A robust viscoelastic surfactant tolerating 20% HCl up to 150℃ for oil well stimulation

Viscoelastic surfactants(VES)are often used as viscous diverters in acidizing stimulation to prolong the acid consumption time and maximize zonal coverage of the acid for improving well productivity.However,the ceiling temperature of commercial VES cannot exceed 120℃in practical use because of the poor thermal stability and fragile molecular structure,hindering their implementation in hightemperature oil reservoirs,i.e.,≥150℃.Here we synthesized a novel C22-tailed diamine,N-erucaminopropyl-N,N-dimethylamine(EDPA),and examined comparatively its rheological behavior,assemblies morphology and molecular stability in 20 wt%HCl with a commercial VES,erucyl dimethyl amidopropyl betaine(EDAB).The feasibility of EDPA for acidizing stimulation was assessed by acid etching of carbonate rock with its HCl solution at 150℃.Rheological results showed that the 2.5 wt%EDPA—20 wt%HCl solution maintains stable viscosity of 90 m Pa s at 150℃for 60 min,while that of 2.0 wt%EDAB HCl solution is just 1 m Pa s under identical conditions.1H NMR spectra and cryo-TEM observations revealed that the chemical structure and self-assembled architectures of EDPA remained intact in such context,but the EDAB suffered from degradation due to the hydrolysis of the amide group,accounting for the poor heat-resistance and acid-tolerance.The reaction rate of 2.5 wt%EDPA HCl solution with carbonate rock was one order of magnitude lower than that of 20 wt%HCl solution at 150℃,underpinning the potential of EDPA to be used in the high-temperature reservoirs acidizing.This work improved the thermal tolerance of VES in highly concentrated HCl solution,paving a feasible way for the acidization of high-temperature reservoir environments(~150℃).

A viscoelastic metamaterial beam for integrated vibration isolation and energy harvesting

Locally resonant metamaterials have low-frequency band gaps and the capability of converging vibratory energy in the band gaps at resonant cells.It has been demonstrated by several researchers that the dissipatioin of vibratory energy within the band gap can be improved by using viscoelastic materials.This paper designs an integrated viscoelastic metamaterial for energy harvesting and vibration isolation.The viscoelastic metamaterial is achieved by a viscoelastic beam periodically arrayed with spatial ball-pendulum nonlinear energy harvesters.The nonlinear resonator with an energy harvesting function is achieved by placing a free-rolling magnetic ball in a spherical cavity with an additional induction coil.The dynamic equations of viscoelastic metamaterials under transverse excitation are established,and the energy harvesting and vibration isolation characteristics within the dispersion relation of viscoelastic metamaterials are analyzed.The results show that the vibrations of the main body of the viscoelastic metamaterial beam are significantly suppressed in the frequency range of the local resonance band gap.At the same time,the elastic waves are limited in the nonlinear resonator with an energy harvesting function,which improves the energy output.Finally,an experimental platform of viscoelastic metamaterial vibration is established for validation purposes.

The effect of reactive plasticizer on viscoelastic and mechanical properties of solid rocket propellants based on different types of HTPB resin

Conventional plasticizers deteriorate mechanical and viscoelastic properties of the propellants due to their migration upon aging and long-term storage,which affects reliability and safety properties during exploitation.To address this issue,conventional plasticizer,dioctyl adipate(DOA),is replaced by reactive one,castor oil(CO).In addition,three different types of HTPB were used to obtain propellants with designed viscoelastic and mechanical properties.The CO increased propellants viscosity,without a significant impact on the propellant processability,regardless to the type of prepolymer.Conversely,mechanical properties were different depending on the type of resin,which were further analyzed by gel permeation chromatography(GPC).Addition of CO formed a denser polymer network and shifted T_(g) to higher values,compared to the compositions with DOA.The tensile strength of CO-containing propellants was lower at +20℃ and +50℃ compared to the reference compositions,while the strain at maximum load and strain at break were significantly increased with pronounced plastic deformation,especially for samples at -30℃.The inclusion of CO in the propellants composition gives more room for adjusting a wide range of mechanical properties.

