Urban ambient aerosols in the size range below 10 μm were measured and sampled for further evalua- tion (by Raman and Thermal-Optical analysis) of the collected material. The presented data shows that monitoring nu...Urban ambient aerosols in the size range below 10 μm were measured and sampled for further evalua- tion (by Raman and Thermal-Optical analysis) of the collected material. The presented data shows that monitoring number and/or surface area concentrations besides the mass concentration provides valu- able information for a meaningful assessment of the actual ambient air quality. The aim of the study was to characterize the urban aerosols using various instruments, methods, and sampling conditions, and to determine whether a split of the PMzs size fraction at PM1 may deliver a more sensible indication of the actual air quality than the current standard of monitoring PMzs. We found substantial differences relating to this split. PM2.5 data frequently include particles from both mechanical and combustion processes, PM1 measurements can be used to better distinguish particles derived from these two sources. We measured number concentrations of PM1 with PM2.5-1 concurrently with particle mass concentration and found that the typical average particle diameter by mass in the urban aerosols investigated was in the range of 120 nm; this corresponded well with the particle number size distributions measured in real time. Raman spectral analysis and thermal-optical evaluation of the sampled material also suggested that it would be sensible to split the measurement of the PM2.5 fraction into PM1 and PM2.s-1 size fractions, especially for analysis of carbonaceous aerosol components using the DRI thermal/optical reflectance carbon analysis system展开更多
The WRF model with chemistry (WRF-Chem) was employed to simulate the impacts of anthropogenic aerosols on summer precipitation over the Beijing-Tianjin-Hebei urban agglomeration in China. With the aid of a high-reso...The WRF model with chemistry (WRF-Chem) was employed to simulate the impacts of anthropogenic aerosols on summer precipitation over the Beijing-Tianjin-Hebei urban agglomeration in China. With the aid of a high-resolution gridded inventory of anthropogenic emissions of trace gases and aerosols, we conducted relatively long-term regional simulations, considering direct, semi-direct and indirect effects of the aerosols. Comparing the results of sensitivity experiments with and without emissions, it was found that anthropogenic aerosols tended to enhance summer precipitation over the metropolitan areas. Domain-averaged rainfall was increased throughout the day, except for the time around noon. Aerosols shifted the precipitation probability distribution from light or moderate to extreme rain. Further analysis showed that the anthropogenic aerosol radiative forcing had a cooling effect at the land surface, but a warming effect in the atmosphere. However, enhanced convective strength and updrafts accompanied by water vapor increases and cyclone-like wind shear anomalies were found in the urban areas. These responses may originate from cloud microphysical effects of aerosols on convection, which were identified as the primary cause for the summer rainfall enhancement.展开更多
PM10 was monitored during 2008-2011 period at LUT and BON, two urban tropical stations close to each other at Saint-Pierre city, in Reunion Island (south-western Indian Ocean). During the study period, notable PM10 co...PM10 was monitored during 2008-2011 period at LUT and BON, two urban tropical stations close to each other at Saint-Pierre city, in Reunion Island (south-western Indian Ocean). During the study period, notable PM10 concentrations are observed at BON close to the coasts. At LUT, a more inland site, the daily PM10 concentration range between 13 and 70 μg/m3. Importantly, the limit value for the protection of the human health is systematically exceeded at BON while it is never exceeded at LUT. Also, the quality objective (QO: 30 μg/m3, on annual average) and the limit value for the human health protection (LV: 40 μg/m3, on annual average) are exceeded at BON each year during 2008-2011, while at LUT no regulatory values are exceeded. Nitrogen dioxide, an atmospheric tracer of anthropogenic activities was also monitored at LUT and BON. The mean diurnal NO2 variation is of the same level and order of magnitude and exhibits a similar pattern at both stations suggesting that distinct sources influence the PM10 at LUT and at BON. Chemical analysis was performed on daily filters sampled in September-November 2011 at the two stations to determine the sea salt contribution on PM10 across Saint-Pierre city. It showed that the sea salt contribution to the PM10 is 55% at BON in September 2011. The sea salt particles are therefore the main cause for the exceedances of the regulatory values of PM10 recorded at BON. The results importantly suggest that the notable PM10 concentrations measured at this urban marine site might have some but minor impact on human health.展开更多
