The Boulon Djounga eastern perimeter is part of the Tiawa operating permit of the Société des Mines du Liptako (SML), located in the central southwestern part of Liptako (Niger). In this study, we used field...The Boulon Djounga eastern perimeter is part of the Tiawa operating permit of the Société des Mines du Liptako (SML), located in the central southwestern part of Liptako (Niger). In this study, we used field data, Reverse Circulation (RC) surveys and chemical analyzes of gold to determine the characteristics of gold and its mineralization style. The eastern perimeter of Boulon Djounga is represented by a succession of metabasalts and metasediments both intersected by intrusions of quartz and dolerite dykes, and covered by sandstone and clayey rocks. Gold is present in low contents (0.00 - 0.30 ppm) in the sedimentary cover and in medium (0.30 - 1.00 ppm) or high contents (1.00 - 4.534 ppm) in the metasediments, and in the gray quartz veins and locally in the volcanics. It exists in a disseminated state or in a concentrated state in the surrounding areas in the form of discrete grains associated with sulphurous minerals (pyrite: FeS<sub>2</sub>, chalcopyrite: CuFeS<sub>2</sub> or arsenopyrite: FeAsS). The presence of gold in the quartz veins, and the NE-SW and NW-SE orientations of the ore bodies suggest that the eastern Boulon Djounga gold mineralization would be established during a late magmatic extensive phase.展开更多
The Penjom Gold Mine is located 30 km from the Bentong-Raub Suture at the western boundary of the Central Belt in Peninsular Malaysia. Gold mineralization hosted within the vein system is associated with pyrite, arsen...The Penjom Gold Mine is located 30 km from the Bentong-Raub Suture at the western boundary of the Central Belt in Peninsular Malaysia. Gold mineralization hosted within the vein system is associated with pyrite, arsenopyrite, and minor base metals including galena. Trace element and lead isotope analysis was undertaken on nine samples that represent two stages of galena formed during two tectonic events. Both the Pb isotopes and the trace elements show that the first stage galena within the mineralized areas at the footwall has different geochemical characteristics compared with galena in non mineralized areas in the hanging wall, suggesting that galena crystallized from two different ore fluids and probably at two different times. Higher Te, Se and Bi in the galena from the mineralized area may indicate hydrothermal fluids that migrate through the structural conduit and leached out the metal along the pathway that consist of dominant carbonaceous unit. The Pb isotopic ratio composition are transitional between the bulk crustal growth and an upper crustal growth curve, indicating that derivation was from arc rocks associated with continental crust or a crustal source that includes arc volcanic and old continental sedimentary rocks.展开更多
The Wulasigou Cu-Pb-Zn deposit,located 15 km northwest of Altay city in Xinjiang,is one of many Cu-Pb-Zn polymetallic deposits in the Devonian Kelan volcanic-sedimentary basin in southern Altaids.Two mineralizing peri...The Wulasigou Cu-Pb-Zn deposit,located 15 km northwest of Altay city in Xinjiang,is one of many Cu-Pb-Zn polymetallic deposits in the Devonian Kelan volcanic-sedimentary basin in southern Altaids.Two mineralizing periods can be distinguished:the marine volcanic sedimentary PbZn mineralization period,and the metamorphic hydrothermal Cu mineralization period,which is further divided into an early bedded foliated quartz vein stage(Q1) and a late sulfide-quartz vein stage(Q2) crosscutting the foliation.Four types of fluid inclusions were recognized in the Q1 and Q2 quartz from the east orebodies of the Wulasigou deposit:H2O-CO2 inclusions,carbonic fluid inclusions,aqueous fluid inclusions,and daughter mineral-bearing fluid inclusions.Microthermometric studies show that solid CO2 melting temperatures(T(m,CO2)) of H2O-CO2 inclusions in Ql are from-62.3℃ to-58.5C,clathrate melting temperatures(T(m,clath)l) are from 0.5 C to 7.5 C,partial homogenization temperatures(T(h,CO2)) vary from 3.3℃ to 25.9℃(to liquid),and the total homogenization temperatures(T(h,tot)) vary from 285℃ to 378℃,with the salinities being 4.9%-15.1%NaCl eqv.and the CO2-phase densities being 0.50-0.86 g/cm-3.H2O-CO2 inclusions in Q2 have T(m,CO2) from-61.9℃ to-56.9℃,T(m,clath)from 1.3℃ to 9.5℃,T(h,CO2) from 3.4℃ to 28.7℃(to liquid),and T(h,tot) from 242℃ to 388℃,with the salinities being 1.0%-15.5%NaCl eqv.and the CO2-phase densities being 0.48-0.89 g/cm-3.The minimum trapping pressures of