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GLOBAL EXISTENCE OF CLASSICAL SOLUTION FOR A VISCOUS LIQUID-GAS TWO-PHASE MODEL WITH MASS-DEPENDENT VISCOSITY AND VACUUM 被引量:2
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作者 王振 张卉 《Acta Mathematica Scientia》 SCIE CSCD 2014年第1期39-52,共14页
In this work, we obtain the global existence and uniqueness of classical solu-tions to a viscous liquid-gas two-phase model with mass-dependent viscosity and vacuum in one dimension, where the initial vacuum is allowe... In this work, we obtain the global existence and uniqueness of classical solu-tions to a viscous liquid-gas two-phase model with mass-dependent viscosity and vacuum in one dimension, where the initial vacuum is allowed. We get the upper and lower bounds of gas and liquid masses n and m by the continuity methods which we use to study the compressible Navier-Stokes equations. 展开更多
关键词 viscous liquid-gas two-phase model global classical solution VACUUM mass-dependent viscosity
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Effect of Continuous Phase Viscosity on Membrane Emulsification
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作者 王志 王世昌 +1 位作者 Volker Schroeder Helmar Schubert 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2000年第2期108-112,共5页
Oil-in-water(o/w) emulsions were produced with a membrane emulsification system. The effect of the continuous phase viscosity on the emulsification was studied. The theoretical analyses show that the continuous phase ... Oil-in-water(o/w) emulsions were produced with a membrane emulsification system. The effect of the continuous phase viscosity on the emulsification was studied. The theoretical analyses show that the continuous phase viscosity influences not only the flow field of the continuous phase but also the interfacial tension. The droplet size distribution and disperse phase flux for different continuous phase viscosity were investigated experimentally at constant wall shear stress and constant volume flow rate of the continuous phase respectively. 展开更多
关键词 membrane emulsification viscosity continuous phase
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Influence of substituting B_(2)O_(3) with Li_(2)O on the viscosity,structure and crystalline phase of low-reactivity mold flux
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作者 Rongzhen Mo Xubin Zhang +2 位作者 Ying Ren Junjie Hu Lifeng Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2023年第7期1320-1328,共9页