A study of the concentration of black carbon particles and its variation in the urban atmosphere has been carried out since 1996 in the Beijing area. The measurements were done in the late autumn and early winter each...A study of the concentration of black carbon particles and its variation in the urban atmosphere has been carried out since 1996 in the Beijing area. The measurements were done in the late autumn and early winter each year, the period before and after domestic heating activities begin. The results show the presence of black carbon particles at the high level that vary over a large range in the urban atmosphere in Beijing. The mean value of daily average concentration for the whole observation period of 1996-2004 is 20.0 μgm^-3. An evident decrease of black carbon particle concentration in the Beijing area is observed after 2000, and the daily average concentration of black carbon particles is estimated to be 16.0 μgm^-3 with a variation range of 2.10-50.50 μgm^-3 for the period of 2000-2004. The observation method and main variation behavior characteristics of black carbon particles in the urban atmosphere in the Beijing area are given and discussed.展开更多
During October 1993 and March 1996, the samples of fine and coarse air particulate matter have been collected at representative urban and rural site of Beijing with the Gent Stacked Filter Unit Sampler. Instrumental n...During October 1993 and March 1996, the samples of fine and coarse air particulate matter have been collected at representative urban and rural site of Beijing with the Gent Stacked Filter Unit Sampler. Instrumental neutron activation analysis (INAA) and proton induced X ray emission (PIXE) method were used to determine the elemental composition of the particulate matter. Average elemental concentrations and enrichment factors were calculated for the fine and coarse size fractions. Based on the particulate matter data obtained at urban and rural site together with the chemical constituents of the aerosol from the different sources are discussed. The results show that the relative particulate mass and elemental concentrations of crustal and pollutant elements in the air particulate matter collected over the urban are higher than rural and winter heating period are higher than in ordinary season. Beijing atmosphere is polluted by aerosols from regional and faraway sources. It was noticed that the toxic or harmful elements such as As, Sb, Pb, Cu, Ni, S and Zn were mainly enriched in fine particles with diameter less than 2 μm. A receptor model was used to assess the relative contribution of major air pollution sources at receptor sites in Beijing. Trace elements were used as the markers for the above assessment. Factor analysis method was used to identify possible emission sources of air particles. The major sources of dust soil, coal burning, motor vehicle emission, industry emission and refuse incineration were identified.展开更多
The quality of the MODIS C6 3-km and 10-km aerosol optical depth(AOD) products retrieved by the Dark Target(DT)method is discussed using ground-based observations in the Beijing–Tianjin–Hebei region from 1 Augus...The quality of the MODIS C6 3-km and 10-km aerosol optical depth(AOD) products retrieved by the Dark Target(DT)method is discussed using ground-based observations in the Beijing–Tianjin–Hebei region from 1 August 2007 to 31 July2008. Good consistency exists between the 3-km and 10-km products and ground-based observations. The retrieval accuracy of the two products both show distinctive seasonality. The percentage falling within the expected error(EE) is largest in the winter, moderate in the spring and autumn, and smallest in the summer. A worse overestimation appears in the spring and summer(27%–66%). However, the 3-km and 10-km products over different surfaces still exhibit obvious deviations. The 10-km product performs better in the large cities, while the 3-km product has advantages in the suburbs. In urban areas, the percentage falling within EE of the 3-km AOD product(18%–59%) is lower than that for the 10-km AOD product(31%–69%). However, in suburban areas, the percentage falling within EE of the 3-km AOD product(61%–84%) is higher than for the 10 km AOD product(54%–83%).The percentages falling within EE differ considerably when the AOD is greater than1.5(73% and 63% for the 3-km and 10-km products, respectively). On the whole, the 3-km(10-km) AOD product performs better in suburban(urban) areas.展开更多
