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Isothermal diffusion of water vapor in unsaturated soils based on Fick’s second law 被引量:7
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作者 LIU Fei-fei MAO Xue-song +3 位作者 ZHANG Jian-xun WU Qian LI Ying-ying XU Cheng 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第7期2017-2031,共15页
In arid regions, water vapor diffusion predominates the total water migration in unsaturated soil, which significantly influences agriculture and engineering applications. With the aim of revealing the diffusion mecha... In arid regions, water vapor diffusion predominates the total water migration in unsaturated soil, which significantly influences agriculture and engineering applications. With the aim of revealing the diffusion mechanism of water vapor in unsaturated soil, a water vapor migration test device was developed to conduct the water vapor migration indoor test. The test results demonstrate that the characteristics of water vapor diffusion in unsaturated soil conformed to Fick’s second law. A mathematical model for water vapor diffusion under isothermal conditions in unsaturated soil was established based on Fick’s law. Factors including the initial moisture content gradient, initial moisture content distribution, soil type and temperature that affect the water vapor diffusion coefficient were analyzed. The results show that there was good agreement between the moisture content calculated by the mathematical model and obtained by the indoor experiment. The vapor diffusion coefficient increased with increasing initial moisture content gradient and temperature. When the initial moisture content gradient is constant, the vapor diffusion coefficient increases with the increase of matrix suction ratio in dry and wet soil section. The effect of soil type on the water vapor diffusion coefficient was complex, as both the moisture content and soil particle sizes affected the water vapor diffusion. 展开更多
关键词 water vapor diffusion coefficient unsaturated soil mathematical model initial moisture content gradient initial moisture content distribution soil type TEMPERATURE
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非传统稳定同位素分馏理论及计算 被引量:9
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作者 刘耘 《地学前缘》 EI CAS CSCD 北大核心 2015年第5期1-28,共28页
综述了稳定同位素平衡和动力学分馏的一些主要的理论方法。首先介绍了平衡分馏的理论方法,从平衡分馏的核心理论—Bigeleisen-Mayer公式(或称Urey模型)以及对它的一些高级能量校正开始,介绍了基于路径积分的分子动力学方法和蒙特卡罗方... 综述了稳定同位素平衡和动力学分馏的一些主要的理论方法。首先介绍了平衡分馏的理论方法,从平衡分馏的核心理论—Bigeleisen-Mayer公式(或称Urey模型)以及对它的一些高级能量校正开始,介绍了基于路径积分的分子动力学方法和蒙特卡罗方法对同位素非谐效应的处理,介绍了压力效应的理论计算方法,最后介绍了核体积效应及其理论计算方法,并强调核体积效应是未来重金属同位素研究的重要部分。另外,综述了同位素动力学分馏的主要理论和计算方法,首先介绍了在稳态下因温度梯度引发的同位素分馏,着重介绍了基于局部热力学平衡理论的计算方法和最新结果;然后从如何使用过渡态理论计算化学反应导致的同位素动力学分馏出发,深入介绍了磁同位素效应和由于核体积效应引发的异常同位素动力学分馏;然后对低温下矿物生长的同位素动力学理论模型进行了介绍,尤其是仔细介绍了其中DePaolo的表面动力学模型,并对由吸附和共沉降过程产生的动力学分馏也进行了介绍。最后详细介绍了在气化过程、固体中、高温硅酸洋熔体中由于扩散引起的同位素动力学分馏,以及如何对这些过程进行理论处理,强调了开展固体矿物扩散理论计算的重要性。 展开更多
关键词 平衡分馏 动力学分馏 Bigeleisen-Mayer公式 UREY模型 高级校正 核体积效应 压力效应 磁同位 素效应 表面动力学模型 吸附和共沉降过程 气化过程 扩散同位素效应
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Gray Synthetic Evaluation on Moisture Comfort of Sportswear Fabrics under the Condition of Heavy Sweating
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作者 李敏 刘瑜 张渭源 《Journal of Donghua University(English Edition)》 EI CAS 2007年第1期146-150,共5页
Moisture and water transfer under the condition of heavy sweating are analyzed. Four different experiments are made to test moisture resistance, water-keep, wicking effect and drying ability of samples. Then gray anal... Moisture and water transfer under the condition of heavy sweating are analyzed. Four different experiments are made to test moisture resistance, water-keep, wicking effect and drying ability of samples. Then gray analysis method is introduced to evaluate the comprehensive comfort of these fabrics. Result shows chemical fiber with high moisture transfer performance has advantage in water transfer and diffusion, which is suitable for human under the condition of heavy sweating. Though natural fiber can absorb moisture well, it cannot transfer fluid sweat. Therefore natural fiber fabrics such as cotton, wool are unsuitable to make functional sportswear. 展开更多
关键词 clothing comfort moisture transfer heavy sweating vapor diffusion gray clustering analysis
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