By means of a coaxial apparatus, microsecond charging have been carried out with ferent ethylene glycol concentrations of ethylene pressurized water breakdown experiments with different surface roughness of electrodes...By means of a coaxial apparatus, microsecond charging have been carried out with ferent ethylene glycol concentrations of ethylene pressurized water breakdown experiments with different surface roughness of electrodes and difglycol/water mixture. The experimental results about the breakdown stress and the effective time are presented. The breakdown stress is normalized to the situation that the effective time is transformed to 1 μs and analyzed. The conclusions are as follows： （1） the breakdown stress formula is modified to E = 0.561MA^-1/10teff^-1/^NP^1/8 ;（2） the coefficient M is significantly increased by surface polishing and ethylene glycol additive; （3） it is accumulative for the capacity of improving electrical breakdown strength for surface polishing, ethylene glycol additive, and pressurization, of which pressurization is the most effective method; （4） the highest stress of 235.5 kV/cm is observed in ethylene glycol/water mixture with an ethylene glycol concentration of 80% at a hydrostatic pressure of 1215.9 kPa and is about one time greater than that in pure water at constant pressure; （5） for pressurization and surface polishing, the primary mechanism to improve the breakdown strength of water dielectric is the increase in the breakdown time delay. Research results indicate great potential in the application of the high power pulse conditioning system of water dielectric.展开更多
The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphi...The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphire laser radiation with pulse duration 〈45 fs and energies up to 7 mJ is determined. A calibration curve was obtained for Fe3＋ concentration range from 0.5 g/L to the limit of detection in water solution, and its saturation was detected for concentrations above 0.25 g/L, which is ascribed to self-absorption. The 3σ- limit of detection obtained for Fe in water solution is 2.6 mg/L in the case of 7 mJ laser pulse energy. It is found that an increase of laser pulse energy insignificantly affects on LOD in the time-resolved LIBS and leads to a slight improvement of the limit of detection.展开更多
Water breakdown studies by Nd-YAG laser pulses of duration 100 fs, 30 ps and 6 ns at wavelength 1064 nm are pre- formed to investigate the physical mechanisms which couple the laser energy into the medium. Calculation...Water breakdown studies by Nd-YAG laser pulses of duration 100 fs, 30 ps and 6 ns at wavelength 1064 nm are pre- formed to investigate the physical mechanisms which couple the laser energy into the medium. Calculations are carried out applying a modified kinetic model of water breakdown previously developed by Kennedy (1995) to investigate the correlation between threshold intensity of breakdown and laser pulse length. The modifications considered the introduction of diffusion and recombination loss processes which might take place under the experimental conditions applied in these calculations. The validity of the model is tested by comparing the calculated threshold intensities and the experimentally measured ones where good agreement is shown. The study of the time evolution of the electron density clarifies the correlation between the pulse length and dominant ionization mechanism. The analysis of the spatial distribution of the electron density along the radial and axial distances of the focal spot showed that the size of the formed plasma increases with the increase of the pulse length. On the other hand, studies of self-focusing effect illustrated that under the investigated experimental conditions the effect of this process has an effective contribution only at laser pulses of the order of femtosecond scale when the laser beam is focused by a lens of a focal length ≥8.0 cm. This result in turns assures that using femtosecond pulses in ophthalmic microsurgery could be a safe tool from the retinal damage.展开更多
A highly-sensitive automatic transient laser-induced breakdown spectroscopy （LIBS） system is designed and integrated. It successfully avoids the delay time selecting problem in the conventional LIBS system, and real...A highly-sensitive automatic transient laser-induced breakdown spectroscopy （LIBS） system is designed and integrated. It successfully avoids the delay time selecting problem in the conventional LIBS system, and realizes the LIBS data acquisition with high spatiotemporal resolution automatically. Multiple transient spectra can be obtained in each measurement, which will provide more information for spectral research. The water-vapour and liquid-water Raman scattering spectra are captured by this system, and the comparison of experimental water-vapour Raman scattering spectrum with theoretical data verifies the reliability of the LIBS system. Based on this system, the air laser induced air breakdown spectra are captured and analysed. The system is also useful for the research on water-vapour Raman Lidar remote sensing.展开更多
