Microstructure evolution and strengthening mechanism of high -performance powder metallurgy TA15 titanium alloy by hot rolling

Hot deformation of sintered billets by powder metallurgy(PM)is an effective preparation technique for titanium alloys,which is more significant for high-alloying alloys.In this study,Ti–6.5Al–2Zr–Mo–V(TA15)titanium alloy plates were prepared by cold press-ing sintering combined with high-temperature hot rolling.The microstructure and mechanical properties under different process paramet-ers were investigated.Optical microscope,electron backscatter diffraction,and others were applied to characterize the microstructure evolution and mechanical properties strengthening mechanism.The results showed that the chemical compositions were uniformly dif-fused without segregation during sintering,and the closing of the matrix craters was accelerated by increasing the sintering temperature.The block was hot rolled at 1200℃ with an 80%reduction under only two passes without annealing.The strength and elongation of the plate at 20–25℃ after solution and aging were 1247 MPa and 14.0%,respectively,which were increased by 24.5%and 40.0%,respect-ively,compared with the as-sintered alloy at 1300℃.The microstructure was significantly refined by continuous dynamic recrystalliza-tion,which was completed by the rotation and dislocation absorption of the substructure surrounded by low-angle grain boundaries.After hot rolling combined with heat treatment,the strength and plasticity of PM-TA15 were significantly improved,which resulted from the dense,uniform,and fine recrystallization structure and the synergistic effect of multiple slip systems.

Design,preparation,microstructure and mechanical property of the lightweight radiation-shielding Mg-Ta-Al composites basing differential temperature hot rolling

A novel lightweight,radiation-shielding Mg-Ta-Al layered metal-matrix composite(LMC)was successful designed by doping the extremely refractory metal(Ta)into Mg sheets.These Mg-based LMCs sheets shows excellent radiation-dose shield effect,about 145 krad·a^(−1),which is about 17 times of traditional Mg alloy,while its surface density is only about 0.9 g·cm^(−2),reducing by 60%than that of pure Ta.The quantitate relationship between radiation-dose and the materials’thickness was also confirmed to the logistic function when the surface density is in the range of 0.6-1.5 g·cm^(−2).Meantime,the rolling parameters,interface microstructure and mechanical properties in both as-rolled and annealing treated samples were evaluated.The sheets possess a special dissimilar atoms diffusion transitional zone containing an obvious inter-diffusion Mg-Al interface and the unique micro-corrugated Ta-Al interface,as well as a thin Al film with a thickness of about 10μm.The special zone could reduce the stress concentration and enhance the strength of Mg-Ta-Al LMCs.The interface bonding strength reaches up to 54-76 MPa.The ultimate tensile strength(UTS)and yield strength(TYS)of the Mg-Ta-Al sheet were high to 413 MPa and 263 MPa,respectively,along with an elongation of 5.8%.The molecular dynamics(MD)analysis results show that the two interfaces exhibit different formation mechanism,the Mg-Al interface primarily depended on Mg/Al atoms diffusion basing point defects movement,while the Ta-Al interface with a micro-interlock pining shape formed by close-packed planes slipping during high temperature strain-induced deformation process.

Influence of Production Sequence of Aluminum Alloy Hot Rolling on Strip Surface Quality

With the intensification of market competition in the aluminum alloy strip processing industry,it is dif-ficult to control the mass production of the same specifications,which is bound to affect the hot rolling production.This paper studied the effect of the hot rolling order of aluminum alloy on the surface quality of strip,such as roll printing,color difference,anodic oxidation,etc.,reasonable discharge sequence and corresponding optimization measures were formulated.

Achieving higher strength in Cu–Ag–Zr alloy by warm/hot rolling

High-strength Cu-3Ag-0.5Zr alloy plates were produced by multi-pass rolling in the temperature range of 500-800 ℃. An increase in strength was observed by rolling in the aforementioned range without significant loss in ductility. All the rolled samples show higher strength than solution-treated and aged samples. The maximum strength was observed for plates rolled at 500 ℃ with a yield strength and ultimate tensile strength of 311 and 385 MPa, respectively, and retaining a ductility of 23 %. Transmission electron microscopy （TEM） studies showed uniform distribution of fine silver precipitates and high dislocation density in the rolled samples. Nevertheless, the size of precipitates and dislocation density varied with the rolling temperature. The superior strength achieved in the rolled samples is attributed to grain refinement, dislocation strengthening, and precipitation hardening. This method can be employed to produce high-strength plates of pre- cipitation hardenable copper alloys.

