The principles for the modulus method and the percentage method are established and discussed in the part following Part Ⅰ of the series papers, in which we proposed the various algorithms of the strength method and ...The principles for the modulus method and the percentage method are established and discussed in the part following Part Ⅰ of the series papers, in which we proposed the various algorithms of the strength method and the work method. The samples of Wool/PET blended fibre bundles, the method of fibre-bundle tensile tests and the typical specific stress-extension curves from the fibre bundles with different blend ratios are the same as in Part Ⅰ. It can be found that the theoretical results estimated by the modulus and percentage methods accord with the experimental values highly though the calculations of the two methods are slightly more complex than those of the strength and work methods. Especially, using the modulus method can not only avoid the influence of the error caused by the determination of the tensile curve of no fibre breaking in stretching, Y(e), but also need not to know the tensile curves of mono-component fibre bundles in certain calculation. The latter advantage of the modulus method exists in the percentage method too, but it should adopt the improved calculation of ones.展开更多
The blend ratio and tensile properties are vital important characteristics of blended fibre bundles. Fibre-bundle tensile behaviour has been measured by means of the Sirolan-Tensor in order to derive a typical specifi...The blend ratio and tensile properties are vital important characteristics of blended fibre bundles. Fibre-bundle tensile behaviour has been measured by means of the Sirolan-Tensor in order to derive a typical specific stress — extension curve. According to the typical tensile curve, the relationships between the blend ratio and the tensile parameters are discussed and established. Two new algorithms, so-called the strength method and the work method, have been developed for the blend-ratio estimation of blended fibre bundles. The relevant blend-ratios and calculations of the two methods are defined in detail. Also, the characteristics have been explained for every calculation and compared to each others. The experimental results show that the blend ratios estimated from the theoretical methods are high coincidence with the measured results. Meanwhile, the specific stress — extension curve of blended fibre bundles depends directly on the blend ratios of the fibre bundles.展开更多
A series of glass fibre reinforced composites based on novel blend matrices were fabricated us-ing reaction injection moulding （RIM） processing.The blends were made of sub-sequentialinterpenetrating polymer networks...A series of glass fibre reinforced composites based on novel blend matrices were fabricated us-ing reaction injection moulding （RIM） processing.The blends were made of sub-sequentialinterpenetrating polymer networks of acrylic-polyurea or acrylic-copoly（urea-isocyanurate）.Themechanical and thermal properties were characterized by tensile test and dynamic mechanical ana-lysis.The fracture data from single edge notch bend tests were analysed using fracture mechanicsfor the composites to give K<sub>IC</sub> and G<sub>IC</sub>.The correlation between reaction kinetics and morphologyof the blend and the composite properties were discussed.The investigations showed that the novelblends have good bonding property on glass fibre,thus good processability in RIM,and the re-suited composites have good mechanical and thermal properties.展开更多
This paper concerns about the compatibility and morphology of the PBT/PET blended fi-bers.According to the theories of solution thermodynamics,the compatibility of this system hasbeen discussed by using the calculated...This paper concerns about the compatibility and morphology of the PBT/PET blended fi-bers.According to the theories of solution thermodynamics,the compatibility of this system hasbeen discussed by using the calculated results e.g.ΔH<sub>m</sub>,Δδandψ<sub>ab</sub>,which were presented by priorinvestigators.The theoretical predictions show that this system may behave as a compatibilitypair.Meanwhile,the compatibility of the crystalline PBT/PET blend system has been studiedwith the help of DSC,WAXD,DDV and SEM.These experiments have further proved that theamorphous region is miscible and the crystal region is not co-crystal.The morphology of thesystem basically belongs to the“interlocked”network.PBT component plays the important rolein increasing the crystallizability and crystallinity of the PBT/PET blend system.In the range ofthe smaller blending proportion,the crystal structure mainly characterizes the crystal configura-tion of the most component and the blending effects is more satisfactory.展开更多