A direct comparison of urban and rural surface energy balances, as well as a variety of other variables including incoming shortwave/longwave radiation and aerosol optical depth, is conducted for the Beijing metropoli...A direct comparison of urban and rural surface energy balances, as well as a variety of other variables including incoming shortwave/longwave radiation and aerosol optical depth, is conducted for the Beijing metropolitan area. The results indicate that, overall, the urban area receives a smaller amount of incoming shortwave radiation but a larger amount of incoming longwave radiation. However, comparisons in the aerosol optical depth and cloud fraction at the two locations suggest that neither aerosol optical depth nor cloud fraction alone can explain the difference in the incoming shortwave radiation. The urban–rural differences in the incoming longwave radiation are unlikely to be caused by the presence of more abundant greenhouse gases over the urban area, as suggested by some previous studies, given that water vapor is the most dominant greenhouse gas and precipitable water is found to be less in urban areas. The higher incoming longwave radiation observed over the urban area is mostly likely due to the higher temperatures of the ambient air. The urban area is also found to always produce higher sensible heat fluxes and lower latent heat fluxes in the growing season. Furthermore, the urban area is associated with a larger amount of available energy(the sum of sensible and latent heat fluxes) than the rural area, except in May and October when evapotranspiration in the rural area significantly exceeds that in the urban area. This study provides observational evidence of urban–rural contrasts in relevant energy-balance components that plausibly arise from urban–rural differences in atmospheric and land-surface conditions.展开更多
Differential optical absorption spectroscopy (DOAS) is a useful technique for measuring nitrogen dioxide (NO2) and aerosol, the most important species in urban environmental pollution. This paper reports on the result...Differential optical absorption spectroscopy (DOAS) is a useful technique for measuring nitrogen dioxide (NO2) and aerosol, the most important species in urban environmental pollution. This paper reports on the results of our dual path DOAS measurements recently conducted in Chiba City, Japan, using xenon flashlights equipped on tall constructions as aviation obstruction lights. Because of the proximity of the southern DOAS path to an industrial area, it is found that the level of air pollution generally increases with the dominance of westerly winds, from the plausible source area to the observation light path. This situation is consistent with the result of wind lidar measurement covering a sector of ±28? with the observation range of approximately 2.8 km. In spite of the fact that the two DOAS paths, having path lengths of 5.5 and 3.5 km each, are located in separated regions of Chiba City, the observed temporal behavior was similar for both nitrogen dioxide and aerosol, though the southern path tends to exhibit slightly higher pollution levels than the northern counterpart. Additionally it is confirmed that size information of aerosol particles can be derived from the DOAS data through the analysis of the wavelength dependence of the aerosol optical thickness, which shows fairly good correlation with the mass ratio between PM2.5 and suspended particulate matter (SPM) obtained from the in-situ sampling station measurement. Thus, the DOAS approach can also be utilized for obtaining information on PM2.5 that is considered to be more harmful to human health than SPM.展开更多
An understanding of the amount and type of aerosols present in the atmosphere is required for the atmospheric correction of satellite imagery. A sensitivity analysis of the atmospheric inputs to the MOD09 software has...An understanding of the amount and type of aerosols present in the atmosphere is required for the atmospheric correction of satellite imagery. A sensitivity analysis of the atmospheric inputs to the MOD09 software has shown that uncertainty in the estimation of Aerosol Optical Depth (AOD) has the greatest impact on the accuracy of atmospheric correction of MODIS data. The MOD09 software used for the generation of surface reflectance products estimates the AOD of the atmosphere at the time of image acquisition. AOD measurements retrieved from MODIS were compared with near-simultaneous AErosol RObotic NETwork (AERONET) data over three sites in Australia, using time-series of MODIS surface reflectance products. The results of the study provide an important independent validation of ACRES MODIS Surface Reflectance Products. This procedure may be applied to long time series MODIS data for estimating the accuracy of MOD09 retrieved AOD.展开更多
The pollution of particulate matter less than 2.5μm (PM2.5) is a serious environmental problem in Beijing. The annual average concentration of PM2.5 in 2001 from seasonal monitor results was more than 6 times that ...The pollution of particulate matter less than 2.5μm (PM2.5) is a serious environmental problem in Beijing. The annual average concentration of PM2.5 in 2001 from seasonal monitor results was more than 6 times that of the U,S, national ambient air quality standards proposed by U.S. EPA. The major contributors to mass of PM2.5 were organics, crustal elements and sulfate. The chemical composition of PM2.5 varied largely with season, but was similar at different monitor stations in the same season. The fine particles (PM2.5) cause atmospheric visibility deterioration through light extinction, The mass concentrations of PM2.5 were anti-correlated to the visibility, the best fits between atmospheric visibility and the mass concentrations of PM2.5 were somehow different: power in spring, exponential in summer, logarithmic in autumn, power or exponential in winter. As in each season the meteorological parameters such as air temperature and relative humidity change from day to day, probably the reason of above correlations between PM2.5 and visibility obtained at different seasons come from the differences in chemical compositions of PM2.5.展开更多
