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FATIGUE BEHAVIOUR OF M/B DUPLEX STRUCTURE IN A HIGH CARBON Cr-Mo-W STEEL
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作者 TIAN Baohong ZHENG Shi’an WU Lei Luoyang Institute of Technology,Luoyang,China ZHENG Shi’an,associate professor,Department of Materials Engineering,Luoyang Institute of Technology,Luoyang 471039,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1993年第5期316-319,共4页
Determination was carried out of fatigue crack propagation rate of steel 65Cr5Mo3W2VSiTi (LM2)with various bainite contents and M/B duplex structure tempered at various tempera- tures.The threshold value of fatigue fo... Determination was carried out of fatigue crack propagation rate of steel 65Cr5Mo3W2VSiTi (LM2)with various bainite contents and M/B duplex structure tempered at various tempera- tures.The threshold value of fatigue for each processing was estimated by experimental data. The mechanism for fatigue crack propagation of M/B duplex structure in steel LM2 seems to be non-continuous.The calculated fatigue crack micro-propagation rates are found to agree with the experimental data. 展开更多
关键词 duplex structure fatigue crack propagation rate threshold value steel 65Cr5Mo3w2VSiTi
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热丝激光熔覆Cr-W-Mo-V钢涂层组织与腐蚀磨损性能
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作者 王彦芳 周雪景 +1 位作者 宋子翰 石志强 《中国表面工程》 EI CAS CSCD 北大核心 2024年第3期25-36,共12页
随着海洋油气资源的开发,钻采装备面临腐蚀与磨损的耦合损伤。开发耐磨耐蚀涂层材料及制备技术是海洋装备安全、可靠运行的保障。利用热丝激光熔覆技术在20钢基材表面制备Cr-W-Mo-V钢涂层,通过光学显微镜(OM)、X射线衍射仪(XRD)、扫描... 随着海洋油气资源的开发,钻采装备面临腐蚀与磨损的耦合损伤。开发耐磨耐蚀涂层材料及制备技术是海洋装备安全、可靠运行的保障。利用热丝激光熔覆技术在20钢基材表面制备Cr-W-Mo-V钢涂层,通过光学显微镜(OM)、X射线衍射仪(XRD)、扫描电子显微镜(SEM)等分析涂层的显微组织和相组成,采用往复电化学腐蚀摩擦磨损试验仪分析涂层的干摩擦、电化学腐蚀及在3.5 wt.%NaCl溶液中的腐蚀磨损行为。制备的涂层组织均匀、致密,无裂纹、气孔等缺陷,主要由碳化物、马氏体和残余奥氏体组成,显微组织主要为柱状晶和胞状晶。涂层的平均硬度约为780 HV_(0.1),约是基材硬度的6.5倍,自腐蚀电位为-0.386 V,自腐蚀电流密度为3.45×10^(-6)A/cm^(2),具有优异的耐蚀性。在3.5 wt.%NaCl溶液中,随摩擦载荷的增大,涂层的开路电位下降,摩擦因数下降,腐蚀电流密度增大,摩擦对腐蚀有明显促进作用。随外加电位增加,涂层腐蚀电流密度增大,摩擦因数降低。热丝激光熔覆技术制备的Cr-W-Mo-V钢涂层结构致密、组织均匀,具有优异的腐蚀磨损性能,可用于海洋油气钻采装备在腐蚀磨损苛刻环境下零部件的表面改性。 展开更多
关键词 热丝激光熔覆 Cr-w-Mo-V钢涂层 显微组织 腐蚀磨损
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矿用W型钢带承载能力研究
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作者 庞威风 杨栋 +1 位作者 梁晓伟 马家辉 《煤炭科技》 2024年第2期86-88,共3页
控制巷道围岩变形是巷道支护面临的首要问题,钢带作为巷道联合支护构件中的关键一环,能够增大锚杆+钢带支护的作用范围,提高其支护能力。以单一W型钢带为例,利用理论计算与实际参数校验的方式对单一W型钢带的承载能力进行了计算,结果表... 控制巷道围岩变形是巷道支护面临的首要问题,钢带作为巷道联合支护构件中的关键一环,能够增大锚杆+钢带支护的作用范围,提高其支护能力。以单一W型钢带为例,利用理论计算与实际参数校验的方式对单一W型钢带的承载能力进行了计算,结果表明:(1)锚杆作用范围有限,上覆不稳定岩体有一部分作用在钢带上,并与锚杆的间排距有关;(2)采用材料力学方法,得出单一钢带的承载能力计算公式,发现单一钢带的承载能力主要由钢带强度、钢带弹性模量以及钢带断面的惯性矩决定;(3)通过实际巷道锚杆+钢带支护参数,对单一钢带的承载能力计算公式进行了校验,能够满足需求。 展开更多
关键词 w型钢带 承载能力 计算校验