Achieving oxidation protection effect for strips hot rolling via Al_(2)O_(3) nanofluid lubrication

It was discovered the application of Al_(2)O_(3) nanofluid as lubricant for steel hot rolling could synchronously achieve oxidation protection of strips surface.The underlying mechanism was investigated through hot rolling tests and molecular dynamics (MD) simulations.The employment of Al_(2)O_(3) nanoparticles contributed to significant enhancement in the lubrication performance of lubricant.The rolled strip exhibited the best surface topography that the roughness reached lowest with the sparsest surface defects.Besides,the oxide scale generated on steel surface was also thinner,and the ratio of Fe_(2)O_(3) among various iron oxides became lower.It was revealed the above oxidation protection effect of Al_(2)O_(3) nanofluid was attributed to the deposition of nanoparticles on metal surface during hot rolling.A protective layer in the thickness of about 193 nm was formed to prevent the direct contact between steel matrix and atmosphere,which was mainly composed of Al_(2)O_(3) and sintered organic molecules.MD simulations confirmed the diffusion of O_(2) and H_(2)O could be blocked by the Al_(2)O_(3) layer through physical absorption and penetration barrier effect.

FEM modeling of dynamical recrystallization during multi-pass hot rolling of AM50 alloy and experimental verification

The microstructure simulation during the multi-pass hot rolling of AM50 alloy was studied by DEFORM-3D. The excellent agreement with the experiment observations shows that the present modeling and user routine are feasible for the reproduce of the hot rolling process. The multi-pass hot rolling contributes to the achievement of a uniformly recrystallized microstructure with fine grains in the rolled sheet. The sheet temperature before the finish rolling strongly affects the final grain size, but hardly affects the grain size distribution. This modeling and the user routine also have a potential to be applied in the researches of the other multi-pass hot deformation process.

Effects of magnetic field and hot rolling on microstructures and properties of cryo ECAPed 1050 aluminum alloy during annealing

The evolution of hardness and microstructures of 1050 aluminum alloy prepared by hot rolling and subsequent equal- channel angular pressing at cryogenic temperature (cryoECAP) after annealing at 150?400 °C for 1 h without and with magnetic field of 12 T was investigated. The electron back scattering diffraction pattern (EBSD) and transmission electron microscopy (TEM) were utilized to characterize the grain microstructures and dislocations. It is demonstrated that the hot rolling before cryoECAP produces more equiaxed grains with a smaller average size and a higher fraction of high angle boundaries (HABs) in the subsequent cryoECAPed 1050 aluminum alloy, thus accelerating the recovery and recrystallization of cryoECAPed alloy and produces more homogeneous microstructure during annealing. The magnetic field promotes the recovery and recrystallization and leads to much lower hardness at 150?250 °C, while it can suppress the abnormal grain growth and form more homogeneous grain size distributions annealed at 300?400 °C.

Comparison of evolution laws of stress and strain fields in hot rolling of titanium alloy large rings with different sizes

For hot rolling of titanium alloy large rings,evolution laws of stress and strain fields in rings with various sizes were explored and compared based on a reliable coupled thermo-mechanical three-dimensional （3D） finite element （FE） model.The results show that for forming processes of different rings,as γ^-（the equivalent distribution ratio of feed amount per revolution of a process） decreases,the final peak Mises stress may transfer from the biting point at the driver roll side to that at the idle roll side,and the final peak equivalent plastic strain may transfer from the outside surface to the inside surface;as L^- （the equivalent deformation zone length of a process） increases,the final peak Mises stress may appear in the middle layer.The final positions of peak Mises stress and equivalent plastic strain are the combined effects of the above two aspects.In the deformation zone of a deformed ring,the surface layers are in the 3D compressive stress state,while the middle layer is in the 1D compressive and 2D tensile stress state or 2D compressive and 1D tensile stress state;the whole ring is in the 1D compressive and 2D tensile strain state.

Dynamic explicit FE modeling of hot ring rolling process

A new FE modeling method of hot ring rolling was presented by solving key technologies such as contact and heat boundary conditions,motion control over guide rolls,and mass scaling.The method has the following features:1)the elastic-plastic dynamic explicit approach instead of the static implicit approach is adopted to solve the process so as to greatly improve computational efficiency without sacrificing computational accuracy;2)the coupled thermal-mechanical effect is considered as opposed to the conventional isothermal assumption,which is more practical;3)in contrast to the simplified 2D or local 3D ring model,the full 3D ring is modeled to simulate the process.Based on the FE modeling method,two cases of hot plain ring rolling are simulated in the FEA software ABAQUS/Explicit.The simulation results are compared with the experimental measurements and the good agreement between them is observed regarding the material flow and the temperature distribution of the ring.

