Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displ...Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displacement reaction in CuSO4 solution using zinc powder as a reductant. The structure and electrochemical property of the so-prepared powders were characterized by means of XRD （powder X-ray diffraction） and the galvanostatic discharge-charge techniques. The results show that the electrochemical property of Cs0.35V2O5/Cu composite material is significantly improved compared to the bulk Cs0.35V2O5 material. The Cs0.35V2O5/Cu composite material exhibits the first discharge capacity as high as 164.3 mAh.g -1 in the range of 4.2-1.8V at a current rate of 10 mA.g-1 and remains at a stable discharge capacity of about 110 mAh.g-1 within 40 cycles.展开更多
Through the vacuum diffusion welding SiCp/ZL 101 aluminum with Cu interlayer,the effect of welding parameter and the thickness of Cu on the welded joint property wasinvestigated, and the optimal welding parameters wer...Through the vacuum diffusion welding SiCp/ZL 101 aluminum with Cu interlayer,the effect of welding parameter and the thickness of Cu on the welded joint property wasinvestigated, and the optimal welding parameters were put forward at the same time. Themicrostructure of joint was analyzed by means of optical-microscope, scanning electron microscope inorder to study the relationship between the macro-properties of joint and the microstructure. Theresults show that diffusion welding with Cu interlayer could be used for welding aluminum matrixcomposites SiCp/ZL 101 successfully.展开更多
The feasibility of preparing Fe/Cu composite sheet was achieved by introducing submillimeter thickness Al sheet as an interlayer by rolling at room temperature.The shear test of the composite sheet supported that the ...The feasibility of preparing Fe/Cu composite sheet was achieved by introducing submillimeter thickness Al sheet as an interlayer by rolling at room temperature.The shear test of the composite sheet supported that the metallurgical bonding strength between Fe/(Al)/Cu interface was stronger than that of Cu sheet at the initial state.With further 300 or 600℃ annealing treatments,the interlayer subsequently exhibited brittle shear fracture,and the shear strength significantly dropped under the shear test.Furthermore,the tensile test pointed out that the tensile fracture mechanism changed from fracture as a whole structure to interlayer-to-layer delamination mode after annealing treatment.The microstructure and X-ray diffraction observations proved that the formation of Cu–Al intermetallic compounds(IMCs)along the interlayer resulted in brittle fracture,rather than that of Fe–Al IMCs after annealing,especially under 600℃ annealing treatment.The investigation of the effect of the rolling process and annealing treatment on the mechanical properties of the Fe/(Al)/Cu composite sheet shall provide instruction for high-quality composite metallic sheet fabrication.展开更多
采用2~5 mm厚的纯V与纯Cu组成复合过渡段,进行了TA2与304不锈钢的激光焊接试验,测试了接头的拉伸强度,利用金相显微镜、扫描电镜以及能谱仪对连接界面处元素扩散、接头断口形貌进行了分析。结果表明,采用加入2~5 mm V/Cu复合过渡段进行...采用2~5 mm厚的纯V与纯Cu组成复合过渡段,进行了TA2与304不锈钢的激光焊接试验,测试了接头的拉伸强度,利用金相显微镜、扫描电镜以及能谱仪对连接界面处元素扩散、接头断口形貌进行了分析。结果表明,采用加入2~5 mm V/Cu复合过渡段进行TA2和304不锈钢的激光焊接时,可以获得连接良好、无裂纹的焊接接头。中间过渡段越厚,接头抗拉强度越大,加入5 mm V/Cu复合过渡段时,接头平均抗拉强度最高达297 MPa,断裂发生在Cu过渡段内,属韧性断裂。展开更多
分别采用Cu箔和Cu膜作为中间层,在853 K保温情况下进行了S iC颗粒增强铝基复合材料的瞬间液相扩散连接试验.用金相显微镜、扫描电镜、能谱仪、X射线衍射仪和拉伸试验机研究了表面状态、保温时间和压力对接头显微组织和性能的影响.结果表...分别采用Cu箔和Cu膜作为中间层,在853 K保温情况下进行了S iC颗粒增强铝基复合材料的瞬间液相扩散连接试验.用金相显微镜、扫描电镜、能谱仪、X射线衍射仪和拉伸试验机研究了表面状态、保温时间和压力对接头显微组织和性能的影响.结果表明:合适的压力和中间层厚度能有效改善接头的组织和力学性能,接头剪切强度随保温时间延长而提高.表面状态对接头强度有较大影响.采用Cu膜作中间层由于没有氧化膜的影响,可以获得更好的接头性能,在加2 M Pa压力,853 K保温120 m in连接时接头剪切强度可达169.1 M Pa,约为母材强度的81.7%.展开更多
文摘Cs0.35V2O5 was successfully synthesized as cathode material for lithium secondary battery by the rheological phase reaction method from Cs2CO3 and NH4VO3. The Cs0.35V2O5/Cu composite material was prepared by the displacement reaction in CuSO4 solution using zinc powder as a reductant. The structure and electrochemical property of the so-prepared powders were characterized by means of XRD （powder X-ray diffraction） and the galvanostatic discharge-charge techniques. The results show that the electrochemical property of Cs0.35V2O5/Cu composite material is significantly improved compared to the bulk Cs0.35V2O5 material. The Cs0.35V2O5/Cu composite material exhibits the first discharge capacity as high as 164.3 mAh.g -1 in the range of 4.2-1.8V at a current rate of 10 mA.g-1 and remains at a stable discharge capacity of about 110 mAh.g-1 within 40 cycles.
