Isotopic Chronological Study of the Huangsha-Tieshanlong Quartz Vein-Type Tungsten Deposit and Timescale of Molybdenum Mineralization in Southern Jiangxi Province,China

The Huangsha-Tieshanlong quartz-vein tungsten polymetallic ore deposit, located in the northern Pangushan-Tieshanlong tungsten ore field in eastern Ganxian-Yudu prospecting areas of the Yushan metallogenic belt, is a well-known tungsten deposit in southern Jiangxi province, China. SHRIMP-determined dating of zircons from the Tieshanlong granite yields ages of 168.1±2.1 Ma （n=11, MSWD-1.3）. Rhenium and osmium isotopic dating of molybdenite from the Huangsha quartz-vein tungsten deposit determined by ICP-MS yields a weighted average ages of 153-3 Ma and model ages of 150.22.1 Ma - 155.4-2.3 Ma. The age of the Huangsha tungsten deposit is 10 to 15 Ma later than the Tieshanlong granite, which shows that there might have been another early Late Jurassic magmatic activity between 150 and 160 Ma, a process which is closely related with tungsten mineralization in this area. The Tieshanlong granite, the Hnangsha tungsten deposit and the Pangushan-Tieshanlong ore field were all formed around 150-170 Ma, belonging to products of a Mesozoic second large-scale mineralization. According to the collected molybdenite Re-Os dating results in southern Jiangxi province, the timescale of the associated molybdenum mineralization is 2-6 Ma in the tungsten deposit and the timescale of independent molybdenum mineralization is 1-4 Ma, implying the complexity of tungsten mineralization. Times of molybdenum mineralization are mainly concentrated in the Yanshanian, which includes three stages of 133-135 Ma, 150-162 Ma, and 166-170 Ma, respectively. The 150-162 Ma-stage is in accordance with ages of large-scale WoSn mineralization, which is mainly molybdenum mineralization characterized by associated molybdenum mineralization with development of an even greater-intensity independent molybdenum mineralization. Independent molybdenum mineralization occurred before and after large-scale W-Sn mineralization, which indicates that favorable prospecting period for molybdenum may be in Cretaceous and early late Jurassic.

A Fluid Inclusion Study of Vein-type Copper Mineralization in the East Wulasigou Pb-Zn-Cu Deposit,Altay,Northwestern China

The Wulasigou Cu-Pb-Zn deposit,located 15 km northwest of Altay city in Xinjiang,is one of many Cu-Pb-Zn polymetallic deposits in the Devonian Kelan volcanic-sedimentary basin in southern Altaids.Two mineralizing periods can be distinguished：the marine volcanic sedimentary PbZn mineralization period,and the metamorphic hydrothermal Cu mineralization period,which is further divided into an early bedded foliated quartz vein stage（Q1） and a late sulfide-quartz vein stage（Q2） crosscutting the foliation.Four types of fluid inclusions were recognized in the Q1 and Q2 quartz from the east orebodies of the Wulasigou deposit：H2O-CO2 inclusions,carbonic fluid inclusions,aqueous fluid inclusions,and daughter mineral-bearing fluid inclusions.Microthermometric studies show that solid CO2 melting temperatures（T（m,CO2）） of H2O-CO2 inclusions in Ql are from-62.3℃ to-58.5C,clathrate melting temperatures（T（m,clath）l） are from 0.5 C to 7.5 C,partial homogenization temperatures（T（h,CO2）） vary from 3.3℃ to 25.9℃（to liquid）,and the total homogenization temperatures（T（h,tot）） vary from 285℃ to 378℃,with the salinities being 4.9%-15.1%NaCl eqv.and the CO2-phase densities being 0.50-0.86 g/cm-3.H2O-CO2 inclusions in Q2 have T（m,CO2） from-61.9℃ to-56.9℃,T（m,clath）from 1.3℃ to 9.5℃,T（h,CO2） from 3.4℃ to 28.7℃（to liquid）,and T（h,tot） from 242℃ to 388℃,with the salinities being 1.0%-15.5%NaCl eqv.and the CO2-phase densities being 0.48-0.89 g/cm-3.The minimum trapping pressures of fluid inclusions in Q1 and Q2 are estimated to be 260-360 MPa and180-370 MPa,respectively.The δ-（34）S values of pyrite from the volcanic sedimentary period vary from2.3‰ to 2.8‰（CDT）,and those from the sulfide-quartz veins fall in a narrow range of-1.9‰ to 2.6‰（CDT）.The δD values of fluid inclusions in Q2 range from-121.0‰ to-100.8‰（SMOW）,and theδ-（18）O（H2O） values calculated from δ-（18）O of quartz range from-0.2‰ to 8.3‰（SMOW）.The δD-δ-（18）O（H2O）data are close to the magmatic and metamorphic fields.The fluid inclusion and stable isotope data documented in this study indicate that the vein-type copper mineralization in the Wulasigou Pb-Zn-Cu deposit took place in an orogenic-metamorphic enviroment.