The algorithms of the strength, work, modulus and percentage methods have been introduced and discussed in Part Ⅰ and Part Ⅱ of the series papers. As the following, the percentage-function calculation and the freque...The algorithms of the strength, work, modulus and percentage methods have been introduced and discussed in Part Ⅰ and Part Ⅱ of the series papers. As the following, the percentage-function calculation and the frequency-function calculation of the definition method are defined and developed in detail. Meanwhile, the procedures to find the tensile parameters are analysed experimentally and involve “ED” being the average values of the corresponding tensile parameters of each bundle tensile curve measured; “EC” being the tensile parameters obtained from the averaged experimental tensile curve; and “TC” being the parameters of the theoretical tensile curve according to the corresponding nominal blend ratio. The theoretical and experimental results indicate that the blend ratio estimated by the definition method from wool/polyester blended fibre bundles has a high correlation with the actual blend ratio though the variables to be known in this method are the most of all the methods and there exist the difficulty to solve fibre bundle tensile behaviour without fibre broken in accuracy and that there are high correlations between the EC and TC data and the tensile parameters should be calculated using the EC method rather than the ED method with the exception of the bundle initial modulus. The relationships between blend ratios and the tensile properties of blended fibre bundles can be used to select the optimum blend ratio of blended tops or yarns.展开更多
The sorption behaviour of acid dyes by soybean protein/poly(vinyl alcohol) blend fibre was studied. The quantity of dye sorbed by the fibre increased markedly with the decrease in the pH of dyebath and reduced with th...The sorption behaviour of acid dyes by soybean protein/poly(vinyl alcohol) blend fibre was studied. The quantity of dye sorbed by the fibre increased markedly with the decrease in the pH of dyebath and reduced with the addition of neutral electrolyte when the pH was below 4.5. Acid dyes exhibited higher sorption rate constant and lower half dyeing time for the fibre than for spun silk and wool, which was related to the special morphological structure of the fibre. At pH 4, the sorption of disulphonated acid dyes with higher molecular weight followed the dual sorption mechanism of Langmuir plus Nernst-type partitioning well as they interacted with the fibre through electrostatic forces, hydrophobic forces and hydrogen bonds. It is considered that soybean protein and PVA components should be simultaneously dyed by disulphonated acid dyes with higher molecular weight.展开更多
According to the yarn forming characteristics in friction spinning, the arrangement of fed sliver is designed, to get the desired fiber distribution in the resultant yarn. On the base of that, the relation between the...According to the yarn forming characteristics in friction spinning, the arrangement of fed sliver is designed, to get the desired fiber distribution in the resultant yarn. On the base of that, the relation between the theoretical fibre distribution and the actual fibre distribution is analyzed by use of electron microscope.展开更多
The phenomenon of a material failure varies with its gauge length in use. In the present study,the breaking strengths of J30/C70 and J55/C45 blended yarns spun by the ring spinning technology were investigated with th...The phenomenon of a material failure varies with its gauge length in use. In the present study,the breaking strengths of J30/C70 and J55/C45 blended yarns spun by the ring spinning technology were investigated with the employment of the equations derived from the Weibull theory. The four probability estimators of the Weibull distribution were also evaluated. The results showed that the estimator (2a) was acceptable for calculating the Weibull modulus of the jute/cotton blended yarns. With the exception of breaking strength of the J30/C70 at the gauge length of 200 mm, the breaking strengths of both blended yarn could be predicted accurately by the Eqs.(9) or (10) in this paper.展开更多
文摘The principles for the modulus method and the percentage method are established and discussed in the part following Part Ⅰ of the series papers, in which we proposed the various algorithms of the strength method and the work method. The samples of Wool/PET blended fibre bundles, the method of fibre-bundle tensile tests and the typical specific stress-extension curves from the fibre bundles with different blend ratios are the same as in Part Ⅰ. It can be found that the theoretical results estimated by the modulus and percentage methods accord with the experimental values highly though the calculations of the two methods are slightly more complex than those of the strength and work methods. Especially, using the modulus method can not only avoid the influence of the error caused by the determination of the tensile curve of no fibre breaking in stretching, Y(e), but also need not to know the tensile curves of mono-component fibre bundles in certain calculation. The latter advantage of the modulus method exists in the percentage method too, but it should adopt the improved calculation of ones.
文摘The blend ratio and tensile properties are vital important characteristics of blended fibre bundles. Fibre-bundle tensile behaviour has been measured by means of the Sirolan-Tensor in order to derive a typical specific stress — extension curve. According to the typical tensile curve, the relationships between the blend ratio and the tensile parameters are discussed and established. Two new algorithms, so-called the strength method and the work method, have been developed for the blend-ratio estimation of blended fibre bundles. The relevant blend-ratios and calculations of the two methods are defined in detail. Also, the characteristics have been explained for every calculation and compared to each others. The experimental results show that the blend ratios estimated from the theoretical methods are high coincidence with the measured results. Meanwhile, the specific stress — extension curve of blended fibre bundles depends directly on the blend ratios of the fibre bundles.
