Municipal solid waste incineration tailings were used as lightweight aggregate(MSWIT-LA)in the preparation of specified density concrete to study the effects on compressive strength,axial compressive strength,flexural...Municipal solid waste incineration tailings were used as lightweight aggregate(MSWIT-LA)in the preparation of specified density concrete to study the effects on compressive strength,axial compressive strength,flexural strength,microhardness,total number of pores,pore area,and pore spacing.The results showed that the internal curing and morphological effects induced by an appropriate quantity of MSWIT-LA improved the compressive response of specified density concrete specimens,whereas an excessive quantity of MSWIT-LA significantly reduced their mechanical properties.An analysis of pore structure indicated that the addition of MSWIT-LA increased the total quantity of pores and promoted cement hydration,resulting in a denser microstructure than that of ordinary concrete.The results of a principal component analysis showed that the mechanical response of specified density concrete prepared with 25%MSWIT-LA was superior to that of an equivalent ordinary concrete.It was therefore concluded that MSWIT-LA can be feasibly applied to achieve excellent specified density concrete properties while utilising municipal solid waste incineration tailings to protect the environment and alleviate shortages of sand and gravel resources.展开更多
In the municipal solid waste incineration process,it is difficult to effectively control the gas oxygen content by setting the air flow according to artificial experience.To address this problem,this paper proposes an...In the municipal solid waste incineration process,it is difficult to effectively control the gas oxygen content by setting the air flow according to artificial experience.To address this problem,this paper proposes an optimization control method of gas oxygen content based on model predictive control.First,a stochastic configuration network is utilized to establish a prediction model of gas oxygen content.Second,an improved differential evolution algorithm that is based on parameter adaptive and t-distribution strategy is employed to address the set value of air flow.Finally,model predictive control is combined with the event triggering strategy to reduce the amount of computation and the controller's frequent actions.The experimental results show that the optimization control method proposed in this paper obtains a smaller degree of fluctuation in the air flow set value,which can ensure the tracking control performance of the gas oxygen content while reducing the amount of calculation.展开更多
Air pollution control poses a major problem in the implementation of municipal solid waste incineration(MSWI).Accurate prediction of nitrogen oxides(NO_(x))concentration plays an important role in efficient NO_(x)emis...Air pollution control poses a major problem in the implementation of municipal solid waste incineration(MSWI).Accurate prediction of nitrogen oxides(NO_(x))concentration plays an important role in efficient NO_(x)emission controlling.In this study,a modular long short-term memory(M-LSTM)network is developed to design an efficient prediction model for NO_(x)concentration.First,the fuzzy C means(FCM)algorithm is utilized to divide the task into several sub-tasks,aiming to realize the divide-and-conquer ability for complex task.Second,long short-term memory(LSTM)neural networks are applied to tackle corresponding sub-tasks,which can improve the prediction accuracy of the sub-networks.Third,a cooperative decision strategy is designed to guarantee the generalization performance during the testing or application stage.Finally,after being evaluated by a benchmark simulation,the proposed method is applied to a real MSWI process.And the experimental results demonstrate the considerable prediction ability of the M-LSTM network.展开更多
Garbage incineration is an ideal method for the harmless and resource-oriented treatment of urban domestic waste.However,current domestic waste incineration power plants often face challenges related to maintaining co...Garbage incineration is an ideal method for the harmless and resource-oriented treatment of urban domestic waste.However,current domestic waste incineration power plants often face challenges related to maintaining consistent steam production and high operational costs.This article capitalizes on the technical advantages of big data artificial intelligence,optimizing the power generation process of domestic waste incineration as the entry point,and adopts four main engine modules of Alibaba Cloud reinforcement learning algorithm engine,operating parameter prediction engine,anomaly recognition engine,and video visual recognition algorithm engine.The reinforcement learning algorithm extracts the operational parameters of each incinerator to obtain a control benchmark.Through the operating parameter prediction algorithm,prediction models for drum pressure,primary steam flow,NOx,SO2,and HCl are constructed to achieve short-term prediction of operational parameters,ultimately improving control performance.The anomaly recognition algorithm develops a thickness identification model for the material layer in the drying section,allowing for rapid and effective assessment of feed material thickness to ensure uniformity control.Meanwhile,the visual recognition algorithm identifies flame images and assesses the combustion status and location of the combustion fire line within the furnace.This real-time understanding of furnace flame combustion conditions guides adjustments to the grate and air volume.Integrating AI technology into the waste incineration sector empowers the environmental protection industry with the potential to leverage big data.This development holds practical significance in optimizing the harmless and resource-oriented treatment of urban domestic waste,reducing operational costs,and increasing efficiency.展开更多
Domestic waste incineration slag(WIS)includes fly ash and slag.Fly ash is classified as hazardous waste because it contains heavy metals.Most of slag are directly stacked or landfilled due to problems such as large ou...Domestic waste incineration slag(WIS)includes fly ash and slag.Fly ash is classified as hazardous waste because it contains heavy metals.Most of slag are directly stacked or landfilled due to problems such as large output and low utilization rate.Harmless treatment is imminent.If WIS is used effectively in the road engineering,which can realize the high-quality and high-efficiency recycling of WIS,and it is of great significance to save resources and protect the environment.This study applies a geopolymer prepared from WIS fly ash as a stabilizing agent in WIS blending macadam for use as a pavement base mixture,and reports the mechanical properties(unconfined compressive strength,splitting strength,and resilience modulus)of the geopolymer-stabilized WIS blending macadam(GeoWIS).The leaching concentrations of harmful heavy metals of GeoWIS soaked in water were also investigated.Finally,the strength formation and heavy metal stability mechanisms were explored.The unconfined compressive strength,splitting strength,and compressive resilient modulus of GeoWIS all increased with increasing geopolymer content and decreasing WIS content.The strength of GeoWIS was derived from its geopolymerization and hydration products(C-S-H gel,N-A-S-H gel,and AFt).When the geopolymer content reached 12%–14%,the GeoWIS without natural macadam met the strength criterion of the asphalt pavement base.Through physical adsorption and chemical bonding,the geopolymer significantly reduced the leaching of harmful heavy metals.In GeoWIS with 50%WIS and stabilized with 10%geopolymer,the Cr,Ni,Cd,and Pb concentrations met the grade III groundwater standard.Concentrations of heavy metals leached from GeoWIS are low and exert little impact on environment.展开更多
