The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in th...The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in this area are all granite-related and they can be divided into three types,namely endogranitic ones,perigranitic ones,and contact zone types.The endogranitic uranium deposits are mainly controlled by the structural alteration zones developing within granites,with fragmentation,hematitization,and alkali metasomatism as their main mineralization characteristics.The perigranitic uranium deposits are mainly produced in the carbonaceous,siliceous,and argillaceous composite layers of epimetamorphic rocks and are controlled by fractured zones formed due to interlayer compression.The contact zone type uranium deposits mainly occur in the contact parts between the granites and favorable horizons.They have developed in favorable sections where multiple sets of structures are combined and intersected.The main metallogenic regularities of uranium in the central Zhuguang Mountains are as follows.The basic conditions for the uranium mineralization in this area include the framework consisting of regional deep large faults and their associated multi-set multi-direction favorable metallogenic structures,multi-cycle and multi-stage uranium-rich rock masses,and uranium-rich folded basement.Meanwhile,the uranium deposits in this area are closely related to granites in terms of genesis and space and they are formed in different structural parts subject to the same metallization.Furthermore,based on the summary of the characteristics and regularities of uranium mineralization in this area,the controlling factors of different types of uranium deposits in the area were explored and six metallogenic target areas were predicted.All these will provide references for the exploration of uranium deposits in this area.展开更多
1 Introduction The Kangdian axis is an important polymetallic metallogenic belt in Southwest China,and it is also an area with a lot of hydrothermal uranium mineralization(Wang Hongjun,et al.,2009.The basic
On June 2011, the Beijing Research Institute of Uranium Geology, an Institute within the China National Nuclear Corporation (CNNC), and the Department of Geology & Mining CNNC carried out a project Scientific Drill...On June 2011, the Beijing Research Institute of Uranium Geology, an Institute within the China National Nuclear Corporation (CNNC), and the Department of Geology & Mining CNNC carried out a project Scientific Drilling.for Deep Metallogenic Research in the Xiangshan Large Uranium Ore Field. A year later on June 21, the project, representing the first scientific drilling of China's uranium, was officially launched, and successfully completed on June 17, 2013. A 2818.88 m of drilling depth has broken the previous record 1200 m of exploration depth.展开更多
East Hunan and its adjacent area is defined as an intraplate orogenic zone with help of new theory of geology and multi-discipline research. The evolutionary stages, deep structrue, geological feature, rotation strain...East Hunan and its adjacent area is defined as an intraplate orogenic zone with help of new theory of geology and multi-discipline research. The evolutionary stages, deep structrue, geological feature, rotation strain and metallogeny of NW-striking transfer fault zone are also discussed. NE-trending strike-slip fault zone, as a whole, entered action during Pacific movement and underwent 3 stages: the strike-slip shear, the pull-apart extension and the’ compressive thrust. The aurthors studied macro-and microscopic features of strike-slip fault and its control of uranium mineralization at Jinguangchung deposit by means of modern structure analysis, micro-submicroscopic investigation and geophysical measurement.展开更多
Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation, and there is a regio...Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation, and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity, although the metamorphic grade is low (Ro=0.40%–0.58%). In the Dongsheng region alone, the accumulative amount of generated coalbed methane (CBM) is about 2028.29 × 108 –2218.72 × 108 m3; the residual amount is about 50.92 × 108 m3, and the lost amount is about 1977 × 108 m3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous, which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous, a mass of CBM dissipated due to the strong tectonic uplift, and the Dongsheng uranium deposit stepped into the preservation phase. Therefore, the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits, but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan’an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems, the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.展开更多
Meso-Cenozoic intracontinental orogenic processes in the Tian Shan orogenic belt have significant effect on the sandstone-hosted uranium deposits in the intramontane basins and those adjacent to the orogen. The Sawafu...Meso-Cenozoic intracontinental orogenic processes in the Tian Shan orogenic belt have significant effect on the sandstone-hosted uranium deposits in the intramontane basins and those adjacent to the orogen. The Sawafuqi uranium deposit, which is located in the South Tian Shan orogenic belt, is investigated to reveal the relationships between uranium mineralization and orogenies. Recent exploration results show that the Sawafuqi uranium deposit has tabular, stratiform, quasi-stratiform, and lens-like orebodies and various geological characteristics different from typical interlayer oxidation zone sandstone-hosted uranium deposits. Systematic studies of ore samples from the Sawafuqi uranium deposit using a variety of techniques, including thin section observation, a-track radiograph, electron microprobe and scanning electron microscope, suggest that uranium mineralization is closely related to pyrite and organic matter. Mineralization-related alterations in the host rocks are mainly silicification and argillation including kaolinite, illite (and illite-smectite mixed layer) and chlorite. Tree stages of mineralization were identified in the Sawafuqi uranium deposit: (i) uranium-bearing detritus and synsedimentary initial pre-enrichment; (ii) interlayer oxidization zone uranium mineralization; and (iii) vein-type uranium mineralization. The synsedimentary uranium pre-enrichment represents an early uranium enrichment in the Sawafuqi uranium deposit, and interlayer oxidation zone uranium mineralization formed the main orebodies, which are superimposed by the vein-type uranium mineralization. Combining the results of this study with previous studies on the Meso-Cenozoic orogenies of South Tian Shan, it is proposed that the synsedimentary uranium pre-enrichment of the Sawafuqi uranium deposit was caused by Triassic Tian Shan uplift, and the interlayer oxidation zone uranium mineralization occurred during the Eocence-Oligocene period, when tectonism was relatively quiet, whereas the vein-type uranium mineralization took place in relation to the strong orogeny of South Tian Shan since Miocene.展开更多
This paper introduces the test results of the soil magnetic survey and the integrated gamma-ray TLD and TC methods for sandstone-type uranium exploration and describes the prospecting mechanism. The tests have proved ...This paper introduces the test results of the soil magnetic survey and the integrated gamma-ray TLD and TC methods for sandstone-type uranium exploration and describes the prospecting mechanism. The tests have proved that these approaches have yielded good results on classifying the sedimentary facies, defining the redox transitional zones and reflecting deep mineralization information. They may probably become new methods on searching for sandstone-type uranium deposits.展开更多