Systemic modulation of skeletal mineralization by magnesium implant promoting fracture healing: Radiological exploration enhanced with PCA-based machine learning in a rat femoral model

The clinical application of magnesium(Mg)and its alloys for bone fractures has been well supported by in vitro and in vivo trials.However,there were studies indicating negative effects of high dose Mg intake and sustained local release of Mg ions on bone metabolism or repair,which should not be ignored when developing Mg-based implants.Thus,it remains necessary to assess the biological effects of Mg implants in animal models relevant to clinical treatment modalities.The primary purpose of this study was to validate the beneficial effects of intramedullary Mg implants on the healing outcome of femoral fractures in a modified rat model.In addition,the mineralization parameters at multiple anatomical sites were evaluated,to investigate their association with healing outcome and potential clinical applications.Compared to the control group without Mg implantation,postoperative imaging at week 12 demonstrated better healing outcomes in the Mg group,with more stable unions in 3D analysis and high-mineralized bridging in 2D evaluation.The bone tissue mineral density(TMD)was higher in the Mg group at the non-operated femur and lumbar vertebra,while no differences between groups were identified regarding the bone tissue volume(TV),TMD and bone mineral content(BMC)in humerus.In the surgical femur,the Mg group presented higher TMD,but lower TV and BMC in the distal metaphyseal region,as well as reduced BMC at the osteotomy site.Principal component analysis(PCA)-based machine learning revealed that by selecting clinically relevant parameters,radiological markers could be constructed for differentiation of healing outcomes,with better performance than 2D scoring.The study provides insights and preclinical evidence for the rational investigation of bioactive materials,the identification of potential adverse effects,and the promotion of diagnostic capabilities for fracture healing.

Three-dimensional Modeling of Ore-forming Elements and Mineralization Prognosis for the Yechangping Mo Deposit,Henan Province,China

Three-dimensional geochemical modeling of ore-forming elements is crucial for predicting deep mineralization.This approach provides key information for the quantitative prediction of deep mineral localization,three-dimensional fine interpolation,analysis of spatial distribution patterns,and extraction of quantitative mineral-seeking markers.The Yechangping molybdenum(Mo)deposit is a significant and extensive porphyry-skarn deposit in the East Qinling-Dabie Mo polymetallic metallogenic belt at the southern margin of the North China Block.Abundant borehole data on oreforming elements underpin deep geochemical predictions.The methodology includes the following steps:(1)Threedimensional geological modeling of the deposit was established.(2)Correlation,cluster,and factor analyses post delineation of mineralization stages and determination of mineral generation sequence to identify(Cu,Pb,Zn,Ag)and(Mo,W,mfe)assemblages.(3)A three-dimensional geochemical block model was constructed for Mo,W,mfe,Cu,Zn,Pb,and Ag using the ordinary kriging method,and the variational function was developed.(4)Spatial distribution and enrichment characteristics analysis of ore-forming elements are performed to extract geological information,employing the variogram and w(Cu+Pb+Zn+Ag)/w(Mo+W)as predictive indicators.(5)Identifying the western,northwestern,and southwestern areas of the mine with limited mineralization potential,contrasted by the northeastern and southeastern areas favorable for mineral exploration.

A review of in situ carbon mineralization in basalt

Global warming has greatly threatened the human living environment and carbon capture and storage(CCS)technology is recognized as a promising way to reduce carbon emissions.Mineral storage is considered a reliable option for long-term carbon storage.Basalt rich in alkaline earth elements facilitates rapid and permanent CO_(2) fixation as carbonates.However,the complex CO_(2)-fluid-basalt interaction poses challenges for assessing carbon storage potential.Under different reaction conditions,the carbonation products and carbonation rates vary.Carbon mineralization reactions also induce petrophysical and mechanical responses,which have potential risks for the long-term injectivity and the carbon storage safety in basalt reservoirs.In this paper,recent advances in carbon mineralization storage in basalt based on laboratory research are comprehensively reviewed.The assessment methods for carbon storage potential are introduced and the carbon trapping mechanisms are investigated with the identification of the controlling factors.Changes in pore structure,permeability and mechanical properties in both static reactions and reactive percolation experiments are also discussed.This study could provide insight into challenges as well as perspectives for future research.

