Kenics static mixers(KSM)are extensively used in industrial mixing-reaction processes by virtue of high mixing efficiency,low power homogenization and easy continuous production.Resolving liquid droplet size and its d...Kenics static mixers(KSM)are extensively used in industrial mixing-reaction processes by virtue of high mixing efficiency,low power homogenization and easy continuous production.Resolving liquid droplet size and its distribution and thus revealing the dispersion characteristics are of great significance for structural optimization and process intensification in the KSM.In this work,a computational fluid dynamics-population balance model(CFD-PBM)coupled method is employed to systematically investigate the effects of operating conditions and structural parameters of KSM on droplet size and its distribution,to further reveal the liquid-liquid dispersion characteristics.Results indicate that higher Reynolds numbers or higher dispersed phase volume fractions increase energy dissipation,reducing Sauter mean diameter(SMD)of dispersed phase droplets and with a shift in droplet size distribution(DSD)towards smaller size.Smaller aspect ratios,greater blade twist and assembly angles amplify shear rate,leading to smaller droplet size and a narrower DSD in the smaller range.The degree of impact exerted by the aspect ratio is notably greater.Notably,mixing elements with different spin enhance shear and stretching efficiency.Compared to the same spin,SMD becomes 3.7-5.8 times smaller in the smaller size range with a significantly narrower distribution.Taking into account the pressure drop and efficiency in a comprehensive manner,optimized structural parameters for the mixing element encompass an aspect ratio of 1-1.5,a blade twist angle of 180°,an assembly angle of 90°,and interlaced assembly of adjacent elements with different spin.This work provides vital theoretical underpinning and future reference for enhancing KSM performance.展开更多
Two types of tightly coupled Selective Catalytic Reduction(SCR)mixers were designed in this study,namely Mixer 1 integrated with an SCR catalyst and Mixer 2 arranged separately.Computational Fluid Dynamics(CFD)softwar...Two types of tightly coupled Selective Catalytic Reduction(SCR)mixers were designed in this study,namely Mixer 1 integrated with an SCR catalyst and Mixer 2 arranged separately.Computational Fluid Dynamics(CFD)software was utilized to model the gas flow,spraying,and pyrolysis reaction of the aqueous urea solution in the tightly coupled SCR system.The parameters of gas flow velocity uniformity and ammonia distribution uniformity were simulated and calculated for both Mixer 1 and Mixer 2 in the tightly coupled SCR system to compare their advantages and disadvantages.The simulation results indicated that Mixer 1 exhibited a gas velocity uniformity of 0.972 and an ammonia distribution uniformity of 0.817,whereas Mixer 2 demonstrated a gas velocity uniformity of 0.988 and an ammonia distribution uniformity of 0.964.Mixer 2 performed better in the simulation analysis.Furthermore,a 3D-printed prototype of Mixer 2 was manufactured and installed on an engine test bench to investigate ammonia distribution uniformity and NOX conversion efficiency.The experimental investigations yielded the following findings:1)The ammonia distribution uniformity of Mixer 2 was measured as 0.976,which closely aligned with the simulation result of 0.964,with a deviation of 1.2%from the model calculations;2)As exhaust temperature increased,the ammonia distribution uniformity gradually improved,while an increase in exhaust flow rate resulted in a decrease in ammonia distribution uniformity;3)When utilizing Mixer 2,the NOX conversion efficiency reached 84.7%at an exhaust temperature of 200°C and 97.4%at 250°C.Within the exhaust temperature range of 300°C to 450°C,the NOX conversion efficiency remained above 98%.This study proposed two innovative mixer structures,conducted simulation analysis,and performed performance testing.The research outcomes indicated that the separately arranged Mixer 2 exhibited superior performance.The tightly coupled SCR systemequippedwith Mixer 2 achieved excellent levels of gas velocity uniformity,ammonia distribution uniformity,and NOX conversion efficiency.These findings can serve as valuable references for the design and development of ultra-low emission after-treatment systems for diesel engines in the field of diesel engine aftertreatment.展开更多