The extraction behavior of heavy metals from municipal waste incineration (MWI) fly ash was investigated systematically. The extraction process includes two steps, namely, fly ash was firstly washed with water, and ...The extraction behavior of heavy metals from municipal waste incineration (MWI) fly ash was investigated systematically. The extraction process includes two steps, namely, fly ash was firstly washed with water, and then subjected to hydrochloric acid leaching. The main parameters for water washing process were tested, and under the optimal conditions, about 86% Na, 70% K and 12% Ca were removed from fly ash, respectively. Hydrochloric acid was used for the extraction of valuable elements from the water-washed fly ash, and the optimal extraction was achieved for each heavy metal as follows: 86% for Pb, 98% for Zn, 82% for Fe, 96% for Cd, 62% for Cu, 80% for Al, respectively. And the main compositions of the finally obtained solid residue are Ca2PbO4, CaSi2Os, PbsSiO7, Ca3A12Si3012 and SiO2.展开更多
The impact of moisture on the partitioning of the heavy metals including Pb,Zn,Cu and Cd in municipal solid waste (MSW) was studied in a laboratory tubular furnace.A thermodynamic investigation using CHEMKIN softwar...The impact of moisture on the partitioning of the heavy metals including Pb,Zn,Cu and Cd in municipal solid waste (MSW) was studied in a laboratory tubular furnace.A thermodynamic investigation using CHEMKIN software was performed to compare the experimental results.Simulated waste,representative of typical MSW with and without chlorine compounds,was burned at the background temperature of 700 and 950°C,respectively.In the absence of chlorine,the moisture content has no evident effect on the volatility of Pb,Zn and Cu at either 700 or 950°C,however,as flue gas moisture increasing the Cd distribution in the bottom ash increased at 700°C and reduced at 950°C,respectively.In the presence of chlorine,the flue gas moisture reduced the volatility of Pb,Zn and Cu due to the transformation of the more volatile metal chlorides into less volatile metal oxides,and the reduction became significant as chlorine content increase.For Cd,the chlorine promotes its volatility through the formation of more volatile CdCl 2.As a result,the increased moisture content increases the Pb,Zn,Cu and Cd concentrations in the bottom ash,which limits the utilization of the bottom ash as a construction material.Therefore,in order to accumulate heavy metals into the fly ash,MSW should be dried before incineration.展开更多
The performance of industrial waste incineration bottom ash in controlled low-strength material (CLSM) was investigated in this paper, as the quarry dust was added. CLSM mixtures were made from the industrial waste ...The performance of industrial waste incineration bottom ash in controlled low-strength material (CLSM) was investigated in this paper, as the quarry dust was added. CLSM mixtures were made from the industrial waste incineration bottom ash, quarry dust, and cement. Tests for fresh density, bleeding, compressive strength, shear strength, hydraulic conductivity, and excavatability were carried out. The com- pressive strength ranges from 60 kPa to 6790 kPa, the friction angle varies from 5°to 19°, and the cohesion is from 4 to 604 kPa. Most of the mixtures are found to be non-excavatable. It is indicated that the quarry dust addition increases the compressive strength and shear parame- ters, decreases bleeding, and increases the removability modulus.展开更多
To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration (MSW1) fly ash were studied by measuring the chemica...To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration (MSW1) fly ash were studied by measuring the chemical element composition, specific surface area, pore sizes, functional groups, TEM image, mineralogy and DSC-TG curves of raw and sintered fly ash specimens. The results show that MSWI fly ash particles mostly have irregular shapes and non-typical pore structure, and the supersonic treatment improves the pore structure; MSWI fly ash consists of Such crystals as SiO2, CaSO4 and silica-aluminates, and some soluble salts like KCl and NaCl. During the sintering process, mineralogy changes largely and novel solid solutions are produced gradually with the rise of temperature. Therefore, the utilization of a proper thermal technology not only destructs those persistent organic toxicants but also stabilizes hazardous heavy metals in MSWI fly ash.展开更多
Grate fly ash and fluidized bed fly ash mixed with glass cullet additive respectively were melted in the electronic arc-furnace. The product, arc-melting slag, was further treated by crushing, pressing and heat treatm...Grate fly ash and fluidized bed fly ash mixed with glass cullet additive respectively were melted in the electronic arc-furnace. The product, arc-melting slag, was further treated by crushing, pressing and heat treatment in order to make the glass-ceramics. The crystallization behaviors of the produced glass-ceramics were examined by differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). Results show that main crystalline phase of the glass-ceramics fi'om grate fly ash is wollastonite (CaSiO3) with small amount of diopside (Ca(Mg,Al)(Si,Al)206), and that from fluidized bed fly ash is diopside (Ca(Mg,Al)(Si,Al)206). It is found that the glass-ceramics sintered at 850 ℃and 1 000℃ from grate fly ash and fluidized bed fly ash respectively have the optimal physical, mechanical and chemical characteristics. Glass-ceramics samples, produced from incinerator fly ash with desirable properties and the low leaching concentration of heavy metals, can be the substitute of nature materials such as marble, granite and porcelain tiles.展开更多
The mechanism of removing phosphate by MSWI(municipal solid waste incineration)fly ash was investigated by SEM(scanning electron microscopy)with EDS(energy dispersion spectrum),XRD(X-ray diffraction),FT-IR(Fourier tra...The mechanism of removing phosphate by MSWI(municipal solid waste incineration)fly ash was investigated by SEM(scanning electron microscopy)with EDS(energy dispersion spectrum),XRD(X-ray diffraction),FT-IR(Fourier transform infrared spectroscopy),BET(specific surface area),and BJH(pore size distribution).The results indicate that the removal rate of phosphate(100 mg/L)in 50 mL phosphorus wastewater reaches at 99.9% as the dosage of MSWI fly ash being 0.9000 g under room temperature.The specific surface area of MSWI fly ash is less than 6.1 m2/g and the total pore volume is below 0.021 cm3/g,suggesting that the absorption capacity of calcite is too weak to play an important role in phosphate removal.SEM images show that drastic changes had taken place on its specific surface shape after reaction,and EDS tests indicate that some phosphate precipitates are formed and attached onto MSWI fly ash particles.Chemical precipitation is the main manner of phosphate removal and the main reaction is: 3Ca2++2 PO4 3-+xH2O→Ca3(PO4)2↓·xH2O.Besides,XRD tests show that the composition of MSWI fly ash is complex,but CaSO4 is likely to be the main source of Ca2+.The soluble heavy metals in MSWI fly ash are stabilized by phosphate.展开更多