The sandstone-hosted uranium deposits in the SW Songliao Basin differ from typical sandstone-hosted uranium deposits in terms of the geological features of the ore-deposits,including the geometry of the orebodies,mine...The sandstone-hosted uranium deposits in the SW Songliao Basin differ from typical sandstone-hosted uranium deposits in terms of the geological features of the ore-deposits,including the geometry of the orebodies,mineral assemblage and petrography.Detailed drill core and microscopic observations,scanning electron microscopy(SEM),electron microprobe analysis(EMPA),heavy mineral concentrates,and fluid inclusion studies of the Upper Cretaceous Yaojia Formation,i.e.,the uranium-bearing layer,were integrated to investigate the roles of hydrothermal fluids in the formation of these uranium deposits.We found that the kaolinite alteration is developed in the mineralized zones,but it is less common in the peripheral areas.The fluid inclusions are hydrothermal fluids with a medium-low temperature(67 to 179 ℃) and a high salinity(5.9 wt.% to 20.1 wt.%).According to the analyses,three kinds of hydrothermal fluids,i.e.,the acid fluid,the groundwater heated by the mafic magma,and the alkaline fluid rich in Ca^(2+) and CO_(3)^(2-),were identified.The fluids might have low U content,but they have participated in the formation of the uranium deposits successively.Kaolinite formed by the acid-hydrothermal fluid absorbed large amounts of uranium.Subsequently,the thermal energy from the hydrothermal fluids changed the intrastratal redox environment and increased the solubility of the uranium minerals in the fluid.The alkaline-hydrothermal fluid rich in Ca^(2+) and C0_(3)^(2-) facilitated the formation of stable Ca-U(Ⅵ)-CO_(3) complex,which led to the enrichment of soluble uranium in solution,and final precipitation as pitchblende,brannerite and Ti-bearing uranium minerals in the uranium ores.展开更多
Many theoretical results on sandstone-type uranium mineralization in northern China obtained by the uranium research team of the Tianjin Center of Geological Survey in recent years are presented.From the source sink s...Many theoretical results on sandstone-type uranium mineralization in northern China obtained by the uranium research team of the Tianjin Center of Geological Survey in recent years are presented.From the source sink system of uranium-producing basins,sedimentary environment of uranium-bearing rock series,ore-forming fluid information,evolution of tectonic events,basin formation and development,we redefine and classify uranium orebodies,redox zoning,and ore-controlling structural styles.We then systematically propose a theoretical system of sandstone-type uranium deposits in northern China.We conclude that sandstone-type uranium deposits in northern China are mainly found in sedimentary environments such as rivers,deltas,and alluvial fans in the Mesozoic and Cenozoic lowstand systems tract and in gray sandstone layers in the vertical redox zoning.The orebodies are controlled by the tectonic slope belt,which is in the shape of a strip on the plane,and spreads in a layer or plate on the section.Vertical(ups and downs)tectonic movement triggers large-scale phreatic flow in the basin,which is the real driving force for controlling the ore-forming fluid.The theoretical system of sandstone-type uranium deposits in northern China should be based on global tectonic movement and environmental changes and take into account factors such as basins as a unit to study mineralization background,ore concentration areas as objects to study mineralization,and the correlation between regional tectonic movement and metallogenic process as a breakthrough point to study tectonic events and metallogenic events.It should also be based on different basin types to establish metallogenic models.The innovative research results and ideas are summarized with the aim of promoting the continuous improvement of sandstone-type uranium mineralization theory in northern China.展开更多
The Ordos Basin of North China is not only an important uranium mineralization province, but also a major producer of oil, gas and coal in China. The genetic relationship between uranium mineralization and hydrocarbon...The Ordos Basin of North China is not only an important uranium mineralization province, but also a major producer of oil, gas and coal in China. The genetic relationship between uranium mineralization and hydrocarbons has been recognized by a number of previous studies, but it has not been well understood in terms of the hydrodynamics of basin fluid flow. We have demonstrated in a previous study that the preferential localization of Cretaceous uranium mineralization in the upper part of the Ordos Jurassic section may have been related to the interface between an upward flowing, reducing fluid and a downward flowing, oxidizing fluid. This interface may have been controlled by the interplay between fluid overpressure related to disequilibrium sediment compaction and which drove the upward flow, and topographic relief, which drove the downward flow. In this study, we carried out numerical modeling for the contribution of oil and gas generation to the development of fluid overpressure, in addition to sedi- ment compaction and heating. Our results indicate that when hydrocarbon generation is taken into account, fluid overpressure during the Cretaceous was more than doubled in comparison with the simu- lation when hydrocarbon generation was not considered. Furthermore, fluid overpressure dissipation at the end of sedimentation slowed down relative to the no-hydrocarbon generation case. These results suggest that hydrocarbon generation may have played an important role in uranium mineralization, not only in providing reducing agents required for the mineralization, but also in contributing to the driving force to maintain the upward flow.展开更多
The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts ...The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts due to its scale, high grade and abundant associated ores. Because of the insufficient reliable dating of intrusive rocks, the relationship between mineralization and the magmatic activities is still unknown. In order to study this key scientific issue and the ore-forming processes of the Zoige uranium ore field, the LA-ICP-MS zircon U-Pb dating of magmatic rocks was obtained:64.08±0.59 Ma for the granite-prophyry and ~200 Ma for the dolerite. U-Pb dating results of uraninite from the Zoige uranium ore field are mainly concentrated on ~90 Ma and ~60 Ma. According to LA-ICP-MS U-Pb zircon dating, the ages for the dolerite, porphyry granite and granodiorite are 200 Ma, 64.08 Ma approximately and 226.5-200.88 Ma, respectively. This indicates that the mineralization has close relationship with activities of the intermediate-acidic magma. The ages of the granite porphyry are consistent with those uraninite U-Pb dating results achieved by previous studies, which reflects the magmatic and ore-forming event during the later Yanshanian. Based on the data from previous researches, the ore bodies in the Zoige uranium ore field can be divided into two categories:the single uranium type and the uranium with polymetal mineralization type. The former formed at late Cretaceous(about 90 Ma), while the latter, closely related to the granite porphyry, formed at early Paleogene(about 60 Ma). And apart from ore forming elemental uranium, the latter is often associated with polymetallic elements, such as molybdenum, nickel, zinc, etc.展开更多