The low-reactivity mold flux with low SiO_(2)content is considered suitable for the continuous casting of high-aluminum steel since it can significantly reduce the reaction between Al in steel and SiO_(2)in mold flux.... The low-reactivity mold flux with low SiO_(2)content is considered suitable for the continuous casting of high-aluminum steel since it can significantly reduce the reaction between Al in steel and SiO_(2)in mold flux.However,the traditional low-reactivity mold flux still presents some problems such as high viscosity and strong crystallization tendency.In this study,the co-addition of Li_(2)O and B_(2)O_(3)in CaO–Al_(2)O_(3)–10wt%Si O_(2)based low-reactivity mold flux was proposed to improve properties of mold flux for high-aluminum steel,and the effect of Li_(2)O replacing B_(2)O_(3)on properties of mold flux was investigated.The viscosity of the mold flux with 2wt%Li_(2)O and 6wt%B_(2)O_(3)reached a minimum value of 0.07 Pa·s.The break temperature and melting point showed a similar trend with the viscosity.Besides,the melt structure and precipitation of the crystalline phase were studied using Raman and X-ray diffraction spectra to better understand the evolution of viscosity.It demonstrated that with increasing Li_(2)O content in the mold flux from 0 to 6 wt%,the degree of polymerization of aluminate and the aluminosilicate network structure increased because of increasing Li+released by Li_(2)O,indicating the added Li_(2)O was preferentially associated with Al^(3+)as a charge compensator.The precipitation of LiAlO_(2)crystalline phase gradually increased with the replacement of B_(2)O_(3)by Li_(2)O.Therefore,Li_(2)O content should be controlled below 2wt%to avoid LiAlO_(2)precipitation,which was harmful to the continuous casting of highaluminum steels. 展开更多
关键词 low-reactivity mold flux viscosity STRUCTURE crystalline phase
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Experimental investigation of the effects of various parameters on viscosity reduction of heavy crude by oil-water emulsion 被引量:3
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作者 Talal Al-Wahaibi Yahya Al-Wahaibi +2 位作者 Abdul-Aziz R.Al-Hashmi Farouq S.Mjalli Safiya Al-Hatmi 《Petroleum Science》 SCIE CAS CSCD 2015年第1期170-176,共7页
The effects of water content, shear rate, temperature, and solid particle concentration on viscosity reduction (VR) caused by forming stable emulsions were investigated using Omani heavy crude oil. The viscosity of ... The effects of water content, shear rate, temperature, and solid particle concentration on viscosity reduction (VR) caused by forming stable emulsions were investigated using Omani heavy crude oil. The viscosity of the crude oil was initially measured with respect to shear rates at different temperatures from 20 to 70℃. The crude oil exhibited a shear thinning behavior at all the temperatures. The strongest shear thinning was observed at 20℃. A non-ionic water soluble surfactant (Triton X-100) was used to form and stabilize crude oil emulsions. The emulsification process has significantly reduced the crude oil viscosity. The degree of VR was found to increase with an increase in water content and reach its maximum value at 50 % water content. The phase inversion from oil- oil emulsion occurred at 30 in-water emulsion to