Research on Up-Conversion Mechanism in Er^(3+)/Yb^(3+)-Codoped Oxyfluoride Glass

Er3+/Yb3+-codoped oxyfluoride crystallite glass was prepared with melting technique. The compositions and the melting temperature and the annealing temperature of the rare earth-doped crystallite glass were studied in detail. The emission spectra of samples were measured with the Hitachi F-4500 fluorescent photometer pumped by 980 nm wavelength laser. The up-conversion luminescence mechanism was illuminated on the view of the photophysics. By measuring the relationship between luminescent intensity and pump power, it is confirmed that the emission peaks at 550 nm belong to two-photon process, while that at 665 nm belongs to three-photon process. Moreover, the distributions of crystalline were determined by SEM.

Up-Conversion Properties of Oxy-Fluoride Glasses Co-Doped with Ho^(3+) and Yb^(3+)

Oxy-fluoride glasses with composition of 25SiO2-65PbF2-9.4AlF3-0.1HoF3-0.5YbF3 were prepared. Their up-conversion fluorescence characteristics were investigated by 980 nm laser. Two emission peaks were observed at 540 and 650 nm. The up-conversion mechanism and processes were analyzed. The relationship between pumping power and relative intensity of emissions was discussed. From the dependence, it is known that the emissions centered at 540 and 650 nm are both attributed to two-photon process.

Optical temperature sensor based on up-conversion fluorescence emission in Yb^(3+):Er^(3+) co-doped ceramics glass

yb^3＋：Er^3＋ co-doped oxy-fluoride ceramics glass has been prepared. The mechanism of up-conversion emissions about Er^3＋ was discussed, and the temperature properties of green up-conversion fluorescence between 303 and 823 K were investigated. The results show that the sensitivity of this sample reaches its maximum value, about 0.0047 K^-1, when the temperature is 383 K, indicating that this kind of sample can be used as high temperature and high sensitivity optical temperature sensor.

Investigation of ultrafast dynamics of CdTe quantum dots by femtosecond fluorescence up-conversion spectroscopy

The ultrafast carrier relaxation processes in CdTe quantum dots are investigated by femtosecond fluorescence upconversion spectroscopy.Photo-excited hole relaxing to the edge of the forbidden gap takes a maximal time of ～ 1.6 ps with exciting at 400 nm,depending on the state of the photo-excited hole.The shallow trapped states and deep trap states in the forbidden gap are confirmed for CdTe quantum dots.In addition,Auger relaxation of trapped carriers is observed to occur with a time constant of ～ 5 ps.A schematic model of photodynamics is established based on the results of the spectroscopy studies.Our work demonstrates that femtosecond fluorescence up-conversion spectroscopy is a suitable and effective tool in studying the transportation and conversion dynamics of photon energy in a nanosystem.

Green and red up-conversion emissions and thermometric application of Er^(3+) -doped silicate glass

The green and red up-conversion emissions centred at about 534, 549 and 663 nm of wavelength, corresponding respectively to the ^2H11/2 → ^4I15/2, ^4S3/2 → ^4I15/2 and ^4F9/2 → ^4I15/2 transitions of Er^3＋ ions, have been observed for the Er^3＋-doped silicate glass excited by a 978 nm semiconductor laser beam. Excitation power dependent behaviour of the up-conversion emission intensity indicates that a two-photon absorption up-conversion process is responsible for the green and red up-conversion emissions. The temperature dependence of the green up-conversion emissions is also studied in a temperature range of 296-673 K, which shows that Er^3＋-doped silicate glass can be used as a sensor in high-temperature measurement.

Up-conversion luminescence from Nd^(3+) ions doped in NaBi(WO_4)_2 single crystal

The luminescence of Nd3+-doped in NaBi(WO4)2 single crystal was investigated from 10 K to room temperature.The excitation source was a pulsed dye laser in resonance into the(4G5/2+2G(1)7/2) levels of Nd3+ ions.Several blue emission bands in the up-conversion luminescence spectra corresponded to transitions from 2P1/2 to 4I9/2.Some violet bands corresponding to transitions of 4D3/2→(4I9/2,4I11/2,4I13/2) were also observed.For comparison,the luminescence spectra and decay curves excited by the pulsed 355 nm l...

Up-conversion detection of mid-infrared light carrying orbital angular momentum

Frequency up-conversion is an effective method of mid-infrared(MIR) detection by converting long-wavelength photons to the visible domain, where efficient detectors are readily available. Here, we generate MIR light carrying orbital angular momentum(OAM) from a difference frequency generation process and perform up-conversion on it via sum frequency conversion in a bulk quasi-phase-matching crystal. The maximum quantum conversion efficiencies from MIR to visible are 34.0%, 10.4%, and 3.5% for light with topological charges of 0, 1, and 2, respectively, achieved by utilizing an optimized strong pump light. We also verify the OAM conservation with a specially designed interferometer, and the results agree well with the numerical simulations. Our study opens up the possibilities for generating, manipulating, and detecting MIR light that carries OAM, and will have great potential for optical communications and remote sensing in the MIR regime.

