A Comparison Study on the δD Value of Polycyclic Aromatic Hydrocarbons in Hydrous Pyrolysate of Herbaceous Peat with Different Water Medium

To investigate the influence of diagenetic water media on the hydrogen isotopes of individual sedimentary aromatic compounds,a series of hydrous pyrolyses were conducted on herbaceous peat.Polycyclic aromatic hydrocarbons(PAHs)in hydrous pyrolysed samples and their hydrogen isotopic composition characteristics were studied.The aqueous medium demonstrated a significant influence on the hydrogen isotopic composition of the individual PAHs generated during pyrolysis.The results showed that the PAHs formed after pyrolysis in the presence of a saltwater medium with high δD value from a salt lake had a heavy hydrogen isotopic composition.The PAHs formed after pyrolysis in the presence of a fresh water medium with low δD value from a swamp had a light hydrogen isotopic composition.The difference in the average PAHδD value between the two hydrous experiments varied from -174‰ to -109‰,suggesting that the hydrogen isotopic composition of individual sedimentary PAHs can reflect the source of the diagenetic water medium.In addition,a comparative study found that the hydrogen isotopes of PAHs were superior to those of n-alkanes in the same sample for diagenetic water indications.The results indicated that the exchange of water-derived inorganic hydrogen and organic hydrogen was more intensive in freshwater experiments than in saltwater experiments.With an increase in the simulation temperature,the average δD value of PAHs generated in the hydrous simulation experiments showed an increasing trend,reflecting that the δD value of sedimentary PAHs formed with the participation of diagenetic water media was still closely related to the thermal maturity of organic matter.Comparative studies showed that theδD values of different types of organic compounds produced by hydrous pyrolysis of peat were in the order,PAHs>n-alkanes>methane.

Effect of Hypomagnetic Field on Water Medium of Living Systems

The article represents the generalizing data for the studying of the effect of hypomagnetic field on physico-chemistry properties of water and bio-objects. It was revealed the changing state of water: increasing of its oxidation-reduction potential and oxidative properties as magnetic induction attenuated pointing to a natural decline, that testifies about the regular decreasing of internal energy of water molecules, which, in our opinion, is caused the inhibition of the germination of seeds of the highest plants, embryonic development of Planorbarius corneus and the changing of energy state of growing mediums for cell culture of mammals. It is supposed that namely the changing state of water is the main component in the effects of weakening of magnetic field on the studying bio-objects.

Water medium retarders for heavy-duty vehicles:Computational fluid dynamics and experimental analysis of filling ratio control method

The water medium（WM） retarder is an auxiliary braking device that could convert the kinetic energy of the vehicle to the thermal energy of the coolant, and it is used instead of the service brake under non-emergency braking conditions. This paper analyzes the flow distribution based on a mathematical model and analyzes the key factors that could affect the filling ratio and the braking torque of the WM retarder. Computational fluid dynamics（CFD） simulations are conducted to compute the braking torque, and theresults are verified by experiments. It is shown that the filling ratio and the braking torque can be expressed by the mathematical model proposed in this paper. Compared with the Reynolds averaged Navier-Stokes（RANS） turbulent model, the shear stress transport（SST） turbulent model can more accurately simulate the braking torque. Finally, the flow distribution and the flow character in the WM retarders are analyzed.

Design of Constant-Speed Control Method for Water Medium Hydraulic Retarders Based on Neural Network PID