water-in- % water content. The results indicated that the VR was inversely proportional to temperature and concentration of silica nanoparticles. For water-in-oil emulsions, VR increased with shear rate and eventually reached a plateau at a shear rate of around 350 s^-1. This was attributed to the thinning behavior of the continuous phase. The VR of oil-in-water emulsions remained almost constant as the shear rate increased due to the Newtonian behavior of water, the continuous phase. 展开更多
关键词 viscosity reduction phase inversion Non-newtonian fluid Oil-in-water emulsions Heavy crude oil
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Shear viscosity to entropy density ratio in BUU transport model 被引量:1
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作者 LI Shaoxin FANG Deqing +1 位作者 MA Yugang ZHOU Chenglong 《Nuclear Science and Techniques》 SCIE CAS CSCD 2011年第4期235-239,共5页
Shear viscosity (η) is a basic transport coefficient of the medium.In this work,we calculate shear viscosity to entropy density ratio (η/S) of an equilibrated system in intermediate energy heavy ion collisions withi... Shear viscosity (η) is a basic transport coefficient of the medium.In this work,we calculate shear viscosity to entropy density ratio (η/S) of an equilibrated system in intermediate energy heavy ion collisions within the framework of the Boltzmann-Uehling-Uhlenbeck model (BUU) model.After the equilibration of Au + Au system at central collision in a fixed volume is reached,temperature,pressure and energy density are extracted by the phase space information and then η/S is calculated using the Green-Kubo formulas.The results show that η/S drops with the incident energy and its value is not so drastically different from the RHIC results. 展开更多
关键词 剪切粘度 运输模型 密度比 BOLTZMANN 中能重离子碰撞 平衡系统 运输系数
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Experimental Investigation of the Influence of Fuel Viscosity on the Spray Characteristics of Diesel Nozzle
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作者 吕兴才 乔信起 +1 位作者 陈剑 黄震 《Journal of Shanghai Jiaotong university(Science)》 EI 2007年第1期61-65,共5页
This paper presented an investigation of atomization characteristics including the velocity vector field and the mean droplet sizes for different percentages of DMM-diesel blended fuels using a phase doppler anemometr... This paper presented an investigation of atomization characteristics including the velocity vector field and the mean droplet sizes for different percentages of DMM-diesel blended fuels using a phase doppler anemometry (PDA) analyzer system. Based on the fuel design concept, an oxygenated fuel named dimethoxy methane (DMM), which has lower viscosity, surface tension, and boiling point, was used to blend with diesel. The experiments were carried out under atmospheric conditions on a single-hole type diesel nozzle, liquid conditions comprise a temperature of 