Intense up-conversion emissions of yb3＋/Dy3＋ co-doped A12O3 nanopowders prepared by non-aqueous sol-gel method＊

yb3＋/Dy3＋ co-doped A1203 nanopowders have been prepared by the non-aqueous sol-gel method and their up- conversion photoluminescence spectra are measured under excitation by a 980-nm semiconductor laser. The results show that there are comparatively abundant spectra of up-conversion emissions centered at 378, 408, 527 and 543, and 663 nm, corresponding to 4C9/2→ 6H13/2, 4C9/2→ 6Hll/2, 4115/2 → 6H13/2, and 4F9/2 →6Hll/2 transitions of Dy3＋, respectively. Two-photon and three-photon processes are involved in ultraviolet, violet, green, and red up-conversion emissions. The energy transition between Yb3＋ and Dy3＋ is discussed.

Up-conversion Properties of Er^(3+)/Yb^(3+) Co-doped Li_3Ba_2Gd_3(MoO_4)_8 Phosphors

Er3＋/Yb3＋ co-doped Li3Ba2Gd3（MoO4）8 phosphors were synthesized by conven- tional solid state reaction method, and their structure and spectral properties were investigated. The diffuse reflectance spectra showed that the 4I15/2→4I11/2 transition of Er3＋ and the 2F7/2→2F5/2 transition of Yb3＋ ions were highly overlapped. Under the excitation of 980 nm, three up-conver- sion （UC） luminescence bands around 530, 555 and 660 nm were observed, corresponding to the 2H11/2→ 4I15/2, 4S3/2 → 4I15/2 and 4F9/2-→4I15/2 transitions of Er3＋ ions, respectively. The effects of the concentration and pumping power on the UC intensities of Li3Ba2Gd3（MoO4）8：Er3＋/yb3＋ phosphors were investigated, and the possible UC mechanism was proposed based on the results.

Synthesis and Characterization of IR Up-Conversion Material SrS∶Eu, Sm

Europium and samarium co-doped strontium sulfide (SrS∶Eu, Sm) infrared up-conversion phosphor was synthesized through calcining the precursor, which prepared by wet-method with strontium carbonate (SrCO_3), sulphur (S), europium oxide (Eu_2O_3) and samarium oxide (Sm_2O_3) as the starting materials, lithium fluoride (LiF) as the fluxing agent, at 750～1200 ℃ in carbon-reducing atmosphere. XRD analysis shows that SrS crystal structure is formed at 750 ℃, most completely at 1100 ℃. The IR up-conversion luminescence properties were characterized by excitation, emission, up-conversion excitation, up-conversion emission and thermoluminescence spectra. The spectral analysis associated with the physical model of up-conversion luminescence shows that the IR up-conversion luminescence is resulted from electron trapping process of Sm 3+ energy level. The thermoluminescence peak does not appear below 500 ℃ indicating the trapping energy level is appropriately deep, 800～1400 nm near infrared light can be the release light to realize up-conversion luminescence.

Hydrothermal synthesis and up-conversion luminescence of Ho^(3+)/Yb^(3+)co-doped CaF_2

CaF2：Ho3＋/Yb3＋ nano-particles with intense green up-conversion （UC） luminescence are successfully synthesized via a facile hydrothermal approach by using NH4F as the fluoride source and Na2EDTA as a chelating reagent. Powder X- ray diffraction （XRD）, transmission electron microscopy （TEM）, field emission scanning electron microscopy （FE-SEM）, and UC emission spectra are used to characterize the structures, shapes, and luminescent properties of the samples. The effects from fluoride sources and chelating reagents on the formations of CaF2 nano-particles are investigated, and the for- mation process is also deduced. Under the excitation of a 980-nm laser diode, the samples each show a green up-conversion emission centered at 540 nm corresponding to the 5S2/5F4-＋518 transitions of Ho3＋. Moreover, the UC mechanisms of Ho3＋/Yb3＋ co-doped CaF2 nano-particles are also discussed.