Numerical Simulation of Temperature Field and Thermal Stress Field of Work Roll During Hot Strip Rolling

Based on the thermal conduction equations, the three-dimensional （3D） temperature field of a work roll was investigated using finite element method （FEM）. The variations in the surface temperature of the work roll during hot strip rolling were described, and the thermal stress field of the work roll was also analyzed. The results showed that the highest roll surface temperature is 593 ℃, and the difference between the minimum and maximum values of thermal stress of the work roll surface is 145.7 MPa. Furthermore, the results of this analysis indicate that temperature and thermal stress are useful parameters for the investigation of roll thermal fatigue and also for improving the quality of strip during rolling.

Three-Dimensional Thermo-mechanical Coupled FEM Simulation for Hot Continuous Rolling of Large-Diameter Mandrel Bar

Based on the important boundary conditions of rolling simulation including friction, heat conduction and interactionsof the workpiece and rolls, the hot continuous rolling processes of large-diameter mandrel round bar (200 mm indiameter) in 6VH-stand hot tandem mill are successfully simulated by three-dimensional coupled thermomechanicalelastoplastic finite element method (FEM). The distributions of stress, strain, temperature and the rolling force andtorque for the two-pass and four-pass continuous rolling are calculated respectively. Thus, the two and four-passroll schedules are verified, respectively. The simulation results show that it is safe to produce 200 mm round barby the two-pass (oval pass and round pass) continuous rolling on the existing equipment compared to the four-passcontinuous rolling. There are concave surfaces and increased widths occurring at the end of rolled billet due touneven deformations between the outside and inside of the workpiece as well as the free spreading close to the rollgap of the final pass.

Three-Di mensional Model for Strip Hot Rolling

A three-dimensional model for strip hot rolling was developed, in which the plastic deformation of strip, the thermal crown of rolls, roll deflection and flattening were calculated by rigid-plastic finite element method, finite difference method, influential function method and elastic finite element method respectively. The roll wear was taken into consideration. The model can provide detailed information such as rolling pressure distribution, contact pressure distribution between backup rolls and work rolls, deflection and flattening of work rolls, lateral distribution of strip thickness, and lateral distribution of front and back tensions. The finish rolling on a 1 450 mm hot strip mill was simulated.

Finite Element Simulation of Hot Strip Continuous Rolling Process Coupling Microstructural Evolution

Using the nonlinear rigid-viscoplastic finite element method （FEM）, a finite element simulation of the hot strip continuous rolling process was done, which completely integrates different phenomena such as the metallurgical behavior of the strip and the thermo-mechanics in the strip based on the physical metallurgical microstructural evolution law. By combining with the process parameters of certain 2 050 mm hot strip rolling, an actual roll- ing process of low carbon steel SS400 was simulated using the FEM model. Based on the simulation results, the distributions of the strain field, the temperature field, and the microstructure were presented. Meanwhile, the simulated rolling force, temperature, and microstructure are in good agreement with the measured results.

Backup roll contour in finishing trains of hot rolling based on hybrid genetic algorithm

On the basis of integrating two-dimensional varying thickness finite elementmethod with hybrid genetic algorithm, a precise model was developed to design ideal backup rollcontour (Varying Contact Backup Roll, in short VCR) in finishing rains of hot rolling rapidly andefficaciously. Additionally, a lot of good actual effects of VCR, such as evident improvement ofprofile and flatness of strip, remarkable decrease of roll consume, excellent maneuverability andmaintenance, and so on, were validated by long-term industrial tests in hot rolling strip plant ofWuhan Iron and Steel Group Corporation (WISCO).

Mechanism of hot-rolling crack formation in lean duplex stainless steel 2101

The thermoplasticity of duplex stainless steel 2205（DSS2205） is better than that of lean duplex steel 2101（LDX2101）, which undergoes severe cracking during hot rolling. The microstructure, microhardness, phase ratio, and recrystallization dependence of the deformation compatibility of LDX2101 and DSS2205 were investigated using optical microscopy（OM）, electron backscatter diffraction（EBSD）, Thermo-Calc software, and transmission electron microscopy（TEM）. The results showed that the phase-ratio transformations of LDX2101 and DSS2205 were almost equal under the condition of increasing solution temperature. Thus, the phase transformation was not the main cause for the hot plasticity difference of these two steels. The grain size of LDX2101 was substantially greater than that of DSS2205, and the microhardness difference of LDX2101 was larger than that of DSS2205. This difference hinders the transfer of strain from ferrite to austenite. In the rolling process, the ferrite grains of LDX2101 underwent continuous softening and were substantially refined. However, although little recrystallization occurred at the boundaries of austenite, serious deformation accumulated in the interior of austenite, leading to a substantial increase in hardness. The main cause of crack formation is the microhardness difference between ferrite and austenite.