In recent years,relevant government departments have achieved the goal of reduction and harmless application through the development and implementation of municipal waste incineration power plants,in order to advocate...In recent years,relevant government departments have achieved the goal of reduction and harmless application through the development and implementation of municipal waste incineration power plants,in order to advocate ecological and environmental protection.At present,in order to further achieve the goal of sustainable development,municipal waste incineration power plants have actively responded to the national call and requirements as well as made overall arrangements for the energy-saving design and optimization design of their internal system.Therefore,with the concept of sustainable development,this paper studies and analyzes the problems of the HVAC design as well as suggests related strategies for municipal waste incineration power plants in order to provide relevant reference.展开更多
Chromium released during municipal solid waste incineration(MSWI)is toxic and carcinogenic.The removal of chromium from simulated MSWI flue gas by four sorbents(CaO,bamboo charcoal(BC),powdered activated carbon(PAC),a...Chromium released during municipal solid waste incineration(MSWI)is toxic and carcinogenic.The removal of chromium from simulated MSWI flue gas by four sorbents(CaO,bamboo charcoal(BC),powdered activated carbon(PAC),and Al_(2)O_(3))and the effects of four oxides(SiO_(2),Al_(2)O_(3),Fe_(2)O_(3),and CaO)on chromium speciation transformationwere investigated.The results showed that the removal rates of total Cr by the four sorbents were Al_(2)O_(3)<CaO<PAC<BC,while the removal rates of Cr(Ⅵ)by the four sorbents were Al_(2)O_(3)<PAC<BC<CaO.CaO had a strong oxidizing effect on Cr(Ⅲ),while BC and PAC had a better-reducing effect on Cr(Ⅵ).SiO_(2)was better for the reduction of Na_(2)CrO_(4)and K_(2)CrO_(4)above 1000℃due to its strong acidity,and the addition of CaO significantly inhibited the reduction of Cr(Ⅵ).MgCrO_(4)decomposed above 700℃to form MgCr_(2)O_(4),and the reaction between MgCrO_(4)and oxides also existed in the form of a more stable trivalent spinel.Furthermore,when investigating the effect of oxides on the oxidation of Cr(Ⅲ)in CrC_(l3),it was discovered that CaO promoted the conversion of Cr(Ⅲ)to Cr(Ⅵ),while the presence of chlorine caused chromium to exist in the form of Cr(V),and increasing the content of CaO and extending the heating time facilitated the oxidation of Cr(Ⅲ).In addition,silicate,aluminate,and ferrite were generated after the addition of SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3),which reduced the alkalinity of CaO and had an important role in inhibiting the oxidation of Cr(Ⅲ).The acidic oxides can not only promote the reduction of Cr(Ⅵ)but also have an inhibitory effect on the oxidation of Cr(Ⅲ)ascribed to alkali metals/alkaline earth metals,and the proportion of acidic oxides can be increased moderately to reduce the generation of harmful substances in the hazardous solid waste heat treatment.展开更多
Due to the large uncertainty in the municipal solid waste incineration(MSWI)process,the furnace temperature of the MSWI process is difficult to control and the controller is updated frequently.To improve the accuracy ...Due to the large uncertainty in the municipal solid waste incineration(MSWI)process,the furnace temperature of the MSWI process is difficult to control and the controller is updated frequently.To improve the accuracy and reduce the number of controller updates,a novel event-triggered control method based correntropy self-organizing TS fuzzy neural network(ETCSTSFNN)is proposed.Firstly,the neurons of the rule layer are grown or pruned adaptively based on activation intensity and control error to meet the dynamic change of the actual operating condition.Meanwhile,the performance index is designed based on the correntropy of tracking errors,and the parameters of the controller are adjusted by gradient descent algorithm.Secondly,a fixed threshold event-triggered condition is designed to determine whether the current controller is updated or not.The stability of the control system is proved based on the Lyapunov stability theory.Finally,the furnace temperature control experiments are conducted based on the actual data of a municipal solid waste incineration plant in Beijing.The experimental results show that the proposed ET-CSTSFNN controller shows a better control performance,which can reduce the number of the controller update significantly while achieving accurate furnace temperature control compared with other traditional control methods.展开更多
Because of coupling,nonlinearity,and uncertainty in a municipal solid waste incineration(MSWI)process,a suitable multivariable controller is difficult to establish under strong disturbance.Additionally,the problems of...Because of coupling,nonlinearity,and uncertainty in a municipal solid waste incineration(MSWI)process,a suitable multivariable controller is difficult to establish under strong disturbance.Additionally,the problems of reducing mechanical wear and energy consumption in the control process should also be considered.To solve these problems,an event-triggered fuzzy neural multivariable controller is proposed in this paper.First,the MSWI object model based on the multiinput multioutput TakagiSugeno fuzzy neural network is established using a data-driven method.Second,a fuzzy neural multivariable controller is designed to control the furnace temperature and flue gas oxygen content synchronously under external disturbance.Third,an event-triggered mechanism is constructed to update the control rate online while ensuring control effects.Then,the stability of the proposed control strategy is proven through the LyapunovⅡtheorem to guide its practical application.Finally,the effectiveness of the controller is verified using the real industrial data of an MSWI factory in Beijing,China.The experimental results show that the proposed control strategy greatly improves the control efficiency,reduces energy consumption by 66.23%,and improves the multivariable tracking control accuracy.展开更多