文摘Urban ambient aerosols in the size range below 10 μm were measured and sampled for further evalua- tion (by Raman and Thermal-Optical analysis) of the collected material. The presented data shows that monitoring number and/or surface area concentrations besides the mass concentration provides valu- able information for a meaningful assessment of the actual ambient air quality. The aim of the study was to characterize the urban aerosols using various instruments, methods, and sampling conditions, and to determine whether a split of the PMzs size fraction at PM1 may deliver a more sensible indication of the actual air quality than the current standard of monitoring PMzs. We found substantial differences relating to this split. PM2.5 data frequently include particles from both mechanical and combustion processes, PM1 measurements can be used to better distinguish particles derived from these two sources. We measured number concentrations of PM1 with PM2.5-1 concurrently with particle mass concentration and found that the typical average particle diameter by mass in the urban aerosols investigated was in the range of 120 nm; this corresponded well with the particle number size distributions measured in real time. Raman spectral analysis and thermal-optical evaluation of the sampled material also suggested that it would be sensible to split the measurement of the PM2.5 fraction into PM1 and PM2.s-1 size fractions, especially for analysis of carbonaceous aerosol components using the DRI thermal/optical reflectance carbon analysis system
基金supported by the Strategic Priority Research Program-Climate Change:Carbon Budget and Relevant Issuesof the Chinese Academy of Sciences(Grant No.XDA05090207)the National Natural Science Foundation of China(Grant Nos.41275108 and 41105051)
文摘The WRF model with chemistry (WRF-Chem) was employed to simulate the impacts of anthropogenic aerosols on summer precipitation over the Beijing-Tianjin-Hebei urban agglomeration in China. With the aid of a high-resolution gridded inventory of anthropogenic emissions of trace gases and aerosols, we conducted relatively long-term regional simulations, considering direct, semi-direct and indirect effects of the aerosols. Comparing the results of sensitivity experiments with and without emissions, it was found that anthropogenic aerosols tended to enhance summer precipitation over the metropolitan areas. Domain-averaged rainfall was increased throughout the day, except for the time around noon. Aerosols shifted the precipitation probability distribution from light or moderate to extreme rain. Further analysis showed that the anthropogenic aerosol radiative forcing had a cooling effect at the land surface, but a warming effect in the atmosphere. However, enhanced convective strength and updrafts accompanied by water vapor increases and cyclone-like wind shear anomalies were found in the urban areas. These responses may originate from cloud microphysical effects of aerosols on convection, which were identified as the primary cause for the summer rainfall enhancement.
文摘PM10 was monitored during 2008-2011 period at LUT and BON, two urban tropical stations close to each other at Saint-Pierre city, in Reunion Island (south-western Indian Ocean). During the study period, notable PM10 concentrations are observed at BON close to the coasts. At LUT, a more inland site, the daily PM10 concentration range between 13 and 70 μg/m3. Importantly, the limit value for the protection of the human health is systematically exceeded at BON while it is never exceeded at LUT. Also, the quality objective (QO: 30 μg/m3, on annual average) and the limit value for the human health protection (LV: 40 μg/m3, on annual average) are exceeded at BON each year during 2008-2011, while at LUT no regulatory values are exceeded. Nitrogen dioxide, an atmospheric tracer of anthropogenic activities was also monitored at LUT and BON. The mean diurnal NO2 variation is of the same level and order of magnitude and exhibits a similar pattern at both stations suggesting that distinct sources influence the PM10 at LUT and at BON. Chemical analysis was performed on daily filters sampled in September-November 2011 at the two stations to determine the sea salt contribution on PM10 across Saint-Pierre city. It showed that the sea salt contribution to the PM10 is 55% at BON in September 2011. The sea salt particles are therefore the main cause for the exceedances of the regulatory values of PM10 recorded at BON. The results importantly suggest that the notable PM10 concentrations measured at this urban marine site might have some but minor impact on human health.
