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Polyamide-6 Polymerization in the VK Tube Reactor with Baffle Structure
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作者 王夏琴 唐志廉 《Journal of Donghua University(English Edition)》 EI CAS 2002年第1期25-29,共5页
The melt flow mechanism of polyamide-6 (PA6) was simulated with the mathematical flow model and tested by Particle Image Velotrimitry (PIV). The complete mathematical model for PA6 polymerization while flowing through... The melt flow mechanism of polyamide-6 (PA6) was simulated with the mathematical flow model and tested by Particle Image Velotrimitry (PIV). The complete mathematical model for PA6 polymerization while flowing through the VK tube reactor was established according to PA6 hydrolytic polymerization kinetics. The characteristic data such as residence time, caprolactam conversion and the degree of polymerization (D. P.), at every stage of polymerization reaction and at every point of the VK tube were presented for the melt flowing through ten alternate conical baffles in VK tube. 展开更多
关键词 vk tube pa6 polymerization characteristic data.
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具有优化的斜挡板内部结构的VK管中尼龙6聚合反应的数学模拟研究
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作者 王夏琴 沈沅 《中国纺织大学学报》 CSCD 1998年第5期14-17,26,共5页
在尼龙6水解聚合数学模型得到实验验证的基础上,模拟熔体流过VK管10块挡板的过程中单体的转化率、产物的聚合度、环状二聚体的含量、大分子的端基浓度、相对分子质量多分散性指数等重要质量指标随时间和位置的变化规律,从聚合指标的计... 在尼龙6水解聚合数学模型得到实验验证的基础上,模拟熔体流过VK管10块挡板的过程中单体的转化率、产物的聚合度、环状二聚体的含量、大分子的端基浓度、相对分子质量多分散性指数等重要质量指标随时间和位置的变化规律,从聚合指标的计算结果反证挡板结构的合理性. 展开更多
关键词 vk 尼龙6 水解聚合 质量指标 聚合反应 斜挡板
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