Development of a Three-Dimensional Multiscale Octree SBFEM for Viscoelastic Problems of Heterogeneous Materials

The multiscale method provides an effective approach for the numerical analysis of heterogeneous viscoelastic materials by reducing the degree of freedoms(DOFs).A basic framework of the Multiscale Scaled Boundary Finite Element Method(MsSBFEM)was presented in our previous works,but those works only addressed two-dimensional problems.In order to solve more realistic problems,a three-dimensional MsSBFEM is further developed in this article.In the proposed method,the octree SBFEM is used to deal with the three-dimensional calculation for numerical base functions to bridge small and large scales,the three-dimensional image-based analysis can be conveniently conducted in small-scale and coarse nodes can be flexibly adjusted to improve the computational accuracy.Besides,the Temporally Piecewise Adaptive Algorithm(TPAA)is used to maintain the computational accuracy of multiscale analysis by adaptive calculation in time domain.The results of numerical examples show that the proposed method can significantly reduce the DOFs for three-dimensional viscoelastic analysis with good accuracy.For instance,the DOFs can be reduced by 9021 times compared with Direct Numerical Simulation(DNS)with an average error of 1.87%in the third example,and it is very effective in dealing with three-dimensional complex microstructures directly based on images without any geometric modelling process.

Intraocular pressure before and after capsulorhexis using two viscoelastic substances and two surgical approaches in enucleated porcine eyes

AIM:To investigate the influence of ophthalmic viscoelastic devices(OVDs)and different surgical approaches on the intraocular pressure(IOP)before and after creation of the curvilinear circular capsulorhexis(CCC)as a measure for anterior chamber stability during this maneuver.METHODS:Prospective experimental WetLab study carried out on enucleated porcine eyes.IOP was measured before and after CCC with the iCare Rebound tonometer(iCare ic200;iCare Finland Oy,Vantaa,Finland).The OVDs used were a cohesive one[Z-Hyalin,Carl Zeiss Meditec AG,Germany;hyaluronic acid(HA)]and a dispersive[Z-Celcoat,Carl Zeiss Meditec AG,Germany;hydroxy propylmethylcellulosis(HPMC)].The CCC was created using Utrata forceps or 23 g microforceps in different combinations with the OVDs.RESULTS:Using the Utrata forceps the IOP dropped from 63.65±6.44 to 11.25±3.63 mm Hg during the CCC.The use of different OVDs made no difference.Using the 23 g microforceps the IOP dropped from 65.35±8.15 to 36.55±6.09 mm Hg.The difference between IOP drop using either Utrata forceps or 23 g microforceps was highly significant regardless of the OVD used.CONCLUSION:Using the sideport for the creation of the capsulorhexis leads to a lesser drop in IOP during this maneuver compared to the main incision in enucleated porcine eyes.The use of different OVD has no significant influence on IOP drop.

A flexible multiscale algorithm based on an improved smoothed particle hydrodynamics method for complex viscoelastic flows

Viscoelastic flows play an important role in numerous engineering fields,and the multiscale algorithms for simulating viscoelastic flows have received significant attention in order to deepen our understanding of the nonlinear dynamic behaviors of viscoelastic fluids.However,traditional grid-based multiscale methods are confined to simple viscoelastic flows with short relaxation time,and there is a lack of uniform multiscale scheme available for coupling different solvers in the simulations of viscoelastic fluids.In this paper,a universal multiscale method coupling an improved smoothed particle hydrodynamics(SPH)and multiscale universal interface(MUI)library is presented for viscoelastic flows.The proposed multiscale method builds on an improved SPH method and leverages the MUI library to facilitate the exchange of information among different solvers in the overlapping domain.We test the capability and flexibility of the presented multiscale method to deal with complex viscoelastic flows by solving different multiscale problems of viscoelastic flows.In the first example,the simulation of a viscoelastic Poiseuille flow is carried out by two coupled improved SPH methods with different spatial resolutions.The effects of exchanging different physical quantities on the numerical results in both the upper and lower domains are also investigated as well as the absolute errors in the overlapping domain.In the second example,the complex Wannier flow with different Weissenberg numbers is further simulated by two improved SPH methods and coupling the improved SPH method and the dissipative particle dynamics(DPD)method.The numerical results show that the physical quantities for viscoelastic flows obtained by the presented multiscale method are in consistence with those obtained by a single solver in the overlapping domain.Moreover,transferring different physical quantities has an important effect on the numerical results.

