Single phases of LnAlO 3:Eu 3+ (Ln=Gd,Y) were obtained by the process of evaporation of their nitric acid solution, and then pyrolysis of their nitrate salts. On monitoring by 613 nm emission, broad bands at around ...Single phases of LnAlO 3:Eu 3+ (Ln=Gd,Y) were obtained by the process of evaporation of their nitric acid solution, and then pyrolysis of their nitrate salts. On monitoring by 613 nm emission, broad bands at around 270 and 170 nm were observed in the excitation spectrum of Gd 0.95Eu 0.05AlO 3. These peaks could be assigned to charge transfer (CT) transitions of Eu 3+-O 2- and Gd 3+-O 2- respectively. All the transitions observed in Gd 0.95Eu 0.05AlO 3 are faithfully reproduced in the Y 0.95Eu 0.05AlO 3, but with an exception of the 8S 7/2→ 6I 11/2 transition of Gd 3+. The 153 nm broad band could be the CT transition of Y 3+-O 2-. Accordingly, the efficiency luminescence of (Gd,Y)BO 3:Eu 3+ was explained as a result of CT transitions of Gd 3+-O 2- and Y 3+-O 2- under 147 nm excitation. Under VUV excitation, Gd 0.95Eu 0.05AlO 3 exhibits a bright red luminescence with CIE chromaticity coordinates of (0.623, 0.335) with a PL intensity of 30 of the commercial phosphor (Gd,Y)BO 3:Eu 3+ (KX-504A). The PL spectrum of Y 0.95Eu 0.05AlO 3 is similar to that of Gd 0.95Eu 0.05AlO 3. Calculation of the color coordinates gives x=0.636, y=0.340 with a PL intensity of 50 of the (Gd,Y)BO 3:Eu 3+ (KX-504A) for Y 0.95Eu 0.05AlO 3, and confirms that it has the appearance of pure spectral red, corresponding approximately to 608 nm. It can be concluded that LnAlO 3:Eu 3+ is a promising red VUV phosphor.展开更多
文摘Single phases of LnAlO 3:Eu 3+ (Ln=Gd,Y) were obtained by the process of evaporation of their nitric acid solution, and then pyrolysis of their nitrate salts. On monitoring by 613 nm emission, broad bands at around 270 and 170 nm were observed in the excitation spectrum of Gd 0.95Eu 0.05AlO 3. These peaks could be assigned to charge transfer (CT) transitions of Eu 3+-O 2- and Gd 3+-O 2- respectively. All the transitions observed in Gd 0.95Eu 0.05AlO 3 are faithfully reproduced in the Y 0.95Eu 0.05AlO 3, but with an exception of the 8S 7/2→ 6I 11/2 transition of Gd 3+. The 153 nm broad band could be the CT transition of Y 3+-O 2-. Accordingly, the efficiency luminescence of (Gd,Y)BO 3:Eu 3+ was explained as a result of CT transitions of Gd 3+-O 2- and Y 3+-O 2- under 147 nm excitation. Under VUV excitation, Gd 0.95Eu 0.05AlO 3 exhibits a bright red luminescence with CIE chromaticity coordinates of (0.623, 0.335) with a PL intensity of 30 of the commercial phosphor (Gd,Y)BO 3:Eu 3+ (KX-504A). The PL spectrum of Y 0.95Eu 0.05AlO 3 is similar to that of Gd 0.95Eu 0.05AlO 3. Calculation of the color coordinates gives x=0.636, y=0.340 with a PL intensity of 50 of the (Gd,Y)BO 3:Eu 3+ (KX-504A) for Y 0.95Eu 0.05AlO 3, and confirms that it has the appearance of pure spectral red, corresponding approximately to 608 nm. It can be concluded that LnAlO 3:Eu 3+ is a promising red VUV phosphor.