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Enhanced Fatigue Property of Welded S355J2W Steel by Forming a Gradient Nanostructured Surface Layer 被引量:2
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作者 Lu An Yan-Tao Sun +1 位作者 Shan-Ping Lu Zhen-Bo Wang 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 2020年第9期1252-1258,共7页
Welded joints are usually characterized by microstructural and compositional inhomogeneities, which may significantly degrade their fatigue properties and result in unpredictable failures. The present work demonstrate... Welded joints are usually characterized by microstructural and compositional inhomogeneities, which may significantly degrade their fatigue properties and result in unpredictable failures. The present work demonstrates a novel and simple method to effectively optimize the microstructure in the surface layer and promote the fatigue properties of welded specimens. By a recently developed approach—surface mechanical rolling treatment(SMRT), a gradient nanostructured surface layer is formed on welded S355 J2 W steel specimens. The mean grain size is refined to nanometer scale, and the hardness is significantly enhanced in the SMRT surface layer. Independent of the initially inhomogeneous microstructure and hardness distributions, the microstructure and hardness distributions in the surface layers are comparable on different zones of a welded specimen after SMRT with the same procedure. Consequently, fatigue property of the SMRT specimens is significantly enhanced relative to that of the as-welded specimens within the high cycle fatigue regime. 展开更多
关键词 Gradient nanostructured Surface mechanical rolling treatment S355J2w steel wELDED Fatigue
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Cr12MoV模具钢化学镀Ni-W-P/PTFE复合镀层及耐磨性能研究 被引量:1
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作者 崔凯 任伟和 《电镀与精饰》 CAS 北大核心 2023年第10期32-39,共8页
以Cr12MoV模具钢作为基体化学镀Ni-W-P/PTFE复合镀层,以期提高模具的耐磨性能。通过改变PTFE颗粒添加量获得不同Ni-W-P/PTFE复合镀层,并对复合镀层的表面形貌、化学成分、晶相结构、硬度及耐磨性能进行表征。结果表明:不同复合镀层表面... 以Cr12MoV模具钢作为基体化学镀Ni-W-P/PTFE复合镀层,以期提高模具的耐磨性能。通过改变PTFE颗粒添加量获得不同Ni-W-P/PTFE复合镀层,并对复合镀层的表面形貌、化学成分、晶相结构、硬度及耐磨性能进行表征。结果表明:不同复合镀层表面都存在尺寸不同、分布不均匀的胞状物,还附着白色PTFE颗粒,但是晶相结构无显著性差异。随着PTFE颗粒添加量从2 g/L增至14 g/L,复合镀层中PTFE颗粒含量呈现先升高,后降低趋势,并且颗粒分散状况不同,硬度呈现减小趋势,而耐磨性能逐步提高,然后变差。当PTFE颗粒添加量为8 g/L获得的Ni-WP/PTFE复合镀层中PTFE颗粒含量达到3.63%,并且颗粒分布趋于均匀,具有优良的耐磨性能,其摩擦系数仅为0.41,表面磨痕宽度和深度分别为500μm和14.7μm,作为表面改性层能有效减轻Cr12MoV模具钢的磨损程度。 展开更多
关键词 Ni-w-P/PTFE复合镀层 化学镀 CR12MOV模具钢 耐磨性能
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MICROSTRUCTURE IN LASER FUSED HIGH SPEED STEEL W6Mo5Cr4V2(M2) 被引量:2