基金National 863 Project of China (No. 807-2020, 803-5051)
文摘By means of a coaxial apparatus, microsecond charging have been carried out with ferent ethylene glycol concentrations of ethylene pressurized water breakdown experiments with different surface roughness of electrodes and difglycol/water mixture. The experimental results about the breakdown stress and the effective time are presented. The breakdown stress is normalized to the situation that the effective time is transformed to 1 μs and analyzed. The conclusions are as follows： （1） the breakdown stress formula is modified to E = 0.561MA^-1/10teff^-1/^NP^1/8 ;（2） the coefficient M is significantly increased by surface polishing and ethylene glycol additive; （3） it is accumulative for the capacity of improving electrical breakdown strength for surface polishing, ethylene glycol additive, and pressurization, of which pressurization is the most effective method; （4） the highest stress of 235.5 kV/cm is observed in ethylene glycol/water mixture with an ethylene glycol concentration of 80% at a hydrostatic pressure of 1215.9 kPa and is about one time greater than that in pure water at constant pressure; （5） for pressurization and surface polishing, the primary mechanism to improve the breakdown strength of water dielectric is the increase in the breakdown time delay. Research results indicate great potential in the application of the high power pulse conditioning system of water dielectric.
基金supported by the Russian Science Foundation(agreement#14-50-00034)(measurements of limit of detection)Russian Foundation for Basic Research(NK 15-32-20878/15)obtained in the frame of "Organization of Scientific Research"in the Far Eastern Federal University supported by Ministry of Education and Science of Russian Federation
文摘The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphire laser radiation with pulse duration 〈45 fs and energies up to 7 mJ is determined. A calibration curve was obtained for Fe3＋ concentration range from 0.5 g/L to the limit of detection in water solution, and its saturation was detected for concentrations above 0.25 g/L, which is ascribed to self-absorption. The 3σ- limit of detection obtained for Fe in water solution is 2.6 mg/L in the case of 7 mJ laser pulse energy. It is found that an increase of laser pulse energy insignificantly affects on LOD in the time-resolved LIBS and leads to a slight improvement of the limit of detection.
文摘Water breakdown studies by Nd-YAG laser pulses of duration 100 fs, 30 ps and 6 ns at wavelength 1064 nm are pre- formed to investigate the physical mechanisms which couple the laser energy into the medium. Calculations are carried out applying a modified kinetic model of water breakdown previously developed by Kennedy (1995) to investigate the correlation between threshold intensity of breakdown and laser pulse length. The modifications considered the introduction of diffusion and recombination loss processes which might take place under the experimental conditions applied in these calculations. The validity of the model is tested by comparing the calculated threshold intensities and the experimentally measured ones where good agreement is shown. The study of the time evolution of the electron density clarifies the correlation between the pulse length and dominant ionization mechanism. The analysis of the spatial distribution of the electron density along the radial and axial distances of the focal spot showed that the size of the formed plasma increases with the increase of the pulse length. On the other hand, studies of self-focusing effect illustrated that under the investigated experimental conditions the effect of this process has an effective contribution only at laser pulses of the order of femtosecond scale when the laser beam is focused by a lens of a focal length ≥8.0 cm. This result in turns assures that using femtosecond pulses in ophthalmic microsurgery could be a safe tool from the retinal damage.
基金Project supported by the Macao Science and Technology Development Fund,Macao Special Administrative Region (SAR),China(Grant No. 021/2007/A2)the National Natural Science Foundation of China (Grant No. 11176019)
文摘A highly-sensitive automatic transient laser-induced breakdown spectroscopy （LIBS） system is designed and integrated. It successfully avoids the delay time selecting problem in the conventional LIBS system, and realizes the LIBS data acquisition with high spatiotemporal resolution automatically. Multiple transient spectra can be obtained in each measurement, which will provide more information for spectral research. The water-vapour and liquid-water Raman scattering spectra are captured by this system, and the comparison of experimental water-vapour Raman scattering spectrum with theoretical data verifies the reliability of the LIBS system. Based on this system, the air laser induced air breakdown spectra are captured and analysed. The system is also useful for the research on water-vapour Raman Lidar remote sensing.