The water medium hydraulic retarder is the latest type of auxiliary braking device and has the characteristics of high power density,large braking torque,and compact structure.During traveling,this device can convert the kinetic energy of a vehicle to the heat energy of the cooling liquid and replace the service brake under non-emergency braking conditions.With regard to the constant-speed function of the water medium hydraulic retarder,this study designs a controller based on the neural network proportional-integral-derivative(PID)algorithm to achieve the steady traveling of the vehicle at constant velocity during a downhill course by controlling the filling ratio of the water medium hydraulic retarder.To validate the algorithm’s effectiveness,the dynamic model of the heavy-duty vehicle in the downhill process and the physical model of the water medium hydraulic retarder are developed.Three operating conditions,including a fixed slope,step-changing slope,and continuous changing slope,are set,and a simulation test is carried out in the MATLAB/Simulink environment.The neural network PID algorithm has better adaptability in controlling than the traditional PID algorithm.Thus,it controls the water medium hydraulic retarder such that the braking requirements of heavy-duty vehicles under a changing slope working condi-tion are satisfied,and it performs constant-speed control when the vehicle travels downhill.Therefore,the proposed control method can significantly improve the safety of road traffic.

Influence of light intensity and water content of medium on total dendrobine of Dendrobium nobile Lindl

Objective: To ascertain the influence of light intensity and water content of medium on the total dendrobine of Dendrobium nobile(D. nobile).Method: The principal component analysis combined with total dendrobine accumulation was conducted to assess the yield and quality of D. nobile in all treatments. In the experiment, D. nobile plants were cultivated in greenhouse as tested materials, and complete test of 9 treatments was adopted with relative light intensities 75.02%, 39.74%,29.93% and relative water content of medium 50%, 65%, 80%. The plants were treated in June and harvested till December. Indexes including agronomic traits, fresh weight and dry weight of stem and leaf, ash content, extract, and dendrobine were measured.Results: Under the light intensity treatments of 75.02% with 50%, 65%, 80% water content of medium, the basal stems of plants were comparatively thicker with more leaves, and the fresh weight and dry weight of stems and leaves were significantly higher than other 6 treatments.Leaves in all treatments contained dendrobine. Under the light intensity treatments of 75.02%with 50%, 65%, 80% water content of medium, dendrobine content of leaves was lower while dendrobine contents of other treatments were more than 0.60%. After comprehensive assessment through the principal component analysis and total dendrobine accumulation, the results showed that 3 treatments with relative light intensity of 75.02% ranked the top three.Conclusions: In brief, the moderately strong light intensity and water content of medium from low to medium can facilitate the growth and yield of D. nobile plants, while light intensity from moderately weak to weak can enhance the dendrobine content.

Numerical Investigations on Hydrodynamic Performance of An Open Comb-Type Breakwater Under Medium Water Levels

The comb-type breakwater(CTB)has been proposed and investigated in recent years due to its advantages in terms of deep-water adaptability,material saving and water exchanges.All existing empirical formulae for CTBs have been so far restricted to the water level above the bottom of the superstructure,which mainly occurs under the high tides or storm tides.However,based on recent engineering applications and experimental observations,the most severe conditions for CTBs are more likely to occur under a medium water level,because impulsive wave pressure may occur due to interactions between waves and the special chamber in CTBs.Meanwhile,during the most of construction and operation periods,the CTBs are mainly working under the medium water levels,i.e.,water levels below the bottom of the superstructure.In this study,the effects of main influence parameters on the horizontal wave force coefficient and wave transmission coefficient for open CTBs(with partially immersed side plates)under medium water levels were investigated based on a 3D numerical wave flume and corresponding empirical formulae were proposed.It is indicated that the location of the side plate related to the main caisson has significant influence on the hydrodynamic performance of CTBs.In engineering applications,the location of the side plate can be designed at b/L≤0.15 or b/L≥0.3(where b is the distance between the side plate and the front face of the main caisson and L is the incident wave length)for efficiently lowering the horizontal wave force and wave transmission.The flow mechanism of impulsive wave force on CTBs was revealed based on synchronous analyses of flow fields and pressure distribution.Through appropriate design of the height of the superstructure according to H/hD≤1.0 or H/hD≥1.5(where H is the incident wave height and hD is the distance between the still water level and the bottom of the superstructure),the likely impulsive wave pressure on the side plate can also be diminished.