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作者 LIU Ning CUI Kun Huazhong University of Science and Technology,Wuhan.China DENG Zonggang Hefei University of Technology,Hefei,China CHENG Benpei KONG Jie Institute of Solid State Physics,Academia Sinica,Hefei,China Doctorate student,Department of Mechanical Engineering No.2,Huazhong University of Science and Technology,Wuhan 430074,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1993年第1期36-39,共4页
Microstructure of the deepest zone of high speed steel W6Mo5Cr4V2(M2)melt after laser fu-sion was found to be so fine as the ehill zone of a solidified ingot.When narrower chill zoneformed,the long columnar dendrites ... Microstructure of the deepest zone of high speed steel W6Mo5Cr4V2(M2)melt after laser fu-sion was found to be so fine as the ehill zone of a solidified ingot.When narrower chill zoneformed,the long columnar dendrites grow into the melt and then the fine equiaxed cellularstructure appears in upper melt region nearly surface.The substructure of cellular grains anddendrites was observed to consist of martensite and retained austenile,while the carbides asM_6C_■ Cr_7C_3 and MC distributed at their boundaries.It is believed that the highermicrohardness up to HV_(0.1)=865-960 of the laser fused structure of the alloy is due to the oc-currence of martensite. 展开更多
关键词 High speed steel w6Mo5Cr4V2(M2) laser fused treatment micrstructure
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W, Mo, Co Co-diffusion on Steel with Different Carbon Content 被引量:2
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作者 ZHANGYan-mei LIZhong-hou LIUYan-ping XUZhong 《材料热处理学报》 EI CAS CSCD 北大核心 2004年第05B期688-691,共4页
Tungsten, molybdenum and cobalt were co-diffused into the surface of ingot, 20 steel, 45 steel and T8 steel by a double glow plasma surface alloying technique. Surface alloyed layers formed on ingot and 20 steel are c... Tungsten, molybdenum and cobalt were co-diffused into the surface of ingot, 20 steel, 45 steel and T8 steel by a double glow plasma surface alloying technique. Surface alloyed layers formed on ingot and 20 steel are composed of -Fe +(Fe,Co)7(W,Mo)6, which possess the same strong age-hardening ability as the metallurgical age-hardened high speed steel, the maximum hardness can reach 1100 HV0.o25 after ageing treatment. Surface alloyed layers formed on 45 steel and T8 steel are composed of M6C, hardness of which are over 1100-1400 HV0.o25- Alloyed layers formed on ingot and 20 steel possess good toughness. Alloyed layer of carbide type exhibits slightly brittleness. 展开更多
关键词 碳含量 表面铸合 碳钢 硬度 脆性 钼钴共扩散
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Study of High Temperature Deformation and Recrystallization in W9Mo3Cr4V Steel 被引量:1
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作者 Wang Jingwen 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 1999年第2期24-28,共5页
