Low palladium content CeO_(2)/ZnO composite for acetone sensor with sub-second response prepared by ultrasonic method

In practical applications,noble metal doping is often used to prepare high performance gas sensors,but more noble metal doping will lead to higher preparation costs.In this study,CeO_(2)/ZnO-Pd with low palladium content was prepared by ultrasonic method with fast response and high selectivity for acetone sensing.With the same amount of palladium added,the selectivity coefficient of CeO_(2)/ZnO-Pd is 1.88 times higher than that of the stirred sensor.Compared with the pure PdO-doped CeO_(2)/ZnO-PdO material,the content of Pd in CeO_(2)/ZnO-PdO is about 30%of that in CeO_(2)/ZnO-PdO,but the selectivity coefficient for acetone is 2.56 times higher.The CeO_(2)/ZnO-Pd sensor has a higher response(22.54)to 50×10^(−6) acetone at 300℃and the selectivity coefficient is 2.57 times that of the CeO_(2)/ZnO sensor.The sensor has a sub-second response time(0.6 s)and still has a 2.36 response to 330×10^(−9) of acetone.Ultrasonic doping makes Pd particles smaller and increases the contact area with gas.Meanwhile,the composition of n-p-n heterojunction and the synergistic effect of Pd/PdO improve the sensor performance.It shows that ultrasonic Pd doping provides a way to improve the utilization rate of doped metals and prepare highly selective gas sensors.

Research and Application of Log Defect Detection and Visualization System Based on Dry Coupling Ultrasonic Method

In order to optimize the wood internal quality detection and evaluation system and improve the comprehensive utilization rate of wood,this paper invented a set of log internal defect detection and visualization system by using the ultrasonic dry coupling agent method.The detection and visualization analysis of internal log defects were realized through log specimen test.The main conclusions show that the accuracy,reliability and practicability of the system for detecting the internal defects of log specimens have been effectively verified.The system can make the edge of the detected image smooth by interpolation algorithm,and the edge detection algorithm can be used to detect and reflect the location of internal defects of logs accurately.The content mentioned above has good application value for meeting the requirement of increasing demand for wood resources and improving the automation level of wood nondestructive testing instruments.

Application of Compactness Detection to Complicated Concrete-Filled Steel Tube by Ultrasonic Method

An example of using ultrasonic method to detect the compactness of complicated concrete-filled steel tube in certain high-rise building was discussed in this study.Because of the particularity of the complicated concrete-filled steel tubular column,the plane detection method and embedded sounding pipe method were adopted in the process of effectively detecting the column.According to the results of the plane detection method and embedded sounding pipe method,the cementing status of steel tube and concrete can be concluded,which cannot be judged by the hammering method in the rectangular steel tube-reinforced concrete.

TECHNOLOGY OF QUANTITATIVE ANALYSIS ON VIBRATORY STRESS RELIEF BASED ON ULTRASONIC TIME-OF-ARRIVAL METHOD

The effect of vibratory stress relief （VSR） is usually evaluated with the indirect method of observing the change of amplitude frequency response characteristics of structures. A new kind of evaluating method of VSR based on the ultrasonic time-of-arrival method （UTM）, which can obtain the residual stress directly through measuring the propagation time of ultrasonic wave in the material, is presented. At first, the principle of the measuring method of residual stress based on UTM is analyzed. Then the measuring system of the method is described, which is in virtue of ultrasonic flaw detector and high-sampling-rate digital oscillograph. And a set of calibration system that contains a piece of standard specimen is also introduced. Experimental results prove the relation between the residual stress and the propagation time of ultrasonic in workpieces. Finally, the measuring and calibration systems are applied in evaluating the effect of VSR. The final test results show that the method is effective.

An efficient nano-adsorbent via surfactants/dual surfactants assisted ultrasonic co-precipitation method for sono-removal of monoazo and diazo anionic dyes