Comparison of Absorbed Dose to Medium and Absorbed Dose to Water for Spine IMRT Plans Using a Commercial Monte Carlo Treatment Planning System

Dose in radiation therapy has been reported as the water-equivalent dose using conventional dose calculation algorithms. The Monte Carlo (MC) algorithm employs characterization of human tissues by elemental composition and mass density. It enables more accurate dose calculation for radiation therapy treatment planning and typically reports absorbed dose to medium. Whether one should use dose to medium or tissue (Dm) in place of dose to water (Dw) for MC treatment planning remains the subject of debate. The aim of the current study is to evaluate the differences between dose-volume indices for Dm and Dw MC-calculated IMRT plans. Thirty-seven spine patients were selected for this study. The IMRT optimization and MC calculations were performed using the iPlan RT DoseTM ver 4.1.2 (Brainlab, Munich, Germany) treatment planning system (TPS) with an X-ray Voxel Monte Carlo (XVMC) dose calculation engine. Dw and Dm results for target and critical structures were evaluated using the dose-volume-based indices. Systematic differences between dose-volume indices computed with Dw and Dm were up to 5.2%, 4.2%, and 4.5% for D2, D50 and D98 indices of the clinical target volume (CTV), respectively and up to 1% for the critical structure dose indices. Our study demonstrates that employing Dm in place of Dw in MC-calculated IMRT treatment plans introduces a significant systematic difference in target DVHs. We recommend that for diffused target structures (such as spine tumors), dose to water is a better quantity for dose prescription in photon beam treatment planning using existing MC TPS. While for critical structures, it would be reasonable to report Dm always. However in future with the availability of finer spatial resolution, Dm will be the most suitable variable for both target and critical structures’ dose prescription and reporting in MC treatment planning.

Comparison of Gamma Pass Rate between the Dose-to-Water and Dose-to-Medium Reporting Modes for Patient-Specific QA Using a Helical Diode Array Dosimeter with a Fixed Phantom Density

Introduction: To compare the measured dose distributions to calculated ones in dose-to-water (Dw) and dose-to-medium (Dm) reporting modes for simple plans and patient-specific intensity modulated radiation therapy (IMRT) and volumetric modulated arc therapy (VMAT) plans using ArcCHECK with a fixed phantom density. Methods: The recommended density value of 1.18 g/cm3 for Acuros XB and X-ray voxel Monte Carlo was assigned to ArcCHECK on CT images. A total of 45 simple plans, including a 1-field plan, a 3-field plan, a 4-field plan, a half-arc plan from 270° to 90°, and a full-arc plan, were assessed. Subsequently, the patient-specific 96 IMRT and VMAT plans were evaluated. Gamma analysis with a 3% normalized global dose error and a 3 mm distance-to-agreement criteria (γ3%G/3mm) was performed in the Dw and Dm. The change in γ3%G/3mm between Dw and Dm were statistically analyzed using JMPPro11 software. Results: The median values of γ3%G/3mm for all simple plans for Dw and Dm were 98.1% (range, 75.2% - 100%) and 95.5% (range, 23.7% - 100%), respectively (p 0.01). In the patient-specific IMRT and VMAT plans, the median values of γ3%G/3mm for Dw and Dm were 98.6% (range, 90.1% - 100%) and 90.5% (range, 38.5% - 97.2%), respectively (p 0.01). Conclusion: Our results showed that the calculated and measured dose distributions were in good agreement for Dw, but were not for Dm. From the viewpoint of the rationale of dosimetry, Dw shows better agreement with measured dose distribution when using the fixedphantom density recommended by the vendor.

Porous Haydite Used as Waste Water Filter Medium for Lake Sludge

Porous haydite used as waste filter medium was prepared by dreging lake sludge to help solve the treatment problem of sludge and realize its reclamation. Several calcination regimes were considered and their effects on the pore structure and the properties such as the strength, the density, the filtering ability and the phosphate absorption ability of the haydite were investigated, For the mixture of 60% lake sludge and 40% fly ash in this experiment, the calcination regime with a pre-caleination period at about 600℃, a temperature keeping period at 1 200 ℃ and a moderate cooling rate are recommended to prepare haydite with reasonable pore structure and good performances for its usage as the waste water filter media.

