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金属热还原法制备V-Ti基合金的动力学研究 被引量:1
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作者 王斌 杜金晶 +2 位作者 刘奎仁 朱军 李林波 《中南大学学报(自然科学版)》 EI CAS CSCD 北大核心 2016年第11期3635-3641,共7页
采用DSC测试技术对金属热还原不同反应体系的放热过程进行研究,并采用Freeman-Carroll法,对相关反应的动力学参数进行计算。研究结果表明:Al与V_2O_5的反应主要为液-液反应,在1 000℃以下就可进行;Al与TiO_2可以以液-固形式反应,但在1 ... 采用DSC测试技术对金属热还原不同反应体系的放热过程进行研究,并采用Freeman-Carroll法,对相关反应的动力学参数进行计算。研究结果表明:Al与V_2O_5的反应主要为液-液反应,在1 000℃以下就可进行;Al与TiO_2可以以液-固形式反应,但在1 100℃以上时,反应才显著发生;以Al-Ca合金替代Al粉作为还原剂,可以促进热还原反应提前发生,但钙热反应先于铝热反应出现;Al与TiO_2反应的活化能明显高于Al与V_2O_5反应的活化能,反应速率受温度的影响更大;原料中添加一定量Ca O,可以促进Al与TiO_2反应的发生,降低此反应的活化能,但会增加Al与V_2O_5反应的活化能。 展开更多
关键词 v-ti基合金 金属热还原法 动力学
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Microstructural aspects of in-situ TiB reinforced Ti-6Al-4V composite processed by spark plasma sintering 被引量:4
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作者 Saeid GHESMATI TABRIZI Abolfazl BABAKHANI +1 位作者 Seyed Abdolkarim SAJJADI 吕维洁 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第5期1460-1467,共8页
Titanium-matrix composites have important and wide applications in the transport and aerospace industries. The current research was focused on powder metallurgy processing of in-situ reinforced titanium-matrix composi... Titanium-matrix composites have important and wide applications in the transport and aerospace industries. The current research was focused on powder metallurgy processing of in-situ reinforced titanium-matrix composite with Ti B whiskers. The Ti-6Al-4V alloy and B4 C additive powders were used as raw materials. Two different consolidation techniques, namely press-and-sintering and spark plasma sintering, were selected. It was observed that in-situ Ti B whiskers were formed during sintering in both methods. The changes in size, aspect ratio and distribution of in-situ whiskers in different composite samples were monitored. The effect of spark plasma sintering temperature on the synthesis of in-situ whiskers was also investigated. Based on the microstructural observations(optical microscopy and scanning electron microscopy) and the energy dispersive spectroscopy analysis, it was concluded that increasing the spark plasma sintering temperature from 900 to 1100 °C would lead to the complete formation of in-situ Ti B whiskers and reduced porosity content. 展开更多
关键词 Ti-6Al-4V metal matrix composite TiB whisker in-situ reaction spark plasma sintering
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