Suspended emulsion polymerization was used to prepare poly(vinyl chloride) (PVC) resin. Fine PVC particleswere formed at low polymerization conversions. The amount of fine panicles decreases as conversion increases an...Suspended emulsion polymerization was used to prepare poly(vinyl chloride) (PVC) resin. Fine PVC particleswere formed at low polymerization conversions. The amount of fine panicles decreases as conversion increases anddisappears at conversions greater than 30%. Scanning electron micrographs show that PVC grains are composed of looselycoalesced primary particles, especially for PVC resins prepared in the presence of poly(vinyl alcohol) dispersant. The size ofprimary particles increases and porosity decreases with the increase of conversion. In view of the particle features of PVCresin, a particle formation mechanism including the formation of primary particles and grains is proposed. The formationprocess of primary particles includes the formation of particle nuclei, coalescence of particle nuclei to form primary particles,and growth of primary particles. PVC grains are formed by the coagulation of primary particles. The loose coalescence ofprimary particles is caused by the colloidal stability of primary particles and the low swelling degree of vinyl chloride in the primary particles.展开更多
Suspended emulsion polymerization of vinyl chloride was carried out in a 5 L autoclave. The influence of agitation, polymerization conversion, dispersant and surfactant on the average particle size (PS) and particle s...Suspended emulsion polymerization of vinyl chloride was carried out in a 5 L autoclave. The influence of agitation, polymerization conversion, dispersant and surfactant on the average particle size (PS) and particle size distribution (PSD), particle morphology and porosity of polyvinyl chloride (PVC) resin was investigated. It showed that the agitator had great influence on the smooth operation of polymerization, PS and PSD. The PS increased and PSD became narrow as polymerization conversion became high. The porosity decreased with the increase of conversion. A convenient choice of additives, both dispersants and non-ionic surfactants, allows one to adjust PS and PSD. The PS decreased with the addition of polyvinyl alcohol or hydroxypropyl methylcellulose dispersants,and increased with the addition of Span surfactants. The addition of dispersants or surfactants also affected the morphology and porosity of resin, and PVC resin with looser agglomeration and homogeneous distribution of primary particles was prepared.展开更多
In the present paper a model equation for calculating the radical desorption rate constant,k<sub>0</sub>,in the emulsion polymerization of vinyl acetate was suggested and the various parameters forevaluati...In the present paper a model equation for calculating the radical desorption rate constant,k<sub>0</sub>,in the emulsion polymerization of vinyl acetate was suggested and the various parameters forevaluating k<sub>0</sub> were determined.Effects of reaction temperature,emulsifier concentration,initiator con-centration,monomer conversion and phase ratio on k<sub>0</sub> were studied.It indicates that the desorptionof radicals from latex particles to aqueous phase must be taken into account in the modelling ofemulsion polymerization for the monomers with higher hydrophilicity such as vinyl acetate.展开更多
The behaviour of water soluble and monomer soluble inhibitors in the emulsion polymerization for CaseI system(e.g.vinyl acetate and vinyl chloride)has been studied.The behaviour of monomer soluble inhibitorsis shown t...The behaviour of water soluble and monomer soluble inhibitors in the emulsion polymerization for CaseI system(e.g.vinyl acetate and vinyl chloride)has been studied.The behaviour of monomer soluble inhibitorsis shown to be quite different from that observed in Case Ⅱ emulsion polymerization system.Model predictionsof the effect of these inhibitors on polymer particle nucleation and growth rate are shown to be in satisfactoryagreement with experimental results.展开更多
Acrylate latex modified by vinyl triisopropoxy silane (C-1706) was synthesized by seeded emulsion polymerization with anionic emulsifier sodium dodecyl sulphonate(SDS) and nonionic emulsifier OP-10 as the multiple emu...Acrylate latex modified by vinyl triisopropoxy silane (C-1706) was synthesized by seeded emulsion polymerization with anionic emulsifier sodium dodecyl sulphonate(SDS) and nonionic emulsifier OP-10 as the multiple emulsifiers at (78±2) ℃. The effects of different factors, such as the emulsifier, C-1706 monomer and its feeding manner on the properties of acrylate latex modified by C-1706 were investigated. The particle size distribution and the structure, the configuration, the weather durability and stain resistance of copolymer latex were characterized by particle size analyzer, Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope(TEM), scanning electron microscope(SEM) and ultraviolet aging instrument respectively. The results show that SDS to OP-10 as multiple emulsifiers can lead to coordinated efficiency, the optimal emulsifier dosage is 2.4%?3.2%(mass fraction), and the mass ratio of SDS to OP-10 is 1?1? 