298 K under the needle valve opening pressure of 6 MPa. The results show that the sauter mean diameter (SMD) and spray cone angle of blended fuels decrease with the increase of DMM content; the axial mean velocity in the centerline increases with the increase of DMM. However, the spray behavior of blended fuel in which DMM exceeds 75% is virtually identical to that of neat DMM. The measurement also reveals the existence of an "S" shape in the radial mean velocity variations with radial distance. 展开更多
关键词 spray characteristics phase doppler anemometry (PDA) fuel design concept dimethoxy methane(DMM) kinetic viscosity
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Numerical method for simulating rarefaction shocks in the approximation of phase-flip hydrodynamics 被引量:1
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作者 M.M.BASKO 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2021年第6期871-884,共14页
A finite-difference algorithm is proposed for numerical modeling of hydrodynamic flows with rarefaction shocks, in which the fluid undergoes a jump-like liquid-gas phase transition. This new type of flow discontinuity... A finite-difference algorithm is proposed for numerical modeling of hydrodynamic flows with rarefaction shocks, in which the fluid undergoes a jump-like liquid-gas phase transition. This new type of flow discontinuity, unexplored so far in computational fluid dynamics, arises in the approximation of phase-flip(PF) hydrodynamics, where a highly dynamic fluid is allowed to reach the innermost limit of metastability at the spinodal, upon which an instantaneous relaxation to the full phase equilibrium(EQ) is assumed. A new element in the proposed method is artificial kinetics of the phase transition, represented by an artificial relaxation term in the energy equation for a "hidden"component of the internal energy, temporarily withdrawn from the fluid at the moment of the PF transition. When combined with an appropriate variant of artificial viscosity in the Lagrangian framework, the latter ensures convergence to exact discontinuous solutions, which is demonstrated with several test cases. 展开更多
关键词 fluid dynamics with phase transitions two-phase flow rarefaction shock Lagrangian scheme artificial viscosity artificial kinetics
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Conditions and Phase Shift of Fluid Resonance in Narrow Gaps of Bottom Mounted Caissons
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作者 ZHU Da-tong WANG Xing-gang LIU Qing-jun 《China Ocean Engineering》 SCIE EI CSCD 2017年第6期724-735,共12页