Tensile Shock Physics in Compressible Thermoviscoelastic Solid Medium

This paper addresses tensile shock physics in thermoviscoelastic (TVE) solids without memory. The mathematical model is derived using conservation and balance laws (CBL) of classical continuum mechanics (CCM), incorporating the contravariant second Piola-Kirchhoff stress tensor, the covariant Green’s strain tensor, and its rates up to order n. This mathematical model permits the study of finite deformation and finite strain compressible deformation physics with an ordered rate dissipation mechanism. Constitutive theories are derived using conjugate pairs in entropy inequality and the representation theorem. The resulting mathematical model is both thermodynamically and mathematically consistent and has closure. The solution of the initial value problems (IVPs) describing evolutions is obtained using a variationally consistent space-time coupled finite element method, derived using space-time residual functional in which the local approximations are in hpk higher-order scalar product spaces. This permits accurate description problem physics over the discretization and also permits precise a posteriori computation of the space-time residual functional, an accurate measure of the accuracy of the computed solution. Model problem studies are presented to demonstrate tensile shock formation, propagation, reflection, and interaction. A unique feature of this research is that tensile shocks can only exist in solid matter, as their existence requires a medium to be elastic (presence of strain), which is only possible in a solid medium. In tensile shock physics, a decrease in the density of the medium caused by tensile waves leads to shock formation ahead of the wave. In contrast, in compressive shocks, an increase in density and the corresponding compressive waves result in the formation of compression shocks behind of the wave. Although these are two similar phenomena, they are inherently different in nature. To our knowledge, this work has not been reported in the published literature.

Hermite Finite Element Method for Vibration Problem of Euler-Bernoulli Beam on Viscoelastic Pasternak Foundation

Viscoelastic foundation plays a very important role in civil engineering. It can effectively disperse the structural load into the foundation soil and avoid the damage caused by the concentrated load. The model of Euler-Bernoulli beam on viscoelastic Pasternak foundation can be used to analyze the deformation and response of buildings under complex geological conditions. In this paper, we use Hermite finite element method to get the numerical approximation scheme for the vibration equation of viscoelastic Pasternak foundation beam. Convergence and error estimation are rigourously established. We prove that the fully discrete scheme has convergence order O(τ2+h4), where τis time step size and his space step size. Finally, we give four numerical examples to verify the validity of theoretical analysis.

On wave dispersion of rotating viscoelastic nanobeam based on general nonlocal elasticity in thermal environment

The present research focuses on the analysis of wave propagation on a rotating viscoelastic nanobeam supported on the viscoelastic foundation which is subject to thermal gradient effects.A comprehensive and accurate model of a viscoelastic nanobeam is constructed by using a novel nonclassical mechanical model.Based on the general nonlocal theory(GNT),Kelvin-Voigt model,and Timoshenko beam theory,the motion equations for the nanobeam are obtained.Through the GNT,material hardening and softening behaviors are simultaneously taken into account during wave propagation.An analytical solution is utilized to generate the results for torsional(TO),longitudinal(LA),and transverse(TA)types of wave dispersion.Moreover,the effects of nonlocal parameters,Kelvin-Voigt damping,foundation damping,Winkler-Pasternak coefficients,rotating speed,and thermal gradient are illustrated and discussed in detail.