1?2. The seeded emulsion polymerization can effectively introduce a organic-siloxane bonding in a macromolecule inter polymer, and the obtained acrylate latex modified by organic-siloxane possesses narrow distribution of particle size with mean diameter of 51.8?76.6 nm and has the excellent properties in weather durability and stain-resistance especially.展开更多
The emulsion polymerization of highly shear-stable copolymer dispersions of methyl methacrylate and butyl acrylate were carried out using poly （vinyl alcohol） with a thiol end group （PVA-SH） as protective colloid....The emulsion polymerization of highly shear-stable copolymer dispersions of methyl methacrylate and butyl acrylate were carried out using poly （vinyl alcohol） with a thiol end group （PVA-SH） as protective colloid. The dispersions can be transformed into corresponding redispersible powder via a spray dryingcooling process. On-line FT-IR monitoring shows that grafting polymer of PVA-g-PMMA was formed mainly at the stage-1 of the emulsion polymerization. TEM images show, the PVA-SH shell was fragmentary when adding SDS at initial stage and integrated when adding at particle growing or final stage. The particle size turns to be smaller when delayed adding SDS surfactant. Triethanolamine, a co-regulator of PVA-SH, controlled the M to 50 000-70 000 and reduced the PDI to 1.5-1.7. The acrylic dispersions with 0.8wt%-1.5wt% PVA-SH1 can be spray-dried into super dispersible polymer powder （SDPP）, which can easily disperse in water and form recon- stituted dispersions with an average particle size smaller than 1 micron.展开更多
Poly (acrylonitrile-co-vinyl acetate)/polypyrrole composite particles with uniform size and morphology have been synthesized using one-step polymerization that involves swelling and coating of polypyrrole (PPy) into P...Poly (acrylonitrile-co-vinyl acetate)/polypyrrole composite particles with uniform size and morphology have been synthesized using one-step polymerization that involves swelling and coating of polypyrrole (PPy) into P (AN-co-VAc) latex nanoparticles. As an initial stage, free radical copolymerization of acrylonitrile (AN) and vinyl acetate (VAc) was synthesized by emulsion polymerization using ammonium persulfate (APS) and dodecyl benzene sulfonic acid salt (DBSA) as a surfactant. P (AN-co-VAc)/PPy composites were obtained first time by in situ addition of the pyrrole into the reaction medium. The electrospun P (AN-co-VAc)/PPy nanofibers were obtained from the nanoparticles with better properties and the effect of PPy on the morphology of nanofibers was studied by scanning electron microscopy (SEM). High degree of homogeneity and molecular order induced by molecular dispersion of polypyrrole on copolymer matrix without phase separation improve the transport properties and stability of polypyrrole, which are critical for high-performance organic electronics.展开更多
研究了一种顶空(HS)-气质联用(GC-MS)的方法来测定乙酸乙烯酯-乙烯共聚物(VAE)中有机物挥发分的方法。首先以N,N-二甲基乙酰胺作为溶剂,加入1 m L,再将1 mL样品置于容器中混合均匀;然后采用静态顶空法,加热使挥发性组分从VAE样品中挥发...研究了一种顶空(HS)-气质联用(GC-MS)的方法来测定乙酸乙烯酯-乙烯共聚物(VAE)中有机物挥发分的方法。首先以N,N-二甲基乙酰胺作为溶剂,加入1 m L,再将1 mL样品置于容器中混合均匀;然后采用静态顶空法,加热使挥发性组分从VAE样品中挥发出来,达到气液两相平衡;随后将顶空瓶上部气体注入气相色谱仪中进行分离,最后导入质谱检测器进行定性分析,采用物质组分的特征质谱图与NIST标准谱库对比进行各物质组成的分析。方法前处理简单、快捷、定性结果准确,能有效指导VAE生产中产品质量的提升。展开更多
基金The project is supported by the National Natural Science Foundation of China (No. 29906009)
文摘Suspended emulsion polymerization was used to prepare poly(vinyl chloride) (PVC) resin. Fine PVC particleswere formed at low polymerization conversions. The amount of fine panicles decreases as conversion increases anddisappears at conversions greater than 30%. Scanning electron micrographs show that PVC grains are composed of looselycoalesced primary particles, especially for PVC resins prepared in the presence of poly(vinyl alcohol) dispersant. The size ofprimary particles increases and porosity decreases with the increase of conversion. In view of the particle features of PVCresin, a particle formation mechanism including the formation of primary particles and grains is proposed. The formationprocess of primary particles includes the formation of particle nuclei, coalescence of particle nuclei to form primary particles,and growth of primary particles. PVC grains are formed by the coagulation of primary particles. The loose coalescence ofprimary particles is caused by the colloidal stability of primary particles and the low swelling degree of vinyl chloride in the primary particles.