This paper studies the viscid and inviscid fluid resonance in gaps of bottom mounted caissons onthe basis of the plane wave hypothesis and full wave model, The theoretical analysis and the numerical results demonstrat... This paper studies the viscid and inviscid fluid resonance in gaps of bottom mounted caissons onthe basis of the plane wave hypothesis and full wave model, The theoretical analysis and the numerical results demonstrate that the condition for the appearance of fluid resonance in narrow gaps is kh=(2n+1)π (n=0, 1, 2, 3 ), rather than kh=nn (n=0, 1, 2, 3, ...); the transmission peaks in viscid fluid are related to the resonance peaks in the gaps. k and h stand for the wave number and the gap length. The combination of the plane wave hypothesis or the full wave model with the local viscosity model can accurately determine the heights and the locations of the resonance peaks. The upper bound for the appearance of fluid resonance in gaps is 2b/L〈l (2b, grating constant; L, wave length) and the lower bound is h/b〈~ l. The main reason for the phase shift of the resonance peaks is the inductive factors. The number of resonance peaks in the spectrum curve is dependent on the ratio of the gap length to the grating constant. The heights and the positions of the resonance peaks predicted by the present models agree well with the experimental data. 展开更多
关键词 gap resonance phase shift of resonance peak fluid local viscosity model plane wave hypothesis full wavemodel bottom mounted caissons
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NdF_(3)-LiF-Nd_(2)O_(3)-NdF_(2)熔盐体系结晶行为的研究
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作者 姜银举 段超 +3 位作者 邓永春 辛文彬 唐家悦 樊文军 《稀有金属与硬质合金》 CAS CSCD 北大核心 2024年第2期1-5,共5页
氟化物体系稀土氧化物熔盐电解过程中,熔盐的结晶析出行为显著影响电解过程,为此本文针对NdF_(3)-LiF-Nd_(2)O_(3)、NdF_(3)-LiF-NdF_(2)以及NdF_(3)-LiF-Nd_(2)O_(3)-NdF_(2)三种熔盐体系(NdF_(3)和LiF质量比固定为85∶15),采用降温黏... 氟化物体系稀土氧化物熔盐电解过程中,熔盐的结晶析出行为显著影响电解过程,为此本文针对NdF_(3)-LiF-Nd_(2)O_(3)、NdF_(3)-LiF-NdF_(2)以及NdF_(3)-LiF-Nd_(2)O_(3)-NdF_(2)三种熔盐体系(NdF_(3)和LiF质量比固定为85∶15),采用降温黏度曲线测定熔盐的结晶温度,通过X射线衍射分析结晶物相。结果表明:NdF_(3)-LiF-Nd_(2)O_(3)和NdF_(3)-LiF-NdF_(2)熔盐体系中,随着熔盐中Nd_(2)O_(3)或NdF_(2)含量的增加,熔盐的结晶温度升高,熔盐的结晶物相分别为NdOF和NdF_(2);NdF_(3)-LiF-Nd_(2)O_(3)-NdF_(2)熔盐体系中,当Nd_(2)O_(3)含量为2%~3%、NdF_(2)含量为1%~3%时,熔盐结晶温度在981~988℃范围内,且NdOF与NdF_(2)共结晶。适当提高电解槽底部温度、改善底部熔盐的流动性,是抑制稀土熔盐电解过程熔盐结晶析出的有效方法。 展开更多
关键词 熔盐电解 NdF_(3)-LiF-Nd_(2)O_(3)-NdF_(2) 黏度 结晶温度 结晶物相
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声共振混合器高黏度流体混合的功耗特性研究
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作者 詹小斌 王会彬 +1 位作者 蒋亚龙 史铁林 《化工学报》 EI CSCD 北大核心 2024年第2期531-542,共12页
声共振混合利用机械共振产生高加速度振动,从而促进流体流动,其功耗特性对于其设计及应用具有重要作用。为研究声共振混合器的功耗特性,基于CFD建立了声共振混合过程仿真模型,分析了高黏度流体声共振混合过程壁面对物料的作用力和做功功... 声共振混合利用机械共振产生高加速度振动,从而促进流体流动,其功耗特性对于其设计及应用具有重要作用。为研究声共振混合器的功耗特性,基于CFD建立了声共振混合过程仿真模型,分析了高黏度流体声共振混合过程壁面对物料的作用力和做功功率,探究了黏度和振动参数改变对混合器功耗特性的影响,并建立了声共振混合器混合功率的预测函数。研究结果表明,在混合过程中,壁面对液相做功的瞬时功率呈现先减少后稳定波动的趋势,而有效功率呈现先增加后稳定波动的趋势,这种不同的变化趋势是由于两者的相位差发生变化所导致的。增加振幅、频率或等加速度下低频大振幅都能够增加瞬时功率和有效功率,并减少液相进入稳定流动阶段所需吸收的外界能量。 展开更多
关键词 声共振混合器 高黏度流体 气液两相流 混合 功耗特性 计算流体力学
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微纳米颗粒三相泡沫体系构筑及特性
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作者 刘宏生 《中国石油大学学报(自然科学版)》 EI CAS CSCD 北大核心 2024年第2期135-141,共7页