Non-harmonic resonance of viscoelastic structures subjected to time-dependent exponentially decreasing transverse distributed loads

In this paper,the non-harmonic resonance of Bernoulli viscoelastic beams,Kirchhoff viscoelastic plates,Timoshenko viscoelastic beams,and Mindlin viscoelastic plates subjected to time-dependent exponentially decreasing transverse distributed load is investigated for the first time.The constitutive equations are expressed utilizing Boltzmann integral law with a constant bulk modulus.The displacement vector is approximated by employing the separation of variables method.The Laplace transformation is used to transfer equations from the time domain to the Laplace domain and vice versa.The novel point of the proposed method is to express,prove and calculate the critical time in which the displacement will be several times the displacement at time zero.In addition,this new method calculates the maximum deflection at the critical time,explicitly and exactly,without any need to follow the time-displacement curve with a low computational cost.Additionally,the proposed method introduces the critical range of time so that the responses are greater than the responses at time zero.

Computational-Analysis of the Non-Isothermal Dynamics of the Gravity-Driven Flow of Viscoelastic-Fluid-Based Nanofluids Down an Inclined Plane

The paper explores the gravity-driven flow of the thin film of a viscoelastic-fluid-based nanofluids(VFBN)along an inclined plane under non-isothermal conditions and subjected to convective cooling at the free-surface.The Newton’s law of cooling is used to model the convective heat-exchange with the ambient at the free-surface.The Giesekus viscoelastic constitutive model,with appropriate modifications to account for non-isothermal effects,is employed to describe the polymeric effects.The unsteady and coupled non-linear partial differential equations(PDEs)describing the model problem are obtained and solved via efficient semi-implicit numerical schemes based on finite difference methods(FDM)implemented in Matlab.The response of the VFBN velocity,temperature,thermal-conductivity and polymeric-stresses to variations in the volume-fraction of embedded nanoparticles is investigated.It is shown that these quantities all increase as the nanoparticle volume-fraction becomes higher.

A Thermochromic, Viscoelastic Nacre-like Nanocomposite for the Smart Thermal Management of Planar Electronics

Cutting-edge heat spreaders for soft and planar electronics require not only high thermal conductivity and a certain degree of flexibility but also remarkable self-adhesion without thermal interface materials, elasticity, arbitrary elongation along with soft devices, and smart properties involving thermal self-healing, thermochromism and so on. Nacre-like composites with excellent in-plane heat dissipation are ideal as heat spreaders for thin and planar electronics. However, the intrinsically poor viscoelasticity, i.e., adhesion and elasticity, prevents them from simultaneous self-adhesion and arbitrary elongation along with current flexible devices as well as incurring high interfacial thermal impedance. In this paper, we propose a soft thermochromic composite(STC) membrane with a layered structure, considerable stretchability, high in-plane thermal conductivity(~30 Wm^(-1) K^(-1)), low thermal contact resistance(~12 mm^2 KW^(-1), 4–5 times lower than that of silver paste), strong yet sustainable adhesion forces(~4607 Jm^(-2), 2220 Jm^(-2) greater than that of epoxy paste) and self-healing efficiency. As a self-adhesive heat spreader, it implements efficient cooling of various soft electronics with a temperature drop of 20℃ than the polyimide case. In addition to its self-healing function, the chameleon-like behavior of STC facilitates temperature monitoring by the naked eye, hence enabling smart thermal management.

Viscoelastic Burger’s model for tunnels supported with tangentially yielding liner

This study proposed an analytical model for the tunnel supported with a tangentially yielding liner in viscoelastic ground.The efficiency of the developed analytical model was verified by comparing the calculated results with associated numerical simulation results.Using the analytical model,a comprehensive parameter sensitivity analysis was performed to examine the effects of the rate of tunnel face advancement,concrete liner thickness,installation time of liner,and strength and thickness of yielding elements on the tunnel responses.The results highlight the significant benefit of the tangentially yielding liner to relieve overstress in the tunnel liner and improve the stability of the tunnel.The yield efficiency of the tangentially yielding liner depends highly on the yielding strength and deformable capacity of the yielding elements and less on the installation time.