To preserve the environment for civilization,we should remove the pollutants like toxic dyes by friendly and cost efficacious method.In this study,the effect of surfactants or mixed surfactants on physicochemical,optical and adsorption properties of ternary mixed oxide CeO_(2)-ZrO_(2)-Al_(2) O_3(CZA) are investigated.The ternary mixed oxide CZA was prepared by surfactants or mixed surfactants assisted ultrasonic coprecipitation method.The physicochemical and optical properties are estimated by different techniques like XRD,TEM,EDX,FTIR,S_(BET) and UV-Vis/DR.The CZA_T and CZA_C have hybrid shapes and high surface area.The adsorption properties of ternary mixed oxides adsorbents were characterized by sono-removing anionic dyes such as Congo red(CR) and Remazol red RB-133(RR).The different factors like contact time,different dye concentrations and temperatures also studied.The kinetics and isotherms applications showed that,the adsorption process was followed pseudo second order kinetics and the Freundlich isotherm model.Also,the adsorption is spontaneous and endothermic process through the thermodynamic study.Finally,the results showed that the ternary mixed oxide nano-adsorbent(CeO_(2)-ZrO_(2)-Al_(2) O_3) is promising and functional materials for anionic dye sweep from wastewater.

Determination of contents of 10-Hydroxycamptothecin in Camptotheca acuminata by high-performance liquid chromatogram

The determination method of 10-hydroxycamptothecin in Camptotheca acuminata fruits by high-performance liquid chromatogram (HPLC) was studied. The HPLC analysis was performed on a HIQ sil C18(4.6×250 mm) column with mobile phase of acetonitrilewater (3:7, V:V), flow rate 1 mLmin-1 and UV detective wavelength 266 nm. Extracting 10-hydroxycamptothecin by ultrasonic method from fruits of C. acuminata to prepare samples for analysis was systematically discussed. The optimal extraction condition was carried out by 60% alcohol solution at 60℃ for 50 minutes.

Effect of ultrasonic on structure and electrochemical performance of α-Ni(OH)_2 electrodes

Al/Co co-doped α-Ni（OH）2 samples were prepared by either ultrasonic co-precipitation method （Sample B） or co-precipitation method （Sample A）. The crystal structure and particle size distribution of the prepared samples were examined by X-ray diffraction （XRD） and laser particle size analyzer, respectively. The results show that Sample B has more crystalline defects and smaller average diameter than Sample A. The cyclic voltammetry and electrochemical impedance spectroscopy measurements indicate that Sample B has better electrochemical performance than Sample A, such as better reaction reversibility, lower charge-transfer resistance and better cyclic stability. Proton diffusion coefficient of Sample B is 1.96×10-10cm2/s, which is two times as large as that （9.78×10-11cm2/s） of Sample A. The charge-discharge tests show that the discharge capacity （308 mA·h/g） of Sample B is 25 mA·h/g higher than that of Sample A （283 mA·h/g）.

Ultrasonic synthesis of Zn-doped CdO nanostructures and their optoelectronic properties

The effect of Zn dopant on the growth of cadmium oxide （CdO） nanostructures through a sonochemical method wasinvestigated. The X-ray diffraction （XRD） patterns of the nanoparticles show CdO cubic structures for the produced samples. Fieldemission scanning electron microscope （FESEM） images reveal that morphologies of the samples change, when they are doped withZn atoms, and their sizes reduce. Room temperature photoluminescence （PL） and UV-Vis spectrometers were used to study opticalproperties of the samples. Evaluation of optical properties indicates that different emission bands result from different transitions andthe value of CdO energy band gap increases due to doping. Studies of electrical properties of the nanostructures demonstrate that Zndopant enhances electrical conductivity and photocurrent generation as the result of light illumination on the nanostructures due toimproved density of photo-generated carriers. Considering the obtained outcomes, Zn dopant can alter the physical property of theCdO nanostructures.

Laminar Mesoporous Structure of Modified Montmorillonite Clays and Its Formation Mechanism

Zr-pillared clays were prepared by heating and ultrasonic methods in intercalation process. The resultants were characterized by XRD, N2 adsorption-desorption, SEM, and TG/DTA analysis. Ultrasonic technology accelerated the pillaring process effectively and obtained better ordered structure than by heating method. The specific surface area and pore volume of the Zr-pillared clays increased by about 13 and 3 times respectively. Rare earth metal （Ce） was introduced into Zr-pillared clays by co-intercalation and dipping method. The specific surface area was increased by co-intercalation approach, but it was decreased dramatically by dipping method. Thermal stability of Ce modified samples prepared by co-intercalation method was enhanced in comparison with Zr-pillared clays. Modification mechanism and ＂corrugation-like＂ structural mode of intercalation process was proposed basing on the double XRD peaks in small-angle range of pillared clays, which was related to the deformation of silicate layer.