为进一步提高聚驱后采收率,结合聚驱后油藏特征,构筑具有自适应堵调驱功能的微纳米颗粒三相泡沫体系,通过黏度、界面、泡沫和堵调驱性能试验,研究微纳米颗粒三相泡沫体系特性,应用归一化和权重系数方法,分析三相泡沫体系溶液特性与驱油... 为进一步提高聚驱后采收率,结合聚驱后油藏特征,构筑具有自适应堵调驱功能的微纳米颗粒三相泡沫体系,通过黏度、界面、泡沫和堵调驱性能试验,研究微纳米颗粒三相泡沫体系特性,应用归一化和权重系数方法,分析三相泡沫体系溶液特性与驱油效果的相关性。结果表明:软体微米颗粒三相泡沫体系的特性参数较好,具有超低界面张力,剖面改善率超过82%,聚驱后可提高采收率超过14%;硬质纳米颗粒三相泡沫体系的特性参数相对较差,但聚驱后仍可提高采收率超过10%;三相泡沫体系泡沫综合指数和运动黏度是驱油效果的主要影响因素,而剪切黏度和界面张力是次要影响因素。 展开更多
关键词 微纳米颗粒 三相泡沫体系 聚驱后 黏度 剖面改善率
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黏度对油气混输泵内气相和泄漏涡分布的影响 被引量:1
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作者 孙国栋 史广泰 +1 位作者 文海罡 黄宗柳 《排灌机械工程学报》 CSCD 北大核心 2024年第2期133-138,146,共7页
为了更准确地探究油气混输泵在高黏度条件下输送介质时,其流道内常常存在的泄漏涡、分离涡等这些涡流的特性,文中选用欧拉-欧拉非均相流模型对油气混输泵内气相分布以及涡分布进行分析,并使用刚性旋转涡量表征涡旋强度.研究表明:在混输... 为了更准确地探究油气混输泵在高黏度条件下输送介质时,其流道内常常存在的泄漏涡、分离涡等这些涡流的特性,文中选用欧拉-欧拉非均相流模型对油气混输泵内气相分布以及涡分布进行分析,并使用刚性旋转涡量表征涡旋强度.研究表明:在混输泵叶轮流道内,气相的存在较大地影响了叶片表面流线的分布规律.偏设计工况下,当黏度较小时气相主要集中分布在压力面后半段,当黏度较大时气相在压力面后段分布较少.不同工况下泄漏涡的分布规律都与气相分布吻合度较高,在偏设计工况下,其气相在流道尾部的聚集度和黏度成正比,但是在大流量工况下流道内局部的气相聚集得到了改善.此外,由于高黏度条件下流道内湍流黏度较低以及剪切涡较多,所以在考虑刚性旋转时的涡量分布更为准确.研究结果可为油气混输泵的优化设计等提供理论参考. 展开更多
关键词 油气混输泵 黏性 涡流 刚性旋转涡量 气相聚集
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欧拉-欧拉双流体模型中颗粒黏性对液固散式流态化的影响
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作者 祝赫 张仪 +1 位作者 齐娜娜 张锴 《化工学报》 EI CSCD 北大核心 2024年第9期3103-3112,共10页
采用无黏性双流体模型、基于颗粒动理学的双流体模型以及Brandani和Zhang简化双流体模型探究了颗粒黏性对液固散式流化特性的影响规律。经与文献中实验数据和Gibilaro公式计算值对比后发现:3种双流体模型均能较好地预测整体固含率,与实... 采用无黏性双流体模型、基于颗粒动理学的双流体模型以及Brandani和Zhang简化双流体模型探究了颗粒黏性对液固散式流化特性的影响规律。经与文献中实验数据和Gibilaro公式计算值对比后发现:3种双流体模型均能较好地预测整体固含率,与实验值相对偏差在3%以内,其中无黏性双流体模型和简化双流体模型对固含率预测更符合散式流态化特点;3种双流体模型对时均颗粒轴向速度预测均呈现整体环核结构的固有属性,其中简化双流体模型在较低和较高两组液速工况下预测的相对偏差平均值分别为0.277和1.028;当入口液速突然变化后,收缩过程中简化双流体模型对响应时间预测准确度略高,而膨胀过程中因低浓度区界面不稳定以及膨胀过程中床内颗粒形成的由浓到稀过渡段延长了稳定时间,3种模型预测均与理想过程存在一定偏差,其中液速较低时三者差异不明显,但液速较高时简化双流体模型准确性略高。基于颗粒动理学的双流体模型对动态过程模拟的计算耗时最长。 展开更多
关键词 流态化 计算流体力学 流体动力学 双流体模型 液固两相流 颗粒黏性
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稠油冷采用冻胶分散体调驱体系的相互作用机制
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作者 杨宁 戴彩丽 +3 位作者 邹辰炜 谢忠旭 刘逸飞 赵光 《石油与天然气化工》 CAS CSCD 北大核心 2024年第2期71-77,共7页
目的旨在有效解决稠油化学冷采过程中降黏剂窜流现象严重、油藏动用效率低的问题,支撑稠油绿色高效开发。方法基于稠油冷采降黏剂高效降黏洗油与冻胶分散体调剖剂储层调控的协同效应,采用复配方式构建了稠油冷采用冻胶分散体调驱体系,... 目的旨在有效解决稠油化学冷采过程中降黏剂窜流现象严重、油藏动用效率低的问题,支撑稠油绿色高效开发。方法基于稠油冷采降黏剂高效降黏洗油与冻胶分散体调剖剂储层调控的协同效应,采用复配方式构建了稠油冷采用冻胶分散体调驱体系,测试其基本性能,并使用界面扩张流变仪以及流变仪,考查了体系的界面流变特性和剪切应力特性。结果体系由质量分数为0.06%~0.12%的冻胶分散体和质量分数为0.05%~0.15%的降黏剂组成,为粒径均一的低黏流体,能够降低界面张力并乳化稠油,降黏率达到95%以上。体系中降黏剂在油水界面的吸附行为决定了体系的乳化降黏能力,降黏剂通过吸附在冻胶分散体的表面提高了体系的聚结稳定性,并考查了组分含量及油藏条件对以上过程的影响。结论构建了一种兼具储层调控和高效降黏能力稠油冷采用冻胶分散体调驱体系,探明了体系中各组分间的相互作用机制,为稠油化学冷采提供了技术支持。 展开更多
关键词 稠油冷采 冻胶分散体 乳化降黏 界面流变特性 固-液相互作用
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吉木萨尔页岩油注气相态物性变化特征实验研究
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作者 杜猛 陆舒艺 +4 位作者 常艺琳 吕建荣 万宜迪 姚兰兰 杨正明 《应用化工》 CAS CSCD 北大核心 2024年第7期1509-1514,共6页