Research progress of CO_(2) capture and mineralization based on natural minerals

Natural minerals,such as kaolinite,halloysite,montmorillonite,attapulgite,bentonite,sepiolite,forsterite,and wollastonite,have considerable potential for use in CO_(2) capture and mineralization due to their abundant reserves,low cost,excellent mechanical prop-erties,and chemical stability.Over the past decades,various methods,such as those involving heat,acid,alkali,organic amine,amino sil-ane,and ionic liquid,have been employed to enhance the CO_(2) capture performance of natural minerals to attain high specific surface area,a large number of pore structures,and rich active sites.Future research on CO_(2) capture by natural minerals will focus on the full utiliza-tion of the properties of natural minerals,adoption of suitable modification methods,and preparation of composite materials with high specific surface area and rich active sites.In addition,we provide a summary of the principle and technical route of direct and indirect mineralization of CO_(2) by natural minerals.This process uses minerals with high calcium and magnesium contents,such as forsterite(Mg_(2)SiO_(4)),serpentine[Mg_(3)Si_(2)O(OH)_(4)],and wollastonite(CaSiO_(3)).The research status of indirect mineralization of CO_(2) using hydro-chloric acid,acetic acid,molten salt,and ammonium salt as media is also introduced in detail.The recovery of additives and high-value-added products during the mineralization process to increase economic benefits is another focus of future research on CO_(2) mineralization by natural minerals.

Basalt Petrology, Water Chemistry, and Their Impact on the CO_(2) Mineralization Simulation at Leizhou Peninsula Sites, Southern China

Mineral carbonation, which precipitates dissolved carbon dioxide(CO_(2)) as carbonate minerals in basaltic groundwater environments, is a potential technique for negative emissions. The Leizhou Peninsula in southwest Guangdong province has extensive basalt, indicating a promising potential for CO_(2) storage through rapid mineralization. However, understanding of the basic geological setting, potential, and mechanisms of CO_(2) mineralization in the basalts of the Leizhou Peninsula is still limited. The mineralization processes associated with CO_(2)storage at two candidate sites in the area are investigated in this paper: Yongshi Farm and Tianyang Basin(of the dried maar lake). Petrography,rock geochemistry, basalt petrophysical properties, and groundwater hydrochemistry analyses are included in the study. Numerical simulation is used to examine the reaction process and its effects. The results show that basalts in the study areas mainly comprise plagioclase, pyroxene, and Fe–Ti oxides, revealing a total volume fraction exceeding 85%. Additionally, small amounts of quartz and fayalite are available, with volume fractions of 5.1% and 1.0%, respectively. The basalts are rich in divalent metal cations, which can form carbonate minerals, with an average of approximately 6.2 moles of metal cations per 1 kg of rock. The groundwater samples have a pH of 7.5–8.2 and are dominated by the Mg–Ca–HCO3 type. The basalts demonstrate a porosity range of 10.9% to 28.8%, with over 70% of interconnected pores. A 20-year geochemical simulation revealed that CO_(2) injection dissolves primary minerals, including anorthite, albite, and diopside, while CO_(2)mineralization dissolves precipitation secondary minerals, such as calcite, siderite, and dolomite. Furthermore, a substantial rise in pH from 7.6to 10.6 is observed in the vicinity of the injected well, accompanied by a slight reduction in porosity from 20% to 19.8%. Additionally, 36.8% of the injected CO_(2) underwent complete mineralization within five years, revealing an increasing percentage of 66.1% if the experimental period is extended to 20 years. The presence of abundant divalent metal cations in basalts and water-bearing permeable rocks in the Leizhou Peninsula supports the potential for mineral carbonation in basalts, as indicated by the geochemical simulation results. Additional research is necessary to identify the factors that influence the CO_(2) mineralization, storage, and sensitivity analysis of basalt in the Leizhou Peninsula.

Geology and mineralization of the Dongping supergiant alkalic-hosted Au-Te deposit(>100 t Au)in Northern Hebei Province,China:A review