The terahertz band,a unique segment of the electromagnetic spectrum,is crucial for observing the cold,dark universe and plays a pivotal role in cutting-edge scientific research,including the study of cosmic environmen...The terahertz band,a unique segment of the electromagnetic spectrum,is crucial for observing the cold,dark universe and plays a pivotal role in cutting-edge scientific research,including the study of cosmic environments that support life and imaging black holes.High-sensitivity superconductor–insulator–superconductor(SIS)mixers are essential detectors for terahertz astronomical telescopes and interferometric arrays.Compared to the commonly used classical Nb/AlO_(x)/Nb superconducting tunnel junction,the Nb/AlN/NbN hybrid superconducting tunnel junction has a higher energy gap voltage and can achieve a higher critical current density.This makes it particularly promising for the development of ultra-wideband,high-sensitivity coherent detectors or mixers in various scientific research fields.In this paper,we present a superconducting SIS mixer based on Nb/AlN/NbN parallel-connected twin junctions(PCTJ),which has a bandwidth extending up to490 GHz–720 GHz.The best achieved double-sideband(DSB)noise temperature(sensitivity)is below three times the quantum noise level.展开更多
The proper selection of a relevant mixer generally requires an effective assessment of several models against theapplication requirements. This is a complex task, as traditional evaluation methods generally focus only...The proper selection of a relevant mixer generally requires an effective assessment of several models against theapplication requirements. This is a complex task, as traditional evaluation methods generally focus only on a single aspect of performance, such as pressure loss, mixing characteristics, or heat transfer. This study assesses aurea-based selective catalytic reduction (SCR) system installed on a ship, where the installation space is limitedand the distance between the urea aqueous solution injection position and the reactor is low;therefore, the staticmixer installed in this pipeline has special performance requirements. In particular, four evaluation indices areused in this study: The B value, C value, pressure loss correction factor (Z′), and the ratio of the required distanceto the equivalent diameter of the pipe (LV/D) when the velocity field after the mixer attains uniformity. Six typesof static mixers were simulated with varying concentrations, flow speeds, and positions. A fuzzy comprehensiveevaluation method was introduced to evaluate and compare the related advantages and disadvantages. The resultsshowed that 1) mixing performance was related to the shape of the mixer and had no direct relationship with flowvelocity. 2) For the same mixer position, the lower the urea concentration, the greater the difficulty of evenly mixing the solution. 3) At a constant urea concentration, the mixing performance improved when the mixer was closer to the injection inlet. 4) The installation of a GK mixer in the SCR system of a 9L20C diesel engine was best.展开更多
Multi-orifice cross-flow jet mixers(MOCJMs)are used in various industrial applications due to their excellent mixing efficiency,but few studies have focused on the micromixing performance of MOCJMs.Herein,the flow cha...Multi-orifice cross-flow jet mixers(MOCJMs)are used in various industrial applications due to their excellent mixing efficiency,but few studies have focused on the micromixing performance of MOCJMs.Herein,the flow characteristics and micromixing performance inside the MOCJM were investigated using experiments and computational fluid dynamics(CFD)simulations based on the Villermaux/Dushman system and the finite-rate/modified eddy-dissipation model.The optimal A value was correlated with the characteristic parameters of MOCJMs to develop a CFD calculation method applicable to the study of the micromixing performance of the MOCJMs.Then the micromixing efficiency was evaluated using the segregation index XS,and the effects of operational and geometric parameters such as mixing flow Reynolds number(ReM),flow ratio(RF),total jet area(ST),the number of jet orifices(n),and outlet configuration on the micromixing efficiency were investigated.It was found that the intensive turbulent region generated by interactions between jets,as well as between jets and crossflows,facilitated rapid reactions.XS decreased with increasing ReM and decreasing RF.Furthermore,MOCJMs with lower ST,four jet orifices,and the narrower outlet configuration demonstrated a better micromixing efficiency.This study contributes to a deeper understanding of the micromixing performance of MOCJMs and provides valuable guidance for their design,optimization,and industrial application.展开更多