Optimization design of wide face water slots for medium-thick slab casting mold

A three-dimensional finite-element model has been established to investigate the thermal behavior of the medium-thick slab copper casting mold with different cooling water slot designs. The mold wall temperatures measured using thermocouples buried in different positions of the mold with the original designed cooling system were analyzed to determine the corresponding heat flux profile. This profile was then used for simulation to predict the temperature distribution and the thermal stress distribution of the molds. The predicted temperatures during operation matched the plant measurements. The results showed that the maximum temperature, about 635 K in the wide hot surface, was found about 60 mm below the meniscus and 226 mm from the center of the mold. For the mold with the type I modified design, there was an insignificant decrease in temperature of about 5 K, and for the mold with the type II modified design, the maximum temperature was decreased by about 15 K and the temperature of the hot surface was distributed more uniformly along the length of the mold. The corresponding maximum thermal stress at the hot surface of the mold was reduced from 408 MPa to 386 MPa with the type II modified design. The results indicated that the modified design II is beneficial to the increase of mold life and the quality of casting slabs.

水介质中DASA的研究进展

从分子笼封装、分子结构修饰以及超分子自组装3个方面综述了水介质中实现DASA分子光开关的研究进展,为其开发和应用提供参考。

黄河内蒙段开河期细菌群落结构特征研究

为探索黄河内蒙段开河初期水-土介质中细菌群落组成情况及生态网络结构,于2021年4月中旬进行取样,共获得黄河水样6个和土样4个.利用16S rRNA基因高通量测序方法对水、土样品进行测定,并从菌门及菌属水平对二者的细菌群落组成进行了分析.结果显示:河漫滩土样细菌群落结构的分布较水样更为分散,且土样中细菌群落丰富度、均匀度及多样性均高于水体,二者多样性存在显著的组间差异;在菌门水平上,变形菌门、放线菌门和酸杆菌门等是构成水-土样品的优势细菌门类,其中变形菌门在河水中相对丰度均值约为36.57%,在土样中则下降到25.39%,而酸杆菌门主要存在土样中,相对丰度约为14.17%;在菌属水平上, hgcI_clade(6.19%~12.75%)、CL500-29_marine_group(2.97%~5.05%)和Acinetobacter(0.74%~12.24%)是水体中的优势菌属,而norank_f__norank_o__norank_c__KD4-96(1.95%~4.91%)、 norank_f__norank_o__Vicinamibacterales(2.35%~4.67%)和norank_f__Gemmatimonadaceae (2.20%~4.73%)是土样中的优势菌属;不同菌属对水-土细菌群落结构的响应并不一致,其中分别归属于酸杆菌门和芽单胞菌门的norank_f__norank_o__Vicinamibacterales及norank_f__Gemmatimonadaceae等是联系水-土细菌群落的主要菌属,而归属于放线菌门的hgcI_clade和CL500-29_marine_group等是造成水、土优势菌门存在差异的主要菌属;虽然土样较水样拥有更大的生态网络结构,且Delftia、Candidatus_Methylopumilus、Arthrobacter和Rb41等是维持黄河内蒙段水、土介质生态网络结构的关键菌属,但相较于土样网络结构,水体网络结构中不同模块关键菌门及菌属间的生态功能较为一致.

