Water Environmental Impact Assessment and Analysis of Foshan Brewery Project

In recent years, the beer industry is a biological food industry that consumes a lot of water, and it has developed rapidly in China. The sewage discharged from the mass production of beer poses a huge threat to the environment. In order to evaluate and better solve the possible environmental impacts of beer treatment engineering projects, a brewery project in Foshan City is taken as an example to investigate the water pollution generation links of the engineering process including surface water and groundwater. According to the relevant technical methods and standards, water pollution factors are screened, and concentration and discharge are monitored. Through comprehensive analysis, predictive evaluation is obtained. It is confirmed that the project meets the requirements of national laws and regulations and environmental protection standards.

Effect of movability of water on the low-velocity pre-Darcy flow in clay soil

Water seepage in soil is a fundamental problem involving various scientific and engineering fields.According to the literature,low-velocity water seepage in low-permeability porous media,such as clay,does not follow Darcy's law,also known as pre-Darcy flow.The formation of immovable water due to water adsorption on the pore wall is believed to be responsible for the formation of pre-Darcy flow.However,this view lacks direct solid evidence.To investigate the pre-Darcy water flow in clay,head permeability experiments are conducted on six clay samples with different densities.The results indicate that water seepage in clay at low hydraulic gradients does not follow Darcy's law.A clear nonlinear relationship between flow velocity and hydraulic gradient is observed.Water flow in clay can be divided into the pre-Darcy flow and Darcy flow regions by the critical hydraulic gradient,which is 10-12 for the Albic soil with dry density between 1.3 g/cm^(3)and 1.8 g/cm^(3).According to the disjoining pressure theory,immovable water due to water adsorption on the pore wall is the primary reason for water flow deviating from Darcy's law in clay.The results indicate that the percentage of movable water ranges from 39.7%to 59.3%for the six samples at a hydraulic gradient of 1.As the hydraulic gradient increases,the percentage of moveable water also increases.Additionally,there is a strong correlation between the percentage of movable water and the variation in hydraulic conductivity with the hydraulic gradient.Furthermore,a quantitative relationship between the percentage of movable water and the hydraulic conductivity has been established.The results of this study suggest that water adsorption on the pore wall not only affects the water movability,but is also closely related to the pre-Darcy flow phenomenon in clay.

Spectrofluorimetric Analysis of the Fungicide Carbendazim and Its Metabolite 2-Aminobenzimidazole in Natural Water

A spectrofluorimetric method for the direct analysis of carbendazim [methyl 2-benzimidazole carbamate (MBC)] fungicide and its metabolite 2-aminobenzimidazole (2-AB) in natural waters is described. Very low limit of detection (LOD) and limit of quantification (LOQ) values of 0.002 - 0.06 ng/mL and 0.006 - 0.2 ng/mL, respectively, were determined by spectrofluorimetric method with small relative standard deviation (RSD) values < 1%. This spectrofluorimetric method was applied to the determination of MBC and 2-AB residues in natural waters, with satisfactory recovery values of (88.5% - 119.2%).

Hydrological behaviour and water balance analysis for Xitiaoxi catchment of Taihu Basin

With the rapid social and economic development of the Taihu region, Taihu Lake now faces an increasingly severe eutrophication problem. Pollution from surrounding catchments contributes greatly to the eutrophication of water bodies in the region. Investigation of surface flow and associated mass transport for the Xitiaoxi catchment is of a significant degree of importance as the Xitiaoxi catchment is one of the major catchments within the Taihu region. A SWAT-based distributed hydrological model was established for the Xitiaoxi catchment. The model was calibrated and verified using hydrometeorological data from 1988 to 2001. The results indicate that the modeled daily and annual stream flow match the observed data both in the calibration period and the verification period, with a linear regression coefficient R2 and a coefficient e for modeled daily stream flow greater than 0.8 at Hengtangcun and Fanjiacun gauge stations. The results show that the runoff process in the Xitiaoxi catchment is affected both by rainfall and human activities （e.g., reservoirs and polder areas）. Moreover, the human activities weaken flood peaks more noticeably during rainstorms. The Water balance analysis reveals the percentages of precipitation made up by surface flow, evapotranspiration, groundwater recharge＇ and the change of soil storage, all of which are considered useful to the further understanding of the hydrological processes in the Xitiaoxi catchment. This study provides a good base for further studies in mass transport modeling and comparison of modeling results from similar hydrological models.

