases with pressure up to 38 GPa. This softening behavior suggests the weakening of the intramolecular bond and the increased intermolecular interactions. Above 237 GPa, the vibron frequency softens very rapidly with pressure at a much higher rate than that of phase HI, corresponding to transformation from phase III into phase IV. The phase transition sequence has been confirmed from phase I to phase III and then to phase IV at 208 and 237 GPa, respectively. Previous theoretical calculations lead to the proposal of an energetically favorable monoclinic C2/c structure for phase HI and orthorhombic Pbcn structure for phase IV. Up to 304 GPa, solid hydrogen is not yet an alkali metal since the sample is still transparent.
文摘In the Central Orogenic Belt, China, two UHP metamorphic belts are discriminated mainly based on a detailed structural analysis of the Kanfenggou UHP metamorphic fragment exposed in the eastern Qinling orogen, and together with previous regional structural, petrological and geochronological data at the scale of the orogenic domain. The first one corresponds to the South Altun North Qaidam North Qinling UHP metamorphic belt. The other is the Dabie Sulu UHP and HP metamorphic belts. The two UHP metamorphic belts are separated by a series of tectonic slices composed by the Qinling rock group, Danfeng rock group and Liuling or Foziling rock group etc. respectively, and are different in age of the peak UHP metamorphism and geodynamic implications for continental deep subduction and collision. Regional field and petrological relationships suggest that the Kanfenggou UHP metamorphic fragment that contains a large volume of the coesite and microdiamond bearing eclogite lenses is compatible with the structures recognized in the South Altun and North Qaidam UHP metamorphic fragments exposed in the western part of China, thereby forming a large UHP metamorphic belt up to 1 000 km long along the orogen strike. This UHP metamorphic belt represents an intercontinental deep subduction and collision belt between the Yangtze and Sino Korean cratons, occurred during the Paleozoic. On the other hand, the well constrained Dabie Sulu UHP and HP metamorphic belts occurred mainly during Triassic time (250-220 Ma), and were produced by the intracontinental deep subduction and collision within the Yangtze craton. The Kanfenggou UHP metamorphic fragment does not appear to link with the Dabie Sulu UHP and HP metamorphic belts along the orogen. There is no reason to assume the two UHP metamorphic belts as a single giant deep subduction and collision zone in the Central Orogenic Belt situated between the Yangtze and Sino Korean cratons. Therefore, any dynamic model for the orogen must account for the development of UHP metamorphic rocks belonging to the separate two tectonic belts of different age and tectono metamorphic history.
文摘There are two models of ultrahigh pressure metamorphism (UHPM) zone in Dabie: the model of under thrusting returning which even arrives at the mantle and the superimposed model of tectonics in the crust. There are two points of view in the argument about formation depth of ultrahigh pressure metamorphism: (1) the depth can be calculated by hydrostatic equation; (2) the high pressure was composed of gravity, tectonic and other forces instead of merely gravity force. Some misunderstandings of mechanical conceptions presented in the paper showing the hydrostatic viewpoints should be open to question. The main conceptions are: (1) the confining pressure was only formed by gravity, and the differential stress was only formed by tectonic force; (2) the differential stress is not big enough to lead to form ultrahigh pressure metamorphism; (3) once tectonic overpressure goes beyond the limited strength of rocks the tectonic force would disappear and the rocks would be broken or rheomorphied at the same time. A short discussion in basic mechanics is made in this paper for a perfect process for discussing the argument.
文摘Some current methods for the calculation of the geogenetic depth are based on the hydrostatic model, it is induced that the depth in certain underground place is equal to the pressure divided by the specific weight of rock, on the assumption that the rock is hydrostatic and overlain by no other force but gravity. However, most of rock is in a deformation environment and non hydrostatic state, especially in an orogenic belt, so that the calculated depth may be exaggerated in comparison with the actual depth according to the hydrostatic formula. In the finite slight deformation and elastic model, the relative actual depth value from the 3 axis strain data was obtained with the measurement of strain including that of superimposed tectonic forces but excluding that of time factor for the strain. If some data on the strain speed are obtained, the depth would be more realistically calculated according to the rheological model because the geological body often experiences long term creep strains.
基金This paper is supported by the Engineering Center of Chinese Continental Scientific Drilling (No. CCSD2004-04-01)the Focused Subject Program of Beijing (No. XK104910598).
文摘Eclogite, one of the important lithologies in the main hole of the Chinese Continental Scientific Drilling (CCSD) Project, exists above the depth of 3 245 m and has distinctive responses of gamma-ray, compensating density and neutron well-logging, and so on. In this study, according to the diversities of minerals and chemical components and well-logging responses, edogites are classified from three aspects of origin, content of oxygen, and sub-mineral. We studied the logging identification method for eclogite sub-classes based on multi-element statistics and reconstructed 11 kinds of eclogite. As a result, eclogites can be divided into 6 types using well logs. In the light of this recognition, the eclogite in the main hole is divided into 20 sections, and the distribution characters of all sub-classes of eclogite are analyzed, which will provide important data for geological research of CCSD.