The uranium deposits in the Tuanyushan area of northern Qaidam Basin commonly occur in coal-bearing series. To decipher the U-enrichment mechanism and controlling factors in this area, a database of 72 drill cores, in...The uranium deposits in the Tuanyushan area of northern Qaidam Basin commonly occur in coal-bearing series. To decipher the U-enrichment mechanism and controlling factors in this area, a database of 72 drill cores, including 56 well-logs and 3 sampling wells, was examined for sedimentology and geochemistry in relation to uranium concentrations. The results show that coal-bearing series can influence uranium mineralization from two aspects, i.e., spatial distribution and dynamic control. Five types of uranium-bearing rocks are recognized, mainly occurring in the braided river and braided delta sedimentary facies, among which sandstones near the coals are the most important. The lithological associations of sandstone-type uranium deposits can be classified into three subtypes, termed as U-coal type, coal-U-coal type, and coal-U type, respectively. The coal and fine siliciclastic rocks in the coal- bearing series confined the U-rich fluid flow and uranium accumulation in the sandstone near them. Thus, the coal-bearing series can provide good accommodations for uranium mineralization. Coals and organic matters in the coal-bearing series may have served as reducing agents and absorbing barriers. Methane is deemed to be the main acidolysis hydrocarbon in the U-bearing beds, which shows a positive correlation with U-content in the sandstones in the coal-bearing series. Additionally, the 613C in the carbonate cements of the U-bearing sandstones indicates that the organic matters, associated with the coal around the sandstones, were involved in the carbonation, one important component of alteration in the Tuanyushan area. Recognition of the dual control of coal-bearing series on the uranium mineralization is significant for the development of coal circular economy, environmental protection during coal utilization and the security of national rare metal resources.展开更多
The Bayingobi basin is located in the middle of Central Asia Orogenic Belt,at the intersection of Paleo-Asian Ocean and Tethys Ocean,as well as the junction of multiple tectonic plates.This unique tectonic setting und...The Bayingobi basin is located in the middle of Central Asia Orogenic Belt,at the intersection of Paleo-Asian Ocean and Tethys Ocean,as well as the junction of multiple tectonic plates.This unique tectonic setting underpins the basin's intricate history of tectonic activity.To unravel the multifaceted tectono-thermal evolution within the southwestern region of the basin and to elucidate the implications of sandstone-hosted uranium mineralization,granitic and clastic rock samples were collected from the Zongnai Mts.uplift and Yingejing depression,and apatite fission track(AFT)dating and thermal history simulation analysis were performed.AFT dating findings reveal that the apparent ages of all samples fall within the range of 244 Ma to 112 Ma.In particular,the bedrock of the Zongnai Mts.and Jurassic detrital apatite fission tracks have undergone complete annealing,capturing the uplift-cooling age.Meanwhile,the AFT ages of Cretaceous detrital rocks are either equivalent to or notably exceed the age of sedimentary strata,signifying the cooling age of the provenance.A comprehensive examination of AFT ages and palaeocurrent direction analyses suggests that the Cretaceous source in the Tamusu area predominantly originated from the central and southern sectors of the Zongnai Mts.uplift.However,at a certain juncture during the Late Early Cretaceous,the Cretaceous provenance expanded to include the northern part of the Zongnai Mts.uplift.Based on the results of thermal history simulations and previous studies,it is considered that the Tamusu area has undergone four distinct tectonic uplift events since the Late Paleozoic.The first is the Late Permian to Early Triassic(260-240 Ma),which is associated with the closure of the Paleo-Asian Ocean and the accretionary orogeny within the Alxa region.The second uplift event took place in the Early Jurassic(190-175 Ma)and corresponded to intraplate orogeny following the closure of the Paleo-Asian Ocean.The third uplift event is the Late Jurassic to Early Cretaceous(160-120 Ma),which is linked to the East Asia's position as the convergence center of multiple tectonic plates during this period.The fourth uplift event is linked to the Late Early Cretaceous(112-100 Ma),driven either by the westward subduction of the eastern Pacific plate or the mantle upwelling resulting from the Bangong-Nujiang oceanic lithosphere subduction and slab break-off.The primary stress orientation for the first three tectonic uplift phases approximated a nearly SN direction,while the fourth stage featured a principal stress direction of NW.The fourth tectonic uplift event of the Late Early Cretaceous and basaltic eruption thermal event during this period likely exerted a significant influence on the formation of the Tamusu sandstone-hosted uranium deposit.展开更多
Uranium,as one of twenty-six kinds of important minerals in China,is strategic resource and energy mineral,which has been thoroughly investigated in the project of National Potential Evaluation of Uranium Resource.Dur...Uranium,as one of twenty-six kinds of important minerals in China,is strategic resource and energy mineral,which has been thoroughly investigated in the project of National Potential Evaluation of Uranium Resource.During the implementation of this project,the authors summarized the metallogenic regularity of uranium resource in China systematically,through the researches of geological characteristics of uranium resource,uranium deposits type(genetic and prediction type),temporal and spatial distribution,and metallogenic series.Based on the investigation of present situation and progress in uranium exploration,this paper proposes the uranium deposits in China should be divided into 4 classes,9 types,21 subtypes in genetic,and 50 types in prediction;suggests to divide China into 29 uranium metallogenic belts and 20 uranium prospective area,and constructs 20uranium-polymetallic metallogenic series,through summarizing temporal and spatial distribution characteristics and metallogenic regularity of uranium deposits in China.The above research is beneficial to the comprehensive understanding of regional uranium metallogenic regularity,and will direct the uranium exploration in the future.展开更多
This paper deals with the metallogenic model of the sandstone type uranium deposit in the northeastern Ordos Basin from aspects of uranium source, migration and deposition. A superposition metallogenic model has been ...This paper deals with the metallogenic model of the sandstone type uranium deposit in the northeastern Ordos Basin from aspects of uranium source, migration and deposition. A superposition metallogenic model has been established due to complex uranium mineralization processes with superposition of oil-gas reduction and thermal reformation.展开更多