Synthesis,Structural Characterization and Hydrogen Storage of Nickel-containing Mesoporous MCM-48 by Electroless Plating

Hydrogen is a promising fuel for it is clean,highly abundant and non-toxic,but on-board storage of hydrogen is still a challenge.So it is imperative to have an efficient method of hydrogen storage.The mesoporous MCM-48 especially the nickel-containing MCM-48 has great potential in hydrogen storage.MCM-48 was prepared by hydrothermal synthesis.Then electroless plating technology was used to deposit Ni on the surface of MCM-48 under ultrasonic environment.Powder X-ray diffraction（XRD）,transmission electron microscopy（TEM）,and N2 adsorption-desorption were employed to investigate the pore structure properties.The results showed that all the samples had Ia3 d cubic structure and pore channels were highly ordered.Hydrogen adsorption studies showed that the MCM-48 after nickel plating adsorbed nearly twice the amount of hydrogen than pure MCM-48 at 2.0 MPa,263 K.So we believe that a small amount of Ni can improve the capacity of hydrogen adsorption of MCM-48 efficiently.

Numerical simulation of flow in Hartmann resonance tube and flow in ultrasonic gas atomizer

The gas flow in the Hartmann resonance tube is numerically investigated by the finite volume method based on the Roe solver. The oscillation of the flow is studied with the presence of a needle actuator set along the nozzle axis. Numerical results agree well with the theoretical and experimental results available. Numerical results indicate that the resonance mode of the resonance tube will switch by means of removing or adding the actuator. The gas flow in the ultrasonic gas atomization （USGA） nozzle is also studied by the same numerical methods. Oscillation caused by the Hartmann resonance tube structure, coupled with a secondary resonator, in the USGA nozzle is investigated. Effects of the variation of parameters on the oscillation are studied. The mechanism of the transition of subsonic flow to supersonic flow in the USGA nozzle is also discussed based on numerical results.

Cobalt/iron bimetal-organic frameworks as efficient electrocatalysts for the oxygen evolution reaction

The development of high efficiency and stable electrocatalysts for oxygen evolution is critical for energy storage and conversion systems. Herein, a series of Co/Fe bimetal-organic frameworks (MOFs) were fabricated using a facile ultrasonic method at room temperature, as electrocatalysts for the oxygen evolution reaction (OER) in alkaline solution. The Co2Fe-MOF exhibited an overpotential of 280 mV at a current density of 10 mA cm^-2, a low Tafel slope of 44.7 mV dec^-1, and long-term stability over 12000 s in 1 mol L^-1 KOH. This impressive performance was attributed to the high charge transfer rate, large specific surface area, and synergistic effects of the cobalt and iron centers.

On the Foundations of the Ultrasonic Non-Destructive Determination of Stresses in Near-the-Surface Layers of Materials： Review

The foundation of the ultrasonic non-destructive determination of stresses in near-the-surface layers of solids is presented. The method is based on the regularities of Rayleigh wave propagation in solids with initial （residual） stresses. A description of the above mentioned method and examples of stress determination are presented. Examples are considered as applied to the residual stresses arising at electric welding and the operating stresses arising at loading.

The spectrum entropy estimation method for ultrasonic backscattering signal in cancellous bones

In the application of cancellous bone ultrasound diagnosis based on backscattering method, it is of great importance to estimate fast and accurately whether the valid backscattering signal exists in the received signal. We propose a fast estimation method based on spectrum entropy method. With 984 records of adult calcaneus clinical data, we estimate the validity of the backscatter signal using this method. The results of the proposed method and the results of experience-base judgement were compared and analyzed. And two key parameters, the signal range length and the segment number of the spectrum entropy, were analyzed. The results show when the signal range length is 13 I^s and the segment number is 15 20, this method can get the best result （accuracy〉95%, sensitivity〉99%, specificity〉87%）, while taking little calculation time （1.5 ms）. Therefore, this spectrum entropy method can satisfy the accuracy and real-time requirements in the ultrasonic estimation for cancellous bone.

Bulk heterojunction thin film formation by single and dual feed ultrasonic spray method for application in organic solar cells

We here present a way of preparing the polymer： fullerene BHJ using dual feed method which can lead to formation of pure phases. In this report, we present results of our initial experiments in this direction.The effect of process parameters on the thickness and surface roughness of the active layer has been discussed.The structural and optical properties have been studied using the optical microscope, UV–visible spectroscopy and photoluminescence spectroscopy. Significant PL quenching indicates efficient charge separation in the BHJ formed using this technique. We have also compared the BHJ thin films prepared with this dual feed ultrasonic technique with the single feed spray method. The BHJ formed using this technique has been used as an active layer in OSC.