基金This work was supported by the Bureau of International Cooperation of the National Science Foundation of China(No.40311120114)the Bureau of International Cooperation of the Chinese Academy of Sciences(No.980491002)
文摘A study of the concentration of black carbon particles and its variation in the urban atmosphere has been carried out since 1996 in the Beijing area. The measurements were done in the late autumn and early winter each year, the period before and after domestic heating activities begin. The results show the presence of black carbon particles at the high level that vary over a large range in the urban atmosphere in Beijing. The mean value of daily average concentration for the whole observation period of 1996-2004 is 20.0 μgm^-3. An evident decrease of black carbon particle concentration in the Beijing area is observed after 2000, and the daily average concentration of black carbon particles is estimated to be 16.0 μgm^-3 with a variation range of 2.10-50.50 μgm^-3 for the period of 2000-2004. The observation method and main variation behavior characteristics of black carbon particles in the urban atmosphere in the Beijing area are given and discussed.
文摘During October 1993 and March 1996, the samples of fine and coarse air particulate matter have been collected at representative urban and rural site of Beijing with the Gent Stacked Filter Unit Sampler. Instrumental neutron activation analysis (INAA) and proton induced X ray emission (PIXE) method were used to determine the elemental composition of the particulate matter. Average elemental concentrations and enrichment factors were calculated for the fine and coarse size fractions. Based on the particulate matter data obtained at urban and rural site together with the chemical constituents of the aerosol from the different sources are discussed. The results show that the relative particulate mass and elemental concentrations of crustal and pollutant elements in the air particulate matter collected over the urban are higher than rural and winter heating period are higher than in ordinary season. Beijing atmosphere is polluted by aerosols from regional and faraway sources. It was noticed that the toxic or harmful elements such as As, Sb, Pb, Cu, Ni, S and Zn were mainly enriched in fine particles with diameter less than 2 μm. A receptor model was used to assess the relative contribution of major air pollution sources at receptor sites in Beijing. Trace elements were used as the markers for the above assessment. Factor analysis method was used to identify possible emission sources of air particles. The major sources of dust soil, coal burning, motor vehicle emission, industry emission and refuse incineration were identified.
基金supported by the National Natural Science Foundation of China(Grant Nos.41375036,41222033,41305076)the Key Project of National Natural Science Foundation of China(Grant Nos.91644226)+1 种基金the CAS(Chinese Academy of Sciences)Strategic Priority Research Program(Grant No.XDA05100102,XDB05020103)the National Basic Research Program of China(Grant Nos.2016YFC0202001 and 2014CB441200)
文摘The quality of the MODIS C6 3-km and 10-km aerosol optical depth(AOD) products retrieved by the Dark Target(DT)method is discussed using ground-based observations in the Beijing–Tianjin–Hebei region from 1 August 2007 to 31 July2008. Good consistency exists between the 3-km and 10-km products and ground-based observations. The retrieval accuracy of the two products both show distinctive seasonality. The percentage falling within the expected error(EE) is largest in the winter, moderate in the spring and autumn, and smallest in the summer. A worse overestimation appears in the spring and summer(27%–66%). However, the 3-km and 10-km products over different surfaces still exhibit obvious deviations. The 10-km product performs better in the large cities, while the 3-km product has advantages in the suburbs. In urban areas, the percentage falling within EE of the 3-km AOD product(18%–59%) is lower than that for the 10-km AOD product(31%–69%). However, in suburban areas, the percentage falling within EE of the 3-km AOD product(61%–84%) is higher than for the 10 km AOD product(54%–83%).The percentages falling within EE differ considerably when the AOD is greater than1.5(73% and 63% for the 3-km and 10-km products, respectively). On the whole, the 3-km(10-km) AOD product performs better in suburban(urban) areas.