This study analyzed the composition and uranium valence of pitchblendes sampled from the hydrothermal Guidong and Zhuguang uranium deposits of the middle Nanling metallogenic belt, Southern China using X-ray photoelec...This study analyzed the composition and uranium valence of pitchblendes sampled from the hydrothermal Guidong and Zhuguang uranium deposits of the middle Nanling metallogenic belt, Southern China using X-ray photoelectron spectroscopy(XPS).A revolutionary discovery is that the uranium not only exists in the forms of tetravalent and hexavalent uranium oxides, but also occurs in the form of native uranium.This is the first discovery of the existence of native uranium in nature.It greatly helps to reveal the origin of hydrothermal mineralization of uranium, and also has great significance for studying the thermal energy, formation and evolution of the earth.展开更多
The Mesozoic–Cenozoic tectonic movement largely controls the northwest region of the Junggar Basin(NWJB), which is a significant area for the exploration of petroleum and sandstone-type uranium deposits in China. T...The Mesozoic–Cenozoic tectonic movement largely controls the northwest region of the Junggar Basin(NWJB), which is a significant area for the exploration of petroleum and sandstone-type uranium deposits in China. This work collected six samples from this sedimentary basin and surrounding mountains to conduct apatite fission track(AFT) dating, and utilized the dating results for thermochronological modeling to reconstruct the uplift history of the NWJB and its response to hydrocarbon migration and uranium mineralization. The results indicate that a single continuous uplift event has occurred since the Early Cretaceous, showing spatiotemporal variation in the uplift and exhumation patterns throughout the NWJB. Uplift and exhumation initiated in the northwest and then proceeded to the southeast, suggesting that the fault system induced a post spread-thrust nappe into the basin during the Late Yanshanian. Modeling results indicate that the NWJB mountains have undergone three distinct stages of rapid cooling: Early Cretaceous(ca. 140–115 Ma), Late Cretaceous(ca. 80–60 Ma), and Miocene–present(since ca. 20 Ma). These three stages regionally correspond to the LhasaEurasian collision during the Late Jurassic–Early Cretaceous(ca. 140–125 Ma), the Lhasa-Gandise collision during the Late Cretaceous(ca. 80–70 Ma), and a remote response to the India-Asian collision since ca. 55 Ma, respectively. These tectonic events also resulted in several regional unconformities between the J3/K1, K2/E, and E/N, and three large-scale hydrocarbon injection events in the Piedmont Thrust Belt(PTB). Particularly, the hydrocarbon charge event during the Early Cretaceous resulted in the initial inundation and protection of paleo-uranium ore bodies that were formed during the Middle–Late Jurassic. The uplift and denudation of the PTB was extremely slow from 40 Ma onward due to a slight influence from the Himalayan orogeny. However, the uplift of the PTB was faster after the Miocene, which led to re-uplift and exposure at the surface during the Quaternary, resulting in its oxidation and the formation of small uranium ore bodies.展开更多
Three uranium provinces are recognized in China, the Southeast China uranium province, the Northeast China-Inner Mongolia uranium province and the Northwest China (Xinjiang) uranium province. The latter two promise go...Three uranium provinces are recognized in China, the Southeast China uranium province, the Northeast China-Inner Mongolia uranium province and the Northwest China (Xinjiang) uranium province. The latter two promise good potential for uranium resources and are major exploration target areas in recent years. There are two major types of uranium deposits: the Phanerozoic hydrothermal type (vein type) and the Meso-Cenozoic sandstone type in different proportions in the three uranium provinces. The most important reason or prerequisite for the formation of these uranium provinces is that Precambrian uranium-enriched old basement or its broken parts (median massifs) exists or once existed in these regions, and underwent strong tectonomagmatic activation during Phanerozoic time. Uranium was mobilized from the old basement and migrated upwards to the upper structural level together with the acidic magma originating from anatexis and the primary fluids, which were then mixed with meteoric water and resulted in the formation of Phanerozoic hydrothermal uranium deposits under extensional tectonic environments. Erosion of uraniferous rocks and pre-existing uranium deposits during the Meso-Cenozoic brought about the removal of uranium into young sedimentary basins. When those basins were uplifted and slightly deformed by later tectonic activity, roll-type uranium deposits were formed as a result of redox in permeable sandstone strata.展开更多
A simulated experimental reduction of and the synthesis of uraninite by a sulfate-reducing bacteria, Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were:...A simulated experimental reduction of and the synthesis of uraninite by a sulfate-reducing bacteria, Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were: 35°C, pH=7.0-7.4, corresponding to the environments of formation of the sandstone-hosted interlayer oxidation-zone type uranium deposits in Xinjiang, NW China. Uraninite was formed on the surface of the host bacteria after a one-week's incubation. Therefore, sulfate-reducing bacteria, which existed extensively in Jurassic sandstone-producing environments, might have participated in the biomineralization of this uranium deposit. There is an important difference in the order- disorder of the crystalline structure between the uraninite produced by Desulfovibrio desulfuricans and naturally occurring uraninite. Long time and slow precipitation and growth of uraninite in the geological environment might have resulted in larger uraninite crystals, with uraninite nanocrystals arranged in order, whereas the experimentally produced uraninite is composed of unordered uraninite nanocrystals which, in contrast, result from the short time span of formation and rapid precipitation and growth of uraninite. The discovery has important implications for understanding genetic significance in mineralogy, and also indicates that in-situ bioremediation of U-contaminated environments and use of biotechnology in the treatment of radioactive liquid waste is being contemplated.展开更多
According to the oxidation intensity of ore-hosting sandstone, the interlayer oxidation zone of the Shihongtan sandstone-type uranium deposit in the Turpan-Hami basin can be divided into 4 geochemical subzones, namely...According to the oxidation intensity of ore-hosting sandstone, the interlayer oxidation zone of the Shihongtan sandstone-type uranium deposit in the Turpan-Hami basin can be divided into 4 geochemical subzones, namely, intenselyoxidized, weakly-oxidized, redox and unoxidized primary subzones. The elemental geochemical characteristics of the four subzones have been studied in detail, and the results show that U, together with other elements such as Re, Mo, Se, Sr, S, REE, Corganic etc., is enriched in the redox subzone. Re and U have similar geochemical properties in the reductionoxidation process. The geochemical properties of Mo and Se are similar to those of U in the reduction condition, but different from those of U in the oxidation condition. It is proposed that the ore-hosting layers can provide a curtain mount of uranium for uranium mineralization.展开更多
基金funded by the project titled Prospect Survey and Exploration Demonstration of Hardrock Mineral Resources such as Uranium and Thorium(12120115014101)initiated by the Tianjin Center of China Geological Survey.The data and achievements cited in this paper are mainly from relevant scientific research,geological survey,and mineral exploration projects undertaken by the No.302 Brigade of Hunan Nuclear Industry Geology Bureau in recent years.