文摘The transitional pressure of quartz coesite under the differential stress and highly strained conditions is far from the pressure of the stable field under the static pressure. Therefore, the effect of the differential stress should be considered when the depth of petrogenesis is estimated about ultrahigh pressure metamorphic (UHPM) rocks. The rheological strength of typical ultrahigh pressure rocks in continental subduction zone was derived from the results of the laboratory experiments. The results indicate the following three points. (1) The rheological strength of gabbro, similar to that of eclogite, is smaller than that of clinopyroxenite on the same condition. (2) The calculated strength of rocks (gabbro, eclogite and clinopyroxenite) related to UHPM decreases by nearly one order of magnitude with the temperature rising by 100 ℃ in the range between 600 and 900 ℃. The calculated strength is far greater than the faulting strength of rocks at 600 ℃, and is in several hundred to more than one thousand mega pascals at 700-800 ℃, which suggests that those rocks are located in the brittle deformation region at 600 ℃, but are in the semi brittle to plastic deformation region at 700-800 ℃. Obviously, the 700 ℃ is a brittle plastic transition boundary. (3) The calculated rheological strength in the localized deformation zone on a higher strain rate condition (1.6×10 -12 s -l ) is 2-5 times more than that in the distributed deformation zone on a lower strain rate condition (1.6×10 -14 s -1 ). The average rheological stress (1 600 MPa) at the strain rate of 10 -12 s -1 stands for the ultimate differential stress of UHPM rocks in the semi brittle flow field, and the average rheological stress (550-950 MPa) at the strain rate of l0 -14 - 10 -13 s -l stands for the ultimate differential stress of UHPM rocks in the plastic flow field, suggesting that the depth for the formation of UHPM rocks is more than 20-60 km below the depth estimated under static pressure condition due to the effect of the differential stress.
文摘The studies on ultra microstructure characteristics of quartz exsolution in eclogite and coesite in UHP eclogite of several localities are done with the appliance of laser Raman spectroscopy and U stage. Research results show that the phase transformation of coesite quartz in garnet and/or omphacite is a continuous process. Topological relationship is present between quartz exsolution in omphacite and its host mineral which shows orientations of two long axes of quartz exsolution parallel to (100) and (-101) of omphacite. At present, some scholars suggest that the quartz exsolution in omphacite of eclogite is the evidence of UHP metamorphism. However, temperature and pressure condition and the exsolution mechanism of oriented needlelike quartz in omphacite still remain unclear. Therefore, further study should be enhanced on experimental research on exsolution mechanism of super silicate clinopyroxene, which could provide experimental quantitative constraint on quartz exsolution as UHP indicator.
基金supported by the 12th five-year National Science and Technology plan of China(2012BAC01B03)the 111 Project of China(B13007)
文摘Phellodendron amurense has been used for many years as a medical plant in traditional Chinese medicine and has shown great prospect in recent clinical trials for future applications. Berberine is an essential active compound contained in P. amurense. Our objective in this study was to quantify the content of berberine in P.amurense from sites at different elevations on Changbai Mountain. We collected samples of P. amurense from five different elevations on Changbai Mountain. Berberine in samples was extracted by ultrahigh pressure extraction(UPE). And the quantity was measured by high performance liquid chromatography(HPLC). First, the optimal HPLC conditions for berberine were identified with satisfactory precision(relative standard deviation, R SD/5.6 %), good accuracy(relative error, R E/ 3.6 %) and good linear relation(R2= 0.9998) in the range of 6.576–328.8 mg L-1. Second, the combination of UPE and HPLC methods in quantitative analysis of berberine showed high repeatability(R SD= 3.28 %), reproducibility(R SD= 4.72 %),stability(R SD/ 1.27 %) and good recovery(99.54 %) for real plant materials. Samples from Heilongjiang Province at the lowest elevation contained the highest amount of berberine.Similarly, the lowest amount of berberine was recorded in samples from Changbai Forest Bureau of Jilin Province collected at the highest elevation in this paper. The proposed UPE–HPLC method is simple, reliable and low-cost for quantitative analysis of berberine. Content of berberine in P.amurense varied significantly by site on Changbai Mountain.
基金This paper is financially supported by the National Natural ScienceFoundation of China (Nos .40372094 and 49972067) .