The behavior of high temperature deformation and recrystallization of W9Mo3Cr4V steel have been studied in this paper. Dynamic precipitation during deformation has also been investigated. In W9Mo3Cr4V steel, stress ... The behavior of high temperature deformation and recrystallization of W9Mo3Cr4V steel have been studied in this paper. Dynamic precipitation during deformation has also been investigated. In W9Mo3Cr4V steel, stress strain curves exhibit many features. The deformation structures and the effects of deformation parameters on dynamic recrystallization are more complicated than those in low alloy steels. For W9Mo3Cr4V steel, there is a large number of residual carbides on the matrix at high temperature. Also, many second carbides precipitate from the matrix during high temperature deformation. These two kinds of carbides (especially the latter) make the behavior of deformation and dynamic recrystallization in W9Mo3Cr4V steel different from those in low alloy steels. ABSTRACT:The behavior of high temperature deformation and recrystallization of W9Mo3Cr4V steel have been studied in this paper. Dynamic precipitation during deformation has also been investigated. In W9Mo3Cr4V steel, stress strain curves exhibit many features. The deformation structures and the effects of deformation parameters on dynamic recrystallization are more complicated than those in low alloy steels. For W9Mo3Cr4V steel, there is a large number of residual carbides on the matrix at high temperature. Also, many second carbides precipitate from the matrix during high temperature deformation. These two kinds of carbides (especially the latter) make the behavior of deformation and dynamic recrystallization in W9Mo3Cr4V steel different from those in low alloy steels. 展开更多
关键词 w9Mo3Cr4V steel high temperature deformation dynamic recrystallization
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45#钢表面Ni-W/ZnO超疏水复合涂层的制备及性能研究 被引量:3
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作者 刘艳 冀杰 《电镀与精饰》 CAS 北大核心 2023年第5期26-33,共8页
采用电沉积工艺并结合喷涂法在45#钢表面制备Ni-W/ZnO超疏水复合涂层,表征了复合涂层的微观形貌和主要成分,并对复合涂层的疏水性、机械稳定性及耐蚀性进行测试分析。结果表明:复合涂层表面形成微纳米分级结构,主要成分为Ni、W、Zn、O、... 采用电沉积工艺并结合喷涂法在45#钢表面制备Ni-W/ZnO超疏水复合涂层,表征了复合涂层的微观形貌和主要成分,并对复合涂层的疏水性、机械稳定性及耐蚀性进行测试分析。结果表明:复合涂层表面形成微纳米分级结构,主要成分为Ni、W、Zn、O、C和Si元素,改性ZnO颗粒在复合涂层中呈较均匀分散状态。复合涂层表面水滴接触角达到151.4°,表现出超疏水性能,并且经20次胶带提拉、20次砂粒冲击和20个周期砂纸摩擦后接触角仍然大于150°,能稳定地保持超疏水性能而且具有良好的机械稳定性。复合涂层还表现出优异的耐蚀性,其腐蚀电流密度仅为6.79×10^(-7)A/cm^(2),极化电阻达到3.25×10^(4)Ω·cm_(2),相比于常规Ni-W合金镀层,能为45#钢提供理想的腐蚀防护作用。 展开更多
关键词 Ni-w/Zn 超疏水复合涂层 45#钢 电沉积 机械稳定性 耐蚀性
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基于粗糙基底的W/316L不锈钢第一壁系统热应力的研究
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作者 刘泽 冷青松 +4 位作者 唐琳 王健 张亚飞 曹智 孙付春 《核技术》 CAS CSCD 北大核心 2023年第10期85-92,共8页