fluid inclusions in Q1 and Q2 are estimated to be 260-360 MPa and180-370 MPa,respectively.The δ-(34)S values of pyrite from the volcanic sedimentary period vary from2.3‰ to 2.8‰(CDT),and those from the sulfide-quartz veins fall in a narrow range of-1.9‰ to 2.6‰(CDT).The δD values of fluid inclusions in Q2 range from-121.0‰ to-100.8‰(SMOW),and theδ-(18)O(H2O) values calculated from δ-(18)O of quartz range from-0.2‰ to 8.3‰(SMOW).The δD-δ-(18)O(H2O)data are close to the magmatic and metamorphic fields.The fluid inclusion and stable isotope data documented in this study indicate that the vein-type copper mineralization in the Wulasigou Pb-Zn-Cu deposit took place in an orogenic-metamorphic enviroment.展开更多
Dikko area, Niger State, North Central Nigeria falls within the Pan-African thermo-tectonic event which occurred in Nigeria as in other parts of West Africa with widespread effect on the mineralization of rejuvenated ...Dikko area, Niger State, North Central Nigeria falls within the Pan-African thermo-tectonic event which occurred in Nigeria as in other parts of West Africa with widespread effect on the mineralization of rejuvenated basement and geosynclinal trough deposits. The Pan-African Belt in Nigeria forms part of the Benin-Nigeria (Dahomeyan) shield which is regarded as the southern prolongation of the circumcratonic Pan-African belt of the West African Craton. Structurally controlled, gold-bearing quartz veins were measured and studied in the area from an extensive geological ground investigation. Field and petrographical studies indicate that the Neoproterozoic rocks constitute gneisses, amphibolite schist, amphibolites and migmatites. The amphibolites are intruded by pegmatites. The associated quartz veins are generally concordant with the main N</span></span><span><span><span>-</span></span></span><span><span><span>S regional structural trend. The lithological and structural studies carried out in these areas have demonstrated the relationship between structures and mineralization and/or lithology. The main characteristics of the gold mineralization in the area appear to indicate hydrothermal mineralization in connection with shear zones. This study allows us to predict that quartz veins in the amphibolite can be mined at a profit and a detailed geochemical and resource valuation needs to be carried out for the Au and associated Galena and Ag mineralization to fully exploit their economic potential.展开更多
The Mirge-Naqshineh gold district is situated at northwest of Iran with a NW-trending brittle- ductile shear zone. It is hosted by Precambrian meta-sedimentary and meta-volcanic units traversed by mineralized quartz v...The Mirge-Naqshineh gold district is situated at northwest of Iran with a NW-trending brittle- ductile shear zone. It is hosted by Precambrian meta-sedimentary and meta-volcanic units traversed by mineralized quartz veins. In terms of cross-cutting relationships and sulfide content three types of quartz veins are identified in the region. Among those, parallel to bedding quartz vein (type I) is the main host for gold mineralization. Gold is found in three different forms: 1) submicrometer-size inclusions of gold in arsenian pyrite, 2) as electrum and 3) in the crystal lattice of sulfides (pyrite, galena and chalcopyrite). Six types of pyrite (Pyl-Py6) were identified in this ore reserve. Py3 coexists with arsenopyrite and contains the greatest As-Au concentrations. There is a negative correlation between the As and S contents in Py2 and Py3, implying the substitution of sulfur by arsenic. Pyrites and mineralized quartz veins were formed via metamorphic-hydrothermal fluid and reflect the gold-transportation as Au(HS)2 under reducing and acidic conditions. The gold precipitation mainly controlled by crystallization of arsenian pyrite during fluid/rock interactions and variation offO2. The volcanic host rock has played an important role in gold concentration, as Py3 in this rock contains inclusion of gold particles, but gold is within the lattice of pyrite in phyllite or other units.展开更多