This work aims to systematically study hydrodynamics and mixing characteristics of non-Newtonian fluid(carboxyl methyl cellulose,CMC)in dual shaft eccentric mixer.Fluid rheology was described by the power law rheologi...This work aims to systematically study hydrodynamics and mixing characteristics of non-Newtonian fluid(carboxyl methyl cellulose,CMC)in dual shaft eccentric mixer.Fluid rheology was described by the power law rheological model.Computational fluid dynamics was employed to simulate the velocity field and shear rate inside the stirred tank.The influence mechanism of the rotational modes,height difference between impellers,impeller eccentricities,and impeller types on the flow field have been well investigated.We studied the performance of different dual-shaft eccentric mixers at the constant power input with its fluid velocity profiles,average shear strain rate,mixing time and mixing energy.The counter-rotation mode shows better mixing performance than co-rotation mode,and greater eccentricity can shorten mixing time on the basis of same stirred condition.To intensify the hydrodynamic interaction between impellers and enhance the overall mixing performance of the dual shaft eccentric mixers,it is critical to have a reasonable combination of impellers and an appropriate spatial position of impellers.展开更多
Aroma compounds are low-molecular-weight organic volatile molecules and are broadly utilized in the food industry.However,due to their high volatility and evaporative losses during processing and storage,the stabiliza...Aroma compounds are low-molecular-weight organic volatile molecules and are broadly utilized in the food industry.However,due to their high volatility and evaporative losses during processing and storage,the stabilization of these volatile ingredients using encapsulation is a commonly investigated practice.Complexation of aroma compounds using starch inclusion complex could be a potential approach due to the hydrophobicity of the left-handed single helical structure.In the present study,we used starch of three different V-type structures,namely V,V,and V,to encapsulate six different aroma compounds,including1-decanol(DN),cis-3-hexen-1-ol(HN),4-allylanisole(AN),γ-decalactone(DA),trans-cinnamaldehyde(CA),and citral(CT).The formed inclusion complexes samples were characterized using complementary techniques,including X-ray diffraction(XRD)and differential scanning calorimetry(DSC).The results showed that upon complexation with aroma compounds,all V-subtypes retained their original crystalline structures.However,different trends of crystallinity were observed for each type of the prepared inclusion complexes.Additionally,among three V-type starches,V-type starch formed inclusion complexes with aroma compounds most efficiently and promoted the formation of FormⅡcomplex.This study suggested that the structure of aroma compounds and the type of V starch could both affect the complexation properties.展开更多
Numerous studies have been conducted on microfluidic mixers in various microanalysis systems, which elucidated the manipulation and control of small fluid volumes within microfluidic chips. These studies have demonstr...Numerous studies have been conducted on microfluidic mixers in various microanalysis systems, which elucidated the manipulation and control of small fluid volumes within microfluidic chips. These studies have demonstrated the ability to control fluids and samples precisely at the microscale. Microfluidic mixers provide high sensitivity for biochemical analysis due to their small volumes and high surface-to-volume ratios. A promising approach in drug delivery is the rapid microfluidic mixer-based extraction of elemental iodine at the micro level, demonstrating the versatility and the potential to enhance diagnostic imaging and accuracy in targeted drug delivery. Micro-mixing inside microfluidic chips plays a key role in biochemical analysis. The experimental study describes a microfluidic mixer for extraction of elemental iodine using carbon tetrachloride with a gas bubble mixing process. Gas bubbles are generated inside the microcavity to create turbulence and micro-vortices resulting in uniform mixing of samples. The bubble mixing of biochemical samples is analyzed at various pressure levels to validate the simulated results in computational fluid dynamics(CFD). The experimental setup includes a high-resolution camera and an air pump to observe the mixing process and volume at different pressure levels with time. The bubble formation is controlled by adjusting the inert gas flow inside the microfluidic chip. Microfluidic chip-based gas bubble mixing effects have been elaborated at various supplied pressures.展开更多
基金supported by the National Natural Science Foundation of China(22078278)Hunan Innovative Talent Project(2022RC1111)+2 种基金Hunan Provincial Education Bureau Foundation(22A0131)Hunan Province Higher Education Key Laboratory of Green Catalysis and Industrial Reaction Process IntensificationFurong Plan Provincial Enterprise Technology Innovation and Entrepreneurship Team.