The Dongping deposit is the largest alkalic-hosted gold deposit in China containing>100 t of Au.This paper presents a new understanding for Dongping ore system,based on the previous studies.The mineralization originally occurred at 400-380 Ma,simultaneous with emplacement of the Shuiquangou alkaline complex,and was overprinted by the hydrothermal activity in the Yanshanian.Isotope compositions of ores indicate metals of the deposit are mainly provided by the Shuiquangou complex.Ore-forming fluids are characterized by increasing oxygen fugacity and decreasing sulfur fugacity,while tellurium fugacity increased in the Stage II-2 and decreased in Stage II-3.These systematic changes are closely related to the processes of mineral precipitation and fluid evolution.Sulfide precipitation from Stage Ⅰ to Stage Ⅱ was triggered by fluid boiling,which leads to the precipitation of Pb-Bi-Te,due to decrement of sulfur fugacity.Condensation of gas phase containing high concentration of H_2Te leads to precipitation of Te-Au-Ag minerals and native tellurium.Based on these hypotheses,this paper present a polyphase metallogenic model as follow.During the Devonian,fluids were released from alkaline magmas,which carried ore-forming materials form the surrounding rocks and precipitate the early ores.During the Jurassic-Cretaceous,fluorine-rich fluids exsolved from highly factionated Shangshuiquan granite,which extracted and concentrated Au from the Shuiquangou complex and the Sanggan Group metamorphic rocks,and finally formed the Dongping gold deposit.

Petrogenesis, oxidation state and volatile content of Dongga tonalite in the Gangdese belt, Xizang: Implication for porphyry Cu mineralization

The Gangdese belt in Xizang has experienced both Jurassic subduction and Cenozoic continental collision processes, making it a globally renowned region for magmatic rocks and porphyry copper deposits. Numerous Jurassic intrusions have been identified in the belt. Apart from the quartz diorite porphyry in the large Xietongmen deposit, the Cu mineralization potential of other Jurassic intrusions in this belt remains unclear. This study presents zircon U–Pb dating and trace elements, apatite major and trace elements as well as published whole-rock geochemical and isotopic data of the Dongga tonalite in the central part of the Gangdese belt, aiming to reveal the petrogenesis, oxidation state, volatile content, and Cu mineralization potential of this intrusion. The Dongga tonalite has a zircon U–Pb age of 179.4 ± 0.9 Ma. It exhibits high whole-rock V/Sc values(8.76–14.6), relatively low apatite CeN/CeN*ratios(1.04–1.28), elevated zircon(Eu/Eu*)Nvalues(an average of 0.44), high Ce4+/Ce3+values(205–1896), and high ?FMQ values(1.3–3.7), collectively suggesting a high magmatic oxygen fugacity. The Dongga tonalite features amphibole phenocrysts, relatively high whole-rock Sr/Y ratios(20.3–58.9), and lower zircon Ti temperatures (502–740 ℃), reflecting a high magmatic water content. Estimation of magmatic sulfur content(0.002–0.024 wt%) based on apatite SO3contents indicates an enriched magma sulfur content. Combined with previous studies and the collected Sr–Nd–Hf isotopes, the Dongga tonalite is derived from juvenile lower crust related with subduction of the Neo-Tethys oceanic slab. When compared with Xietongmen orebearing porphyries, the Dongga tonalite exhibits remarkable similarities with the Xietongmen ore-bearing porphyries in terms of magma source, tectonic background, magmatic redox state, and volatile components, which indicates that the Dongga tonalite has a high porphyry Cu mineralization potential, and therefore, provides important guidance for the future mineralization exploration.

Characteristics of Gold Mineralization at the Baguiomo Gold Panning Site, Koudougou Region, Burkina Faso, West Africa

The Birimian Baguiomo formations are located in the northern part of the Boromo greenstone belt. In this belt, the volcanic rocks (tholeiitic basalt, calcalkaline basalt, andesite) hosting the gold mineralization are located in the Kwademen-Baguiomo shear zone. This mineralization, located only a few kilometers from the Kwademen gold deposit, is uncharacterized and, together with the latter, could constitute a gold potential capable of being economically exploitable. It is in this sense that this work is carried out with a view to characterizing the gold mineralization of the Baguiomo gold panning site. To carry out this work, we have made direct field measurements, combined with microstructures, and combined all this with data from geochemical rock analysis of the basalts that are the main host formations. Geochemical data show that tholeitic basalts formed from a mantle plume that was emplaced in an oceanic plateau context. Calc-alkaline basalts and andesites are comparable to Paleoproterozoic tholeitic basalts (PTH3), which are slightly enriched in light rare earths. Fertility tests show that these basalts concentrate between 3 and 6 ppb of gold at the time of accretion, which is sufficient for remobilization of this primary gold during the Eburnian orogeny to yield a deposit of around 4 - 5 Moz. Gold mineralization is associated with pyrite crystals when the latter are disseminated in the rock mass, whereas it is associated with hematite in quartz veins concordant with S1 shear deformation. It is mainly the pyrite crystals in the pressure shadows that contain the gold grains, whose development would be synchronous with micro-shear zone reactivation during the first phase of D1B deformation. The second phase of D2B deformation, which is a crenulation or fracture schistosity, does not significantly affect the shear deformation that controls mineralization.