Comparative Study of Hydrogen and Carbon Isotopic Composition of Gases Generated from the Pyrolysis of a Peat under Saltwater and Freshwater Conditions

To understand the influence of the diagenetic water medium on the isotopic compositions of thermogenic coalbed gas, both hydrous and anhydrous closed-system pyrolyses were performed at temperatures of 250°C to 650°C on an herbaceous marsh peat. Compared to the results of anhydrous pyrolysis, the hydrocarbon gases generated from hydrous pyrolyses have very different hydrogen isotopic compositions. However, the carbon isotopic compositions of the hydrocarbon gases became only slightly heavier in hydrous pyrolysis, compared to that from anhydrous pyrolysis. With the progress of thermal evolution from peat to a more advanced thermal maturity of vitrinite reflectance values（Ro） of 5.5% during the pyrolysis, the difference in the average δD value increased from 52‰ to 64‰ between the hydrous pyrolysis with saltwater and anhydrous pyrolysis and increased from 18‰ to 29‰ between the hydrous pyrolysis with freshwater and anhydrous pyrolysis, respectively. The difference in the average δ^（13）C value was only 1‰–2‰ between the hydrous and anhydrous pyrolysis. The relationships between the δD values of the generated hydrocarbon gases and Ro values as well as among δD values of the hydrocarbon gas species are established. The close relationships among these parameters suggest that the water medium had a significant effect on the hydrogen isotopic composition and a minimal effect on the carbon isotopic composition of the hydrocarbon gases. The results of these pyrolyses may provide information for the understanding of the genesis of coalbed gas from herbaceous marsh material with the participation of different diagenetic water media.

泰山北翼岩溶含水介质分布及地下水循环规律研究

为了深入认识济南岩溶泉水及地热水循环过程,本文以泰山北翼碳酸盐岩含水介质空间分布特征为研究出发点,分析其埋藏条件和连续性特征,并利用数理统计、空间插值、Piper三线图、概念模型等方法,结合水动力场、水化学场、水温度场和水年龄场“四场”分析,揭示区域地下水循环规律。结果表明:地表分水岭与齐广断裂、禹王山断裂、聊考断裂等深大断裂控制了泰山北翼地区岩溶含水介质空间展布,大致呈现由南向北埋藏深度逐渐增大的变化趋势,受马山断裂、东坞断裂、文祖断裂等次级断裂影响岩溶含水介质上下盘有不同错动,但东西展布仍具有较好连续性;区域地下水循环过程极其复杂,泰山岩群、寒武纪及奥陶纪各类含水岩组通过排泄-渗漏、断裂垂向径流、水平地下径流等形式发生水流交汇,并在山前局部地区与第四纪松散孔隙水产生水量交换,最终通过泉或人工开采形式排泄。区域地下水流具有统一的“四场”,并且呈现明显的水平与垂向分带特征,大致沿东阿断裂及其延长线—吴家堡—华山—章丘区—淄博磁村一线划分冷泉与地热水的分界线,以600 m、1000 m划分出浅、中、深循环深度分界线;冷泉以浅循环为主,中、深循环为辅,地下水矿化度、温度、年龄偏低,而地热水以中、深循环为主,浅循环为辅,地下水矿化度、温度、年龄偏大。不同含水介质水流具有一定内在关联,构成一个完整的岩溶水系统。

多介质过滤处理农村灰水影响因素实验研究

为寻求多介质过滤技术处理农村灰水的可行性及最佳运行条件,以内蒙古呼和浩特市某村生活灰水为研究对象,选择玉米茎、陶粒、活性炭作为过滤介质构建多介质过滤系统处理农村灰水,研究滤速、介质配比、进水LAS、COD、SS浓度和温度等影响因素对多介质过滤系统处理效果的影响。结果表明多介质过滤处理农村灰水的最佳滤速为0.26 m/h;介质配比玉米茎∶陶粒∶活性炭为1.5∶2∶0.5;多介质过滤系统处理灰水中LAS、COD、SS的浓度限值为30、300、300 mg/L;温度为2℃时,系统出水仍满足农田灌溉水质标准(GB 5084-2021)。研究表明,多介质过滤技术对农村灰水有较好的处理效果,降低农村灰水处理设备建设和运行成本,有利于农村污水就地回用资源化利用。