Low frequency ultrasonic multi-mode Lamb wave method for characterizing the ultra-thin transversely isotropic laminate composite: Theory and experiment

A low-frequency multi-mode ultrasonic Lamb wave method suitable for character- izing the thickness, the density and the elastic constants of the ultra-thin transversely isotropic laminate composite is presented. The 'ultra-thin' here means that the thickness of the plate is much less than the wavelength of the ultrasonic wave so that the echoes from the front and back faces of the plate can't be separated in the time domain. The dispersion equations for the low frequency ultrasonic Lamb waves with the propagation directions parallel and vertical to the fiber direction are derived. In conjunction with the least square algorithm method, the secant algorithm is used to estimate the parameters of the ultra-thin fiber-reinforced composite layer. The evaluation errors and the sensitivity of the method to different paramters of the thin composite are analyzed. The technique has been used to characterize the ultra-thin grass fiber reinforced PES composite with thickness down to ten percents of the ultrasonic wavelength. It is observed that the agreement between the nominal and the estimation values is reasonably good.

Effect of diffraction on the ultrasonic velocity measuredby the pulse interference method in VHF range

The effect of diffraction on the ultrasonic velocity measured by the pulse interference method has been investigated in VHF range theoretically and experimentally. Two silicate glasses are taken as the specimens, their frequency dependences of longitudinal velocities are measured in the frequency range of 50-350 MHz, and the phase advances of ultrasonic signals caused by diffraction effect are calculated using A. O. Williams' theoretical expression. For the velocity error due to diffraction effect, the experimental results are in good agreement with the theoretical prediction. It has been shown that the velocity error due to diffraction effect is directly proportional to dθ21 (f)/df, whereθ21 (f) is the phase advances difference between the two partial reflection signals used in velocity measurement and f is the ultrasonic frequency.

An assessment on the wideband and narrowband methods for ultrasonic blood flow measurements

A comparison study on the ultrasonic blood flow estimation methods is carried out in this paper. The methods are divided into two classes-narrowband and wideband techniques.The pulsed Doppler systems and the autocorrelation methods are essentially the narrowband estAnators. They give the results with low velocity resolution and probably the aliased spectrum.The wider the frequency band of the signals, the worse the results. Time domain crosscorrelation technique, wideband makimum likelihood estimation and 2D Fourier transform method are three wideband techniques. The high velocity resolution and the ability of anti-aliasing are shown by these wideband estimation strategies.

Multicolor biomass based carbon nanodots for bacterial imaging

Biomass-based carbon nanodots(CNDs) are becoming promising fluorescent materials due to their superior optical properties and excellent biocompatibility. However, most fluorescent CNDs are prepared under high temperatures with artificial chemicals as precursors. In this work, multicolor biomass-based CNDs have been prepared by employing natural biomass as precursors through an ultrasonic-assisted method at room temperature. The multicolor biomass-based CNDs can be prepared within 10 min, and cavitation produced by ultrasound in solution contributes to the polymerization of biomolecules into nanodots. The emission of the CNDs covers from blue to red region, with emission peaks centered at 410 nm, 520 nm and 670 nm, and the corresponding photoluminescence quantum yields of the CNDs are 11%, 12% and28%, respectively. Furthermore, bacterial imaging by using the biomass-based CNDs as fluorescent imaging agent has been demonstrated. This work provides a convenient ultrasonic-assisted way for fabrication multicolor and eco-friendly biomass CNDs, demonstrating their application in bacterial imaging.

Ultrasound Assisted Synthesis of Nanoscale NH2-MIL-53(Fe) for the Adsorption of Dye

Nanometer blocks of amide-functionalized Fe(Ⅲ)-based metal-organic frameworks,NH2-MIL-53(Fe),were prepared via ultrasonic method without any surfactants at room temperature and atmospheric pressure.The characterization for the as-prepared nano-structured MOFs was established by XRD,SEM,TEM,XPS and N2 adsorption-desorption.The as-prepared sample with high specific surface area(179.9 m^(2)·g^(-1))showed excellent adsorption for methylene blue in the liquid phase.The as-prepared NH_(2)-MIL-53(Fe)adsorbent seems to be a promising material in practice for organic dye removal from aqueous solution.