第一壁系统中热应力的大小是决定聚变堆安全运行的关键因素之一。本文通过Ansys Workbench有限元软件,对具有粗糙基底的W/316L不锈钢系统中的热应力分布,以及影响热应力大小的诸如温度、涂层厚度、基底厚度等因素进行了深入分析。同时... 第一壁系统中热应力的大小是决定聚变堆安全运行的关键因素之一。本文通过Ansys Workbench有限元软件,对具有粗糙基底的W/316L不锈钢系统中的热应力分布,以及影响热应力大小的诸如温度、涂层厚度、基底厚度等因素进行了深入分析。同时从系统中交界面剪切应力入手,研究了粗糙基底对涂层结合强度的影响。结果表明:粗糙基底系统中热应力随着温度、基底厚度的增加而增加,随着涂层厚度的增加而降低。除此之外,粗糙基底提升了系统中热应力的极值,在一定程度上提高了涂层与基底的结合强度。研究结果为后期高结合强度第一壁涂层系统的研发提供了一定的参考价值。 展开更多
关键词 w/316L不锈钢第一壁系统 粗糙基底 热应力
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IN-SITU OBSERVATION OF THERMAL FATIGUE CRACK GROWTH IN STEEL 3Cr2W8V
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作者 LIU Jianhong HE Shiyu YAO Mei Harbin Institute of Technology,Harbin,China lecturer,Depatment of Metallic Materials,Harbin Institute of Technology,Harbin 150006,China 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1993年第3期191-192,共2页
The growing process of thermal fatigue cracking,in steel 3Cr2WSV was observed under desk SEM fitted with sell-made minisized device for thermal faligue test.Before the growing of thermal fatigue crack,the main crack t... The growing process of thermal fatigue cracking,in steel 3Cr2WSV was observed under desk SEM fitted with sell-made minisized device for thermal faligue test.Before the growing of thermal fatigue crack,the main crack tip reveals to blunt firstly,and some holes and uncontinuous microcraeks occur in front of it.The growth is developed by bridging of main crack together with holes and microcracks. 展开更多
关键词 steel 3Cr2w8V thermal fatigue crack growth in-situ observation
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Calculation and Inspection of Alloy Design of Cr-W- Mo-V High Alloy Steel Addition Niobium for Machinery Knives 被引量:1
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作者 Yongqing Ma Ming Hu 《材料科学研究(中英文版)》 2015年第1期8-14,共7页
关键词 设计计算 高合金钢 合金设计 机械刀具 钒合金 微量铌 钨钼 MC碳化物
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Effects of carbon,sulphur,phosphorus,and nickel compositions and hot working on thermal fatigue properties of H13 steel
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作者 TIAN Yuxin 《Baosteel Technical Research》 CAS 2015年第4期57-62,共6页
For precise composition control and the selection of hot-w orking operation,effects of carbon( C),sulphur( S),phosphorus( P),and nickel( Ni) compositions and hot working on thermal fatigue properties of H13 st... For precise composition control and the selection of hot-w orking operation,effects of carbon( C),sulphur( S),phosphorus( P),and nickel( Ni) compositions and hot working on thermal fatigue properties of H13 steel under thermal cycling conditions w ere studied by a self-restraint thermal fatigue test. Results show ed that the control of the C content at about 0. 35%,Ni content at about 0. 50%,and S and P contents as low as possible and the forging operation used lead to an improvement of the thermal fatigue resistance of the steel. 展开更多