文摘Kenics static mixers(KSM)are extensively used in industrial mixing-reaction processes by virtue of high mixing efficiency,low power homogenization and easy continuous production.Resolving liquid droplet size and its distribution and thus revealing the dispersion characteristics are of great significance for structural optimization and process intensification in the KSM.In this work,a computational fluid dynamics-population balance model(CFD-PBM)coupled method is employed to systematically investigate the effects of operating conditions and structural parameters of KSM on droplet size and its distribution,to further reveal the liquid-liquid dispersion characteristics.Results indicate that higher Reynolds numbers or higher dispersed phase volume fractions increase energy dissipation,reducing Sauter mean diameter(SMD)of dispersed phase droplets and with a shift in droplet size distribution(DSD)towards smaller size.Smaller aspect ratios,greater blade twist and assembly angles amplify shear rate,leading to smaller droplet size and a narrower DSD in the smaller range.The degree of impact exerted by the aspect ratio is notably greater.Notably,mixing elements with different spin enhance shear and stretching efficiency.Compared to the same spin,SMD becomes 3.7-5.8 times smaller in the smaller size range with a significantly narrower distribution.Taking into account the pressure drop and efficiency in a comprehensive manner,optimized structural parameters for the mixing element encompass an aspect ratio of 1-1.5,a blade twist angle of 180°,an assembly angle of 90°,and interlaced assembly of adjacent elements with different spin.This work provides vital theoretical underpinning and future reference for enhancing KSM performance.
文摘Two types of tightly coupled Selective Catalytic Reduction(SCR)mixers were designed in this study,namely Mixer 1 integrated with an SCR catalyst and Mixer 2 arranged separately.Computational Fluid Dynamics(CFD)software was utilized to model the gas flow,spraying,and pyrolysis reaction of the aqueous urea solution in the tightly coupled SCR system.The parameters of gas flow velocity uniformity and ammonia distribution uniformity were simulated and calculated for both Mixer 1 and Mixer 2 in the tightly coupled SCR system to compare their advantages and disadvantages.The simulation results indicated that Mixer 1 exhibited a gas velocity uniformity of 0.972 and an ammonia distribution uniformity of 0.817,whereas Mixer 2 demonstrated a gas velocity uniformity of 0.988 and an ammonia distribution uniformity of 0.964.Mixer 2 performed better in the simulation analysis.Furthermore,a 3D-printed prototype of Mixer 2 was manufactured and installed on an engine test bench to investigate ammonia distribution uniformity and NOX conversion efficiency.The experimental investigations yielded the following findings:1)The ammonia distribution uniformity of Mixer 2 was measured as 0.976,which closely aligned with the simulation result of 0.964,with a deviation of 1.2%from the model calculations;2)As exhaust temperature increased,the ammonia distribution uniformity gradually improved,while an increase in exhaust flow rate resulted in a decrease in ammonia distribution uniformity;3)When utilizing Mixer 2,the NOX conversion efficiency reached 84.7%at an exhaust temperature of 200°C and 97.4%at 250°C.Within the exhaust temperature range of 300°C to 450°C,the NOX conversion efficiency remained above 98%.This study proposed two innovative mixer structures,conducted simulation analysis,and performed performance testing.The research outcomes indicated that the separately arranged Mixer 2 exhibited superior performance.The tightly coupled SCR systemequippedwith Mixer 2 achieved excellent levels of gas velocity uniformity,ammonia distribution uniformity,and NOX conversion efficiency.These findings can serve as valuable references for the design and development of ultra-low emission after-treatment systems for diesel engines in the field of diesel engine aftertreatment.