文摘The central Zhuguang Mountains in Hunan Province is located at the junction of the three provinces,namely Hunan,Jiangxi,and Guangdong,where the famous Lujing uranium ore field lies.The uranium deposits occurring in this area are all granite-related and they can be divided into three types,namely endogranitic ones,perigranitic ones,and contact zone types.The endogranitic uranium deposits are mainly controlled by the structural alteration zones developing within granites,with fragmentation,hematitization,and alkali metasomatism as their main mineralization characteristics.The perigranitic uranium deposits are mainly produced in the carbonaceous,siliceous,and argillaceous composite layers of epimetamorphic rocks and are controlled by fractured zones formed due to interlayer compression.The contact zone type uranium deposits mainly occur in the contact parts between the granites and favorable horizons.They have developed in favorable sections where multiple sets of structures are combined and intersected.The main metallogenic regularities of uranium in the central Zhuguang Mountains are as follows.The basic conditions for the uranium mineralization in this area include the framework consisting of regional deep large faults and their associated multi-set multi-direction favorable metallogenic structures,multi-cycle and multi-stage uranium-rich rock masses,and uranium-rich folded basement.Meanwhile,the uranium deposits in this area are closely related to granites in terms of genesis and space and they are formed in different structural parts subject to the same metallization.Furthermore,based on the summary of the characteristics and regularities of uranium mineralization in this area,the controlling factors of different types of uranium deposits in the area were explored and six metallogenic target areas were predicted.All these will provide references for the exploration of uranium deposits in this area.
基金supported by the China Nuclear Industry Geological Bureau Foundation (No.201637 and 201638)
文摘1 Introduction The Kangdian axis is an important polymetallic metallogenic belt in Southwest China,and it is also an area with a lot of hydrothermal uranium mineralization(Wang Hongjun,et al.,2009.The basic
文摘On June 2011, the Beijing Research Institute of Uranium Geology, an Institute within the China National Nuclear Corporation (CNNC), and the Department of Geology & Mining CNNC carried out a project Scientific Drilling.for Deep Metallogenic Research in the Xiangshan Large Uranium Ore Field. A year later on June 21, the project, representing the first scientific drilling of China's uranium, was officially launched, and successfully completed on June 17, 2013. A 2818.88 m of drilling depth has broken the previous record 1200 m of exploration depth.
文摘East Hunan and its adjacent area is defined as an intraplate orogenic zone with help of new theory of geology and multi-discipline research. The evolutionary stages, deep structrue, geological feature, rotation strain and metallogeny of NW-striking transfer fault zone are also discussed. NE-trending strike-slip fault zone, as a whole, entered action during Pacific movement and underwent 3 stages: the strike-slip shear, the pull-apart extension and the’ compressive thrust. The aurthors studied macro-and microscopic features of strike-slip fault and its control of uranium mineralization at Jinguangchung deposit by means of modern structure analysis, micro-submicroscopic investigation and geophysical measurement.
基金sponsored by the National Natural Science Foundation Program of China (Nos.40772072 and 40802023)the Uranium Deposit Geological Program of Bureau of Geology,CNNC,the National Important Basic Research Program of China (No.2003CB214603 and No.2015CB453003)the Dongsheng coal and uranium exploration program of Central Geological exploration Fund (No.2008150013)
文摘Outcrop and drill hole data show that the Jurassic coal measures in the northeastern Ordos Basin are composed mainly of the Yan’an Formation and the lowstand system tract of the Zhiluo Formation, and there is a regional unconformity between them. The Dongsheng uranium deposit is associated with the Jurassic coal measures. Research data indicate that the Jurassic coal measures in the study area have a certain hydrocarbon-generating capacity, although the metamorphic grade is low (Ro=0.40%–0.58%). In the Dongsheng region alone, the accumulative amount of generated coalbed methane (CBM) is about 2028.29 × 108 –2218.72 × 108 m3; the residual amount is about 50.92 × 108 m3, and the lost amount is about 1977 × 108 m3. Analysis of the burial history of the host rocks and the evolutionary history of the Dongsheng uranium deposit suggests that the Jurassic coal measures generated hydrocarbon mainly from Middle Jurassic to Early Crataceous, which is the main mineralization phase of the Dongsheng uranium deposit. By the Late Cretaceous, a mass of CBM dissipated due to the strong tectonic uplift, and the Dongsheng uranium deposit stepped into the preservation phase. Therefore, the low-mature hydrocarbon-containing fluid in the Jurassic coal measures not only served as a reducing agent for the formation of sandstone-type uranium deposits, but also rendered the second reduction of paleo-interlayer oxidation zone and become the primary reducing agent for ore conservation. Regional strata correlation reveals that the sandstone-type uranium reservoir at the bottom of the Zhiluo Formation is in contact with the underlying industrial coal seams in the Yan’an Formation through incision or in the form of an unconformity surface. In the Dongsheng region with poorly developed fault systems, the unconformity surface and scour surface served as the main migration pathways for low-mature hydrocarbon-containing fluid migrating to the uranium reservoir.
基金supported by the National Key Basic Research Program of China (No.2015CB453004)National Pre-research Project (No.3210402)
文摘Meso-Cenozoic intracontinental orogenic processes in the Tian Shan orogenic belt have significant effect on the sandstone-hosted uranium deposits in the intramontane basins and those adjacent to the orogen. The Sawafuqi uranium deposit, which is located in the South Tian Shan orogenic belt, is investigated to reveal the relationships between uranium mineralization and orogenies. Recent exploration results show that the Sawafuqi uranium deposit has tabular, stratiform, quasi-stratiform, and lens-like orebodies and various geological characteristics different from typical interlayer oxidation zone sandstone-hosted uranium deposits. Systematic studies of ore samples from the Sawafuqi uranium deposit using a variety of techniques, including thin section observation, a-track radiograph, electron microprobe and scanning electron microscope, suggest that uranium mineralization is closely related to pyrite and organic matter. Mineralization-related alterations in the host rocks are mainly silicification and argillation including kaolinite, illite (and illite-smectite mixed layer) and chlorite. Tree stages of mineralization were identified in the Sawafuqi uranium deposit: (i) uranium-bearing detritus and synsedimentary initial pre-enrichment; (ii) interlayer oxidization zone uranium mineralization; and (iii) vein-type uranium mineralization. The synsedimentary uranium pre-enrichment represents an early uranium enrichment in the Sawafuqi uranium deposit, and interlayer oxidation zone uranium mineralization formed the main orebodies, which are superimposed by the vein-type uranium mineralization. Combining the results of this study with previous studies on the Meso-Cenozoic orogenies of South Tian Shan, it is proposed that the synsedimentary uranium pre-enrichment of the Sawafuqi uranium deposit was caused by Triassic Tian Shan uplift, and the interlayer oxidation zone uranium mineralization occurred during the Eocence-Oligocene period, when tectonism was relatively quiet, whereas the vein-type uranium mineralization took place in relation to the strong orogeny of South Tian Shan since Miocene.