Research of Water Quality Analysis,Treatment and Reuse Technology for Rainwater on the North University Campus

The pollution situation of different underlying surface and the change rule of each water quality index were researched,on the basis of rainwater quality monitoring by different approaches in a university campus. The results showed that due to some factors,such as the underlying surface material pollution,road materials,road surface pollution condition and surrounding atmospheric environment quality,the pollution of different underlying surface rainwater would be different. Main pollutants of rainwater runoff in the city campus area were such as COD,SS,NH;-N,TP,etc. Ultimately,along with the increase of accumulated rainfall,the pollutants tended to gradually decrease. The road rain pollution was more serious than roof runoff pollution and the early rain pollution was serious,but the late rain water quality was much better. According to the rainwater conditions,subsequent rainwater recycling technology and processing technology were determined as a way to alleviate the problem of water shortage and water pollution.

Provenance analysis of surface sediments in the Holocene mud area of the southern coastal waters off Shandong Peninsula,China

The sedimentary record of mud areas is an important carrier of information on the Holocene evolution of marine environments. Based on fine interpretations of the shallow stratigraphic section data, a small mud deposit area has been found in the southern coastal waters off Shandong Peninsula. This mud area is mainly distributed in coastal waters north of Laoshantou to the vicinity of Rushan Estuary. Overall, it is parallel to the coastline and spreads in a banded pattern, gradually thinning from offshore to the sea. The isopach map of depth distribution is parallel with the shoreline, and the depocenter lies in coastal waters of the Aoshan Bay where the maximum thickness is up to 22.5 m. Accelerator mass spectrometry（AMS） ^（14）C dating shows that the mud area was formed in the Holocene. The test data of surface sediments from the mud area, including particle size, mineral characteristics, and rare earth element contents, are used in comparisons with the composition of materials from the major surrounding medium and small rivers flowing into the sea and the Huanghe（Yellow） River. In this paper, the sedimentary characteristics and provenance of the mud deposit area are discussed. The results show that the formation of this mud area resulted from the joint action of the Huanghe River and surrounding rivers flowing into the sea.

Chemical Analysis of Water and the Resource of Br,K Prospects of Oilfield Brines from Ordovician and Carboniferous in Tarim,China

China is lack of bromine and potassium seriously.Oilfield brines is the headline goal of bromine and potassium resources exploration.Applicants grab 24oilfield brines samples from various wells of Ordovician

Analysis of Water and Soil Quality Characteristics in Turpan City

[ Objective] The study aimed to analyze water and soil quality characteristics in Turpan City. [ Method] According to Drinking Water Hy- gienic Standards （GB5749-2006） and Standards for Irrigation Water Quality （GB5084-2005）, five kinds of water samples collected from a karez, motor-pumped well, canal, village well and Aydingkol Lake in Turpan City as well as two types of soil samples irrigated by the karez and motor- pumped well water were analyzed in quality. [ Remit] Chloride and sulfate content in the village well and Aydingkol Lake water were higher than their limits in Dnnking Water Hygienic Standards, as well as sulfate content in the motor-pumped well and canal water. However, chloride and sul- fate content in the karez water did not exceed their limits. The soil irrigated by the karez water was salinized slightly, and organic matter content was higher; the soil irrigated by the motor-pumped well water was salinized seriously, and organic matter content was lower. [ Conclusion] The karez water is more applicable to farmland irrigation.

Groundwater Quality Analysis and Vulnerability Assessment in Longdong Area

Groundwater is important drinking water source in Longdong area. In recent years,as gradual expanding of industrial and agricultural production scales,seen from change trend of water quality,major impact factors of groundwater in the zone were ammonia nitrogen,COD,sulfate and total dissolved solid. By using specific thought of parameter system method,vulnerability assessment factor system of groundwater and meter point system calculation model in the zone were established. Via calculation and analysis,vulnerability distribution of groundwater in the zone was obtained. According to vulnerability index（ higher,moderate and lower）,zone dividing was conducted,and the areas were respectively 623. 25,4 005. 00 and 6 621. 75 km2,which respectively accounted for 5.54%,35. 60% and 58. 86%. The evaluation provided research basis for prevention,control and protection of groundwater environment in Longdong area.