In the syenitic pluton of Guider (593 ± 4 Ma) in the North-West Cameroon domain of Central African Fold Belt, mineralized N-S to NE-SW vertical or sub-vertical quartz and quartz feldspar veins has been recently i...In the syenitic pluton of Guider (593 ± 4 Ma) in the North-West Cameroon domain of Central African Fold Belt, mineralized N-S to NE-SW vertical or sub-vertical quartz and quartz feldspar veins has been recently identified. In this contribution, we present petrography and mineralogy of these veins, in order to constrain their genesis and emplacement mechanisms based on detailed field work, petrographic studies and chemical characterization of minerals by using an electron probe microanalyser (EPMA). Field observations and vein microstructures show that the emplacement of the veins has been controlled by the dextral N-S trending strike-slip shear zones related to the regional D2 deformation phase. The results of mineralogical analysis reveal the co-presence of silicates and metallic minerals that include magnetite, ilmenite, pyrite, bismuthite, galena (very rare) and sulphide complexes (BiPbS, BiAgPbS, FeBiPbCuS, BiFe(TeS), FeBiPbS, BiPbCuS). The gangue is represented by quartz (quartz 1, quartz 2 and quartz 3), feldspars, sericite, chlorite, yellowish brown clay minerals, and hematite. The textural relationships between sulphides, quartz and alteration products show that the mineralization is essentially syn- to late-D2 and suggest that syenitic country rock and dextral shear zones have played an important role in the metallogenesis of these veins. This mineralization shows characteristics for copper-bearing calc-alkaline deposits, but differs from these by its more extensive alteration and its abundance in hematite. Substitutions of Al(IV) by Si(IV) in sericite associated with the sulphide mineralization and cataclastic deformation suggest that the temperature of trapping of the fluids is between 230°C and 275°C.展开更多
Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential en...Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.展开更多
After studying the characteristics and special texture of the fluidogenous tectonics, mineral assemblage in the cemented vein between breccia and their special distribution, and stress analyzing the joint structures i...After studying the characteristics and special texture of the fluidogenous tectonics, mineral assemblage in the cemented vein between breccia and their special distribution, and stress analyzing the joint structures in and around the breccia pipe, it is found that the observed phenomena are caused by a new tectonic dynamic mechanics of fluid——double-fracturing caused bytemperature and pressure of fluids and pulsating expansion. Under the actions of thermal stress and the pressure of fluids, thermal cracks and joints that developed along parts of the thermal cracks formed systematically in the rocks. Under these conditions, up-arching fracture zones that pulsatively expanded upward and cylindrical pressing breccia body were formed. Rocks at the peak of the pyramidal fractures zone break down instantly. Where the difference between pressure of fluids and the overburden pressure exceeded greatly the competence of the rocks, fluid junctions occurred and the velocity of the fluid flow increased as a result. Explosive body expanded upward in the shape of an inverse cone, cone-like explosive breccia body and cover-like shattering breccia body located on the upper part of the breccia pipe were ultimately formed. Gold-rich fluids were enriched and mineralized near the boiling surface in the lower part of the inverse cone-like explosive breccia body where temperature and pressure decreased rapidly, while copper-rich fluids were enriched and mineralized in the junction area where temperature and pressure were relatively high.展开更多
The mineralogy of shock vein matrix in the Suizhou meteorite has been investigated by optical and transmission electron microscopy. It was revealed that the vein matrix is composed of majorite-pyrope garnet, mag- aesi...The mineralogy of shock vein matrix in the Suizhou meteorite has been investigated by optical and transmission electron microscopy. It was revealed that the vein matrix is composed of majorite-pyrope garnet, mag- aesiowtistite, and ringwoodite, with FeNi-FeS inter- growths. The observation and character of ring-like selected electron diffraction (SAED) patterns indicate that Lhe idiomorphic garnet crystals in the vein matrix have different orientations. The polycrystalline nature of magnesiowtistite is also confirmed by a ring-like SAED pattern. Both garnet and magnesiowtistite crystals showed sharp Jiffraction spots, signifying the good crystallinity of these :wo minerals. The SAED pattern of cryptocrystalline 5ngwoodite shows only diffuse concentric diffraction tings. FeNi metal and troilite (FeS), which were molten during the shock event, occur in the matrix as fine eutectic FeNi-FeS intergrowths filling the interstices between garaet and magnesiowiistite grains. Based on the phase dia- gram of the Allende chondrite and the results of this TEM study, it is inferred that majorite-pyrope garnet first crystallized from the Suizhou chondritic melt at 22-26 GPa, Followed by crystallization of magnesiowtistite at 20-24 GPa, and then ringwoodite at 18-20 GPa. The eutectic intergrowths of FeNi-metal and troilite are proposed to have crystallized during meteorite cooling and solidified at the last stage of vein formation.展开更多