MODELING OF FERRITE GRAIN GROWTH OF LOW CARBON STEELS DURING HOT ROLLING

For most commercial steels the prediction of the final properties depends on accurately calculating the room temperature ferrite grain size. A grain growth model is proposed for low carbon steels Q235B during hot rolling. By using this model, the initial ferrite grain size after continuous cooling and ferrite grain growing in coiling procedure can be predicted. In-plant trials were performed in the hot strip mill of Ansteel. The calculated final ferrite grain sizes are in good agreement with the experimental ones. It is helpful both for simulation of microstructure evolution and prediction of mechanical properties.

Analysis of the thermal profile of work rolls in the hot strip rolling process

A 2-dimension axisymmetric model was developed by the finite-differencemethod, which can be used to predict the transient temperature field and thermal profile of workrolls in the hot strip rolling process. To demonstrate the accuracy and reliability of the solutiondeveloped, the calculation results were compared with the production data of a 1700 mm hot striprolling mill and good agreement was found between them. The effect of strip width and roll shiftingon the thermal expansion of the work rolls was studied. It is found that the strip width has markedeffect on the efficient thermal crown. Initially, when the rolling strip changes from narrow towide, a bigger efficient thermal crown can be quickly achieved; afterwards, when the rolling stripchanges from wide to narrow, not only the influence of uneven wear can be reduced but also theexcessive efficient thermal crown can be avoided. It is also found that the work roll shifting has adeterminate but not obvious effect on the reduction of the efficient thermal crown, and will makethe strip shape unstable without being used properly.

3D FE Analysis of Thermal Behavior of Billet in Rod and Wire Hot Continuous Rolling Process

An FE model was developed to study thermal behavior during the rod and wire hot continuous rolling process. The FE code MSC. Marc was used in the simulation using implicit static arithmetic. The whole rolling process of 30 passes was separated and simulated with several continuous 3D elastic-plastic FE models. A rigid pushing body and a data transfer technique were introduced into this model. The on-line experiments were conducted on 304 stainless steel and GCr15 steel hot continuous rolling process to prove the results of simulation by implicit static FEM. The results show that the temperature results of finite element simulations are in good agreement with experiments, which indicate that the FE model developed in this study is effective and efficient.

On the texture evolution of Mg-Zn-Ca alloy with different hot rolling paths

In the present study,the texture evolution and mechanical anisotropy in a typical Mg–Zn–Ca alloy through hot cross rolling(CR)and unidirectional rolling(UR)were systematically studied.The results show that the rolling path greatly affects the annealed texture.The UR develops a texture with basal poles mainly distributing along the transverse direction(TD).By contrast,an ellipse-like(0002)texture with basal pole inclining largely away from the normal direction(ND)is developed after hot cross rolling and annealing.Therefore,the CR is an effective method to tailor the texture of the experimental alloy.Unfortunately,this ellipse-like texture could not reserve during the subsequent unidirectional hot rolling and annealing.Both UR and CR plates exhibit a strong planar mechanical anisotropy compared with the traditional unidirectional rolled plate.

Effect of hot rolling on microstructure and properties of the ZEK100 alloy

Attempts to expand manufacturing capabilities of magnesium-based sheet materials are described.The as-cast ZEK100(Mg-1.2Zn-0.35Zr-0.17Nd,in wt%)magnesium alloy was subjected to hot rolling at temperatures from 350℃to 450℃using the laboratory 50 ton reversible mill with preheated rolls to manufacture the 1.5-1.7 mm thick sheet.The rolling temperature affected the sheet properties and an increase in the rolling temperature from 250 to 450℃caused reduction of tensile strength from 257 to 228 MPa ac-companied by a reduction in tensile yield stress from 237 to 185 MPa.At the same time,the alloy elongation increased from 17 to 21%.For the same rolling temperature range,the compressive strength reduced from 418 to 351 MPa.The post-rolling annealing at 450℃led to reduction of both tensile and compressive properties with the largest changes corresponding to the rolling temperature of 350°C.The correlation between the alloy grain size after rolling and the sheet properties was established where a reduction in grain size was accompanied by an increase of both the tensile/compressive strength and yield stress.Based on Hall-Petch relationship and an average grain size the correlation developed in this study may be used as the prediction model for properties of the hot rolled magnesium sheet.The results are discussed in terms of recent developments in magnesium sheet alloys and the vital role played in this process by rare earth elements.