基金Project supported in part by the National Key Research and Development Program of China(Grant Nos.2023YFA1608201 and 2023YFF0722301)the National Natural Science Foundation of China(Grant Nos.11925304,12020101002,12333013,12273119,and 12103093)supported by grant from the Russian Science Foundation(Grant No.23-7900019)。
文摘The terahertz band,a unique segment of the electromagnetic spectrum,is crucial for observing the cold,dark universe and plays a pivotal role in cutting-edge scientific research,including the study of cosmic environments that support life and imaging black holes.High-sensitivity superconductor–insulator–superconductor(SIS)mixers are essential detectors for terahertz astronomical telescopes and interferometric arrays.Compared to the commonly used classical Nb/AlO_(x)/Nb superconducting tunnel junction,the Nb/AlN/NbN hybrid superconducting tunnel junction has a higher energy gap voltage and can achieve a higher critical current density.This makes it particularly promising for the development of ultra-wideband,high-sensitivity coherent detectors or mixers in various scientific research fields.In this paper,we present a superconducting SIS mixer based on Nb/AlN/NbN parallel-connected twin junctions(PCTJ),which has a bandwidth extending up to490 GHz–720 GHz.The best achieved double-sideband(DSB)noise temperature(sensitivity)is below three times the quantum noise level.
基金wasfinancially aided by the National Natural Science Foundation of China(52276122).
文摘The proper selection of a relevant mixer generally requires an effective assessment of several models against theapplication requirements. This is a complex task, as traditional evaluation methods generally focus only on a single aspect of performance, such as pressure loss, mixing characteristics, or heat transfer. This study assesses aurea-based selective catalytic reduction (SCR) system installed on a ship, where the installation space is limitedand the distance between the urea aqueous solution injection position and the reactor is low;therefore, the staticmixer installed in this pipeline has special performance requirements. In particular, four evaluation indices areused in this study: The B value, C value, pressure loss correction factor (Z′), and the ratio of the required distanceto the equivalent diameter of the pipe (LV/D) when the velocity field after the mixer attains uniformity. Six typesof static mixers were simulated with varying concentrations, flow speeds, and positions. A fuzzy comprehensiveevaluation method was introduced to evaluate and compare the related advantages and disadvantages. The resultsshowed that 1) mixing performance was related to the shape of the mixer and had no direct relationship with flowvelocity. 2) For the same mixer position, the lower the urea concentration, the greater the difficulty of evenly mixing the solution. 3) At a constant urea concentration, the mixing performance improved when the mixer was closer to the injection inlet. 4) The installation of a GK mixer in the SCR system of a 9L20C diesel engine was best.
基金the financial support from the Shanghai Sailing Program,China(21YF1409500)the National Natural Science Foundation of China(22308100,22308105)+1 种基金the State Key Laboratory of Chemical Engineering(SKL-ChE-23Z01)the National Science Fund for Distinguished Young Scholars of China(22225804).
文摘Multi-orifice cross-flow jet mixers(MOCJMs)are used in various industrial applications due to their excellent mixing efficiency,but few studies have focused on the micromixing performance of MOCJMs.Herein,the flow characteristics and micromixing performance inside the MOCJM were investigated using experiments and computational fluid dynamics(CFD)simulations based on the Villermaux/Dushman system and the finite-rate/modified eddy-dissipation model.The optimal A value was correlated with the characteristic parameters of MOCJMs to develop a CFD calculation method applicable to the study of the micromixing performance of the MOCJMs.Then the micromixing efficiency was evaluated using the segregation index XS,and the effects of operational and geometric parameters such as mixing flow Reynolds number(ReM),flow ratio(RF),total jet area(ST),the number of jet orifices(n),and outlet configuration on the micromixing efficiency were investigated.It was found that the intensive turbulent region generated by interactions between jets,as well as between jets and crossflows,facilitated rapid reactions.XS decreased with increasing ReM and decreasing RF.Furthermore,MOCJMs with lower ST,four jet orifices,and the narrower outlet configuration demonstrated a better micromixing efficiency.This study contributes to a deeper understanding of the micromixing performance of MOCJMs and provides valuable guidance for their design,optimization,and industrial application.