Effects of viscoelasticity on the stability and bifurcations of nonlinear energy sinks

Due to the increasing use of passive absorbers to control unwanted vibrations,many studies have been done on energy absorbers ideally,but the lack of studies of real environmental conditions on these absorbers is felt.The present work investigates the effect of viscoelasticity on the stability and bifurcations of a system attached to a nonlinear energy sink(NES).In this paper,the Burgers model is assumed for the viscoelasticity in an NES,and a linear oscillator system is considered for investigating the instabilities and bifurcations.The equations of motion of the coupled system are solved by using the harmonic balance and pseudo-arc-length continuation methods.The results show that the viscoelasticity affects the frequency intervals of the Hopf and saddle-node branches,and by increasing the stiffness parameters of the viscoelasticity,the conditions of these branches occur in larger ranges of the external force amplitudes,and also reduce the frequency range of the branches.In addition,increasing the viscoelastic damping parameter has the potential to completely eliminate the instability of the system and gradually reduce the amplitude of the jump phenomenon.

Modelling and predicting the dynamic response of an axially graded viscoelastic core sandwich beam

The present study explored the influence of axial gradation of viscoelastic materials on the dynamic response of the sandwich beam for structural applications.The finite element(FE)formulations are used to model and investigate dynamic response of the sandwich beam.The classical beam theory is used to develop the FE formulations and Lagrange's approach is considered to obtain the equations of motion(EOM).FE code is developed and validated with the existing literature and also conducted the convergence study for the developed FE method.Further,the influence of different viscoelastic materials and boundary conditions on the dynamic response of the sandwich beam is investigated.Four different axial gradation configurations of viscoelastic materials are considered for the present work to explore the influence on natural frequency,loss factor and frequency response of the sandwich beam.The modeled axial gradation of viscoelastic material has displayed a considerable impact on the peak vibrational amplitude response of the sandwich beam for all the boundary conditions and these configurations improved the damping capabilities at different configurations for the structural applications.

Nonlocal stress gradient formulation for damping vibration analysis of viscoelastic microbeam in thermal environment

An integral nonlocal stress gradient viscoelastic model is proposed on the basis of the integral nonlocal stress gradient model and the standard viscoelastic model,and is utilized to investigate the free damping vibration analysis of the viscoelastic BernoulliEuler microbeams in thermal environment.Hamilton's principle is used to derive the differential governing equations and corresponding boundary conditions.The integral relations between the strain and the nonlocal stress are converted into a differential form with constitutive constraints.The size-dependent axial thermal stress due to the variation of the environmental temperature is derived explicitly.The Laplace transformation is utilized to obtain the explicit expression for the bending deflection and moment.Considering the boundary conditions and constitutive constraints,one can get a nonlinear equation with complex coefficients,from which the complex characteristic frequency can be determined.A two-step numerical method is proposed to solve the elastic vibration frequency and the damping ratio.The effects of length scale parameters,viscous coefficient,thermal stress,vibration order on the vibration frequencies,and critical viscous coefficient are investigated numerically for the viscoelastic Bernoulli-Euler microbeams under different boundary conditions.

A sutureless technique for securing leaking sclerotomies with viscoelastic substances in 23-gauge microincision vitrectomy surgery

AIM:To introduce and evaluate the clinical efficacy of a new technique,the use of viscoelastic substances(VS)to close leaking sclerotomy in 23G microincision vitrectomy,and to observe its effect on the visual acuity and intraocular pressure(IOP)of patients.METHODS:Patients who underwent 23G vitrectomy in Ningbo Eye Hospital before the use of VS technique(June 2019 to September 2020)and after the use of VS technique(October 2020 to December 2021)were selected as the subjects of this study.The above cases underwent operation by the same surgeon and were retrospectively analyzed.VS technique was used as the alternative to suturing,in which a small amount of VS was injected at the leaking sclerotomy and then gently massaged to confirm leaking sclerotomy closure.RESULTS:A total of 174 eyes were covered in the study,including 84 eyes in the control group(before the use of VS technique)and 90 eyes in the VS technique group.The number of eyes that needed to be sutured decreased considerably from 42.9%in the control group to 3.3%in the VS technique group,and the proportion of subconjunctival hemorrhage at 1-2d after surgery decreased remarkably from 35.7%in the control group to 2.2%in the VS technique group.No substantial differences in the incidence of mean IOP and low IOP were found between 1-2 and 3-20d after surgery in the VS technique group.No major complications associated with VS technique were identified during the study.CONCLUSION:In 23G microincision vitrectomy,VS technique is a safe,simple,and effective method to close leaking sclerotomy.