文摘This paper introduces the test results of the soil magnetic survey and the integrated gamma-ray TLD and TC methods for sandstone-type uranium exploration and describes the prospecting mechanism. The tests have proved that these approaches have yielded good results on classifying the sedimentary facies, defining the redox transitional zones and reflecting deep mineralization information. They may probably become new methods on searching for sandstone-type uranium deposits.
基金supported by the National Natural Science Foundation of China (Nos. U2067202, 41772068, 42172098)the Natural Science Foundation of Jiangxi Province (No. 20202BAB213017)+1 种基金the Joint Innovation Fund of China Uranium Industry Co., LTD and East China University of Technology (No. NRE2021-02)Open Foundation of State Key Laboratory of Nuclear Resources and Environment (No. JELRGBDT202007)。
文摘The sandstone-hosted uranium deposits in the SW Songliao Basin differ from typical sandstone-hosted uranium deposits in terms of the geological features of the ore-deposits,including the geometry of the orebodies,mineral assemblage and petrography.Detailed drill core and microscopic observations,scanning electron microscopy(SEM),electron microprobe analysis(EMPA),heavy mineral concentrates,and fluid inclusion studies of the Upper Cretaceous Yaojia Formation,i.e.,the uranium-bearing layer,were integrated to investigate the roles of hydrothermal fluids in the formation of these uranium deposits.We found that the kaolinite alteration is developed in the mineralized zones,but it is less common in the peripheral areas.The fluid inclusions are hydrothermal fluids with a medium-low temperature(67 to 179 ℃) and a high salinity(5.9 wt.% to 20.1 wt.%).According to the analyses,three kinds of hydrothermal fluids,i.e.,the acid fluid,the groundwater heated by the mafic magma,and the alkaline fluid rich in Ca^(2+) and CO_(3)^(2-),were identified.The fluids might have low U content,but they have participated in the formation of the uranium deposits successively.Kaolinite formed by the acid-hydrothermal fluid absorbed large amounts of uranium.Subsequently,the thermal energy from the hydrothermal fluids changed the intrastratal redox environment and increased the solubility of the uranium minerals in the fluid.The alkaline-hydrothermal fluid rich in Ca^(2+) and C0_(3)^(2-) facilitated the formation of stable Ca-U(Ⅵ)-CO_(3) complex,which led to the enrichment of soluble uranium in solution,and final precipitation as pitchblende,brannerite and Ti-bearing uranium minerals in the uranium ores.
基金The“Northern Sandstone-type Uranium Deposits Investigation Project”(Project 0108)of the China Geological Survey has led to the discovery of many new sandstone-type uranium depositsThe National Basic Research Program(973 Program)(No.2015CB453000)+1 种基金the National Key R&D Program of China(No.2018YFC0604200)both from the Ministry of Science and Technology of the People’s Republic of China have led to innovations in many theoretical understandings of sandstone-type uranium depositsUnder the International Geoscience Programme(No.IGCP-675),a comparative study of sandstone-type uranium deposits between China and the rest of the world has been conducted。
文摘Many theoretical results on sandstone-type uranium mineralization in northern China obtained by the uranium research team of the Tianjin Center of Geological Survey in recent years are presented.From the source sink system of uranium-producing basins,sedimentary environment of uranium-bearing rock series,ore-forming fluid information,evolution of tectonic events,basin formation and development,we redefine and classify uranium orebodies,redox zoning,and ore-controlling structural styles.We then systematically propose a theoretical system of sandstone-type uranium deposits in northern China.We conclude that sandstone-type uranium deposits in northern China are mainly found in sedimentary environments such as rivers,deltas,and alluvial fans in the Mesozoic and Cenozoic lowstand systems tract and in gray sandstone layers in the vertical redox zoning.The orebodies are controlled by the tectonic slope belt,which is in the shape of a strip on the plane,and spreads in a layer or plate on the section.Vertical(ups and downs)tectonic movement triggers large-scale phreatic flow in the basin,which is the real driving force for controlling the ore-forming fluid.The theoretical system of sandstone-type uranium deposits in northern China should be based on global tectonic movement and environmental changes and take into account factors such as basins as a unit to study mineralization background,ore concentration areas as objects to study mineralization,and the correlation between regional tectonic movement and metallogenic process as a breakthrough point to study tectonic events and metallogenic events.It should also be based on different basin types to establish metallogenic models.The innovative research results and ideas are summarized with the aim of promoting the continuous improvement of sandstone-type uranium mineralization theory in northern China.
基金supported by NSFC(41072069,40772061 and 40930423)State Basic Research Plan(2009CB421005)+1 种基金IRT (0755)111 Plan(B07011)
文摘The Ordos Basin of North China is not only an important uranium mineralization province, but also a major producer of oil, gas and coal in China. The genetic relationship between uranium mineralization and hydrocarbons has been recognized by a number of previous studies, but it has not been well understood in terms of the hydrodynamics of basin fluid flow. We have demonstrated in a previous study that the preferential localization of Cretaceous uranium mineralization in the upper part of the Ordos Jurassic section may have been related to the interface between an upward flowing, reducing fluid and a downward flowing, oxidizing fluid. This interface may have been controlled by the interplay between fluid overpressure related to disequilibrium sediment compaction and which drove the upward flow, and topographic relief, which drove the downward flow. In this study, we carried out numerical modeling for the contribution of oil and gas generation to the development of fluid overpressure, in addition to sedi- ment compaction and heating. Our results indicate that when hydrocarbon generation is taken into account, fluid overpressure during the Cretaceous was more than doubled in comparison with the simu- lation when hydrocarbon generation was not considered. Furthermore, fluid overpressure dissipation at the end of sedimentation slowed down relative to the no-hydrocarbon generation case. These results suggest that hydrocarbon generation may have played an important role in uranium mineralization, not only in providing reducing agents required for the mineralization, but also in contributing to the driving force to maintain the upward flow.