Incineration is widely adopted in municipal solid waste management,which produces large amounts of municipal solid waste incineration(MSWI)fly ash.The harmless treatment of MSWI fly ash requires the appropriate dispos...Incineration is widely adopted in municipal solid waste management,which produces large amounts of municipal solid waste incineration(MSWI)fly ash.The harmless treatment of MSWI fly ash requires the appropriate disposal of heavy metals and dioxins that are enriched in fly ash.This review summarizes recently developed harmless disposal methods for MSWI fly ash including solidification/stabilization,thermal treatment,and separation/extraction.In addition,we discuss heavy metal and dioxin fixation,and the removal capacity of fly ash via solidification/stabilization(including cement solidification,chemical stabilization,hydrothermal processes,and mechano-chemical methods),thermal treatment(including sintering,fuel-burning,or electric melting/vitrification),and separation/extraction(including water-washing,chemical reagent leaching,biological leaching,electrodialysis separation,chemical reagent extraction,and nanomaterials extraction).The advantages and disadvantages of different harmless treatment methods are compared and future research prospects and suggestions are summarized.This review provides general guidelines for the harmless treatment of MSWI fly ash in the future.展开更多
A novel time-span input neural network was developed to accurately predict the trend of the main steam temperature of a 750-t/d waste incineration boiler.Its historical operating data were used to retrieve sensitive p...A novel time-span input neural network was developed to accurately predict the trend of the main steam temperature of a 750-t/d waste incineration boiler.Its historical operating data were used to retrieve sensitive parameters for the boiler output steam temperature by correlation analysis.Then,the 15 most sensitive parameters with specified time spans were selected as neural network inputs.An external testing set was introduced to objectively evaluate the neural network prediction capability.The results show that,compared with the traditional prediction method,the time-span input framework model can achieve better prediction performance and has a greater capability for generalization.The maximum average prediction error can be controlled below 0.2°C and 1.5°C in the next 60 s and 5 min,respectively.In addition,setting a reasonable terminal training threshold can effectively avoid overfitting.An importance analysis of the parameters indicates that the main steam temperature and the average temperature around the high-temperature superheater are the two most important variables of the input parameters;the former affects the overall prediction and the latter affects the long-term prediction performance.展开更多
Municipal solid waste incineration(MSWI)fly ash(FA)is classified as hazardous waste,which requires additional treatment before disposal or further utilization.Stabilization/solidification(S/S)is regarded as a low-cost...Municipal solid waste incineration(MSWI)fly ash(FA)is classified as hazardous waste,which requires additional treatment before disposal or further utilization.Stabilization/solidification(S/S)is regarded as a low-cost and high-efficient method for MSWI FA treatment.“Low-carbon S/S”has captured extensive interest in recent years,which could treat hazardous wastes and enable resource recycling in a sustainable way.This article introduced the state-of-art low-carbon S/S strategies for MSWI FA treatment.The immobilization mechanisms of pollutants in various matrices were also discussed.Prospects were raised to foster the actualization of sustainable management of MSWI FA.展开更多
Development space of the waste incineration power generation is expanding. According to the technical route of previous planning and related policies, the principles of our garbage disposal are based on sanitary landf...Development space of the waste incineration power generation is expanding. According to the technical route of previous planning and related policies, the principles of our garbage disposal are based on sanitary landfill, supplemented by burning. However, with the accelerated process of urbanization, land resources are increasingly strained and most large cities have been unable to find a suitable landfill within the feasible urban extent, the main equipment for the incinerator and the localization of the overall process greatly reduced its capital investment and these factors will promote the rapid development of waste incineration power generation industry. Waste incineration and power generation technology has the dual benefits of environmental protection and energy and it is the development direction of waste disposal in the future. According to the condition that our country's waste incineration power generation started from scratch and developed rapidly in recent years ,there is a introduction about the application of the waste incineration and a brief analysis of the its obstacles in the promotion and financing, as well as the potential for future applications.展开更多
Cl is one of the main pollutants emitted from domestic waste incineration systems. In this study, we focused on the process of Ca dechlorination in the furnace of a circulating fluidized-bed waste incineration system....Cl is one of the main pollutants emitted from domestic waste incineration systems. In this study, we focused on the process of Ca dechlorination in the furnace of a circulating fluidized-bed waste incineration system. We analyzed the stability of CaCl_(2) and Ca in the furnace, the dechlorination process, and distribution of Cl in the incineration system. The results show that the optimal Ca/Cl molar ratio for Ca dechlorination in the circulating fluidized-bed waste incinerator is 2:1;moreover, the dechlorination product CaCl_(2) was found to decompose at high temperatures (> 850℃). At temperatures > 700℃, we measured CaCl_(2) decomposition rates up to 80%. Ca was added in the furnace, mainly to provide a dechlorination Ca source for the decomposition of limestone into tail flue gas. The amount of Ca^(2+) in the flue decreased gradually, parallelly to the temperature of the flue gas. Stable CaCl_(2) was formed after HCl was captured, and relatively small solid particles appeared in the ash collecting bag.展开更多
基金Funded by the National Natural Science Foundation of China(Nos.U21A20150,52208249,51878153,52108219,52008196,52178216)Research and Demonstration of Key Technologies of Green and Smart Highways in Gansu Province(No.21ZD3GA002)+1 种基金Gansu Provincial Natural Science Foundation(No.23JRRA799)Key Projects of Chongqing Science and Technology Bureau(No.2021jscx-jbgs0029)。
文摘Municipal solid waste incineration tailings were used as lightweight aggregate(MSWIT-LA)in the preparation of specified density concrete to study the effects on compressive strength,axial compressive strength,flexural strength,microhardness,total number of pores,pore area,and pore spacing.The results showed that the internal curing and morphological effects induced by an appropriate quantity of MSWIT-LA improved the compressive response of specified density concrete specimens,whereas an excessive quantity of MSWIT-LA significantly reduced their mechanical properties.An analysis of pore structure indicated that the addition of MSWIT-LA increased the total quantity of pores and promoted cement hydration,resulting in a denser microstructure than that of ordinary concrete.The results of a principal component analysis showed that the mechanical response of specified density concrete prepared with 25%MSWIT-LA was superior to that of an equivalent ordinary concrete.It was therefore concluded that MSWIT-LA can be feasibly applied to achieve excellent specified density concrete properties while utilising municipal solid waste incineration tailings to protect the environment and alleviate shortages of sand and gravel resources.