In situ U-Pb dating and trace elements of magmatic rutile from Mujicun Cu-Mo deposit,North China Craton:Insights into porphyry mineralization

Porphyry Cu(Mo-Au)deposit is one of the most important types of copper deposit and usually formed under magmatic arc-related settings,whilst the Mujicun porphyry Cu-Mo deposit in North China Craton uncommonly generated within intra-continental settings.Although previous studies have focused on the age,origin and ore genesis of the Mujicun deposit,the ore-forming age,magma source and tectonic evolution remain controversial.Here,this study targeted rutile(TiO_(2))in the ore-hosting diorite porphyry from the Mujicun Cu-Mo deposit to conduct in situ U-Pb dating and trace element composition studies,with major views to determine the timing and magma evolution and to provide new insights into porphyry Cu-Mo metallogeny.Rutile trace element data show flat-like REE patterns characterized by relatively enrichment LREEs and depleted HREEs,which could be identified as magmatic rutile.Rutile U-Pb dating yields lower intercept ages of 139.3–138.4 Ma,interpreted as post magmatic cooling timing below about 500℃,which are consistent or slightly postdate with the published zircon U-Pb ages of diorite porphyry(144.1–141.7 Ma)and skarn(146.2 Ma;139.9 Ma)as well as the molybdenite Re-Os ages of molybdenum ores(144.8–140.0 Ma).Given that the overlap between the closure temperature of rutile U-Pb system and ore-forming temperature of the Mujicun deposit,this study suggests that the ore-forming ages of the Mujicun deposit can be constrained at 139.3–138.4 Ma,with temporal links to the late large-scale granitic magmatism at 138–126 Ma in the Taihang Orogen.Based on the Mg and Al contents in rutile,the magma of ore-hosting diorite porphyry was suggested to be derived from crust-mantle mixing components.In conjunction with previous studies in Taihang Orogen,this study proposes that the far-field effect and the rollback of the subducting Paleo-Pacific slab triggered lithospheric extension,asthenosphere upwelling,crust-mantle interaction and thermo-mechanical erosion,which jointly facilitated the formation of dioritic magmas during the Early Cretaceous.Subsequently,the dioritic magmas carrying crust-mantle mixing metallic materials were emplaced and precipitated at shallow positions along NNE-trending ore-controlling faults,eventually resulting in the formation of the Mujicun Cu-Mo deposit within an intracontinental extensional setting.

Geology and mineralization of the Hongqiling large magmatic nickel-copper-cobalt deposit(22×10^(4)t)in Jilin Province,China:A review

The Hongqiling large nickel-copper-cobalt deposit(hereafter referred to as the Hongqiling deposit),a typical mafic-ultramafic copper-nickel deposit in China,boasts proven Ni(Ni)resources of approximately 22×10^(4)t,associated copper resources of 2×10^(4)t,and associated cobalt(Co)resources of 0.5×10^(4)t,with Ni reserves ranking 10th among China's magmatic nickel deposits.Geotectonically,the Hongqiling deposit is situated in the superimposed zone between the Xing'an-Mongolian orogenic belt and the circum-Western Pacific's active continental margin belt.Its ore-bearing plutons occur within the metamorphic rocks of the Ordovician Hulan Group,with the emplacement of plutons and the locations of orebodies governed by the deep-seated Huifahe fault and its secondary NW-trending Fujia-Hejiagou-Beixinglong-Changsheng fault zone.In the deposit,the rock assemblages of ore-bearing plutons predominantly encompass gabbro-pyroxenite-olivine pyroxenite-pyroxene peridotite(pluton No.1)and norite-orthopyroxenite-harzburgite(pluton No.7),with ore-bearing lithofacies consisting primarily of olivine pyroxenite and pyroxenite facies.The Hongqiling deposit hosts stratoid,overhanging lentoid,veined,and pure-sulfide veined orebodies.Its ores principally contain metallic minerals including pyrrhotite,pentlandite,chalcopyrite,violarite,and pyrite.Despite unidentified magma sources of ore-bearing mafic-ultramafic rocks,it is roughly accepted that the magmatic evolution in the Hongqiling deposit primarily involved fractional crystallization and crustal contamination.The ore-forming materials were primarily derived from the upper mantle,mixed with minor crustal materials.The ore-bearing mafic-ultramafic rocks in the deposit,primarily emplaced during the Indosinian(208-239 Ma),were formed in an intense extension setting followed by the collisional orogeny between the North China Plate and the Songnen-Zhangguangcai Range Block during the Middle-Late Triassic.From the perspective of the metallogenic geological setting,surrounding rocks,ore-controlling structures,and rock assemblages,this study identified one favorable condition and seven significant indicators for prospecting for Hongqiling-type nickel deposits and developed a prospecting model of the Hongqiling deposit.These serve as valuable references for exploring similar nickel deposits in the region,as well as the deep parts and margins of the Hongqiling deposit.