为探索不同注入气体对页岩油的相态行为及物性变化特征,综合利用高温高压PVT物理模拟实验系统及气相色谱,开展了减氧空气(含氧量10%)、空气、CO_(2)的注气膨胀实验研究,通过实时监测不同油气体系相态行为的变化情况,分析了不同注入气对... 为探索不同注入气体对页岩油的相态行为及物性变化特征,综合利用高温高压PVT物理模拟实验系统及气相色谱,开展了减氧空气(含氧量10%)、空气、CO_(2)的注气膨胀实验研究,通过实时监测不同油气体系相态行为的变化情况,分析了不同注入气对地层油体系饱和压力、膨胀系数、黏度和密度等物性参数的影响。结果表明,不同注入气体对于地层油的相态行为及物性影响存在显著差异。向页岩储层注入空气,可与原油接触,发生低温氧化反应,空气含氧量越高低温氧化作用越强,越有助于气相溶解至油相中,体系饱和压力越低;注入CO_(2)时,易与原油产生较好的混相作用进而可增强气体的溶解性。受限于较高的溶解饱和压力,高含氧量空气与减氧空气的膨胀系数相差不大,但高含氧量空气的降黏效果较明显,CO_(2)可在压差和扩散作用下进入原油内部,抽提萃取强度更大,膨胀降黏效果最好。高含氧量空气与原油接触时,可产生质量交换,使得轻质组分萃取至气相中,加速重质组分占比升高,原油密度逐渐增大。CO_(2)对于低碳组分的强抽提作用可促使原油轻质组分向重质组分转化,进而导致原油密度上升的幅度更大,注CO_(2)开发有望成为页岩油提高采收率并兼顾埋存的有效途径。该研究成果可为页岩储层注气的高效开发提供借鉴。 展开更多
关键词 相态特征 页岩油 提高采收率 CCUS 膨胀降黏 物理模拟 低温氧化
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石蜡Pickering乳液及其微胶囊相变非织造材料的制备与性能
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作者 柯文涛 陈明 +2 位作者 郑淳天 石小丽 朱新生 《纺织学报》 EI CAS CSCD 北大核心 2024年第7期130-139,共10页
Pickering乳液固含量和储存稳定性等性能显著优于传统乳液,但是,其乳化剂品种仍然稀缺,以苯乙烯(St)、甲基丙烯酰氧乙基三甲基氯化铵(DMC)为主要单体,二乙烯基苯(DVB)为交联剂,乙醇为助溶剂,用无皂乳液聚合法制备了阳离子型共聚物颗粒(P... Pickering乳液固含量和储存稳定性等性能显著优于传统乳液,但是,其乳化剂品种仍然稀缺,以苯乙烯(St)、甲基丙烯酰氧乙基三甲基氯化铵(DMC)为主要单体,二乙烯基苯(DVB)为交联剂,乙醇为助溶剂,用无皂乳液聚合法制备了阳离子型共聚物颗粒(P(St-co-DMC)),并将其作为乳化剂制备了石蜡Pickering乳液;并将石蜡乳液浸渍粘胶水刺非织造布制备石蜡微胶囊相变材料(Vis-PCM)。借助红外光谱仪、扫描电子显微镜、热重/差热联用仪、差示扫描量热仪和接触角测量仪等对共聚物及相变材料微观结构与性能进行表征与测试。实验结果表明:随着DMC用量、引发剂用量和乙醇含量的增加,单体转化率先增大后减小,P(St-co-DMC)粒径和分散指数先减小后增大,其Zeta电位则先快速增大而后趋于恒定,而亲水性持续增强;所得石蜡Pickering乳液的油水体积比高达3∶1,储存稳定性超过3个月;Vis-PCM的相变潜热高达139.3 J/g,经过20次冷热循环处理后,Vis-PCM中的石蜡泄漏率仅0.6%。本文制备的Vis-PCM具有良好的储热与放热性能,在相变储能领域具有广阔的应用前景。 展开更多
关键词 甲基丙烯酰氧乙基三甲基氯化铵 无皂乳液聚合 石蜡 Pickering乳液 粘胶非织造布 相变材料
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基于CFD仿真的高黏发酵反应物降黏研究
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作者 张超 陈涛 +3 位作者 周中林 杨健 张华 肖宗亮 《轻工机械》 CAS 2024年第5期44-50,共7页
为了实现农林剩余物玉米秸秆、玉米芯和小麦秸秆的一种或多种混合物的预处理浆料的快速降黏液化,笔者进行了降黏研究。笔者对混合物中物料搅拌降黏机理提出假设,并利用CFD仿真技术对搅拌器结构、物料预处理类型及液化工艺组合的搅拌降... 为了实现农林剩余物玉米秸秆、玉米芯和小麦秸秆的一种或多种混合物的预处理浆料的快速降黏液化,笔者进行了降黏研究。笔者对混合物中物料搅拌降黏机理提出假设,并利用CFD仿真技术对搅拌器结构、物料预处理类型及液化工艺组合的搅拌降黏体系进行液固两相流非稳态数值仿真,探究了速度场、湍流场的分布情况,确定了生物反应釜结构、尺寸及降黏液化工艺,最后进行了试验验证。结果表明:当反应釜上搅拌器直径为70mm、下搅拌器直径为75 mm,物料为酸处理下平均粒径为830~1450μm的颗粒,搅拌转速为200~300r/min时,搅拌液化的效果最优;由此确定了搅拌降黏体系,试验验证效果较好。CFD仿真结果可为浓稠物料反应釜搅拌器的设计及液化糖化工艺优选提供参考。 展开更多
关键词 生物反应釜 降黏 液化工艺 非稳态数值仿真 液固两相流
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聚己内酰胺-己内酯微球/PA6原位微纤化复合材料的制备及性能研究
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作者 张珞涛 汪继承 +2 位作者 王伟 宋理想 戚栋明 《纺织科学与工程学报》 CAS 2024年第3期45-53,共9页
原位微纤化是提高复合材料强度和韧性的有效方法,但传统原位微纤化材料是基于两相体系的不相容特点。为了探究在相容体系下,两相粘度比对微纤化行为及复合材料性能的影响,通过阴离子聚合制得聚己内酰胺-己内酯(P (CL-CLO))共聚微球,并与... 原位微纤化是提高复合材料强度和韧性的有效方法,但传统原位微纤化材料是基于两相体系的不相容特点。为了探究在相容体系下,两相粘度比对微纤化行为及复合材料性能的影响,通过阴离子聚合制得聚己内酰胺-己内酯(P (CL-CLO))共聚微球,并与PA6切片于双螺杆挤出机中通过共混纺丝,得到P(CL-CLO)/PA6原位微纤化复合材料。分别考察了CLO含量、共混比和牵伸比对共聚微球和微纤的形貌以及P(CL-CLO)/PA6的性能影响。通过SEM观察到,CLO含量为25 wt%以下时,能得到形貌规则的P(CL-CLO)共聚微球。旋转流变仪测结果表明,通过调控CLO含量实现了P(CL-CLO)与PA6的粘度比在1.25~1.65之间调控。对微纤形貌的观察发现,粘度比为1.45~1.65时所形成的微纤尺寸均匀。同时当共混比为2:8、牵伸比为4时,微纤复合材料伸长率和断裂强度分别比纯PA6提高了31.6%和2.96%。这表明微纤与基体间有良好的界面作用力,实现了复合纤维的增强增韧。 展开更多