According to the differences in ore-controlling structural systems and the characteristics of host rocks, textures and structures of ores and mineral associations of ores, quartz vein-type gold deposits in the Rushan ...According to the differences in ore-controlling structural systems and the characteristics of host rocks, textures and structures of ores and mineral associations of ores, quartz vein-type gold deposits in the Rushan area can be divided into the Rushan and Tongling styles. Rushan style gold deposits, occurring in the Kunyushan complex, include Rushan, Tangjiagou and Tongxishan gold mines. They are distributed along four NNE-trending and sinistral, compresso-shear faults with a right stepping array. A prominent characteristic of the gold mineralization is that the orebodies in neighbouring gold deposits distributed in a single ore-controlling fault zone take opposite pitches. Study of the locating structures of the quartz vein gold deposits shows that the Rushan-style gold deposits are characterized by NNE and NE zoning. Therefore, the intersections of the NE direction of the known gold deposit and the neighbouring NNE-trending fault zones are favourable for looking for gold deposits, and the ends of the curving segments of sinistral and right-stepping faults are favourable for looking for large gold deposits. Tongling-style gold deposits occur in the Sanfosan porphyritic monzonitic granite. Emplacement of gold deposits is controlled by arcuate and radiate structures formed during the intrusion of the Sanfoshan porphyritic monzonitic granite; the radiate faults controlled the distribution of orebodies and the arcuate faults controlled the pitch of the orebodies.展开更多
文摘The Boulon Djounga eastern perimeter is part of the Tiawa operating permit of the Société des Mines du Liptako (SML), located in the central southwestern part of Liptako (Niger). In this study, we used field data, Reverse Circulation (RC) surveys and chemical analyzes of gold to determine the characteristics of gold and its mineralization style. The eastern perimeter of Boulon Djounga is represented by a succession of metabasalts and metasediments both intersected by intrusions of quartz and dolerite dykes, and covered by sandstone and clayey rocks. Gold is present in low contents (0.00 - 0.30 ppm) in the sedimentary cover and in medium (0.30 - 1.00 ppm) or high contents (1.00 - 4.534 ppm) in the metasediments, and in the gray quartz veins and locally in the volcanics. It exists in a disseminated state or in a concentrated state in the surrounding areas in the form of discrete grains associated with sulphurous minerals (pyrite: FeS<sub>2</sub>, chalcopyrite: CuFeS<sub>2</sub> or arsenopyrite: FeAsS). The presence of gold in the quartz veins, and the NE-SW and NW-SE orientations of the ore bodies suggest that the eastern Boulon Djounga gold mineralization would be established during a late magmatic extensive phase.
基金partly supported by a University of Malaya research grant(PV095-2012A)
文摘The Penjom Gold Mine is located 30 km from the Bentong-Raub Suture at the western boundary of the Central Belt in Peninsular Malaysia. Gold mineralization hosted within the vein system is associated with pyrite, arsenopyrite, and minor base metals including galena. Trace element and lead isotope analysis was undertaken on nine samples that represent two stages of galena formed during two tectonic events. Both the Pb isotopes and the trace elements show that the first stage galena within the mineralized areas at the footwall has different geochemical characteristics compared with galena in non mineralized areas in the hanging wall, suggesting that galena crystallized from two different ore fluids and probably at two different times. Higher Te, Se and Bi in the galena from the mineralized area may indicate hydrothermal fluids that migrate through the structural conduit and leached out the metal along the pathway that consist of dominant carbonaceous unit. The Pb isotopic ratio composition are transitional between the bulk crustal growth and an upper crustal growth curve, indicating that derivation was from arc rocks associated with continental crust or a crustal source that includes arc volcanic and old continental sedimentary rocks.