Unified two-phase nonlocal formulation for vibration of functionally graded beams resting on nonlocal viscoelastic Winkler-Pasternak foundation

A nonlocal study of the vibration responses of functionally graded(FG)beams supported by a viscoelastic Winkler-Pasternak foundation is presented.The damping responses of both the Winkler and Pasternak layers of the foundation are considered in the formulation,which were not considered in most literature on this subject,and the bending deformation of the beams and the elastic and damping responses of the foundation as nonlocal by uniting the equivalently differential formulation of well-posed strain-driven(ε-D)and stress-driven(σ-D)two-phase local/nonlocal integral models with constitutive constraints are comprehensively considered,which can address both the stiffness softening and toughing effects due to scale reduction.The generalized differential quadrature method(GDQM)is used to solve the complex eigenvalue problem.After verifying the solution procedure,a series of benchmark results for the vibration frequency of different bounded FG beams supported by the foundation are obtained.Subsequently,the effects of the nonlocality of the foundation on the undamped/damping vibration frequency of the beams are examined.

Finite-difference modeling of Maxwell viscoelastic media developed from perfectly matched layer

In numerical simulation of wave propagation,both viscoelastic materials and perfectly matched layers(PMLs)attenuate waves.The wave equations for both the viscoelastic model and the PML contain convolution operators.However,convolution operator is intractable in finite-difference time-domain(FDTD)method.A great deal of progress has been made in using time stepping instead of convolution in FDTD.To incorporate PML into viscoelastic media,more memory variables need to be introduced,which increases the code complexity and computation costs.By modifying the nonsplitting PML formulation,I propose a viscoelastic model,which can be used as a viscoelastic material and/or a PML just by adjusting the parameters.The proposed viscoelastic model is essentially equivalent to a Maxwell model.Compared with existing PML methods,the proposed method requires less memory and its implementation in existing finite-difference codes is much easier.The attenuation and phase velocity of P-and S-waves are frequency independent in the viscoelastic model if the related quality factors(Q)are greater than 10.The numerical examples show that the method is stable for materials with high absorption(Q=1),and for heterogeneous media with large contrast of acoustic impedance and large contrast of viscosity.

Rayleigh–Taylor instability of viscoelastic self-rewetting film flowing down a temperature-controlled inclined substrate

Rayleigh–Taylor(RT) instability of gravity-driven viscoelastic self-rewetting film flowing under an inclined substrate uniformly heated or cooled is considered. The surface tension of self-rewetting film is considered as a quadratic function of temperature. The long wave hypothesis is used to derive a nonlinear free surface evolution equation of the thin viscoelastic film. Linear stability analysis shows that for a prescribed the viscoelastic coefficient, substrate cooling products instability,while substrate heating remains stability. Furthermore, we analyze the influence of viscoelastic coefficient on RT instability. Results show that the viscoelastic coefficient reinforces the RT instability whether the substrate is heated or cooled.Moreover, we use the line method to numerically simulate the nonlinear evolution equation and systematically examine the space-time variation of the film free surface. The numerical results illustrate that increasing the viscoelastic coefficient can enhance the disturbance amplitude and wave frequency. This means that the viscoelastic coefficient makes the system unstable, which is consistent with result of the linear stability analysis. In addition, the oscillation tends to accumulate downstream of the inclined substrate when the evolution time is long enough. Finally, the variation of film thickness with related parameters for different viscoelastic coefficients is investigated.