Viscosity stability indexes of mold flux at high temperature and low temperature havebeen introduced and the effects of flux compositions on viscosity stability indexeshave been studied. Two mold fluxes have been deve...Viscosity stability indexes of mold flux at high temperature and low temperature havebeen introduced and the effects of flux compositions on viscosity stability indexeshave been studied. Two mold fluxes have been developed by analyzing the effects offlux viscosity stability on the process and the condition of continuous casting slab ofmedium carbon steel. The results show that the fluxes are suitable for the process.展开更多
Viscosity index (VI) and shear stability index (SSI) are standard methods used in the lubricant industry to determine temperature-viscosity dependency and resistance to product degradation, respectively. A variety of ...Viscosity index (VI) and shear stability index (SSI) are standard methods used in the lubricant industry to determine temperature-viscosity dependency and resistance to product degradation, respectively. A variety of oil-soluble polymers, including poly(alkyl methacrylates) (PAMAs) are routinely used to control these properties in fully-formulated liquid lubricants. In this report, we use reversible addition-fragmentation chain transfer (RAFT) polymerization to precisely target identical degrees of polymerization in a family of PAMAs with varying lauryl, hexyl, butyl, ethyl, and methyl groups. Then, expanding on previous methodology reported in the literature, we establish structure property relationships for these PAMAs, specifically looking at how intrinsic viscosity [η] and Martin interaction parameters K<sub>M</sub> relate to VI and SSI characteristics. While the intrinsic viscosity [η] is associated with the volume of macromolecules at infinite dilution, the parameter K<sub>M</sub> reflects the hydrodynamic interactions of polymer chains at actual polymer concentrations in lubricating oils. In this paper, we show that the dependence of VI on the non-dimensional concentration c/c* (or c[η]) can be presented in a form of master curve with shift factors proportional to K<sub>M</sub> that decreases with increasing size of alkyl groups. This finding implies that even in the dilute regime, the coil-expansion theory used to explain the effect of macromolecules on VI should be complemented with the idea of hydrodynamic interactions between polymer molecules that can be controlled by the choice of alkyl chains in the family of PAMAs.展开更多
Polyalkylmethacrylate (PAMA) based viscosity index improver (VII) and pour point depressant (PPD), with the versatile chemistry and unique performance characteristics, are widely used in advanced formulations, enablin...Polyalkylmethacrylate (PAMA) based viscosity index improver (VII) and pour point depressant (PPD), with the versatile chemistry and unique performance characteristics, are widely used in advanced formulations, enabling fluids to meet rheological requirement of modern specifications. This paper will be dedicated to the application of PAMA in helping China automotive lubricant formulators tackle the challenges of improving fuel economics from using lower viscosity fluids, of better protection strengthten in transmission performance and meeting new global specifications for low temperature performance.展开更多
文摘Viscosity stability indexes of mold flux at high temperature and low temperature havebeen introduced and the effects of flux compositions on viscosity stability indexeshave been studied. Two mold fluxes have been developed by analyzing the effects offlux viscosity stability on the process and the condition of continuous casting slab ofmedium carbon steel. The results show that the fluxes are suitable for the process.
文摘Viscosity index (VI) and shear stability index (SSI) are standard methods used in the lubricant industry to determine temperature-viscosity dependency and resistance to product degradation, respectively. A variety of oil-soluble polymers, including poly(alkyl methacrylates) (PAMAs) are routinely used to control these properties in fully-formulated liquid lubricants. In this report, we use reversible addition-fragmentation chain transfer (RAFT) polymerization to precisely target identical degrees of polymerization in a family of PAMAs with varying lauryl, hexyl, butyl, ethyl, and methyl groups. Then, expanding on previous methodology reported in the literature, we establish structure property relationships for these PAMAs, specifically looking at how intrinsic viscosity [η] and Martin interaction parameters K<sub>M</sub> relate to VI and SSI characteristics. While the intrinsic viscosity [η] is associated with the volume of macromolecules at infinite dilution, the parameter K<sub>M</sub> reflects the hydrodynamic interactions of polymer chains at actual polymer concentrations in lubricating oils. In this paper, we show that the dependence of VI on the non-dimensional concentration c/c* (or c[η]) can be presented in a form of master curve with shift factors proportional to K<sub>M</sub> that decreases with increasing size of alkyl groups. This finding implies that even in the dilute regime, the coil-expansion theory used to explain the effect of macromolecules on VI should be complemented with the idea of hydrodynamic interactions between polymer molecules that can be controlled by the choice of alkyl chains in the family of PAMAs.
文摘Polyalkylmethacrylate (PAMA) based viscosity index improver (VII) and pour point depressant (PPD), with the versatile chemistry and unique performance characteristics, are widely used in advanced formulations, enabling fluids to meet rheological requirement of modern specifications. This paper will be dedicated to the application of PAMA in helping China automotive lubricant formulators tackle the challenges of improving fuel economics from using lower viscosity fluids, of better protection strengthten in transmission performance and meeting new global specifications for low temperature performance.