基金funded by National Nature Science Foundation of China(41372096)
文摘The Wulasigou Cu-Pb-Zn deposit,located 15 km northwest of Altay city in Xinjiang,is one of many Cu-Pb-Zn polymetallic deposits in the Devonian Kelan volcanic-sedimentary basin in southern Altaids.Two mineralizing periods can be distinguished:the marine volcanic sedimentary PbZn mineralization period,and the metamorphic hydrothermal Cu mineralization period,which is further divided into an early bedded foliated quartz vein stage(Q1) and a late sulfide-quartz vein stage(Q2) crosscutting the foliation.Four types of fluid inclusions were recognized in the Q1 and Q2 quartz from the east orebodies of the Wulasigou deposit:H2O-CO2 inclusions,carbonic fluid inclusions,aqueous fluid inclusions,and daughter mineral-bearing fluid inclusions.Microthermometric studies show that solid CO2 melting temperatures(T(m,CO2)) of H2O-CO2 inclusions in Ql are from-62.3℃ to-58.5C,clathrate melting temperatures(T(m,clath)l) are from 0.5 C to 7.5 C,partial homogenization temperatures(T(h,CO2)) vary from 3.3℃ to 25.9℃(to liquid),and the total homogenization temperatures(T(h,tot)) vary from 285℃ to 378℃,with the salinities being 4.9%-15.1%NaCl eqv.and the CO2-phase densities being 0.50-0.86 g/cm-3.H2O-CO2 inclusions in Q2 have T(m,CO2) from-61.9℃ to-56.9℃,T(m,clath)from 1.3℃ to 9.5℃,T(h,CO2) from 3.4℃ to 28.7℃(to liquid),and T(h,tot) from 242℃ to 388℃,with the salinities being 1.0%-15.5%NaCl eqv.and the CO2-phase densities being 0.48-0.89 g/cm-3.The minimum trapping pressures of fluid inclusions in Q1 and Q2 are estimated to be 260-360 MPa and180-370 MPa,respectively.The δ-(34)S values of pyrite from the volcanic sedimentary period vary from2.3‰ to 2.8‰(CDT),and those from the sulfide-quartz veins fall in a narrow range of-1.9‰ to 2.6‰(CDT).The δD values of fluid inclusions in Q2 range from-121.0‰ to-100.8‰(SMOW),and theδ-(18)O(H2O) values calculated from δ-(18)O of quartz range from-0.2‰ to 8.3‰(SMOW).The δD-δ-(18)O(H2O)data are close to the magmatic and metamorphic fields.The fluid inclusion and stable isotope data documented in this study indicate that the vein-type copper mineralization in the Wulasigou Pb-Zn-Cu deposit took place in an orogenic-metamorphic enviroment.
文摘Dikko area, Niger State, North Central Nigeria falls within the Pan-African thermo-tectonic event which occurred in Nigeria as in other parts of West Africa with widespread effect on the mineralization of rejuvenated basement and geosynclinal trough deposits. The Pan-African Belt in Nigeria forms part of the Benin-Nigeria (Dahomeyan) shield which is regarded as the southern prolongation of the circumcratonic Pan-African belt of the West African Craton. Structurally controlled, gold-bearing quartz veins were measured and studied in the area from an extensive geological ground investigation. Field and petrographical studies indicate that the Neoproterozoic rocks constitute gneisses, amphibolite schist, amphibolites and migmatites. The amphibolites are intruded by pegmatites. The associated quartz veins are generally concordant with the main N</span></span><span><span><span>-</span></span></span><span><span><span>S regional structural trend. The lithological and structural studies carried out in these areas have demonstrated the relationship between structures and mineralization and/or lithology. The main characteristics of the gold mineralization in the area appear to indicate hydrothermal mineralization in connection with shear zones. This study allows us to predict that quartz veins in the amphibolite can be mined at a profit and a detailed geochemical and resource valuation needs to be carried out for the Au and associated Galena and Ag mineralization to fully exploit their economic potential.