关键词 原位微纤化 粘度比 共聚微球 相分离
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驱油剂对无碱三元复合驱采出液乳化稳定性影响
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作者 韩晓瑜 魏立新 +1 位作者 刘文杰 白雨鑫 《应用化工》 CAS CSCD 北大核心 2024年第8期1817-1822,1826,共7页
为探究无碱三元驱油剂对于采出液乳化稳定的机理,为采出液处理提供依据。对游离水中含油量、油水动态界面张力、液滴界面寿命与油滴粒径分布状态及粒径随驱油剂含量的变化进行了研究。加入低浓度表面活性剂(100 mg/L)时,动态界面张力、... 为探究无碱三元驱油剂对于采出液乳化稳定的机理,为采出液处理提供依据。对游离水中含油量、油水动态界面张力、液滴界面寿命与油滴粒径分布状态及粒径随驱油剂含量的变化进行了研究。加入低浓度表面活性剂(100 mg/L)时,动态界面张力、界面寿命、油滴粒径均显著降低,水中含油量显著增加,随着表面活性剂浓度增加,动态界面张力、界面寿命、粒径、含油量变化均不明显;随着NaCl浓度上升,动态界面张力与界面寿命变化不明显,油滴粒径变大,水中含油量增加;随着聚合物浓度增加,动态界面张力与界面寿命变化不明显,对于油滴粒径与含油量出现双重作用。这表明表面活性剂与NaCl有利于乳化稳定,但表面活性剂作用远大于NaCl;低浓度聚合物不利于乳化稳定,随着浓度增加,有利于乳化稳定。 展开更多
关键词 驱油剂 稳定性 动态界面张力 油滴粒径 絮凝 水相黏度
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Three-segment control theory of MgO/Al2O3 ratio based on viscosity experiments and phase diagram analyses at 1500℃ 被引量:4
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作者 Xin Jiang Huai-yu Zhang +2 位作者 Hai-yan Zheng Qiang-jian Gao Feng-man Shen 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2020年第6期624-630,共7页
In recent years, more and more high Al2O3 iron ores were used in East Asia, especially in China, which increased the Al2O3 content in blast furnace (BF) slag and resulted in poor metallurgical properties of slag. Addi... In recent years, more and more high Al2O3 iron ores were used in East Asia, especially in China, which increased the Al2O3 content in blast furnace (BF) slag and resulted in poor metallurgical properties of slag. Adding MgO-bearing flux is one of the methods to improve the metallurgical properties of slag with high Al2O3. However, there is lack of theoretical basis for the proper MgO/Al2O3 ratio. Therefore, the properties of slag in SiO2-CaO-MgO-Al2O3 system were investigated based on viscosity experiments and phase diagram analyses at 1500℃, and the proper MgO/Al2O3 ratio was explored according to the Al2O3 content in slag. The experimental results show that: (1) in the case of Al2O3 content less than 14mass%, there is no limitation of the MgO/Al2O3 ratio, and the amount of MgO in slag can be determined according to the hearth tempera-ture and desulfurization;(2) in the case of Al2O3 content between 15 and 17mass%, the proper MgO/Al2O3 ratio should be 0.40-0.50;(3) in the case of Al2O3 content between 18 and 20mass%, the proper MgO/Al2O3 ratio should be 0.45-0.55. Consequently, the three-segment control theory of MgO/Al2O3 for BF slag was built, and the actual BF performances proved the validity and applicability of this theory. The research contents and results can give theoretical guidelines for stable BF operation in a wide range of Al2O3 content of 12-20mass%. 展开更多
关键词 MgO/Al2O3 ratio Blast furnace slag viscosity IRONMAKING phase diagram
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