Nitrogen mineralization in the oldest climax communities in the eastern Mediterranean region

In this study,we investigated how tree species affect N mineralization in connection to some soil properties and seconder metabolite levels of litter,in the soil of the old-est native forest communities.In the oldest pure communi-ties of Pinus nigra(PN),Fagus orientalis(FO),and Abies bornmuelleriana(AB)in the mountain range of Mount Uludağ,Bursa,Turkey,annual net yield and N mineraliza-tion in the 0-5-and 5-20-cm soil layers were determined in a field incubation study over 1 year.Sampling locations were chosen from 1300 to 1600 m a.s.l.,and moisture content(%),pH,water-holding capacity(%),organic C,total N,and C/N ratio,and annual net mineral N yield of the soil and hydro-lyzed tannic acid and total phenolic compounds in litter were compared for these forest communities.F.orientalis had the highest annual net Nmin yield(43.9±4.8 kg ha^(-1) a^(-1)),P.nigra the lowest(30.5±4.2 kg ha^(-1) a^(-1)).Our findings show that in the oldest forest ecosystems,the seasonal soil moisture content and tree species play an essential role in N cycling and that hydrolyzed tannic acids and total phenolic compounds effectively control N turnover.Tannic acid and total phenolics in the litter were found to inhibit nitrification,but total phenolics were found to stimulate ammonification.

Trace element compositions of pyrite and stibnite:implications for the genesis of antimony mineralization in the Yangla Cu skarn deposit,Northwestern Yunnan,China

The Yangla Cu skarn deposit is located in the central part of the Jinshajiang Suture Zone,southwest China,with a total reserve of 150 Mt Cu@1.03%.The newly discovered antimony orebodies at the depth of Yangla are strictly controlled by the stratum,structure,and lithology,which are lenticular and vein-like within the marble fracture zone,which can provide a window into multistage miner-alization and ore genesis at Yangla.Mineralization can be divided into three types,Cu–Pb–Zn(skarn)pyrite,galena,and sphalerite,Cu(porphyry)chalcopyrite and pyrite,and Sb(hydrothermal)stibnite and pyrite.The mineral assem-blages were stibnite+pyrite+calcite+quartz±minor scheelite in antimony ores.This study presents quantitative measurements of the trace element compositions of pyrite and stibnite from the Yangla antimony ores.Analysis of pyrite with electron probe microanalysis(EPMA)showed enrichment in Co,Ni,Sb,As,and Mo,and deficit in its S and Fe contents when compared to the stoichiometric con-centrations of S and Fe in pyrite.The Sb-related pyrite may belong to sedimentary-reworked genesis and may be modi-fied by hydrothermalfluids,thereby presenting a certain dif-ference(i.e.,crystal morphology,texture,and chemical com-position)compared to the skarn and porphyry Cu-related pyrite in the Yangla Cu skarn deposit.Analysis of stibnite with EPMA and inductively coupled plasma-mass spectrom-etry showed enrichment in As,Pb,Sn,Pb,Cu,and Zn,and presented much higher Sb contents and slightly lower S con-tents when compared to the stoichiometric concentrations of Sb and S in stibnite.Statistical analysis of the stibnite trace elements showed correlations for the elemental pairs Cu–Pb,As–Sb,and Sn–Pb,and the coupled substitution equations Sb^(3+)↔Cu^(+)+Pb^(2+),Sb^(3+)↔As^(3+),and Sn^(2+)↔Pb^(2+)may be the major factors governed the incorporating Cu,Pb,As and Sn within the stibnite.Moreover,this study preliminary shows that the antimony mineralization may belong to a car-bonate replacement hydrothermal genesis at Yangla.