关键词 H13 steel chemical composition hot w orking thermal fatigue
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EFFECT OF W ON MECHANICAL PROPERTIES OF 12%Cr HEAT-RESISTANT STEEL
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作者 FUJITA Toshio 《Acta Metallurgica Sinica(English Letters)》 SCIE EI CAS CSCD 1992年第2期95-100,共6页
The effect of W on mechanical properties of 12% Cr-W-V-Nb heat resistant steel at high temperatures and room temperature is reported.The experimental results indicated that if the W content was about 2.2—3.0 wt-%,the... The effect of W on mechanical properties of 12% Cr-W-V-Nb heat resistant steel at high temperatures and room temperature is reported.The experimental results indicated that if the W content was about 2.2—3.0 wt-%,there was no obviously change of R.T.tensile strength, but impact toughness decreased with the rise of W content.On the other hand,the increase of W content enhanced the short time stress rupture strength,but did not for the long time one. The increase of W have two effects on the precipitation behavior,promoting Laves formation of type Fe_2W,increasing the precipitated phase amount and speeding up the coarsening pro- cess of precipitated phase at high temperatures.The effect of W on the mechanical properties is closely associated with precipitation behaviors.When the rupture life is short,there has no enough time to coarsen the precipitated phases,so the increase of precipitated phases results in strengthening effect,i.e.the W increases the high temperature strength.After prolonged expo- sure,the evident coarsening took plaee,that decreased the effect of precipitation. 展开更多
关键词 12%Cr-w-V-Nb steel martensitic heat-resistant steel Laves phase precipitation behavior
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活化处理对高速钢Ni-W-P化学镀层结合力影响
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作者 王靖炎 朱世照 +2 位作者 张振钢 马利杰 刘贯军 《工具技术》 北大核心 2023年第6期52-55,共4页
为提高Ni-W-P化学镀层与高速钢基体之间的结合力,重点研究了高速钢化学镀前的表面活化处理工艺。以不同浓度的盐酸、硫酸、氢氟酸和活化时间为研究对象,以Ni-W-P镀层与高速钢基体的结合力为研究指标,通过正交试验对活化剂组分和活化时... 为提高Ni-W-P化学镀层与高速钢基体之间的结合力,重点研究了高速钢化学镀前的表面活化处理工艺。以不同浓度的盐酸、硫酸、氢氟酸和活化时间为研究对象,以Ni-W-P镀层与高速钢基体的结合力为研究指标,通过正交试验对活化剂组分和活化时间进行优化。结果表明,在试验条件下,当活化剂中添加8%的浓盐酸和2.5%的氢氟酸(其余为水)并对高速钢基体进行3 min活化处理时,制备的Ni-W-P镀层与基体的结合力最大。 展开更多
关键词 化学镀NI-w-P 结合力 高速钢 活化处理
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Ti、Mn对Q690钢SMAW熔敷金属组织和力学性能的影响
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作者 陈建国 杨咏梅 +2 位作者 李俐群 王泽军 陈洋 《热加工工艺》 北大核心 2023年第15期51-54,共4页