基金Supported by the National Natural Science Foundation of China (No. 29906009).
文摘Suspended emulsion polymerization of vinyl chloride was carried out in a 5 L autoclave. The influence of agitation, polymerization conversion, dispersant and surfactant on the average particle size (PS) and particle size distribution (PSD), particle morphology and porosity of polyvinyl chloride (PVC) resin was investigated. It showed that the agitator had great influence on the smooth operation of polymerization, PS and PSD. The PS increased and PSD became narrow as polymerization conversion became high. The porosity decreased with the increase of conversion. A convenient choice of additives, both dispersants and non-ionic surfactants, allows one to adjust PS and PSD. The PS decreased with the addition of polyvinyl alcohol or hydroxypropyl methylcellulose dispersants,and increased with the addition of Span surfactants. The addition of dispersants or surfactants also affected the morphology and porosity of resin, and PVC resin with looser agglomeration and homogeneous distribution of primary particles was prepared.
基金Supported by the National Natural Science Foundation of China
文摘In the present paper a model equation for calculating the radical desorption rate constant,k<sub>0</sub>,in the emulsion polymerization of vinyl acetate was suggested and the various parameters forevaluating k<sub>0</sub> were determined.Effects of reaction temperature,emulsifier concentration,initiator con-centration,monomer conversion and phase ratio on k<sub>0</sub> were studied.It indicates that the desorptionof radicals from latex particles to aqueous phase must be taken into account in the modelling ofemulsion polymerization for the monomers with higher hydrophilicity such as vinyl acetate.
文摘The behaviour of water soluble and monomer soluble inhibitors in the emulsion polymerization for CaseI system(e.g.vinyl acetate and vinyl chloride)has been studied.The behaviour of monomer soluble inhibitorsis shown to be quite different from that observed in Case Ⅱ emulsion polymerization system.Model predictionsof the effect of these inhibitors on polymer particle nucleation and growth rate are shown to be in satisfactoryagreement with experimental results.
基金Project(2003B10506) supported by Science and Technology Department of Guangdong Province, China
文摘Acrylate latex modified by vinyl triisopropoxy silane (C-1706) was synthesized by seeded emulsion polymerization with anionic emulsifier sodium dodecyl sulphonate(SDS) and nonionic emulsifier OP-10 as the multiple emulsifiers at (78±2) ℃. The effects of different factors, such as the emulsifier, C-1706 monomer and its feeding manner on the properties of acrylate latex modified by C-1706 were investigated. The particle size distribution and the structure, the configuration, the weather durability and stain resistance of copolymer latex were characterized by particle size analyzer, Fourier transform infrared spectroscopy (FT-IR), transmission electron microscope(TEM), scanning electron microscope(SEM) and ultraviolet aging instrument respectively. The results show that SDS to OP-10 as multiple emulsifiers can lead to coordinated efficiency, the optimal emulsifier dosage is 2.4%?3.2%(mass fraction), and the mass ratio of SDS to OP-10 is 1?1? 1?2. The seeded emulsion polymerization can effectively introduce a organic-siloxane bonding in a macromolecule inter polymer, and the obtained acrylate latex modified by organic-siloxane possesses narrow distribution of particle size with mean diameter of 51.8?76.6 nm and has the excellent properties in weather durability and stain-resistance especially.