Magmatic-hydrothermal Evolution and Mineralization Mechanisms of the Wangjiazhuang Cu(-Mo)Deposit in the Zouping Volcanic Basin,Shandong Province,China:Constraints from Fluid Inclusions

The Wangjiazhuang Cu(-Mo)deposit,located within the Zouping volcanic basin in western Shandong Province,China,is unique in this area for having an economic value.In order to expound the metallogenetic characteristics of this porphyry-like hydrothermal deposit,a detailed fluid inclusion study has been conducted,employing the techniques of representative sampling,fluid inclusion petrography,microthermometry,Raman spectroscopy,LA-ICP-MS analysis of single fluid inclusions,as well as cathode fluorescence spectrometer analysis of host mineral quartz.The deposit contains mainly two types of orebodies,i.e.veinlet-dissemination-stockwork orebodies in the K-Si alteration zone and pegmatiticquartz sulfide veins above them.In addition,minor breccia ore occurs locally.Four types of fluid inclusions in the deposit and altered quartz monzonite are identified:L-type one-or two-phase aqueous inclusions,V-type vapor-rich inclusions with V/L ratios greater than 50%-90%,D-type multiphase fluid inclusions containing daughter minerals or solids and S-type silicate-bearing fluid inclusions containing mainly muscovite and biotite.Ore petrography and fluid inclusion study has revealed a three-stage mineralization process,driven by magmatic-hydrothermal fluid activity,as follows.Initially,a hydrothermal fluid,separated from the parent magma,infiltrated into the quartz monzonite,resulting in its extensive K-Si alteration,as indicated by silicate-bearing fluid inclusions trapped in altered quartz monzonite.This is followed by the early mineralization,the formation of quartz veinlets and dissemination-stockwork ores.During the main mineralization stage,due to the participation and mixing of meteoric groundwater with magmatic-sourced hydrothermal fluid,the cooling and phase separation caused deposition of metals from the hydrothermal fluids.As a result,the pegmatitic-quartz sulfide-vein ores formed.In the late mineralization stage,decreasing fluid salinity led to the formation of L-type aqueous inclusions and chalcopyrite-sulfosalt ore.Coexistence of V-type and D-type inclusions and their similar homogenization temperatures with different homogenization modes suggest that phase separation or boiling of the ore-forming fluids took place during the early and the main mineralization stages.The formation P-T conditions of S-type inclusions and the early and the main mineralization stages were estimated as ca.156-182 MPa and 450-650℃,350-450℃,18-35 MPa and 280-380℃,8-15 MPa,respectively,based on the microthermometric data of the fluid inclusions formed at the individual stages.

Synergistic CO_(2) mineralization using coal fly ash and red mud as a composite system

CO_(2) mineralization plays a critical role in the storage and utilization of CO_(2).Coal fly ash(CFA)and red mud(RM)are widely utilized as CO_(2) mineralizers.However,the inert calcium species in CFA limit its carbonation capacity,meanwhile the substantial Ca^(2+)releasing of RM is hindered by a covering layer of calcium carbonate.In this study,CO_(2) mineralization in a composite system of CFA and RM was investigated to enhance the carbonation capacity.Multiple analyzers were employed to characterize the raw materials and resulting mineralization products.The results demonstrated that a synergistic effect existed in the composite system of CFA and RM,resulting in improving CO_(2) mineralization rate and efficiency.The produced calcium carbonate was ectopically attached the surface of CFA in the composite system,thus slowing down its coverage on the surface of RM.This phenomenon facilitated further releasing Ca^(2+)from the internal RM,thereby enhancing CO_(2) mineralization efficiency.Meanwhile,the inclusion of RM significantly improved the alkalinity of the composite system,which not only promoted the dissolution of Ca^(2+)of the inert CaSO_(4)(H_(2)O)_(2) in CFA,but also accelerated CO_(2) mineralization rate.The investigation would be beneficial to CO_(2) mineralization using industrial solid wastes.

Lithostructural Control of the Gold Mineralization of the Douta Permit of African Star Resources (Kédougou-Kéniéba Inlier, Southeastern Senegal)

The Douta permit of African Star Resources/Thor Explorations, located in the southeast of Senegal, in the Kédougou-Kéniéba Inlier (western part of the West African Craton), is dominated to the East by metasedimentary formations such as greywackes, shales, graphitic shales, quartzites, cherts, claystones and breccias characteristic of the Dialé-Daléma basin. To the West, the mafic formations of the Mako volcanic belt are the most common. Metasedimentary rocks are associated with metavolcanosedimentary terms found at the contact zones between the two (2) Birimian groups. These different geological formations are cut by mafic dolerite and gabbro sills and/or dykes, as well as quartz and microgranite veins. The Douta gold project is crossed from North to South by the MTZ (Main Transcurrent Zone), generally oriented NE-SW and becoming N-S towards the North. The permit is characterized by several shear corridors. The rocks are affected by brittle, brittle-ductile to ductile deformations. The gold mineralization is hosted by a NE-trending shear corridor called the Makosa corridor (Makosa shear zone), therefore sub-parallel to the MTZ. It has a subvertical dip (75˚ to 85˚ to the NW). It is associated with a hydrothermal phase characterized by quartz-sericite-epidote-fine, disseminated pyrite and arsenopyrite ± albite ± chlorite paragenesis. These minerals testify to the existence of a low degree of metamorphism (greenschist facies, epizonal domain) in the area. However, metamorphism reaches amphibolite facies in some places, particularly in the vicinity of intrusive bodies, with the presence of hornblende (amphiboles) and plagioclase. The gold mineralization is mainly hosted by two (2) metasedimentary lithological units: meta-greywackes and shales.

