Mechanism of Surface Vertical Deformation in Parts of the Underground Gas Storage Reservoir of Hutubi, Xinjiang, China

The Underground Gas Storage( UGS) in Hutubi( HTB),Xinjiang is the largest gas storage reservoir in China and it has significance for coordinating the gas supply and demand relationship,peak-load regulation,implementation of strategic reserves,national security, and social economic sustainable development. Therefore, the deformation monitoring and simulation analysis of UGS operation has important technical support and reference value for the stability and safe operation of the underground gas storage. In this paper,we use the elevation data obtained from 7 periods of second-order leveling surveys in the Hutubi underground gas storage area in 2013- 2015 to analyze the influence of gas well pressure on the vertical deformation of the underground gas storage reservoir.Research has shown that the absolute vertical subsidence rate is approximately in the range from 11. 8mm to 16. 1mm and the relative subsidence change is about 4. 3mm,near the surface deformation of Hutubi underground gas storage area except for the annual subsidence rate of- 2. 86 mm by the basic influence of uplift of the Tianshan Mountains.Groundwater over-extraction in the Hutubi area also has an impact on the vertical variation of the surface in this region. The land surface change per unit pressure of gas storage has an impact of about 0. 625mm- 1. 125 mm. 17 scenes Terra SAR-X radar images acquired from August,2013 to August,2014 are exploited by Small Baseline Subset( SBAS) In SAR method to obtain the surface deformation time series during the operation of UGS in Hutubi,meanwhile combined with the pressure data of injection / productionwells,the multi-point source Mogi model is used to simulate the UGS deformation field in Hutubi. The results show that the deformation characteristics of the whole UGS area is a discontinuous distribution with the peak deformation value of 10 mm and- 8mm in the satellite line of sight( LOS) during gas injection and production,respectively and the retrieved deformation sequences correspond very well to the gas injection / production pressure changes. Based on the multi- point source Mogi model, we simulate the deformation process of UGS,HTB,and with the adaptive forward search method,the radius and depth of point source are obtained. The simulated results indicate that when the average injection / production pressure of UGS,HTB is 18 MPa and 15 MPa, LOS deformation is up to 7mm and- 4mm,respectively,and surface deformation is related to the density of gas injection( production) wells. The UGS gas distribution is not uniform,indicating that the structure of underground gas storage is complex. Thus using a more elaborate geomechanical model and other deformation observation data will be helpful for better simulating the UGS internal structure and explaining the mechanism of deformation.

Vertical crosslinking MoS_2/three-dimensional graphene composite towards high performance supercapacitor

Molybdenum disulfide（MoS2） has been stimulated in extensive researches due to its layered structure and the potential as an electrochemical energy material. However, the effects on electrochemical performance of concentration of MoS2 are rarely mentioned. In this paper, the effects of different concentrated layered MoS2 on the morphology and electrochemical properties of the composite of MoS2 and three-dimensional graphene（MoS2/3DG） were discussed. The results show that layered MoS2 was successfully compounded to 3DG and formed a vertical crosslinking structure. It can be observed that MoS2 nanosheets are vertically loaded on the inner and outer surface of graphee when the concentration of MoS2 is 0.20 mg/L. The specific capacitance of composite（MoS2（0.20 mg/L）/3 DG）reaches 2182.33 mF/cm^2 at the current density of 1 mA/cm^2, and the specific capacitance remains 116.83% after 5000 cycles. When the current density increased 100 times（from 1 mA/cm^2 to 100 mA/cm^2）, the specific capacitance retains 78.9%. Meanwhile, the hybrid energy storage devises can deliver an energy density of 130.34 Wh/m^2. The superior electrochemical properties are attributed to the synergistic effect of MoS2 and 3DG. Therefore, the material has a potential application on supercapacitor electrode material.