以开发与Q690高强钢匹配的焊接材料为目的,通过扫描电镜、能谱分析等手段研究了Ti和Mn含量对焊条电弧焊(SMAW,shielded metal arc welding)熔敷金属组织和力学性能的影响。结果表明,Ti和Mn可以有效地改善熔敷金属的微观组织和力学性能... 以开发与Q690高强钢匹配的焊接材料为目的,通过扫描电镜、能谱分析等手段研究了Ti和Mn含量对焊条电弧焊(SMAW,shielded metal arc welding)熔敷金属组织和力学性能的影响。结果表明,Ti和Mn可以有效地改善熔敷金属的微观组织和力学性能。适量添加Ti、Mn会促使熔敷金属中针状铁素体的形成。随着Mn含量的增加,熔敷金属的微观组织由粒状贝氏体+针状铁素体转变为板条贝氏体+马氏体,导致其抗拉强度升高,冲击性能下降。 展开更多
关键词 Q690钢 焊条电弧焊(SMAw) 熔敷金属
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“W”型钢结构桁架工程现场吊装技术方案研究
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作者 姚群勇 陈志强 《价值工程》 2023年第29期64-66,共3页
大跨度钢结构桁架的现场吊装存在难度大、施工危险性高等特征。文章以福州高新区科技东路“W”型钢构大门的现场吊装工程为例,对该类型工程的吊装技术方案进行总结,从拆除工序、安装工序等角度进行了详细分析,旨在为开展大跨度钢结构桁... 大跨度钢结构桁架的现场吊装存在难度大、施工危险性高等特征。文章以福州高新区科技东路“W”型钢构大门的现场吊装工程为例,对该类型工程的吊装技术方案进行总结,从拆除工序、安装工序等角度进行了详细分析,旨在为开展大跨度钢结构桁架现场吊装提供借鉴。 展开更多
关键词 w”型钢结构桁架 现场吊装 胎架安装与验收 工程监控
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齿轮钢电沉积Ni-W/MoS_(2)自润滑复合镀层及性能研究
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作者 毛望军 高志廷 《电镀与精饰》 CAS 北大核心 2023年第4期31-37,共7页
采用电沉积工艺在制造齿轮常用的40Cr钢表面制备掺杂MoS_(2)颗粒的Ni-W/MoS_(2)自润滑复合镀层,并研究MoS_(2)颗粒对复合镀层表面形貌、晶相结构、显微硬度和耐磨性能的影响。结果表明:Ni-W/MoS_(2)自润滑复合镀层完整覆盖40Cr钢表面,... 采用电沉积工艺在制造齿轮常用的40Cr钢表面制备掺杂MoS_(2)颗粒的Ni-W/MoS_(2)自润滑复合镀层,并研究MoS_(2)颗粒对复合镀层表面形貌、晶相结构、显微硬度和耐磨性能的影响。结果表明:Ni-W/MoS_(2)自润滑复合镀层完整覆盖40Cr钢表面,主要成分为Ni、W、Mo和S元素,存在4个Ni的衍射峰并且都呈现(220)晶面择优取向。镀液中MoS_(2)颗粒质量浓度变化导致镀层的晶粒形态及致密性显现出差异,MoS_(2)颗粒含量呈现先升高后降低趋势,造成显微硬度先增大后减小,耐磨性能先改善后变差。当镀液中MoS_(2)颗粒质量浓度为5 g/L,Ni-W/MoS_(2)复合镀层中MoS_(2)颗粒含量达到4.17%,形成条状与乳突状不同形态的晶粒,结合更紧密,其硬度达到607.5 HV,表面磨痕宽度仅为420μm,表现出良好的耐磨性能,能起到较理想的减摩作用,从而显著提高40Cr钢的耐磨性能。 展开更多
关键词 Ni-w/MoS_(2)自润滑复合镀层 电沉积 齿轮钢 MoS_(2)颗粒质量浓度 耐磨性能
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W+C双注入H13钢抗腐蚀特性的研究 被引量:6
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作者 王晓妍 张通和 +3 位作者 梁宏 周固 赵渭江 薛建明 《核技术》 CAS CSCD 北大核心 1997年第3期138-142,共5页
研究了W+C双注入H13钢在表面形成的抗腐蚀的优化表面层。电化学极化曲线测量结果表明双注入极化电流密度峰值随极化次数的增加而达到饱和,其饱和电流密度峰值比H13钢的小100倍以上,比纯W的小2-3倍。双注入次序对腐蚀... 研究了W+C双注入H13钢在表面形成的抗腐蚀的优化表面层。电化学极化曲线测量结果表明双注入极化电流密度峰值随极化次数的增加而达到饱和,其饱和电流密度峰值比H13钢的小100倍以上,比纯W的小2-3倍。双注入次序对腐蚀特性也有影响,先注入W的W5C8样品比后注入W的双注入样品C5W5的极化电流密度峰值要小1倍。扫描电镜观察到样品腐蚀后的抗腐蚀结构。X射线分析表明这些结构是WC、W2C、FeW、Fe2W、FeW2C和铁的碳化物组成的。俄歇分析表明这种结构是多层结构的优化复合层,表面有一层薄碳层,在碳层下面是一层金属化合物的弥散层,紧接着又有一个铁的碳化物弥散层,这些结构具有良好的抗腐蚀特性。 展开更多
关键词 离子注入 双离子注入 抗腐蚀特性 碳-钨离子
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低碳钢上Ni-W-Al_2O_3纳米复合电镀层的耐腐蚀性能研究 被引量:4
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作者 王利 吴玉程 +3 位作者 舒霞 王文芳 李云 黄新民 《材料保护》 CAS CSCD 北大核心 2008年第1期17-19,共3页
通过电沉积方法在Q235低碳钢上制备出Ni-W-Al2O3纳米复合镀层,采用测定浸泡腐蚀失重和测定交流阻抗的方法研究了其耐腐蚀性能。结果表明:Ni-W-Al2O3纳米复合镀层的耐蚀性优于普通Ni-W镀层;Ni-W-Al2O3纳米复合镀层在电解液中剥蚀发生之前... 通过电沉积方法在Q235低碳钢上制备出Ni-W-Al2O3纳米复合镀层,采用测定浸泡腐蚀失重和测定交流阻抗的方法研究了其耐腐蚀性能。结果表明:Ni-W-Al2O3纳米复合镀层的耐蚀性优于普通Ni-W镀层;Ni-W-Al2O3纳米复合镀层在电解液中剥蚀发生之前,电化学阻抗谱由一个容抗弧组成,剥蚀后的阻抗谱呈现Warburg阻抗特征。 展开更多
关键词 纳米复合镀层 Ni-w-Al2O3 低碳钢 耐腐蚀性 电化学阻抗谱
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