基金supported financially by the National Natural Scientific Foundation of China (Grants No. 40872069 and 41173059)the National Basic Research Program of China (973 Program) (Grants No. 2015CB453000)+1 种基金China Geological Survey (Grants No. 12120113095500)the Foundation of China Nuclear Geology (Grants No. 201148)
文摘The carbonaceous-siliceous-argillitic rock type uranium deposit in the Zoige area is located in the northeastern margin of the Tibetan Plateau, and has gained much attention of many geologists and ore deposit experts due to its scale, high grade and abundant associated ores. Because of the insufficient reliable dating of intrusive rocks, the relationship between mineralization and the magmatic activities is still unknown. In order to study this key scientific issue and the ore-forming processes of the Zoige uranium ore field, the LA-ICP-MS zircon U-Pb dating of magmatic rocks was obtained:64.08±0.59 Ma for the granite-prophyry and ~200 Ma for the dolerite. U-Pb dating results of uraninite from the Zoige uranium ore field are mainly concentrated on ~90 Ma and ~60 Ma. According to LA-ICP-MS U-Pb zircon dating, the ages for the dolerite, porphyry granite and granodiorite are 200 Ma, 64.08 Ma approximately and 226.5-200.88 Ma, respectively. This indicates that the mineralization has close relationship with activities of the intermediate-acidic magma. The ages of the granite porphyry are consistent with those uraninite U-Pb dating results achieved by previous studies, which reflects the magmatic and ore-forming event during the later Yanshanian. Based on the data from previous researches, the ore bodies in the Zoige uranium ore field can be divided into two categories:the single uranium type and the uranium with polymetal mineralization type. The former formed at late Cretaceous(about 90 Ma), while the latter, closely related to the granite porphyry, formed at early Paleogene(about 60 Ma). And apart from ore forming elemental uranium, the latter is often associated with polymetallic elements, such as molybdenum, nickel, zinc, etc.
基金supported by the Major National Science and Technology Program of China (grants No. 2016ZX05041004)the National Natural Science Foundation of China (grant No. 41572090)High-level Talent Recruitment Project of North China University of Water Resource and Electric (grant No. 40481)
文摘The uranium deposits in the Tuanyushan area of northern Qaidam Basin commonly occur in coal-bearing series. To decipher the U-enrichment mechanism and controlling factors in this area, a database of 72 drill cores, including 56 well-logs and 3 sampling wells, was examined for sedimentology and geochemistry in relation to uranium concentrations. The results show that coal-bearing series can influence uranium mineralization from two aspects, i.e., spatial distribution and dynamic control. Five types of uranium-bearing rocks are recognized, mainly occurring in the braided river and braided delta sedimentary facies, among which sandstones near the coals are the most important. The lithological associations of sandstone-type uranium deposits can be classified into three subtypes, termed as U-coal type, coal-U-coal type, and coal-U type, respectively. The coal and fine siliciclastic rocks in the coal- bearing series confined the U-rich fluid flow and uranium accumulation in the sandstone near them. Thus, the coal-bearing series can provide good accommodations for uranium mineralization. Coals and organic matters in the coal-bearing series may have served as reducing agents and absorbing barriers. Methane is deemed to be the main acidolysis hydrocarbon in the U-bearing beds, which shows a positive correlation with U-content in the sandstones in the coal-bearing series. Additionally, the 613C in the carbonate cements of the U-bearing sandstones indicates that the organic matters, associated with the coal around the sandstones, were involved in the carbonation, one important component of alteration in the Tuanyushan area. Recognition of the dual control of coal-bearing series on the uranium mineralization is significant for the development of coal circular economy, environmental protection during coal utilization and the security of national rare metal resources.
基金financially supported by the project of nuclear energy development。
文摘The Bayingobi basin is located in the middle of Central Asia Orogenic Belt,at the intersection of Paleo-Asian Ocean and Tethys Ocean,as well as the junction of multiple tectonic plates.This unique tectonic setting underpins the basin's intricate history of tectonic activity.To unravel the multifaceted tectono-thermal evolution within the southwestern region of the basin and to elucidate the implications of sandstone-hosted uranium mineralization,granitic and clastic rock samples were collected from the Zongnai Mts.uplift and Yingejing depression,and apatite fission track(AFT)dating and thermal history simulation analysis were performed.AFT dating findings reveal that the apparent ages of all samples fall within the range of 244 Ma to 112 Ma.In particular,the bedrock of the Zongnai Mts.and Jurassic detrital apatite fission tracks have undergone complete annealing,capturing the uplift-cooling age.Meanwhile,the AFT ages of Cretaceous detrital rocks are either equivalent to or notably exceed the age of sedimentary strata,signifying the cooling age of the provenance.A comprehensive examination of AFT ages and palaeocurrent direction analyses suggests that the Cretaceous source in the Tamusu area predominantly originated from the central and southern sectors of the Zongnai Mts.uplift.However,at a certain juncture during the Late Early Cretaceous,the Cretaceous provenance expanded to include the northern part of the Zongnai Mts.uplift.Based on the results of thermal history simulations and previous studies,it is considered that the Tamusu area has undergone four distinct tectonic uplift events since the Late Paleozoic.The first is the Late Permian to Early Triassic(260-240 Ma),which is associated with the closure of the Paleo-Asian Ocean and the accretionary orogeny within the Alxa region.The second uplift event took place in the Early Jurassic(190-175 Ma)and corresponded to intraplate orogeny following the closure of the Paleo-Asian Ocean.The third uplift event is the Late Jurassic to Early Cretaceous(160-120 Ma),which is linked to the East Asia's position as the convergence center of multiple tectonic plates during this period.The fourth uplift event is linked to the Late Early Cretaceous(112-100 Ma),driven either by the westward subduction of the eastern Pacific plate or the mantle upwelling resulting from the Bangong-Nujiang oceanic lithosphere subduction and slab break-off.The primary stress orientation for the first three tectonic uplift phases approximated a nearly SN direction,while the fourth stage featured a principal stress direction of NW.The fourth tectonic uplift event of the Late Early Cretaceous and basaltic eruption thermal event during this period likely exerted a significant influence on the formation of the Tamusu sandstone-hosted uranium deposit.
基金National Mineral Resource Potential Evaluation Project
文摘Uranium,as one of twenty-six kinds of important minerals in China,is strategic resource and energy mineral,which has been thoroughly investigated in the project of National Potential Evaluation of Uranium Resource.During the implementation of this project,the authors summarized the metallogenic regularity of uranium resource in China systematically,through the researches of geological characteristics of uranium resource,uranium deposits type(genetic and prediction type),temporal and spatial distribution,and metallogenic series.Based on the investigation of present situation and progress in uranium exploration,this paper proposes the uranium deposits in China should be divided into 4 classes,9 types,21 subtypes in genetic,and 50 types in prediction;suggests to divide China into 29 uranium metallogenic belts and 20 uranium prospective area,and constructs 20uranium-polymetallic metallogenic series,through summarizing temporal and spatial distribution characteristics and metallogenic regularity of uranium deposits in China.The above research is beneficial to the comprehensive understanding of regional uranium metallogenic regularity,and will direct the uranium exploration in the future.