基金supported by the National Natural Science Foundation of China(22078030,52021004)National Natural Science Foundation of Chongqing(2022NSCQ-LZX0271)+2 种基金Fundamental Research Funds for the Central Universities(2022CDJQY-005)National Key Research and Development Project(2019YFC1905802,2022YFC3901204)Key Project of Independent Research Project of State Key Laboratory of coal mine disaster dynamics and control(2011DA105287-zd201902).
文摘This work aims to systematically study hydrodynamics and mixing characteristics of non-Newtonian fluid(carboxyl methyl cellulose,CMC)in dual shaft eccentric mixer.Fluid rheology was described by the power law rheological model.Computational fluid dynamics was employed to simulate the velocity field and shear rate inside the stirred tank.The influence mechanism of the rotational modes,height difference between impellers,impeller eccentricities,and impeller types on the flow field have been well investigated.We studied the performance of different dual-shaft eccentric mixers at the constant power input with its fluid velocity profiles,average shear strain rate,mixing time and mixing energy.The counter-rotation mode shows better mixing performance than co-rotation mode,and greater eccentricity can shorten mixing time on the basis of same stirred condition.To intensify the hydrodynamic interaction between impellers and enhance the overall mixing performance of the dual shaft eccentric mixers,it is critical to have a reasonable combination of impellers and an appropriate spatial position of impellers.
基金funded by the USDA National Institute of Food and Agriculture,Agriculture and Food Research Initiative Program,Competitive Grants Program award from the Improving Food Quality(A1361)program FY 2018 as grant#2018-67017-27558。
文摘Aroma compounds are low-molecular-weight organic volatile molecules and are broadly utilized in the food industry.However,due to their high volatility and evaporative losses during processing and storage,the stabilization of these volatile ingredients using encapsulation is a commonly investigated practice.Complexation of aroma compounds using starch inclusion complex could be a potential approach due to the hydrophobicity of the left-handed single helical structure.In the present study,we used starch of three different V-type structures,namely V,V,and V,to encapsulate six different aroma compounds,including1-decanol(DN),cis-3-hexen-1-ol(HN),4-allylanisole(AN),γ-decalactone(DA),trans-cinnamaldehyde(CA),and citral(CT).The formed inclusion complexes samples were characterized using complementary techniques,including X-ray diffraction(XRD)and differential scanning calorimetry(DSC).The results showed that upon complexation with aroma compounds,all V-subtypes retained their original crystalline structures.However,different trends of crystallinity were observed for each type of the prepared inclusion complexes.Additionally,among three V-type starches,V-type starch formed inclusion complexes with aroma compounds most efficiently and promoted the formation of FormⅡcomplex.This study suggested that the structure of aroma compounds and the type of V starch could both affect the complexation properties.
基金Project supported by the National Natural Science Foundation of China (Grant No. 51175101)。
文摘Numerous studies have been conducted on microfluidic mixers in various microanalysis systems, which elucidated the manipulation and control of small fluid volumes within microfluidic chips. These studies have demonstrated the ability to control fluids and samples precisely at the microscale. Microfluidic mixers provide high sensitivity for biochemical analysis due to their small volumes and high surface-to-volume ratios. A promising approach in drug delivery is the rapid microfluidic mixer-based extraction of elemental iodine at the micro level, demonstrating the versatility and the potential to enhance diagnostic imaging and accuracy in targeted drug delivery. Micro-mixing inside microfluidic chips plays a key role in biochemical analysis. The experimental study describes a microfluidic mixer for extraction of elemental iodine using carbon tetrachloride with a gas bubble mixing process. Gas bubbles are generated inside the microcavity to create turbulence and micro-vortices resulting in uniform mixing of samples. The bubble mixing of biochemical samples is analyzed at various pressure levels to validate the simulated results in computational fluid dynamics(CFD). The experimental setup includes a high-resolution camera and an air pump to observe the mixing process and volume at different pressure levels with time. The bubble formation is controlled by adjusting the inert gas flow inside the microfluidic chip. Microfluidic chip-based gas bubble mixing effects have been elaborated at various supplied pressures.