Preliminary analysis of distribution and variation of perennialmonthly mean water masses in the Bohai Sea,the Huanghai Sea and the East China Sea

On the basis of perennial monthly mean temperature and salinity data, the classification of monthly water masses at the surface and the bottom in the Bohai Sea, the Huanghai Sea and the East China Sea, has been made by using the method of fuzzy cluster from the modified characteristic of water masses in the shallow water area. In this paper, the basic features, growth and decline patterns of water masses in relation to fishing grounds in the whole shelves of the Bohai Sea, the Huanghai Sea and the East China Sea are discussed with emphasis.

APPLICATION OF REMOTE SENSING IN THE ANALYSIS OF WATER ENVIRONMENT IN ZHUJIANG RIVER ESTUARY

1. PREFACE Lingdingyang is a trumpet estuary. It accepts the runoff of the Dongjiang River, the Beijiang River, the Zhengjiang River and the Liusihe River. It also accepts a part of the runoff of the Xijiang River. Its mean year runoff is 1.742×10" M^3. In resent ten years, industry and agriculture are developing rapidly in Guangzhou City, Dongguan City, Zhongshan City, Shunde County, Panyu County. Lingdingyang’s pollution is increesing. Water quality of lingdingyang is steadily deteriorated. In order to investigate the situation of water environment of Lingdingyang, we study its static environmental capacity of nitrogen and phosphorus. LANDSAT imageries are used in the study. The concentrations of nitrogen and phosphorous is detected by convention method.

Determination of Ultratrace Amounts of Copper(Ⅱ) in Water Samples by Electrothermal Atomic Absorption Spectrometry After Cloud Point Extraction

A novel approach was developed for the determination of ultratrace amounts of copper in water samples by using electrothermal atomic absorption spectrometry （ETAAS） after cloud point extraction （ CPE ）. 1-（ 2-Pyridylazo ） -2- naphthol was used as the chelating reagent and Triton X-114 as the mieellar-forming surfactant. CPE was conducted in a pH 8. 0 medium at 40 ℃ for 10 rain. After the separation of the phases by contrifugafion, the surfactant-rieh phase was diluted with 1 mL of a methanol solution of 0. 1 mol/L HNO3. Then 20μL of the diluted surfactant-rieh phase was injected into the graphite furnace for atomization in the absence of any matrix modifier. Various experimental conditions that affect the extraction and atomization processes were optimized. A detection limit of 5 ng/L was obtained after preconeentration. The linear dynamic range of the copper mass concentration was found to be 0-2.0 ng/mL, and the relative standard deviation was found to be less than 3. 1% for a sample containing 1.0 ng/mL Cu （ Ⅱ ）. This developed method was successfully applied to the determination of uhratraee amounts of Cu in drinking water, tap water, and seawater samples.

Simultaneous Determination of Ten Endocrine Hormone Disrupters in Water Using SPE/LC-(ESI)MS-MS

The aim of this study was developed and validated an analytical method based on liquid chromatography and tandem mass spectrometry after solid phase extraction to monitorizing ten endocrine hormone disrupters in Lisbon drinking water system. Natural and synthetic hormones (17-β-estradiol, ethinylestradiol, estriol, estrone, progesterone, mestranol and diethylstilbestrol) and some industrial products (4-n-nonylphenol, 4-tert-octylphenol and bisphenol A) were studied. Mass spectrometer detection parameters were optimized, such as the best conditions for the precursor ion formation, namely cone voltage, when applying negative and positive electrospray ionization, and also collision energy for MRM1 and MRM2 transitions. The best conditions of the solid phase extraction (SPE) using Waters Oasis HLB (6 mL, 200 mg) and Isolute C18 (EC) (6 ml, 1000 mg) were also optimized. The method was validated through the application of several statistical tests and the uncertainty estimation of the analytical assay. This method showed a very good linear range for all the studied analytes with determination coefficients (r2) between 0.9962 and 0.9999 and coefficients of variation lower than 4%. There were no significant differences between recoveries obtained with the studied matrices, like groundwater, surface water and water for human consumption. In these matrices, the recovery values varied between 32 and 95%. The limits of method detection were between 0.28 and 22 ng/L. The validated method was applied for the analysis of water samples from the EPAL (Empresa Portuguesa das águas Livres, S.A.) water supply system including tap water, spring water, groundwater, and river water. Some target compounds (bisphenol A, progesterone, 4-tert-octylphenol, and 4-n-nonylphenol) were found in trace amounts in analysed waters.