基金supported by the National Natural Science Foundation of China(62373017,62073006)and the Beijing Natural Science Foundation of China(4212032)。
文摘In the municipal solid waste incineration process,it is difficult to effectively control the gas oxygen content by setting the air flow according to artificial experience.To address this problem,this paper proposes an optimization control method of gas oxygen content based on model predictive control.First,a stochastic configuration network is utilized to establish a prediction model of gas oxygen content.Second,an improved differential evolution algorithm that is based on parameter adaptive and t-distribution strategy is employed to address the set value of air flow.Finally,model predictive control is combined with the event triggering strategy to reduce the amount of computation and the controller's frequent actions.The experimental results show that the optimization control method proposed in this paper obtains a smaller degree of fluctuation in the air flow set value,which can ensure the tracking control performance of the gas oxygen content while reducing the amount of calculation.
基金the financial support from the National Natural Science Foundation of China(62021003,61890930-5,61903012,62073006)Beijing Natural Science Foundation(42130232)the National Key Research and Development Program of China(2021ZD0112301,2021ZD0112302)。
文摘Air pollution control poses a major problem in the implementation of municipal solid waste incineration(MSWI).Accurate prediction of nitrogen oxides(NO_(x))concentration plays an important role in efficient NO_(x)emission controlling.In this study,a modular long short-term memory(M-LSTM)network is developed to design an efficient prediction model for NO_(x)concentration.First,the fuzzy C means(FCM)algorithm is utilized to divide the task into several sub-tasks,aiming to realize the divide-and-conquer ability for complex task.Second,long short-term memory(LSTM)neural networks are applied to tackle corresponding sub-tasks,which can improve the prediction accuracy of the sub-networks.Third,a cooperative decision strategy is designed to guarantee the generalization performance during the testing or application stage.Finally,after being evaluated by a benchmark simulation,the proposed method is applied to a real MSWI process.And the experimental results demonstrate the considerable prediction ability of the M-LSTM network.
文摘Garbage incineration is an ideal method for the harmless and resource-oriented treatment of urban domestic waste.However,current domestic waste incineration power plants often face challenges related to maintaining consistent steam production and high operational costs.This article capitalizes on the technical advantages of big data artificial intelligence,optimizing the power generation process of domestic waste incineration as the entry point,and adopts four main engine modules of Alibaba Cloud reinforcement learning algorithm engine,operating parameter prediction engine,anomaly recognition engine,and video visual recognition algorithm engine.The reinforcement learning algorithm extracts the operational parameters of each incinerator to obtain a control benchmark.Through the operating parameter prediction algorithm,prediction models for drum pressure,primary steam flow,NOx,SO2,and HCl are constructed to achieve short-term prediction of operational parameters,ultimately improving control performance.The anomaly recognition algorithm develops a thickness identification model for the material layer in the drying section,allowing for rapid and effective assessment of feed material thickness to ensure uniformity control.Meanwhile,the visual recognition algorithm identifies flame images and assesses the combustion status and location of the combustion fire line within the furnace.This real-time understanding of furnace flame combustion conditions guides adjustments to the grate and air volume.Integrating AI technology into the waste incineration sector empowers the environmental protection industry with the potential to leverage big data.This development holds practical significance in optimizing the harmless and resource-oriented treatment of urban domestic waste,reducing operational costs,and increasing efficiency.
基金This work was supported by the Fundamental Research Funds for the Central Universities,CHD(grant number 300102212906)the Key R&D Plan of Shaanxi Province(grant number 2023-YBSF-390)+1 种基金the Innovation Capability Support Program of Shaanxi(grant number 2022TD-07)the Xianyang City,Shaanxi Province,China 2019 Key Research and Development Program(grant number 2019k02-125).