基金supported by the National Key Basic Research Program (Grant Nos. 2010CB428502 and 2012CB417203)the National Natural Science Foundation of China (Grant Nos. 41405018 and 41275022)+2 种基金the China Meteorological Administration (Grant No. GYHY201006024)the CAS Strategic Priority Research Program (Grant No. XDA05110101)the support of the State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry, Institute of Atmospheric Physics, Chinese Academy of Sciences (Grant No. LAPC-KF-2009-02)
文摘A direct comparison of urban and rural surface energy balances, as well as a variety of other variables including incoming shortwave/longwave radiation and aerosol optical depth, is conducted for the Beijing metropolitan area. The results indicate that, overall, the urban area receives a smaller amount of incoming shortwave radiation but a larger amount of incoming longwave radiation. However, comparisons in the aerosol optical depth and cloud fraction at the two locations suggest that neither aerosol optical depth nor cloud fraction alone can explain the difference in the incoming shortwave radiation. The urban–rural differences in the incoming longwave radiation are unlikely to be caused by the presence of more abundant greenhouse gases over the urban area, as suggested by some previous studies, given that water vapor is the most dominant greenhouse gas and precipitable water is found to be less in urban areas. The higher incoming longwave radiation observed over the urban area is mostly likely due to the higher temperatures of the ambient air. The urban area is also found to always produce higher sensible heat fluxes and lower latent heat fluxes in the growing season. Furthermore, the urban area is associated with a larger amount of available energy(the sum of sensible and latent heat fluxes) than the rural area, except in May and October when evapotranspiration in the rural area significantly exceeds that in the urban area. This study provides observational evidence of urban–rural contrasts in relevant energy-balance components that plausibly arise from urban–rural differences in atmospheric and land-surface conditions.
文摘Differential optical absorption spectroscopy (DOAS) is a useful technique for measuring nitrogen dioxide (NO2) and aerosol, the most important species in urban environmental pollution. This paper reports on the results of our dual path DOAS measurements recently conducted in Chiba City, Japan, using xenon flashlights equipped on tall constructions as aviation obstruction lights. Because of the proximity of the southern DOAS path to an industrial area, it is found that the level of air pollution generally increases with the dominance of westerly winds, from the plausible source area to the observation light path. This situation is consistent with the result of wind lidar measurement covering a sector of ±28? with the observation range of approximately 2.8 km. In spite of the fact that the two DOAS paths, having path lengths of 5.5 and 3.5 km each, are located in separated regions of Chiba City, the observed temporal behavior was similar for both nitrogen dioxide and aerosol, though the southern path tends to exhibit slightly higher pollution levels than the northern counterpart. Additionally it is confirmed that size information of aerosol particles can be derived from the DOAS data through the analysis of the wavelength dependence of the aerosol optical thickness, which shows fairly good correlation with the mass ratio between PM2.5 and suspended particulate matter (SPM) obtained from the in-situ sampling station measurement. Thus, the DOAS approach can also be utilized for obtaining information on PM2.5 that is considered to be more harmful to human health than SPM.
文摘An understanding of the amount and type of aerosols present in the atmosphere is required for the atmospheric correction of satellite imagery. A sensitivity analysis of the atmospheric inputs to the MOD09 software has shown that uncertainty in the estimation of Aerosol Optical Depth (AOD) has the greatest impact on the accuracy of atmospheric correction of MODIS data. The MOD09 software used for the generation of surface reflectance products estimates the AOD of the atmosphere at the time of image acquisition. AOD measurements retrieved from MODIS were compared with near-simultaneous AErosol RObotic NETwork (AERONET) data over three sites in Australia, using time-series of MODIS surface reflectance products. The results of the study provide an important independent validation of ACRES MODIS Surface Reflectance Products. This procedure may be applied to long time series MODIS data for estimating the accuracy of MOD09 retrieved AOD.
基金The General Project of the Beijing Municipal Natural Science Foundation (No. 8012009) and the Key Project of the BeijingMunicipal Sciences & Technology Commission (No. H020620190091-H020620250230)
文摘The pollution of particulate matter less than 2.5μm (PM2.5) is a serious environmental problem in Beijing. The annual average concentration of PM2.5 in 2001 from seasonal monitor results was more than 6 times that of the U,S, national ambient air quality standards proposed by U.S. EPA. The major contributors to mass of PM2.5 were organics, crustal elements and sulfate. The chemical composition of PM2.5 varied largely with season, but was similar at different monitor stations in the same season. The fine particles (PM2.5) cause atmospheric visibility deterioration through light extinction, The mass concentrations of PM2.5 were anti-correlated to the visibility, the best fits between atmospheric visibility and the mass concentrations of PM2.5 were somehow different: power in spring, exponential in summer, logarithmic in autumn, power or exponential in winter. As in each season the meteorological parameters such as air temperature and relative humidity change from day to day, probably the reason of above correlations between PM2.5 and visibility obtained at different seasons come from the differences in chemical compositions of PM2.5.