基金supported by Urmia UniversityIMIDRO(Iranian Mines and Mining Industries Development and Renovation Organization)
文摘The Mirge-Naqshineh gold district is situated at northwest of Iran with a NW-trending brittle- ductile shear zone. It is hosted by Precambrian meta-sedimentary and meta-volcanic units traversed by mineralized quartz veins. In terms of cross-cutting relationships and sulfide content three types of quartz veins are identified in the region. Among those, parallel to bedding quartz vein (type I) is the main host for gold mineralization. Gold is found in three different forms: 1) submicrometer-size inclusions of gold in arsenian pyrite, 2) as electrum and 3) in the crystal lattice of sulfides (pyrite, galena and chalcopyrite). Six types of pyrite (Pyl-Py6) were identified in this ore reserve. Py3 coexists with arsenopyrite and contains the greatest As-Au concentrations. There is a negative correlation between the As and S contents in Py2 and Py3, implying the substitution of sulfur by arsenic. Pyrites and mineralized quartz veins were formed via metamorphic-hydrothermal fluid and reflect the gold-transportation as Au(HS)2 under reducing and acidic conditions. The gold precipitation mainly controlled by crystallization of arsenian pyrite during fluid/rock interactions and variation offO2. The volcanic host rock has played an important role in gold concentration, as Py3 in this rock contains inclusion of gold particles, but gold is within the lattice of pyrite in phyllite or other units.
文摘In the syenitic pluton of Guider (593 ± 4 Ma) in the North-West Cameroon domain of Central African Fold Belt, mineralized N-S to NE-SW vertical or sub-vertical quartz and quartz feldspar veins has been recently identified. In this contribution, we present petrography and mineralogy of these veins, in order to constrain their genesis and emplacement mechanisms based on detailed field work, petrographic studies and chemical characterization of minerals by using an electron probe microanalyser (EPMA). Field observations and vein microstructures show that the emplacement of the veins has been controlled by the dextral N-S trending strike-slip shear zones related to the regional D2 deformation phase. The results of mineralogical analysis reveal the co-presence of silicates and metallic minerals that include magnetite, ilmenite, pyrite, bismuthite, galena (very rare) and sulphide complexes (BiPbS, BiAgPbS, FeBiPbCuS, BiFe(TeS), FeBiPbS, BiPbCuS). The gangue is represented by quartz (quartz 1, quartz 2 and quartz 3), feldspars, sericite, chlorite, yellowish brown clay minerals, and hematite. The textural relationships between sulphides, quartz and alteration products show that the mineralization is essentially syn- to late-D2 and suggest that syenitic country rock and dextral shear zones have played an important role in the metallogenesis of these veins. This mineralization shows characteristics for copper-bearing calc-alkaline deposits, but differs from these by its more extensive alteration and its abundance in hematite. Substitutions of Al(IV) by Si(IV) in sericite associated with the sulphide mineralization and cataclastic deformation suggest that the temperature of trapping of the fluids is between 230°C and 275°C.
基金supported by the projects of the China Geological Survey(DD20230043,DD20240048)the project of the National Natural Science Foundation of China(42102123)。
文摘Black shales are important products of material cycling and energy exchange among the lithosphere,atmosphere,hydrosphere,and biosphere.They are widely distributed throughout geological history and provide essential energy and mineral resources for the development of human society.They also record the evolution process of the earth and improve the understanding of the earth.This review focuses on the diagenesis and formation mechanisms of black shales sedimentation,composition,evolution,and reconstruction,which have had a significant impact on the formation and enrichment of shale oil and gas.In terms of sedimentary environment,black shales can be classified into three types:Marine,terrestrial,and marine-terrestrial transitional facies.The formation processes include mechanisms such as eolian input,hypopycnal flow,gravity-driven and offshore bottom currents.From a geological perspective,the formation of black shales is often closely related to global or regional major geological events.The enrichment of organic matter is generally the result of the interaction and coupling of several factors such as primary productivity,water redox condition,and sedimentation rate.In terms of evolution,black shales have undergone diagenetic evolution of inorganic minerals,thermal evolution of organic matter and hydrocarbon generation,interactions between organic matter and inorganic minerals,and pore evolution.In terms of reconstruction,the effects of fold deformation,uplift and erosion,and fracturing have changed the stress state of black shale reservoirs,thereby having a significant impact on the pore structure.Fluid activity promotes the formation of veins,and have changed the material composition,stress structure,and reservoir properties of black shales.Regarding resource effects,the deposition of black shales is fundamental for shale oil and gas resources,the evolution of black shales promotes the shale oil and gas formation and storage,and the reconstruction of black shales would have caused the heterogeneous distribution of oil and gas in shales.Exploring the formation mechanisms and interactions of black shales at different scales is a key to in-depth research on shale formation and evolution,as well as the key to revealing the mechanism controlling shale oil and gas accumulation.The present records can reveal how these processes worked in geological history,and improve our understanding of the coupling mechanisms among regional geological events,black shales evolution,and shale oil and gas formation and enrichment.