文摘Domestic waste incineration slag(WIS)includes fly ash and slag.Fly ash is classified as hazardous waste because it contains heavy metals.Most of slag are directly stacked or landfilled due to problems such as large output and low utilization rate.Harmless treatment is imminent.If WIS is used effectively in the road engineering,which can realize the high-quality and high-efficiency recycling of WIS,and it is of great significance to save resources and protect the environment.This study applies a geopolymer prepared from WIS fly ash as a stabilizing agent in WIS blending macadam for use as a pavement base mixture,and reports the mechanical properties(unconfined compressive strength,splitting strength,and resilience modulus)of the geopolymer-stabilized WIS blending macadam(GeoWIS).The leaching concentrations of harmful heavy metals of GeoWIS soaked in water were also investigated.Finally,the strength formation and heavy metal stability mechanisms were explored.The unconfined compressive strength,splitting strength,and compressive resilient modulus of GeoWIS all increased with increasing geopolymer content and decreasing WIS content.The strength of GeoWIS was derived from its geopolymerization and hydration products(C-S-H gel,N-A-S-H gel,and AFt).When the geopolymer content reached 12%–14%,the GeoWIS without natural macadam met the strength criterion of the asphalt pavement base.Through physical adsorption and chemical bonding,the geopolymer significantly reduced the leaching of harmful heavy metals.In GeoWIS with 50%WIS and stabilized with 10%geopolymer,the Cr,Ni,Cd,and Pb concentrations met the grade III groundwater standard.Concentrations of heavy metals leached from GeoWIS are low and exert little impact on environment.
文摘The extraction behavior of heavy metals from municipal waste incineration (MWI) fly ash was investigated systematically. The extraction process includes two steps, namely, fly ash was firstly washed with water, and then subjected to hydrochloric acid leaching. The main parameters for water washing process were tested, and under the optimal conditions, about 86% Na, 70% K and 12% Ca were removed from fly ash, respectively. Hydrochloric acid was used for the extraction of valuable elements from the water-washed fly ash, and the optimal extraction was achieved for each heavy metal as follows: 86% for Pb, 98% for Zn, 82% for Fe, 96% for Cd, 62% for Cu, 80% for Al, respectively. And the main compositions of the finally obtained solid residue are Ca2PbO4, CaSi2Os, PbsSiO7, Ca3A12Si3012 and SiO2.
基金supported by the National Natural Science Foundation of China (No. 50776007)the Beijing Municipal Science and Technology Commission under the Municipal Solid Waste Development Program(No. H020620330120)
文摘The impact of moisture on the partitioning of the heavy metals including Pb,Zn,Cu and Cd in municipal solid waste (MSW) was studied in a laboratory tubular furnace.A thermodynamic investigation using CHEMKIN software was performed to compare the experimental results.Simulated waste,representative of typical MSW with and without chlorine compounds,was burned at the background temperature of 700 and 950°C,respectively.In the absence of chlorine,the moisture content has no evident effect on the volatility of Pb,Zn and Cu at either 700 or 950°C,however,as flue gas moisture increasing the Cd distribution in the bottom ash increased at 700°C and reduced at 950°C,respectively.In the presence of chlorine,the flue gas moisture reduced the volatility of Pb,Zn and Cu due to the transformation of the more volatile metal chlorides into less volatile metal oxides,and the reduction became significant as chlorine content increase.For Cd,the chlorine promotes its volatility through the formation of more volatile CdCl 2.As a result,the increased moisture content increases the Pb,Zn,Cu and Cd concentrations in the bottom ash,which limits the utilization of the bottom ash as a construction material.Therefore,in order to accumulate heavy metals into the fly ash,MSW should be dried before incineration.
基金the Ministry of Science, Technology and Innovation (MOSTI), Government of Malaysia and University of Malaya for providing the funds to support this research work
文摘The performance of industrial waste incineration bottom ash in controlled low-strength material (CLSM) was investigated in this paper, as the quarry dust was added. CLSM mixtures were made from the industrial waste incineration bottom ash, quarry dust, and cement. Tests for fresh density, bleeding, compressive strength, shear strength, hydraulic conductivity, and excavatability were carried out. The com- pressive strength ranges from 60 kPa to 6790 kPa, the friction angle varies from 5°to 19°, and the cohesion is from 4 to 604 kPa. Most of the mixtures are found to be non-excavatable. It is indicated that the quarry dust addition increases the compressive strength and shear parame- ters, decreases bleeding, and increases the removability modulus.
基金Project(50808184) supported by the National Natural Science Foundation of China
文摘To analyze the feasibility of utilization of thermal technology in fly ash treatment, thermal properties and microstructures of municipal solid waste incineration (MSW1) fly ash were studied by measuring the chemical element composition, specific surface area, pore sizes, functional groups, TEM image, mineralogy and DSC-TG curves of raw and sintered fly ash specimens. The results show that MSWI fly ash particles mostly have irregular shapes and non-typical pore structure, and the supersonic treatment improves the pore structure; MSWI fly ash consists of Such crystals as SiO2, CaSO4 and silica-aluminates, and some soluble salts like KCl and NaCl. During the sintering process, mineralogy changes largely and novel solid solutions are produced gradually with the rise of temperature. Therefore, the utilization of a proper thermal technology not only destructs those persistent organic toxicants but also stabilizes hazardous heavy metals in MSWI fly ash.
基金Project(20806051) supported by the National Natural Science Foundation of ChinaProject(20080440680) supported by China Postdoctoral Science Foundation
文摘Grate fly ash and fluidized bed fly ash mixed with glass cullet additive respectively were melted in the electronic arc-furnace. The product, arc-melting slag, was further treated by crushing, pressing and heat treatment in order to make the glass-ceramics. The crystallization behaviors of the produced glass-ceramics were examined by differential thermal analysis (DTA), X-ray diffractometry (XRD) and scanning electron microscopy (SEM). Results show that main crystalline phase of the glass-ceramics fi'om grate fly ash is wollastonite (CaSiO3) with small amount of diopside (Ca(Mg,Al)(Si,Al)206), and that from fluidized bed fly ash is diopside (Ca(Mg,Al)(Si,Al)206). It is found that the glass-ceramics sintered at 850 ℃and 1 000℃ from grate fly ash and fluidized bed fly ash respectively have the optimal physical, mechanical and chemical characteristics. Glass-ceramics samples, produced from incinerator fly ash with desirable properties and the low leaching concentration of heavy metals, can be the substitute of nature materials such as marble, granite and porcelain tiles.