文摘A series of glass fibre reinforced composites based on novel blend matrices were fabricated us-ing reaction injection moulding （RIM） processing.The blends were made of sub-sequentialinterpenetrating polymer networks of acrylic-polyurea or acrylic-copoly（urea-isocyanurate）.Themechanical and thermal properties were characterized by tensile test and dynamic mechanical ana-lysis.The fracture data from single edge notch bend tests were analysed using fracture mechanicsfor the composites to give K<sub>IC</sub> and G<sub>IC</sub>.The correlation between reaction kinetics and morphologyof the blend and the composite properties were discussed.The investigations showed that the novelblends have good bonding property on glass fibre,thus good processability in RIM,and the re-suited composites have good mechanical and thermal properties.
文摘This paper concerns about the compatibility and morphology of the PBT/PET blended fi-bers.According to the theories of solution thermodynamics,the compatibility of this system hasbeen discussed by using the calculated results e.g.ΔH<sub>m</sub>,Δδandψ<sub>ab</sub>,which were presented by priorinvestigators.The theoretical predictions show that this system may behave as a compatibilitypair.Meanwhile,the compatibility of the crystalline PBT/PET blend system has been studiedwith the help of DSC,WAXD,DDV and SEM.These experiments have further proved that theamorphous region is miscible and the crystal region is not co-crystal.The morphology of thesystem basically belongs to the“interlocked”network.PBT component plays the important rolein increasing the crystallizability and crystallinity of the PBT/PET blend system.In the range ofthe smaller blending proportion,the crystal structure mainly characterizes the crystal configura-tion of the most component and the blending effects is more satisfactory.
文摘The algorithms of the strength, work, modulus and percentage methods have been introduced and discussed in Part Ⅰ and Part Ⅱ of the series papers. As the following, the percentage-function calculation and the frequency-function calculation of the definition method are defined and developed in detail. Meanwhile, the procedures to find the tensile parameters are analysed experimentally and involve “ED” being the average values of the corresponding tensile parameters of each bundle tensile curve measured; “EC” being the tensile parameters obtained from the averaged experimental tensile curve; and “TC” being the parameters of the theoretical tensile curve according to the corresponding nominal blend ratio. The theoretical and experimental results indicate that the blend ratio estimated by the definition method from wool/polyester blended fibre bundles has a high correlation with the actual blend ratio though the variables to be known in this method are the most of all the methods and there exist the difficulty to solve fibre bundle tensile behaviour without fibre broken in accuracy and that there are high correlations between the EC and TC data and the tensile parameters should be calculated using the EC method rather than the ED method with the exception of the bundle initial modulus. The relationships between blend ratios and the tensile properties of blended fibre bundles can be used to select the optimum blend ratio of blended tops or yarns.
基金the Science and Technology Development Project of the Chinese Ministry of Science and Technology ( No2004BA304B05-03)
文摘The sorption behaviour of acid dyes by soybean protein/poly(vinyl alcohol) blend fibre was studied. The quantity of dye sorbed by the fibre increased markedly with the decrease in the pH of dyebath and reduced with the addition of neutral electrolyte when the pH was below 4.5. Acid dyes exhibited higher sorption rate constant and lower half dyeing time for the fibre than for spun silk and wool, which was related to the special morphological structure of the fibre. At pH 4, the sorption of disulphonated acid dyes with higher molecular weight followed the dual sorption mechanism of Langmuir plus Nernst-type partitioning well as they interacted with the fibre through electrostatic forces, hydrophobic forces and hydrogen bonds. It is considered that soybean protein and PVA components should be simultaneously dyed by disulphonated acid dyes with higher molecular weight.
文摘According to the yarn forming characteristics in friction spinning, the arrangement of fed sliver is designed, to get the desired fiber distribution in the resultant yarn. On the base of that, the relation between the theoretical fibre distribution and the actual fibre distribution is analyzed by use of electron microscope.
基金National Key Technologies R&D Programof China (No.2007BAE41B01)
文摘The phenomenon of a material failure varies with its gauge length in use. In the present study,the breaking strengths of J30/C70 and J55/C45 blended yarns spun by the ring spinning technology were investigated with the employment of the equations derived from the Weibull theory. The four probability estimators of the Weibull distribution were also evaluated. The results showed that the estimator (2a) was acceptable for calculating the Weibull modulus of the jute/cotton blended yarns. With the exception of breaking strength of the J30/C70 at the gauge length of 200 mm, the breaking strengths of both blended yarn could be predicted accurately by the Eqs.(9) or (10) in this paper.