文摘This paper deals with the metallogenic model of the sandstone type uranium deposit in the northeastern Ordos Basin from aspects of uranium source, migration and deposition. A superposition metallogenic model has been established due to complex uranium mineralization processes with superposition of oil-gas reduction and thermal reformation.
文摘This study analyzed the composition and uranium valence of pitchblendes sampled from the hydrothermal Guidong and Zhuguang uranium deposits of the middle Nanling metallogenic belt, Southern China using X-ray photoelectron spectroscopy(XPS).A revolutionary discovery is that the uranium not only exists in the forms of tetravalent and hexavalent uranium oxides, but also occurs in the form of native uranium.This is the first discovery of the existence of native uranium in nature.It greatly helps to reveal the origin of hydrothermal mineralization of uranium, and also has great significance for studying the thermal energy, formation and evolution of the earth.
基金jointly conjugal supported by the Nuclear energy development project(grant No.H1142)Nation Pre-research Project(grant No.3210402)
文摘The Mesozoic–Cenozoic tectonic movement largely controls the northwest region of the Junggar Basin(NWJB), which is a significant area for the exploration of petroleum and sandstone-type uranium deposits in China. This work collected six samples from this sedimentary basin and surrounding mountains to conduct apatite fission track(AFT) dating, and utilized the dating results for thermochronological modeling to reconstruct the uplift history of the NWJB and its response to hydrocarbon migration and uranium mineralization. The results indicate that a single continuous uplift event has occurred since the Early Cretaceous, showing spatiotemporal variation in the uplift and exhumation patterns throughout the NWJB. Uplift and exhumation initiated in the northwest and then proceeded to the southeast, suggesting that the fault system induced a post spread-thrust nappe into the basin during the Late Yanshanian. Modeling results indicate that the NWJB mountains have undergone three distinct stages of rapid cooling: Early Cretaceous(ca. 140–115 Ma), Late Cretaceous(ca. 80–60 Ma), and Miocene–present(since ca. 20 Ma). These three stages regionally correspond to the LhasaEurasian collision during the Late Jurassic–Early Cretaceous(ca. 140–125 Ma), the Lhasa-Gandise collision during the Late Cretaceous(ca. 80–70 Ma), and a remote response to the India-Asian collision since ca. 55 Ma, respectively. These tectonic events also resulted in several regional unconformities between the J3/K1, K2/E, and E/N, and three large-scale hydrocarbon injection events in the Piedmont Thrust Belt(PTB). Particularly, the hydrocarbon charge event during the Early Cretaceous resulted in the initial inundation and protection of paleo-uranium ore bodies that were formed during the Middle–Late Jurassic. The uplift and denudation of the PTB was extremely slow from 40 Ma onward due to a slight influence from the Himalayan orogeny. However, the uplift of the PTB was faster after the Miocene, which led to re-uplift and exposure at the surface during the Quaternary, resulting in its oxidation and the formation of small uranium ore bodies.
文摘Three uranium provinces are recognized in China, the Southeast China uranium province, the Northeast China-Inner Mongolia uranium province and the Northwest China (Xinjiang) uranium province. The latter two promise good potential for uranium resources and are major exploration target areas in recent years. There are two major types of uranium deposits: the Phanerozoic hydrothermal type (vein type) and the Meso-Cenozoic sandstone type in different proportions in the three uranium provinces. The most important reason or prerequisite for the formation of these uranium provinces is that Precambrian uranium-enriched old basement or its broken parts (median massifs) exists or once existed in these regions, and underwent strong tectonomagmatic activation during Phanerozoic time. Uranium was mobilized from the old basement and migrated upwards to the upper structural level together with the acidic magma originating from anatexis and the primary fluids, which were then mixed with meteoric water and resulted in the formation of Phanerozoic hydrothermal uranium deposits under extensional tectonic environments. Erosion of uraniferous rocks and pre-existing uranium deposits during the Meso-Cenozoic brought about the removal of uranium into young sedimentary basins. When those basins were uplifted and slightly deformed by later tectonic activity, roll-type uranium deposits were formed as a result of redox in permeable sandstone strata.
基金the National Science Foundation.USA.(NSF Grant EAR 02-10820)the National Natural ScienceFoundation of China(NSFC Grant No.40173031)+1 种基金the International Cooperative Research Foundation of NSFC(Grant No.2002-40210104086) the Ph.D.Base Foundation of the Ministry of Education of China(Grant No.20020284036).
文摘A simulated experimental reduction of and the synthesis of uraninite by a sulfate-reducing bacteria, Desulfovibrio desulfuricans DSM 642, are first reported. The simulated physicochemical experimental conditions were: 35°C, pH=7.0-7.4, corresponding to the environments of formation of the sandstone-hosted interlayer oxidation-zone type uranium deposits in Xinjiang, NW China. Uraninite was formed on the surface of the host bacteria after a one-week's incubation. Therefore, sulfate-reducing bacteria, which existed extensively in Jurassic sandstone-producing environments, might have participated in the biomineralization of this uranium deposit. There is an important difference in the order- disorder of the crystalline structure between the uraninite produced by Desulfovibrio desulfuricans and naturally occurring uraninite. Long time and slow precipitation and growth of uraninite in the geological environment might have resulted in larger uraninite crystals, with uraninite nanocrystals arranged in order, whereas the experimentally produced uraninite is composed of unordered uraninite nanocrystals which, in contrast, result from the short time span of formation and rapid precipitation and growth of uraninite. The discovery has important implications for understanding genetic significance in mineralogy, and also indicates that in-situ bioremediation of U-contaminated environments and use of biotechnology in the treatment of radioactive liquid waste is being contemplated.
文摘According to the oxidation intensity of ore-hosting sandstone, the interlayer oxidation zone of the Shihongtan sandstone-type uranium deposit in the Turpan-Hami basin can be divided into 4 geochemical subzones, namely, intenselyoxidized, weakly-oxidized, redox and unoxidized primary subzones. The elemental geochemical characteristics of the four subzones have been studied in detail, and the results show that U, together with other elements such as Re, Mo, Se, Sr, S, REE, Corganic etc., is enriched in the redox subzone. Re and U have similar geochemical properties in the reductionoxidation process. The geochemical properties of Mo and Se are similar to those of U in the reduction condition, but different from those of U in the oxidation condition. It is proposed that the ore-hosting layers can provide a curtain mount of uranium for uranium mineralization.