We investigated the effects of calcination temperature(950-1450℃),steel slag content,and the total chromium content of steel slag on the Cr^(6+)contents of clinker samples produced using steel slags with different ch...We investigated the effects of calcination temperature(950-1450℃),steel slag content,and the total chromium content of steel slag on the Cr^(6+)contents of clinker samples produced using steel slags with different chromium contents.Additionally,the reactions of chromium in clinker(produced using steel slag)during calcination were studied.It is found that Cr^(6+)conversion increases with increasing calcination temperature to 1250℃,reaching a maximum of 43%-79%,before decreasing to 18%-42%at 1450℃.Cr^(6+)is mainly formed by the oxidation of trivalent chromium(Cr^(3+))during the solid-phase reaction stage of clinker calcination.Furthermore,the Cr^(6+)content of a clinker sample is proportional to the chromium content of its raw meal precursor and is mainly in the form of water-insoluble calcium chromate(CaCrO_(4)).The chromium in clinker is mainly distributed in tricalcium aluminate and tetracalcium aluminoferrite,however,some is present in silicate minerals.We expect to inform the monitoring and control of the Cr^(6+)content of clinker(produced using steel slag)and resulting cement.展开更多
文摘We investigated the effects of calcination temperature(950-1450℃),steel slag content,and the total chromium content of steel slag on the Cr^(6+)contents of clinker samples produced using steel slags with different chromium contents.Additionally,the reactions of chromium in clinker(produced using steel slag)during calcination were studied.It is found that Cr^(6+)conversion increases with increasing calcination temperature to 1250℃,reaching a maximum of 43%-79%,before decreasing to 18%-42%at 1450℃.Cr^(6+)is mainly formed by the oxidation of trivalent chromium(Cr^(3+))during the solid-phase reaction stage of clinker calcination.Furthermore,the Cr^(6+)content of a clinker sample is proportional to the chromium content of its raw meal precursor and is mainly in the form of water-insoluble calcium chromate(CaCrO_(4)).The chromium in clinker is mainly distributed in tricalcium aluminate and tetracalcium aluminoferrite,however,some is present in silicate minerals.We expect to inform the monitoring and control of the Cr^(6+)content of clinker(produced using steel slag)and resulting cement.