基金This work is financially supported by the National Natural Science Foundation of China(No.50171025)
文摘Through the vacuum diffusion welding SiCp/ZL 101 aluminum with Cu interlayer,the effect of welding parameter and the thickness of Cu on the welded joint property wasinvestigated, and the optimal welding parameters were put forward at the same time. Themicrostructure of joint was analyzed by means of optical-microscope, scanning electron microscope inorder to study the relationship between the macro-properties of joint and the microstructure. Theresults show that diffusion welding with Cu interlayer could be used for welding aluminum matrixcomposites SiCp/ZL 101 successfully.
基金This study is supported by Innovation and Technology Fund(ITP/045/19AP)Guangdong Academy of Science Fund(2020GDASYL-20200101001,2021GDASYL-20210102002)+2 种基金National Natural Science Foundation of China(51905111)Guangdong Basic and Applied Basic Research Project(2020B0301030006,2021A1515011730)International Science and Technology Cooperation Project of Guangdong Province(2021A0505030051).
文摘The feasibility of preparing Fe/Cu composite sheet was achieved by introducing submillimeter thickness Al sheet as an interlayer by rolling at room temperature.The shear test of the composite sheet supported that the metallurgical bonding strength between Fe/(Al)/Cu interface was stronger than that of Cu sheet at the initial state.With further 300 or 600℃ annealing treatments,the interlayer subsequently exhibited brittle shear fracture,and the shear strength significantly dropped under the shear test.Furthermore,the tensile test pointed out that the tensile fracture mechanism changed from fracture as a whole structure to interlayer-to-layer delamination mode after annealing treatment.The microstructure and X-ray diffraction observations proved that the formation of Cu–Al intermetallic compounds(IMCs)along the interlayer resulted in brittle fracture,rather than that of Fe–Al IMCs after annealing,especially under 600℃ annealing treatment.The investigation of the effect of the rolling process and annealing treatment on the mechanical properties of the Fe/(Al)/Cu composite sheet shall provide instruction for high-quality composite metallic sheet fabrication.
文摘采用2~5 mm厚的纯V与纯Cu组成复合过渡段,进行了TA2与304不锈钢的激光焊接试验,测试了接头的拉伸强度,利用金相显微镜、扫描电镜以及能谱仪对连接界面处元素扩散、接头断口形貌进行了分析。结果表明,采用加入2~5 mm V/Cu复合过渡段进行TA2和304不锈钢的激光焊接时,可以获得连接良好、无裂纹的焊接接头。中间过渡段越厚,接头抗拉强度越大,加入5 mm V/Cu复合过渡段时,接头平均抗拉强度最高达297 MPa,断裂发生在Cu过渡段内,属韧性断裂。
文摘分别采用Cu箔和Cu膜作为中间层,在853 K保温情况下进行了S iC颗粒增强铝基复合材料的瞬间液相扩散连接试验.用金相显微镜、扫描电镜、能谱仪、X射线衍射仪和拉伸试验机研究了表面状态、保温时间和压力对接头显微组织和性能的影响.结果表明:合适的压力和中间层厚度能有效改善接头的组织和力学性能,接头剪切强度随保温时间延长而提高.表面状态对接头强度有较大影响.采用Cu膜作中间层由于没有氧化膜的影响,可以获得更好的接头性能,在加2 M Pa压力,853 K保温120 m in连接时接头剪切强度可达169.1 M Pa,约为母材强度的81.7%.