基金Projects(51108100,50808184)supported by the National Natural Science Foundation of ChinaProject(100Z007)supported by the Ministry of Education of China+1 种基金Project(200103YB020)supported by Foundation of Guangxi Educational Committee,ChinaProject supported by Guangxi Normal University Education Development Foundation for Young Scholars,China
文摘The mechanism of removing phosphate by MSWI(municipal solid waste incineration)fly ash was investigated by SEM(scanning electron microscopy)with EDS(energy dispersion spectrum),XRD(X-ray diffraction),FT-IR(Fourier transform infrared spectroscopy),BET(specific surface area),and BJH(pore size distribution).The results indicate that the removal rate of phosphate(100 mg/L)in 50 mL phosphorus wastewater reaches at 99.9% as the dosage of MSWI fly ash being 0.9000 g under room temperature.The specific surface area of MSWI fly ash is less than 6.1 m2/g and the total pore volume is below 0.021 cm3/g,suggesting that the absorption capacity of calcite is too weak to play an important role in phosphate removal.SEM images show that drastic changes had taken place on its specific surface shape after reaction,and EDS tests indicate that some phosphate precipitates are formed and attached onto MSWI fly ash particles.Chemical precipitation is the main manner of phosphate removal and the main reaction is: 3Ca2++2 PO4 3-+xH2O→Ca3(PO4)2↓·xH2O.Besides,XRD tests show that the composition of MSWI fly ash is complex,but CaSO4 is likely to be the main source of Ca2+.The soluble heavy metals in MSWI fly ash are stabilized by phosphate.
文摘In recent years,relevant government departments have achieved the goal of reduction and harmless application through the development and implementation of municipal waste incineration power plants,in order to advocate ecological and environmental protection.At present,in order to further achieve the goal of sustainable development,municipal waste incineration power plants have actively responded to the national call and requirements as well as made overall arrangements for the energy-saving design and optimization design of their internal system.Therefore,with the concept of sustainable development,this paper studies and analyzes the problems of the HVAC design as well as suggests related strategies for municipal waste incineration power plants in order to provide relevant reference.
基金supported by the National R&D Program Project of China(No.2019YFC1907000)the Key Research and Development Program of Hubei Province(No.2020BCA076)+1 种基金the Natural Sciences Foundation of China(No.52176127)Natural Science Foundation of Hubei Province(No.2022CFB045)。
文摘Chromium released during municipal solid waste incineration(MSWI)is toxic and carcinogenic.The removal of chromium from simulated MSWI flue gas by four sorbents(CaO,bamboo charcoal(BC),powdered activated carbon(PAC),and Al_(2)O_(3))and the effects of four oxides(SiO_(2),Al_(2)O_(3),Fe_(2)O_(3),and CaO)on chromium speciation transformationwere investigated.The results showed that the removal rates of total Cr by the four sorbents were Al_(2)O_(3)<CaO<PAC<BC,while the removal rates of Cr(Ⅵ)by the four sorbents were Al_(2)O_(3)<PAC<BC<CaO.CaO had a strong oxidizing effect on Cr(Ⅲ),while BC and PAC had a better-reducing effect on Cr(Ⅵ).SiO_(2)was better for the reduction of Na_(2)CrO_(4)and K_(2)CrO_(4)above 1000℃due to its strong acidity,and the addition of CaO significantly inhibited the reduction of Cr(Ⅵ).MgCrO_(4)decomposed above 700℃to form MgCr_(2)O_(4),and the reaction between MgCrO_(4)and oxides also existed in the form of a more stable trivalent spinel.Furthermore,when investigating the effect of oxides on the oxidation of Cr(Ⅲ)in CrC_(l3),it was discovered that CaO promoted the conversion of Cr(Ⅲ)to Cr(Ⅵ),while the presence of chlorine caused chromium to exist in the form of Cr(V),and increasing the content of CaO and extending the heating time facilitated the oxidation of Cr(Ⅲ).In addition,silicate,aluminate,and ferrite were generated after the addition of SiO_(2),Al_(2)O_(3),and Fe_(2)O_(3),which reduced the alkalinity of CaO and had an important role in inhibiting the oxidation of Cr(Ⅲ).The acidic oxides can not only promote the reduction of Cr(Ⅵ)but also have an inhibitory effect on the oxidation of Cr(Ⅲ)ascribed to alkali metals/alkaline earth metals,and the proportion of acidic oxides can be increased moderately to reduce the generation of harmful substances in the hazardous solid waste heat treatment.
基金supported by the National National Science Foundation of China(Grant Nos.62073006 and 62021003)Beijing Natural Science Foundation(Grant No.4212032)。
文摘Due to the large uncertainty in the municipal solid waste incineration(MSWI)process,the furnace temperature of the MSWI process is difficult to control and the controller is updated frequently.To improve the accuracy and reduce the number of controller updates,a novel event-triggered control method based correntropy self-organizing TS fuzzy neural network(ETCSTSFNN)is proposed.Firstly,the neurons of the rule layer are grown or pruned adaptively based on activation intensity and control error to meet the dynamic change of the actual operating condition.Meanwhile,the performance index is designed based on the correntropy of tracking errors,and the parameters of the controller are adjusted by gradient descent algorithm.Secondly,a fixed threshold event-triggered condition is designed to determine whether the current controller is updated or not.The stability of the control system is proved based on the Lyapunov stability theory.Finally,the furnace temperature control experiments are conducted based on the actual data of a municipal solid waste incineration plant in Beijing.The experimental results show that the proposed ET-CSTSFNN controller shows a better control performance,which can reduce the number of the controller update significantly while achieving accurate furnace temperature control compared with other traditional control methods.