削痂清创与水刀清创治疗中面积深Ⅱ度烧伤创面的临床效果比较

目的:比较中面积深Ⅱ度烧伤患者应用削痂清创与水刀清创治疗的临床效果。方法:选取2021年1月—2023年3月吉安市中心人民医院收治的中面积深Ⅱ度烧伤患者,共82例,按照随机数字表法分成水刀清创组(41例)与削痂清创组(41例)。水刀清创组采用水刀清创治疗,削痂清创组采用削痂清创治疗。比较两组临床指标、预后情况、创面愈合质量、炎症因子及疼痛介质。结果:水刀清创组每1%面积清创时间、创面愈合时间、住院时间均较削痂清创组短,创面细菌菌落数更少,差异均有统计学意义(P<0.05)。相较削痂清创组,水刀清创组二次清创率更低,差异有统计学意义(P<0.05)。相较削痂清创组,水刀清创组改良温哥华瘢痕评估量表(mVSS)评分均更低,差异均有统计学意义(P<0.05)。治疗后,两组降钙素原(PCT)、C反应蛋白(CRP)水平均较治疗前下降,相较削痂清创组,水刀清创组均更低,差异均有统计学意义(P<0.05)。治疗后,两组5-羟色胺(5-HT)、神经肽Y(NPY)水平均较治疗前下降,相较削痂清创组,水刀清创组均更低,差异均有统计学意义(P<0.05)。结论:与削痂清创比较,中面积深Ⅱ度烧伤患者应用水刀治疗的效果更好,能够改善临床指标及预后情况,促进创面良好愈合,调节炎症因子、疼痛介质水平。

双层多孔板结构相变发汗冷却的数值模拟研究

为了提高相变发汗冷却的冷却性能,提出不同孔隙率组合的双层多孔板结构设计代替传统的单层多孔板结构.以液态水作为冷却剂,使用修正后的局部热非平衡两相混合流模型,数值研究了不同孔隙率组合的多孔板内流-固耦合传热和冷却剂流动输运特性.数值模拟结果表明存在可以降低结构表面温度的双层多孔板设计,并且在冷却剂流量较大、液体水相变发生在上层多孔板内时,该新型结构相较于传统结构的表面温度降低更为明显.与此同时,冷却剂的注射压力被重点关注.由于水蒸气的运动黏度远高于液体水,研究中发现当冷却剂相变发生在多孔板内时,冷却剂的注射压力主要取决于水蒸气所集中的上层多孔板孔隙率.因此基于多孔介质内的渗流特性,采用孔隙率较大的上层多孔板有助于降低结构内的水蒸气压力,从而实现多孔板板底冷却剂注射压力的降低,在某一孔隙率组合中冷却剂注射压力的最大降幅可以达到65%.如果采用相反的孔隙率设计,即下层多孔板的孔隙率较大,虽然也可以在一定程度上降低表面温度,但是注射压力将会数倍增加,不利于相变发汗冷却的实际应用.

乌梁素海重金属在冰-水介质中迁移的微观机理

为探究乌梁素海重金属在冰-水介质中迁移的微观机理,对冰封期乌梁素海不同重金属(Fe、As、Cr、Cu、Zn、Mn、Cd、Hg、Pb)水样进行室内单向结冰模拟,总结重金属在冰体和冰下水体中的分布特征,并根据第一性原理进行结合能计算,从结合能的角度分析其微观机理。结果表明:各重金属与水体的结合能均大于与冰体的,表明重金属在水体中比在冰体中更稳定,驱使重金属从冰体向冰下水体迁移。

海上重力储能技术研究进展及展望

该文从储能介质角度出发,分别介绍国内外海上重力储能技术研究进展和工程实例,总结并分析其优势与不足。目前,国内外已提出诸多可行性方案,但大部分方案仍处于初步研究阶段。借此对海上重力储能作出前景展望,以期为相关人员提供参考和借鉴。