文摘An attempt is made to confirm the existence of the two discrete UHP and HP metamorphic belts in the central orogenic belt in China. Detailed geological mapping and structural and petrological analyses of the Kanfenggou (看丰沟 ) and Xiangfanggou ( 香坊沟 ) slices exposed in the eastern Qinling (秦岭) orogen indicate that they experienced ultrahigh pressure and high pressure metamorphism, respectively. The former, situated in northern Qinling, contains a large volume of fine-grained coesite and quartz pseudomorphs after coesite- and microdiamond-bearing eclogite lenses, whereas the latter, located in southern Qinling, preserves the relicts of a high pressure metamorphic mineral assemblage. Based on extensive fieldwork together with compilations at the scale of the orogenic belt, and a comparison of Pb isotopic compositions between the UHP metamorphic rocks from Kanfenggou slice and the Dabie UHP metamorphic belt, we propose that there are at least two discrete ultrahigh pressure metamorphic belts with different ages and tectonic evolution within the central orogenic belt in China. The first is the South AItun-North Qaidam-North Qinling ultrahigh pressure metamorphic belt of Early Paleozoic age ( -500 -400 Ma). The Kanfenggou ultrahigh pressure slab is located at its eastern segment. The second is the well constrained Dabie ( 大别 )-Sulu (苏鲁 ) ultrahigh/high pressure metamorphic belt of Triassic age (-250-220 Ma). The Xiangfanggou high pressure metamorphic slab is a westward extension of the Dabie-Sulu ultrahigh/high pressure metamorphic belt. The Pb isotopic compositions of the UHP metamorphic rocks from Kanfenggou UHP fragment in East Qinling are different from those of the UHP rocks in Dabie UHP metamorphic belt, but are consistent with those of the rocks from the Qinling rock group and Erlangping (二郎坪) rock group. The East Qinling UHP metamorphic belt does not appear to link with the Dabie-Sulu UHP metamorphic belt. These two ultrahigh metamorphic belts are separated by the suture-like Shangnan ( 商南 )-Danfeng (丹凤 ) fault system or Guishan ( 龟山 )-Meishan ( 梅山) fault, and a series of fault-bounded tectonic slices with different ages and rock assemblages. The Early Paleozoic ultrahigh metamorphic belt towards the east cannot be linked to the Triassic Dabie-Sulu ultrahigh/high pressure metamorphic belt, and so does not form a huge ultrahigh pressure metamorphic belt extending more than 4 000 km in the central orogenic belt. In addition, the South Altun-North Qaidam- North Qinling ultrahigh metamorphic belt probably represents an intercontinental deep subduction/ collision belt between the Sino-Korean and Yangtze cratons, occurring during the Early Paleozoic. The Dabie-Sulu ultrahigh/high pressure belt may have been formed by an intracontinental deep subduction/ collision process occurring in the northern part of the Yangtze craton during the Triassic. It is suggested that the two phase crustal subduction/collision processes, with an interval of 4200--300 Ma, responsible for the formation of the two ultrahigh/high pressure metamorphic belts occurred along spatially different belts within the central orogenic belt, China.
基金This paper is supported by the Focused Subject Program of Beijing (No. XK104910598).
文摘A preliminary study of paleomagnetism and rock magnetism has been done on 55 eclogite samples collected from the Chinese Continental Scientific Drilling (CCSD) site at the Maobei (毛北) area, Donghai (东海) County, Jiangsu (江苏) Province. Also the isothermal remanence, hysteresis loop, magnetic fabric, thermal susceptibility were measured, and analyses were made by electron-probe and scanning electric microscope on some samples synchronously. The result indicates that there are two groups of stable remanence, the normal and reversed magnetization. The remanence orientations are: D=94.3°, I=-29.1° and D=273.7°, I=15.4°, respectively. The magnetization intensity and the density of the samples which carry the normal magnetization are very different from those bearing reversed magnetization. The magnetic anisotropy is weak, and the minimum axis is hardly determined. The isothermal remanence and the hysteresis loop show that the magnetic carriers of the eclogite are likely SD (single domain) and PSD (pseudo.single domain) magnetite. According to the magnetic property, the cause of formation of magnetic carriers, the mechanism of the remanence, and the significance for the tectonics are discussed.
基金supported by the Special Fund for Basic Scientific Research of Central Colleges (No. CUG090106)the National Basic Research Program of China (No. 2003CB716500)
文摘The lithologies of the Chinese Continental Scientific Drilling main hole (CCSD-MH) are mainly comprised of orthogneiss,paragneiss,eclogite,amphibolite,and ultramafic rocks.The statistical results of logs of CCSD-MH indicate that ultramafic rocks are characterized by very high CNL (neutron log) and very low GR (gamma ray log) and RD (resistivity log);eclogites are characterized by high DEN (density),VP (P-wave velocity) and PE (photoelectric absorption capture cross section);orthogneiss and paragneiss are characterized by high GR,U (uranium content),Th (thorium content),K (potassium content) and RD,and low DEN,PE,and CNL;logging values of amphibolite are between the logging values of eclogites and paragneiss.In addition,the logs could reflect the degree of retrograde metamorphism of eclogites.The upper section (100-2 000 m) shows higher DEN,PE,VP,and lower GR,U,Th,K,RD than the lower section (2 000-5 000 m).Most logs of the upper section are more fluctuant than those of the lower section.This indicates that the upper section has more heterogeneities than the lower section.The cross plots of logs indicate that DEN,GR,K,and CNL are more powerful in identifying ultrahigh pressure metamorphic (UHPM) rocks at the CCSD-MH.GR value of the rocks from CCSD-MH shows obviously an increasing trend from ultramafic rock (the most mafic rocks at CCSD-MH) to orthogneiss (the most acid rocks at CCSD-MH).On the contrary,DEN value decreases from the ultramafic rock to the orthogneiss.CNL log is a good indicator of the content of structure water in crystalline rocks.