文摘The emulsion polymerization of highly shear-stable copolymer dispersions of methyl methacrylate and butyl acrylate were carried out using poly （vinyl alcohol） with a thiol end group （PVA-SH） as protective colloid. The dispersions can be transformed into corresponding redispersible powder via a spray dryingcooling process. On-line FT-IR monitoring shows that grafting polymer of PVA-g-PMMA was formed mainly at the stage-1 of the emulsion polymerization. TEM images show, the PVA-SH shell was fragmentary when adding SDS at initial stage and integrated when adding at particle growing or final stage. The particle size turns to be smaller when delayed adding SDS surfactant. Triethanolamine, a co-regulator of PVA-SH, controlled the M to 50 000-70 000 and reduced the PDI to 1.5-1.7. The acrylic dispersions with 0.8wt%-1.5wt% PVA-SH1 can be spray-dried into super dispersible polymer powder （SDPP）, which can easily disperse in water and form recon- stituted dispersions with an average particle size smaller than 1 micron.
文摘Poly (acrylonitrile-co-vinyl acetate)/polypyrrole composite particles with uniform size and morphology have been synthesized using one-step polymerization that involves swelling and coating of polypyrrole (PPy) into P (AN-co-VAc) latex nanoparticles. As an initial stage, free radical copolymerization of acrylonitrile (AN) and vinyl acetate (VAc) was synthesized by emulsion polymerization using ammonium persulfate (APS) and dodecyl benzene sulfonic acid salt (DBSA) as a surfactant. P (AN-co-VAc)/PPy composites were obtained first time by in situ addition of the pyrrole into the reaction medium. The electrospun P (AN-co-VAc)/PPy nanofibers were obtained from the nanoparticles with better properties and the effect of PPy on the morphology of nanofibers was studied by scanning electron microscopy (SEM). High degree of homogeneity and molecular order induced by molecular dispersion of polypyrrole on copolymer matrix without phase separation improve the transport properties and stability of polypyrrole, which are critical for high-performance organic electronics.
文摘研究了一种顶空(HS)-气质联用(GC-MS)的方法来测定乙酸乙烯酯-乙烯共聚物(VAE)中有机物挥发分的方法。首先以N,N-二甲基乙酰胺作为溶剂,加入1 m L,再将1 mL样品置于容器中混合均匀;然后采用静态顶空法,加热使挥发性组分从VAE样品中挥发出来,达到气液两相平衡;随后将顶空瓶上部气体注入气相色谱仪中进行分离,最后导入质谱检测器进行定性分析,采用物质组分的特征质谱图与NIST标准谱库对比进行各物质组成的分析。方法前处理简单、快捷、定性结果准确,能有效指导VAE生产中产品质量的提升。
文摘采用种子乳液聚合,引入乙烯基三甲氧基硅烷(A-171),以十二烷基苯磺酸钠(DSB)和壬基酚聚氧乙烯(20)醚(OP-10)作复合乳化剂,以过硫酸钾(KPS)为引发剂,在反应温度为78±2 ℃条件下,合成了A-171改性醋酸乙烯酯(VAc)-丙烯酸酯共聚乳液.实验采用单体滴加工艺,考察了配方中丙烯酸丁酯(BA)、甲基丙烯酸(MAA)和A-171用量对共聚物性能和乳液聚合过程的影响,并用红外光谱仪(FTIR)、粒度仪和差示量热扫描仪(DSC)对共聚物的结构及性能进行了表征.结果表明,引入w(BA)=10%～15%(相对于配方中单体总质量,下同)、w(MAA)=4%、w(A-171)=1%到VAc -丙烯酸酯共聚物乳液中,共聚物乳液涂膜的吸水率<5.0%,耐寒性通过10个循环,60 ℃加速贮存稳定性>100 d.