Evaluation of Physico-Chemical Parameters as Veritable Indicators of Faecal Escherichia coli Contamination of Surface Waters

There is need for alternate quick-search of pathogens’distribution in community water sources,instead of the cumbersome“Escherichia coli detection.”Physical and chemical(physico-chemical)parameters were evaluated as veritable indicators of faecal Escherichia coli contamination of surface waters,using Adada River in Nigeria as case-study.Thirty-two(32)physico-chemical parameters were analyzed in the river(at specified geographical coordinates)for their quality and quantity and connected(using Pearson’s Correlation Analysis)with the distribution of the river’s isolated Escherichia coli.The 32 physico-chemical parameters consist of 11 cations,6 anions,7 physical properties,3 properties relating to oxygen and 5 properties relating to anions/cations.Physico-chemical indices from the analysis,revealed very significant positive correlation relationship of Escherichia coli with the presence of Mg(Magnesium)and K(Potassium)in the dry and rainy season,respectively.E.coli affinity tests(Kirby-Bauer Disc Diffusion)for these metals were also positive.Mg and K also showed significant positive Pearson’s possible paired correlation relationship.From this evaluation,potential index analysis indicated that Mg and K could serve as markers for the faecal bacteria indicators,and possible index for future monitoring of the potability of such surface water.The method is straight forward,cost effective,less cumbersome than other currently existing approaches.

Study on the Impact of Elements in Water on the Diversity of Water Mites(Acari,Hydrachnidia)Species

In this study the distribution and relationships of element levels in water and water mite species (Acari, Hydrachnidia) selected as model organisms have been examined in two different lakes. Water samples from Eber and Karamik Lakes were analyzed with ICP (ICP-OES Instrument Spectro Genesis Fee, Germany) equipment to determine the element levels in the water. That impact level of these elements on the distribution of species was discussed. Change in the lake water composition was not a significantly determining factor in the number of species and diversities of water mites. However, eutrophication was observed to be a determining factor on the distribution of species.

Determination of Mercuric Ion in Water Samples with a LED Exciting and CCD Based Portable Spectrofluorimeter

The fluorescent characteristics of a fluorimetric chemosensor for mercuric ion, Hg2+, employing a synthesized Rhodamine 6G derivative, have been analyzed. For that, a portable spectrofluorimeter composed of a 515 nm LED as excitation source, two fiber-optics and a CCD camera as detector, has been used, intended for “in situ” analysis. A highly selective Rhodamine based probe for Hg2+, that is water soluble and gives a positive response upon analyte binding, is reported. The reagent is bearing a monothiospirolactone group in a Rhodamine 6G architecture and the thiol atom served for the direct attack of thiophilic Hg2+. The fluorescence enhancement is attributed to the spirolactone ring opening and the coordination of two sulphur atoms to Hg2+ giving a 2:1 reagent: Hg2+ stoichiometry complex.

Determination of Iron in Water Solution by Time-Resolved Femtosecond Laser-Induced Breakdown Spectroscopy

The influence of the energy of femtosecond laser pulses on the intensity of Fe I （371.99 nm） emission line and the continuous spectrum of the plasma generated on the surface of Fe^3＋ water solution by a Ti： sapphire laser radiation with pulse duration 〈45 fs and energies up to 7 mJ is determined. A calibration curve was obtained for Fe3＋ concentration range from 0.5 g/L to the limit of detection in water solution, and its saturation was detected for concentrations above 0.25 g/L, which is ascribed to self-absorption. The 3σ- limit of detection obtained for Fe in water solution is 2.6 mg/L in the case of 7 mJ laser pulse energy. It is found that an increase of laser pulse energy insignificantly affects on LOD in the time-resolved LIBS and leads to a slight improvement of the limit of detection.