文摘After studying the characteristics and special texture of the fluidogenous tectonics, mineral assemblage in the cemented vein between breccia and their special distribution, and stress analyzing the joint structures in and around the breccia pipe, it is found that the observed phenomena are caused by a new tectonic dynamic mechanics of fluid——double-fracturing caused bytemperature and pressure of fluids and pulsating expansion. Under the actions of thermal stress and the pressure of fluids, thermal cracks and joints that developed along parts of the thermal cracks formed systematically in the rocks. Under these conditions, up-arching fracture zones that pulsatively expanded upward and cylindrical pressing breccia body were formed. Rocks at the peak of the pyramidal fractures zone break down instantly. Where the difference between pressure of fluids and the overburden pressure exceeded greatly the competence of the rocks, fluid junctions occurred and the velocity of the fluid flow increased as a result. Explosive body expanded upward in the shape of an inverse cone, cone-like explosive breccia body and cover-like shattering breccia body located on the upper part of the breccia pipe were ultimately formed. Gold-rich fluids were enriched and mineralized near the boiling surface in the lower part of the inverse cone-like explosive breccia body where temperature and pressure decreased rapidly, while copper-rich fluids were enriched and mineralized in the junction area where temperature and pressure were relatively high.
基金financially supported by National Natural Science foundation of China under Grant 41172046 and 40972044 in part
文摘The mineralogy of shock vein matrix in the Suizhou meteorite has been investigated by optical and transmission electron microscopy. It was revealed that the vein matrix is composed of majorite-pyrope garnet, mag- aesiowtistite, and ringwoodite, with FeNi-FeS inter- growths. The observation and character of ring-like selected electron diffraction (SAED) patterns indicate that Lhe idiomorphic garnet crystals in the vein matrix have different orientations. The polycrystalline nature of magnesiowtistite is also confirmed by a ring-like SAED pattern. Both garnet and magnesiowtistite crystals showed sharp Jiffraction spots, signifying the good crystallinity of these :wo minerals. The SAED pattern of cryptocrystalline 5ngwoodite shows only diffuse concentric diffraction tings. FeNi metal and troilite (FeS), which were molten during the shock event, occur in the matrix as fine eutectic FeNi-FeS intergrowths filling the interstices between garaet and magnesiowiistite grains. Based on the phase dia- gram of the Allende chondrite and the results of this TEM study, it is inferred that majorite-pyrope garnet first crystallized from the Suizhou chondritic melt at 22-26 GPa, Followed by crystallization of magnesiowtistite at 20-24 GPa, and then ringwoodite at 18-20 GPa. The eutectic intergrowths of FeNi-metal and troilite are proposed to have crystallized during meteorite cooling and solidified at the last stage of vein formation.
基金This research was supported by the Funds for Key Scientific and Technological Projects of the 9th Five-Year Plan.
文摘According to the differences in ore-controlling structural systems and the characteristics of host rocks, textures and structures of ores and mineral associations of ores, quartz vein-type gold deposits in the Rushan area can be divided into the Rushan and Tongling styles. Rushan style gold deposits, occurring in the Kunyushan complex, include Rushan, Tangjiagou and Tongxishan gold mines. They are distributed along four NNE-trending and sinistral, compresso-shear faults with a right stepping array. A prominent characteristic of the gold mineralization is that the orebodies in neighbouring gold deposits distributed in a single ore-controlling fault zone take opposite pitches. Study of the locating structures of the quartz vein gold deposits shows that the Rushan-style gold deposits are characterized by NNE and NE zoning. Therefore, the intersections of the NE direction of the known gold deposit and the neighbouring NNE-trending fault zones are favourable for looking for gold deposits, and the ends of the curving segments of sinistral and right-stepping faults are favourable for looking for large gold deposits. Tongling-style gold deposits occur in the Sanfosan porphyritic monzonitic granite. Emplacement of gold deposits is controlled by arcuate and radiate structures formed during the intrusion of the Sanfoshan porphyritic monzonitic granite; the radiate faults controlled the distribution of orebodies and the arcuate faults controlled the pitch of the orebodies.