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Review on thermochromic vanadium dioxide based smart coatings: from lab to commercial application 被引量:6
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作者 Tian-Ci Chang Xun Cao +3 位作者 Shan-Hu Bao Shi-Dong Ji Hong-Jie Luo Ping Jin 《Advances in Manufacturing》 SCIE CAS CSCD 2018年第1期1-19,共19页
With an urgent demand of energy efficientcoatings for building fenestrations, vanadium dioxide(VO2)-based thermochromic smart coatings have beenwidely investigated due to the reversible phase transition ofVO2 at a c... With an urgent demand of energy efficientcoatings for building fenestrations, vanadium dioxide(VO2)-based thermochromic smart coatings have beenwidely investigated due to the reversible phase transition ofVO2 at a critical transition temperature of 68 ℃, which isaccompanied by the modulation of solar irradiation, espe-cially in the near-infrared region. As for commercialapplications in our daily life, there are still some obstaclesfor VO2-based smart coatings, such as the high phasetransition temperature, optical properties (luminous trans-mittance and solar modulation ability), environmental sta-bility in a long-time period, as well as mass production. Inthis review, recent progress of thermochromic smart coat-ings to solve above obstacles has been surveyed. Mean-while, future development trends have also been given topromote the goal of commercial production of VO2 smartcoatings. 展开更多
关键词 vanadium dioxide (v02) Thermochromic Multilayer films Nanoparticles Commercial production
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掺锗提高VO_(2)薄膜的相变温度机理研究
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作者 崔景贺 蒋权伟 +1 位作者 高忙忙 梁森 《人工晶体学报》 CAS 北大核心 2022年第4期666-672,共7页
二氧化钒(VO_(2))作为一种长久以来备受关注的新型可逆相变材料,发展潜力巨大,其相变温度(T_(MIT))的调控一直是研究热点。本文主要利用锗离子作为掺杂离子探索其对VO_(2)薄膜T_(MIT)的影响,并尝试解释其内部作用机理。在约1 cm2大小抛... 二氧化钒(VO_(2))作为一种长久以来备受关注的新型可逆相变材料,发展潜力巨大,其相变温度(T_(MIT))的调控一直是研究热点。本文主要利用锗离子作为掺杂离子探索其对VO_(2)薄膜T_(MIT)的影响,并尝试解释其内部作用机理。在约1 cm2大小抛光的氧化铝薄片上沉积了一系列含不同比例锗离子VO_(2)薄膜。研究发现锗离子作为掺杂离子确实有利于T_(MIT)的提高(本课题T_(MIT)最大可达84.7℃)。T_(MIT)提高的主要原因是锗离子的引入能够强化单斜态V-V二聚体的稳定性,进而增强单斜态的稳定性,使得低温单斜态向四方金红石态转变更加困难。 展开更多
关键词 二氧化钒 薄膜 相变温度 二氧化锗 晶格畸变 电学性能 v-v二聚体
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