In the presence of 1-（3-dimethylaminopropyl）-3-ethylcarbodiimide hydrochloride （EDC） and N-hydroxysuccinimide （NHS）, carboxylic group-functionalized single-walled carbon nanotubes （SWNTs） were assembled vertic...In the presence of 1-（3-dimethylaminopropyl）-3-ethylcarbodiimide hydrochloride （EDC） and N-hydroxysuccinimide （NHS）, carboxylic group-functionalized single-walled carbon nanotubes （SWNTs） were assembled vertically on the glassy carbon electrode using ethylenediamine as linking agent to fabricate an aligned electrode （SWNTE）. The morphological characteristic was studied with atomic force microscope （AFM） and its electrochemical property was investigated using K3[Fe（CN）6] as probe. ssDNA had a sensitive voltammetric response at the SWNTE and the oxidative peak potentials of guanine base and adenine base were 0.608 Vand 0.896 V, respectively. Under the optimal conditions, the DPV peak current of guanine base vs. the concentration of ssDNA was linear in the range of 5.4 μg/L-10.8 mg/L with a detection limit of 1 μg/L （S/N = 3）.展开更多
A new glassy carbon electrode modified with novel caHx[4]arene derivative was prepared and then applied to the selective recognition of lead ion in aqueous media by cyclic and square wave voltammtry. A new anodic stri...A new glassy carbon electrode modified with novel caHx[4]arene derivative was prepared and then applied to the selective recognition of lead ion in aqueous media by cyclic and square wave voltammtry. A new anodic stripping peak at - 0.92 V (vs. Ag/Ag+) in square wave voltammogram can be obtained by scanning the potential from - 1.5 to - 0.6 V, of which the peak current is proportional to the concentration of Pb2+. The modified electrode in 0.1 moVL HNO3 solution showed a linear voltammetric response in the range of 2.0 x 10(-8)-1.0 x 10(-6) mol/L and a detection limit of 6.1 x 10(-9) mol/L. In the modified glassy carbon electrode no significant interference occurred from alkali, alkaline and transition metal ions except Hg2+, Ag+ and Cu2+ ions, which can be eliminated by the addition of KSCN. The proposed method was successfully applied to determine lead in aqueous samples.展开更多
基金supports from the National Science Foundation of China(No.20635020,No.20375020)Doctoral Foundation of the Ministry of Education of China(No.20060426001).
文摘In the presence of 1-（3-dimethylaminopropyl）-3-ethylcarbodiimide hydrochloride （EDC） and N-hydroxysuccinimide （NHS）, carboxylic group-functionalized single-walled carbon nanotubes （SWNTs） were assembled vertically on the glassy carbon electrode using ethylenediamine as linking agent to fabricate an aligned electrode （SWNTE）. The morphological characteristic was studied with atomic force microscope （AFM） and its electrochemical property was investigated using K3[Fe（CN）6] as probe. ssDNA had a sensitive voltammetric response at the SWNTE and the oxidative peak potentials of guanine base and adenine base were 0.608 Vand 0.896 V, respectively. Under the optimal conditions, the DPV peak current of guanine base vs. the concentration of ssDNA was linear in the range of 5.4 μg/L-10.8 mg/L with a detection limit of 1 μg/L （S/N = 3）.
文摘A new glassy carbon electrode modified with novel caHx[4]arene derivative was prepared and then applied to the selective recognition of lead ion in aqueous media by cyclic and square wave voltammtry. A new anodic stripping peak at - 0.92 V (vs. Ag/Ag+) in square wave voltammogram can be obtained by scanning the potential from - 1.5 to - 0.6 V, of which the peak current is proportional to the concentration of Pb2+. The modified electrode in 0.1 moVL HNO3 solution showed a linear voltammetric response in the range of 2.0 x 10(-8)-1.0 x 10(-6) mol/L and a detection limit of 6.1 x 10(-9) mol/L. In the modified glassy carbon electrode no significant interference occurred from alkali, alkaline and transition metal ions except Hg2+, Ag+ and Cu2+ ions, which can be eliminated by the addition of KSCN. The proposed method was successfully applied to determine lead in aqueous samples.