High-sensitive terahertz detection by parametric up-conversion using nanosecond pulsed laser

A high-sensitive terahertz detector operating at room temperature was demonstrated based on parametric upconversion.A nanosecond 1064-nm Nd:YAG laser was used to pump the parametric up-conversion detector and the upconversion from terahertz wave to NIR laser was realized in a lithium niobate crystal.The minimum detectable terahertz energy of 9 p J was realized with the detection dynamic range of 54 d B,which was three orders of magnitude higher than that of commercial Golay cell.The detectable terahertz frequency range of the detection system was 0.90 Thz–1.83 THz.Besides,the effects of pump energy and effective gain length on the detection sensitivity were studied in experiment.The results showed that higher pump energy and longer effective gain length are helpful for improving the detection sensitivity of parametric up-conversion detector.

A New Organic Up-conversion Laser Dye HEASPS

A new organic dye, trans-4-[p-(N-hydroxyethyl-N-ethylamino)styryl]-N-methyl- pyridinium p-toluene sulfonate (HEASPS) has been synthesized and its structure has been determined. Pumped with a 1064 nm, 50 ps laser pulses, 0.05 mol/L HEASPS/DMF solution showed the two-photon pumped (TPP) output/input efficiency of 9.1% which is higher than that of known TPP laser dyes trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium iodide (ASPI) and trans-4-[p-(N-hydroxyethyl-N-methylamino) styryl]-N-methylpyridinium p-toluene sulfonate (HMASPS) at the same experimental conditions.

Up-conversion luminescence properties and energy transfer of Er^(3+)/Yb^(3+)co-doped oxyfluoride glass ceramic containing CaF_2 nano-crystals

The Er^3＋/yb^3＋ co-doped transparent oxyfluoride glass-ceramics containing CaF2 nano-crystals were successfully prepared. After heat treatments, transmission electron microscopy （TEM） images showed that CaF2 nano-crystals of 20-30 nm in diameter precipitated uniformly in the glass matrix. luminescence of Er^3＋ at 540 nm and 658 nm was observed in Comparing with the host glass, high efficiency upconversion the glass ceramics under the excitation of 980 nm. Moreover, the size of the precipitated nano-crystals can be controlled by heat-treatment temperature and time. With the increase of the nano-crystal size, the intensity of the red emission increased more rapidly than that of the green emission. The energy transfer process of Er^3＋ and Yb^3＋ was convinced and the possible mechanism of Er^3＋ up-conversion was discussed.

Sensitized Up-Conversion Luminescence of Ho^(3+) in Nd^(3+)-Yb^(3+)-Ho^(3+) Co-doped ZrF_4-Based Glass

Up-conversion processes for the blue, green and red emissions were foundtwo-photon phenomenon, known as the cooperative phenomenon. This phenomenon was assisted by Nd^(3+)→ Yb^(3+) → Ho^(3+) energy transfer. The strong green emission due to the Ho^(3+) : (~5F_4, ~5S_2)→ ~5I_8 transitions was observed in Nd^(3+) - Ho^(3+) co-doped ZrF_4-based fluoride glasses under800 nm excitation. As an attempt to enhance Ho^(3+) up-conversion luminescences in the Nd^(3+) -Ho^(3+) co-doped ZrF_4-based glasses, Yb^(3+) ions were added to the glasses. As a result it wasfound that, in 800 nm excitation of 60ZrF_4. 30BaF2. (8-x)LaF_3. 1NdF_3. xYbF_3. 1HoF_3 glasses (x =0 to 7), sensitized up-conversion luminescences are observed at around 490 nm (blue), 545 nm(green), and 650 nm (red), which correspond to the Ho^(3+) : ~5F_3 → ~5I_8, ( ~5F_4, ~5S_2) →~5I_8 and ~5F_5 → ~5I_8 transitions respectively. The intensities of the green and red emissions ina 3 mol% YbF_3-containing glass were about 50 times stronger than those glasses without YbF_3. Thisis based on sensitization due to Yb^(3+) ions. In particular, the green emission was extremelystrong and the Nd^(3+) - Yb^(3+) - Ho^(3+) co-doped ZrF_4-based glasses have a high possibility ofrealizing a green up-conversion laser glass. In this paper the up-conversion mechanism in theglasses is discussed in detail.

Generation of Short Wavelength in Up-Conversion of Tm⁺³Doped Fluoride Glass and Its Application in Fiber Lasers

We report on the experimental study of the visible and ultraviolet (UV) fluorescence emission in a (1% molar) Thulium (Tm+3)-doped Zirconium fluoride glass sample. From red at 650 nm, blue (453 & 480 nm) and UV at 365 & 284 nm, have been observed under excitation of a Nd:YAG laser at 1.064 μm. The responsible up-conversion mechanisms are investigated based on experimental data. The related problem of photo-degradation associated with formation of color centers is also addressed.

