In the present work a new thermal conductivity model is developed for two-phase composite materials,which are consisted of a continuous matrix and dispersed 3 D-particles separated from each other by the matrix as a f...In the present work a new thermal conductivity model is developed for two-phase composite materials,which are consisted of a continuous matrix and dispersed 3 D-particles separated from each other by the matrix as a function of grain size and volume ratio of the dispersed particles at different temperatures.The model is applied to reproduce experimental thermal conductivity values of cemented carbide systems WC-Co and WC-Ag.Good agreement was found between measured thermal conductivity data originating from both this work and recent literature and the calculated ones only using semi-empirical parameters for the interfacial thermal resistance(ITR)values at WC/Co,WC/Ag and WC/WC interfaces as a function of temperature.Additionally,the temperature and grain size dependence of the thermal conductivity for WC is established for the first time.The model works well for the case when the matrix(Ag)has a higher thermal conductivity compared to that of the WC particles and also for the case when the matrix(Co)has a lower thermal conductivity compared to that of the WC particles.The new model forms a physically sound basis for further development/materials design of cemented carbides and particlereinforced composite materials.展开更多
基金financially supported by the National Natural Science Foundation of China(No.52031017)the National Key R&D Program of China(No.2019YFC1904901)+1 种基金the Special Funds for the Construction of Hunan Innovation Province(No.2019GK2052)supported by nano-Ginop Project GINOP-2.3.2-15-2016-00027 in the framework of the Szechenyi 2020 program supported by the European Union。
文摘In the present work a new thermal conductivity model is developed for two-phase composite materials,which are consisted of a continuous matrix and dispersed 3 D-particles separated from each other by the matrix as a function of grain size and volume ratio of the dispersed particles at different temperatures.The model is applied to reproduce experimental thermal conductivity values of cemented carbide systems WC-Co and WC-Ag.Good agreement was found between measured thermal conductivity data originating from both this work and recent literature and the calculated ones only using semi-empirical parameters for the interfacial thermal resistance(ITR)values at WC/Co,WC/Ag and WC/WC interfaces as a function of temperature.Additionally,the temperature and grain size dependence of the thermal conductivity for WC is established for the first time.The model works well for the case when the matrix(Ag)has a higher thermal conductivity compared to that of the WC particles and also for the case when the matrix(Co)has a lower thermal conductivity compared to that of the WC particles.The new model forms a physically sound basis for further development/materials design of cemented carbides and particlereinforced composite materials.