基金supported by the Science and Technology Innovation 2030-“New Generation Artificial Intelligence”Major Project of China(Grant No.2021ZD0112300)the Innovative Research Group Project of the National Natural Science Foundation of China(Grant No.62021003)+1 种基金the National Natural Science Foundation of China(Grant No.62073006)the Natural Science Foundation of Beijing(Grant Nos.4212032 and4192009)。
文摘Because of coupling,nonlinearity,and uncertainty in a municipal solid waste incineration(MSWI)process,a suitable multivariable controller is difficult to establish under strong disturbance.Additionally,the problems of reducing mechanical wear and energy consumption in the control process should also be considered.To solve these problems,an event-triggered fuzzy neural multivariable controller is proposed in this paper.First,the MSWI object model based on the multiinput multioutput TakagiSugeno fuzzy neural network is established using a data-driven method.Second,a fuzzy neural multivariable controller is designed to control the furnace temperature and flue gas oxygen content synchronously under external disturbance.Third,an event-triggered mechanism is constructed to update the control rate online while ensuring control effects.Then,the stability of the proposed control strategy is proven through the LyapunovⅡtheorem to guide its practical application.Finally,the effectiveness of the controller is verified using the real industrial data of an MSWI factory in Beijing,China.The experimental results show that the proposed control strategy greatly improves the control efficiency,reduces energy consumption by 66.23%,and improves the multivariable tracking control accuracy.
文摘Incineration is widely adopted in municipal solid waste management,which produces large amounts of municipal solid waste incineration(MSWI)fly ash.The harmless treatment of MSWI fly ash requires the appropriate disposal of heavy metals and dioxins that are enriched in fly ash.This review summarizes recently developed harmless disposal methods for MSWI fly ash including solidification/stabilization,thermal treatment,and separation/extraction.In addition,we discuss heavy metal and dioxin fixation,and the removal capacity of fly ash via solidification/stabilization(including cement solidification,chemical stabilization,hydrothermal processes,and mechano-chemical methods),thermal treatment(including sintering,fuel-burning,or electric melting/vitrification),and separation/extraction(including water-washing,chemical reagent leaching,biological leaching,electrodialysis separation,chemical reagent extraction,and nanomaterials extraction).The advantages and disadvantages of different harmless treatment methods are compared and future research prospects and suggestions are summarized.This review provides general guidelines for the harmless treatment of MSWI fly ash in the future.
基金Project supported by the National Key Research and Development Program of China(No.2018YFC1901300)the Research Project of Multi-data Fusion and Strategy of Intelligent Control and Optimization for Large Scale Industrial Combustion System,China。
文摘A novel time-span input neural network was developed to accurately predict the trend of the main steam temperature of a 750-t/d waste incineration boiler.Its historical operating data were used to retrieve sensitive parameters for the boiler output steam temperature by correlation analysis.Then,the 15 most sensitive parameters with specified time spans were selected as neural network inputs.An external testing set was introduced to objectively evaluate the neural network prediction capability.The results show that,compared with the traditional prediction method,the time-span input framework model can achieve better prediction performance and has a greater capability for generalization.The maximum average prediction error can be controlled below 0.2°C and 1.5°C in the next 60 s and 5 min,respectively.In addition,setting a reasonable terminal training threshold can effectively avoid overfitting.An importance analysis of the parameters indicates that the main steam temperature and the average temperature around the high-temperature superheater are the two most important variables of the input parameters;the former affects the overall prediction and the latter affects the long-term prediction performance.
基金support from the Open Project of State Key Laboratory of Clean Energy Utilization,Zhejiang University(No.ZJUCEU2022001)for this study.
文摘Municipal solid waste incineration(MSWI)fly ash(FA)is classified as hazardous waste,which requires additional treatment before disposal or further utilization.Stabilization/solidification(S/S)is regarded as a low-cost and high-efficient method for MSWI FA treatment.“Low-carbon S/S”has captured extensive interest in recent years,which could treat hazardous wastes and enable resource recycling in a sustainable way.This article introduced the state-of-art low-carbon S/S strategies for MSWI FA treatment.The immobilization mechanisms of pollutants in various matrices were also discussed.Prospects were raised to foster the actualization of sustainable management of MSWI FA.
文摘Development space of the waste incineration power generation is expanding. According to the technical route of previous planning and related policies, the principles of our garbage disposal are based on sanitary landfill, supplemented by burning. However, with the accelerated process of urbanization, land resources are increasingly strained and most large cities have been unable to find a suitable landfill within the feasible urban extent, the main equipment for the incinerator and the localization of the overall process greatly reduced its capital investment and these factors will promote the rapid development of waste incineration power generation industry. Waste incineration and power generation technology has the dual benefits of environmental protection and energy and it is the development direction of waste disposal in the future. According to the condition that our country's waste incineration power generation started from scratch and developed rapidly in recent years ,there is a introduction about the application of the waste incineration and a brief analysis of the its obstacles in the promotion and financing, as well as the potential for future applications.
文摘Cl is one of the main pollutants emitted from domestic waste incineration systems. In this study, we focused on the process of Ca dechlorination in the furnace of a circulating fluidized-bed waste incineration system. We analyzed the stability of CaCl_(2) and Ca in the furnace, the dechlorination process, and distribution of Cl in the incineration system. The results show that the optimal Ca/Cl molar ratio for Ca dechlorination in the circulating fluidized-bed waste incinerator is 2:1;moreover, the dechlorination product CaCl_(2) was found to decompose at high temperatures (> 850℃). At temperatures > 700℃, we measured CaCl_(2) decomposition rates up to 80%. Ca was added in the furnace, mainly to provide a dechlorination Ca source for the decomposition of limestone into tail flue gas. The amount of Ca^(2+) in the flue decreased gradually, parallelly to the temperature of the flue gas. Stable CaCl_(2) was formed after HCl was captured, and relatively small solid particles appeared in the ash collecting bag.