Source Enrichment Control on the Scale of Magmatic-Hydrothermal W-Sn Mineralization:Insights from Triassic and Jurassic Magma Reservoirs in the Continental Crust,Xitian,South China

There are two factors,source composition and magmatic differentiation,potentially controlling W-Sn mineralization.Which one is more important is widely debated and may need to be determined for each individual deposit.The Xitian granite batholith located in South China is a natural laboratory for investigating the above problem.It consists essentially of two separate components,formed in the Triassic at ca.226 Ma and Jurassic at ca.152 Ma,respectively.The Triassic and Jurassic rocks are both composed of porphyritic and fine-grained phases.The latter resulted from highlydifferentiated porphyritic ones but they have similar textural characteristics and mineral assemblages,indicating that they reached a similar degree of crystal fractionation.Although both fine-grained phases are highly differentiated with elevated rare metal contents,economic W–Sn mineralization is rare in the Triassic granitoids and this can be attributed to less fertile source materials than their Jurassic counterparts,with a slightly more enriched isotopic signature and whole-rockεNd(226 Ma)of−10.4 to−9.2(2σ=0.2)compared withεNd(152 Ma)of−9.2 to−8.2(2σ=0.2)for the Jurassic rocks.The initial W-Sn enrichment was derived from the metasedimentary rocks and strongly enhanced by reworking of the continental crust,culminating in the Jurassic.

Petrogenesis of Oligocene Granitoids and its Implications on Beryllium Mineralization at Pagele,Nianqingtanggula Mountain(Central Tibet)

The newly discovered Oligocene granitoids(33.1-28.7 Ma)at Pagele are magmatic rocks related to beryllium mineralization during the India-Asia late-collisional stage.This discovery provides an ideal example to study the latecollisional orogeny and beryllium prospecting in the Lhasa terrane.The Oligocene granitoids include porphyritic granodiorite,StageⅠ,ⅡandⅢgranites,and granitic pegmatite.Geochemical analysis shows that the porphyritic granodiorite is characterized by high SiO_(2),K_(2)O,totalΣREE contents,and(La/Yb)N ratios;while the latter two by higher SiO_(2),lowerΣREE and(La/Yb)N ratios.Notably,the granitic pegmatite has extremely high Y/Ho,low K/Rb and Zr/Hf,and distinct REE tetrad effect(1.14-1.21).This study suggests that the porphyritic granodiorite may be derived from partial melting of beryllium-rich materials composed of Lhasa ancient crust(70%-80%)and enriched Lhasa lithospheric mantle(20%-30%)under the tearing subduction of Indian slab.The three-stage granites and granitic pegmatite,which contain higher beryllium contents or beryls,were likely generated by highly fractionation of the porphyritic granodioritic magma or other homologous magma.Considering the possible genetic and spatial link between Indian slab tear and rifts,we suggest that highly-fractionated granites in rifting systems represent important Be prospecting targets in the Lhasa terrane.

Characteristics of Gold and Its Mineralization Style in the Boulon Djounga Eastern Perimeter of Liptako Mining Company (Central Southwestern Niger)

The Boulon Djounga eastern perimeter is part of the Tiawa operating permit of the Société des Mines du Liptako (SML), located in the central southwestern part of Liptako (Niger). In this study, we used field data, Reverse Circulation (RC) surveys and chemical analyzes of gold to determine the characteristics of gold and its mineralization style. The eastern perimeter of Boulon Djounga is represented by a succession of metabasalts and metasediments both intersected by intrusions of quartz and dolerite dykes, and covered by sandstone and clayey rocks. Gold is present in low contents (0.00 - 0.30 ppm) in the sedimentary cover and in medium (0.30 - 1.00 ppm) or high contents (1.00 - 4.534 ppm) in the metasediments, and in the gray quartz veins and locally in the volcanics. It exists in a disseminated state or in a concentrated state in the surrounding areas in the form of discrete grains associated with sulphurous minerals (pyrite: FeS2, chalcopyrite: CuFeS2 or arsenopyrite: FeAsS). The presence of gold in the quartz veins, and the NE-SW and NW-SE orientations of the ore bodies suggest that the eastern Boulon Djounga gold mineralization would be established during a late magmatic extensive phase.