Frequency Up-conversion Luminescence Properties and Mechanism of Tm^(3+) /Er^(3+)/Yb^(3+) Co-doped Oxyfluorogermanate Glasses

Oxyfluoride glasses were developed with composition 60GeO 2 ·10AlF 3 ·25BaF 2 ·（1.95-x）GdF 3 · 3YbF 3 ·0.05TmF 3 ·xErF 3 （x=0.02,0.05,0.08,0.11,0.14,0.17）in mole percent.Intense blue（476 nm）,green（524 and 546 nm）and red（658 nm）emissions which identified from the 1G 4 →3H 6 transition of Tm3＋and the（2H 11/2 ,4S 3/2 ）→4I 15/2 ,4F 9/2 →4I 15/2 transitions of Er3＋,respectively,were simultaneously observed under 980 nm excitation at room temperature.The results show that multicolor luminescence including white light can be adjustably tuned by changing doping concentrations of Er3＋ion or the excitation power.In addition,the energy transfer processes among Tm3＋,Er3＋and Yb3＋ions,and up-conversion mechanisms are discussed.

Comparison study of two aldehyde group finishing agents in surface modification of up-conversion luminescence materials

Surface modification of up-conversion luminescence materials （Na[Y0.57Yb0.39Er0.04]F4 modified by amino groups） by grafting and modifying with aldehyde groups was studied by means of Fourier transform infrared spectroscopy （FTIR）, scanning electron microscopy （SEM）, thermogravimetric analysis （TGA）, and emission spectrum （EM）. The surface modification effect was compared using two different finishhag agents, p-phthalaldehyde and glutaraldehyde. It was found that the surface of up-conversion luminescence materials could be modified by aldehyde groups of the two finishing agents, the systematic dispersibility and the thermostability of the up-conversion luminescence material modified by p-phthalaldehyde were better than those of the material modified by glutaraldehyde, and the luminous intensity of the material modified by p-phthalaldehyde was increased. The AI （the ratio of the suspended segmental quality in the specimen to the total mass of the specimen） of the material modified by p-phthalaldehyde was higher than that of the material modified by glutaraldehyde. It is obviously seen that the embellishment effect of p-phthalaldehyde as a finishing agent was better than that of glutaraldehyde. In addition, the reasons why p-phthalaldehyde is a good finishing agent are also explained.

Up-Conversion Properties in KGd_2F_7∶Yb^(3+)/Tm ^(3+)

The infrared to visible up-conversion emissions in Yb 3+-Tm 3+ co-doped KGd_2F_7 samples excited at 980 nm was reported. The observed up-conversion emissions include intense blue 1G_4→3H_6 (482 nm) transition and other weak transitions: 1D_2→3H_6 (367 nm), 1G_4→3F_4 (651 nm) and 1G_4→3H_5 (776 nm). The concentration quenching of Tm 3+ or Yb 3+ is obvious at higher concentration due to the cross-relaxation. The optimum doping levels are 10% Yb 3+ and 0.2%～0.4% Tm 3+ for blue emission. Power studies reveal that the blue emission of Tm 3+ ion results from three-photon processes, which require three energy transfers from Yb 3+ to excite Tm 3+ from 3H_6 to 1G_4 in succession.

Up-conversion luminescence tuning in Er^3+ -doped ceramic glass by femtosecond laser pulse at different laser powers

The up-conversion luminescence tuning of rare-earth ions is an important research topic for understanding luminescence mechanisms and promoting related applications. In this paper, we experimentally study the up-conversion luminescence tuning of Er3+-doped ceramic glass excited by the unshaped, V-shaped and cosine-shaped femtosecond laser field with different laser powers. The results show that green and red up-conversion luminescence can be effectively tuned by varying the power or spectral phase of the femtosecond laser field. We further analyze the up-conversion luminescence tuning mechanism by considering different excitation processes, including single-photon absorption(SPA), two-photon absorption(TPA), excited state absorption(ESA), and energy transfer up-conversion(ETU). The relative weight of TPA in the whole excitation process can increase with the increase of the laser power, thereby enhancing the intensity ratio between green and red luminescence(I547/I656). However, the second ETU(ETU2) process can generate red luminescence and reduce the green and red luminescence intensity ratio I547/I656, while the third ESA(ESA3) process can produce green luminescence and enhance its control efficiency. Moreover, the up-conversion luminescence tuning mechanism is further validated by observing the up-conversion luminescence intensity, depending on the laser power and the down-conversion luminescence spectrum under the excitation of 400-nm femtosecond laser pulse. These studies can present a clear physical picture that enables us to understand the up-conversion luminescence tuning mechanism in rare-earth ions, and can also provide an opportunity to tune up-conversion luminescence to promote its related applications.